JP2016505484A - 液状化合物および水素貯蔵体としてのその使用方法 - Google Patents
液状化合物および水素貯蔵体としてのその使用方法 Download PDFInfo
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 70
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 70
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 239000007788 liquid Substances 0.000 title claims abstract description 26
- 150000001875 compounds Chemical class 0.000 title claims abstract description 19
- 238000003860 storage Methods 0.000 title claims description 12
- 239000000203 mixture Substances 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 12
- 230000003197 catalytic effect Effects 0.000 claims abstract description 8
- 238000012546 transfer Methods 0.000 claims abstract description 8
- 125000003118 aryl group Chemical group 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 239000000446 fuel Substances 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 3
- 239000011949 solid catalyst Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 12
- 239000000463 material Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000004146 energy storage Methods 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 4
- 150000003613 toluenes Chemical class 0.000 description 4
- PKQYSCBUFZOAPE-UHFFFAOYSA-N 1,2-dibenzyl-3-methylbenzene Chemical compound C=1C=CC=CC=1CC=1C(C)=CC=CC=1CC1=CC=CC=C1 PKQYSCBUFZOAPE-UHFFFAOYSA-N 0.000 description 3
- FUUPYXUBNPJSOA-UHFFFAOYSA-N 9-ethyl-1,2,3,4,4a,4b,5,6,7,8,8a,9a-dodecahydrocarbazole Chemical compound C12CCCCC2N(CC)C2C1CCCC2 FUUPYXUBNPJSOA-UHFFFAOYSA-N 0.000 description 3
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 3
- 230000003578 releasing effect Effects 0.000 description 3
- 125000003944 tolyl group Chemical group 0.000 description 3
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical compound C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- GDPISEKNRFFKMM-UHFFFAOYSA-N 1,3-diphenylpropan-2-ylbenzene Chemical class C=1C=CC=CC=1CC(C=1C=CC=CC=1)CC1=CC=CC=C1 GDPISEKNRFFKMM-UHFFFAOYSA-N 0.000 description 1
- PLAZXGNBGZYJSA-UHFFFAOYSA-N 9-ethylcarbazole Chemical compound C1=CC=C2N(CC)C3=CC=CC=C3C2=C1 PLAZXGNBGZYJSA-UHFFFAOYSA-N 0.000 description 1
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 231100000584 environmental toxicity Toxicity 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002470 thermal conductor Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0015—Organic compounds; Solutions thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K15/00—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
- B60K15/03—Fuel tanks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K15/00—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
- B60K15/03—Fuel tanks
- B60K15/03006—Gas tanks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K15/00—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
- B60K15/03—Fuel tanks
- B60K2015/03309—Tanks specially adapted for particular fuels
- B60K2015/03315—Tanks specially adapted for particular fuels for hydrogen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
- C01B2203/1058—Nickel catalysts
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
- C01B2203/107—Platinum catalysts
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- C—CHEMISTRY; METALLURGY
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/84—Energy production
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
Abstract
Description
Claims (6)
- 炭素および水素の元素だけから構成されており、かつ幾つかの公知の組成において熱伝導液として用い得る合成物質混合体を構成している2種以上の化合物から成る室温で液状の混合物において、少なくとも2つの縮合されておらずπ共役でない芳香族単位を有する少なくとも1種の化合物を含有しており、混合物に水素を結合または混合物から水素を遊離させるための触媒的方法において使用されることを特徴とする混合物。
- 請求項1に記載の混合物を使用して水素を消費体に少なくとも配分に応じて供給するための方法において、反応器が、水素を担持する混合物のための第1の貯蔵タンクから流入管を介して混合物を供給され、反応器内で高い温度および低い圧力で脱水素化された混合物が流出管を介して反応器から第2の貯蔵タンクに導出され、その際、反応器が接続管を介して消費体に水素を供給することを特徴とする方法。
- 消費体が内燃機関または少なくとも1つの燃料電池であることを特徴とする、請求項2に記載の方法。
- 消費体が自動車のエネルギー供給に寄与することを特徴とする、請求項2または3に記載の方法。
- 混合物が反応器内で金属含有触媒と接触し、水素を結合または遊離させ、その際、水素充填のために使用される金属含有触媒と水素放出のために使用される金属含有触媒が同じまたは異なる固体触媒であり、固体触媒が、パラジウム、ニッケル、白金、イリジウム、ルテニウム、コバルト、ロジウム、銅、金、レニウム、または鉄という金属の1種または複数を多孔質で非極性の担体上で細かく分散された形態で含有することを特徴とする、請求項2〜4のいずれか一つに記載の方法。
- 反応器内で、水素を充填された混合物から、高い温度および低い圧力での触媒的脱水素により水素が遊離されることを特徴とする、請求項2〜5のいずれか一つに記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012221809.2 | 2012-11-28 | ||
DE102012221809.2A DE102012221809A1 (de) | 2012-11-28 | 2012-11-28 | Flüssige Verbindungen und Verfahren zu deren Verwendung als Wasserstoffspeicher |
PCT/EP2013/072156 WO2014082801A1 (de) | 2012-11-28 | 2013-10-23 | Flüssige verbindungen und verfahren zu deren verwendung als wasserstoffspeicher |
Publications (2)
Publication Number | Publication Date |
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JP2016505484A true JP2016505484A (ja) | 2016-02-25 |
JP6280559B2 JP6280559B2 (ja) | 2018-02-14 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2015544397A Active JP6280559B2 (ja) | 2012-11-28 | 2013-10-23 | 液状化合物および水素貯蔵体としてのその使用方法 |
Country Status (11)
Country | Link |
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US (1) | US10450194B2 (ja) |
EP (1) | EP2925669B1 (ja) |
JP (1) | JP6280559B2 (ja) |
KR (2) | KR101954305B1 (ja) |
CN (1) | CN104812698B (ja) |
AU (1) | AU2013351445B2 (ja) |
BR (1) | BR112015012183B1 (ja) |
CA (1) | CA2892228C (ja) |
DE (1) | DE102012221809A1 (ja) |
ES (1) | ES2696080T3 (ja) |
WO (1) | WO2014082801A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2019532455A (ja) * | 2016-08-17 | 2019-11-07 | ペズ,ギド,ピー | 電気化学的エネルギー変換及び貯蔵のためのシステム及び方法 |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102014201332A1 (de) * | 2014-01-24 | 2015-07-30 | Hydrogenious Technologies Gmbh | System und Verfahren zur stofflichen Nutzung von Wasserstoff |
US9879828B2 (en) | 2014-09-03 | 2018-01-30 | Hydrogenious Technologies Gmbh | Arrangement and method for operating hydrogen filling stations |
DE102014226282A1 (de) | 2014-12-17 | 2016-06-23 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Reaktor zur Dehydrierung von flüssigen Wasserstoffträgermaterialien |
DE102015223997A1 (de) * | 2015-12-02 | 2017-06-08 | Siemens Aktiengesellschaft | Verfahren und Vorrichtung zur Speicherung von Wasserstoff |
DE102016004684A1 (de) * | 2016-04-19 | 2017-10-19 | Linde Aktiengesellschaft | Kraftstoff für Luft- und Raumfahrtfahrzeuge |
KR101862012B1 (ko) | 2016-09-09 | 2018-05-30 | 한국화학연구원 | 피리딘계 수소저장 물질을 활용한 수소 저장 및 방출 시스템 |
KR101845515B1 (ko) | 2016-09-30 | 2018-04-04 | 한국과학기술연구원 | 액상 수소저장물질 및 이를 이용한 수소 저장 방법 |
EP3378848B1 (de) | 2017-03-23 | 2021-11-24 | Karlsruher Institut für Technologie | Hydrierungsverfahren zur synthese von methan und methanol |
CN109704274B (zh) * | 2017-10-26 | 2021-08-03 | 中国石油化工股份有限公司 | 有机液体储氢的原料体系 |
KR101987553B1 (ko) | 2017-11-23 | 2019-06-10 | 서울여자대학교 산학협력단 | 액상의 수소 저장 물질 |
DE102018109254A1 (de) | 2018-04-18 | 2019-10-24 | Clariant lnternational Ltd | Platin-Schalenkatalysator |
EP3788001A1 (en) | 2018-05-02 | 2021-03-10 | Hysilabs, SAS | Hydrogen carrier compounds |
CN109353987A (zh) * | 2018-11-23 | 2019-02-19 | 汽解放汽车有限公司 | 一种液态储氢材料及其制备方法 |
KR102622005B1 (ko) * | 2019-01-04 | 2024-01-10 | 한국화학연구원 | 피리딘 그룹을 포함하는 방향족 화합물을 제조하는 방법 |
DE102019211876B4 (de) * | 2019-08-07 | 2022-09-29 | Rolls-Royce Solutions GmbH | Leistungsanordnung und Verfahren zu deren Betrieb |
DE102019211877A1 (de) * | 2019-08-07 | 2021-02-11 | Mtu Friedrichshafen Gmbh | Verfahren zum Betreiben einer Brennkraftmaschine und Brennkraftmaschine, eingerichtet zur Durchführung eines solchen Verfahrens |
US20230002220A1 (en) | 2019-10-31 | 2023-01-05 | Hysilabs Sas | Process for producing and regenerating hydrogen carrier compounds |
CA3154904A1 (en) | 2019-10-31 | 2021-05-06 | Benjamin BURCHER | Hydrogen carrier compounds |
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KR102310957B1 (ko) | 2019-11-13 | 2021-10-12 | 한국과학기술원 | 액상화합물 기반 수소저장용 탈수소화 반응 촉매 및 그 제조방법 |
CN111392691B (zh) * | 2020-02-17 | 2021-09-21 | 浙江大学 | 一种钯基催化剂催化全氢化有机液体储氢材料低温脱氢的方法 |
FR3107843A1 (fr) | 2020-03-03 | 2021-09-10 | Arkema France | DÉSHYDROGÉNATION PARTIELLE de LIQUIDES ORGANIQUES |
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KR20210120550A (ko) | 2020-03-27 | 2021-10-07 | 한국과학기술원 | 액상화합물 기반 수소저장 시스템 및 그 운용방법 |
KR102303911B1 (ko) | 2020-04-03 | 2021-09-24 | 한국과학기술원 | 모듈타입 수소저장 시스템 및 그 운용방법 |
FR3112289B1 (fr) | 2020-07-10 | 2022-07-22 | Arkema France | Purification de liquides aromatiques |
FR3112339B1 (fr) | 2020-07-10 | 2022-07-22 | Arkema France | Procédé d’amélioration de la qualité des liquides organiques porteur d’hydrogène |
KR102480065B1 (ko) * | 2020-08-03 | 2022-12-23 | 한국화학연구원 | 메틸벤질-나프탈렌계 수소 저장 물질 및 이를 이용한 수소저장 및 방출 방법 |
WO2022030917A1 (ko) * | 2020-08-03 | 2022-02-10 | 한국화학연구원 | 메틸벤질-나프탈렌계 수소 저장 물질 및 이를 이용한 수소저장 및 방출 방법 |
FR3115031B1 (fr) | 2020-10-08 | 2023-12-22 | Arkema France | Stockage d’hydrogène au moyen de composés liquides organiques |
FR3115030B1 (fr) | 2020-10-08 | 2023-12-22 | Arkema France | Stockage d’hydrogène au moyen de dérivés de composés d’origine renouvelable |
FR3117113B1 (fr) | 2020-12-09 | 2024-04-12 | Arkema France | Formulation liquide pour stockage d’hydrogène |
FR3117114B1 (fr) | 2020-12-09 | 2024-04-12 | Arkema France | Formulation liquide pour stockage d’hydrogène |
KR20220134179A (ko) | 2021-03-26 | 2022-10-05 | 한국과학기술원 | Lohc 수소화 반응 시스템 및 그 운전방법 |
KR102557863B1 (ko) | 2021-03-26 | 2023-07-24 | 한국과학기술원 | Lohc 탈수소화 반응기 용 촉매구조체 |
EP4108630A1 (en) | 2021-06-25 | 2022-12-28 | Hysilabs, SAS | Hydrogen carrier compounds |
KR102563327B1 (ko) | 2021-09-13 | 2023-08-03 | 한국화학연구원 | 벤질(메틸벤질)벤젠을 포함하는 수소 저장 물질 및 이를 이용한 수소 저장 및 방출 방법 |
WO2023055108A1 (ko) | 2021-09-29 | 2023-04-06 | 한양대학교 산학협력단 | 수소화/탈수소화의 가역성이 개선된 백금 담지 촉매 및 이를 이용한 액체 유기 수소 운반체 기반의 수소 저장 및 방출 방법 |
US11891300B2 (en) * | 2021-11-01 | 2024-02-06 | Chevron U.S.A. Inc. | Clean liquid fuels hydrogen carrier processes |
KR20230103045A (ko) * | 2021-12-31 | 2023-07-07 | 경북대학교 산학협력단 | 나프탈렌계 유도체를 이용한 수소 저장 물질 및 이의 제조방법 |
KR20230135810A (ko) * | 2022-03-17 | 2023-09-26 | 한양대학교 산학협력단 | 모노벤질톨루엔 이성질체 혼합물을 함유하는 액체 유기 수소 운반체용 조성물 및 이를 이용한 수소 저장 및 방출 방법 |
DE102022210825A1 (de) | 2022-10-13 | 2024-04-18 | Forschungszentrum Jülich GmbH | Katalysatorsystem und Verfahren zum katalytischen Dehydrieren eines Wasserstoffträgermaterials, Reaktoranordnung mit einem derartigen Katalysatorsystem sowie Verfahren zum Herstellen eines derartigen Katalysatorsystems |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57172992A (en) * | 1981-02-13 | 1982-10-25 | Nippon Steel Chem Co Ltd | Lubricating oil for power transmission means |
JPS6087231A (ja) * | 1983-09-23 | 1985-05-16 | アトーシュム | ポリアリールアルカンオリゴマー組成物及びその製造法 |
JP2007269522A (ja) * | 2006-03-30 | 2007-10-18 | Chiyoda Corp | 水素の貯蔵輸送システム |
US20080260630A1 (en) * | 2007-04-16 | 2008-10-23 | Air Products And Chemicals, Inc. | Autothermal Hydrogen Storage and Delivery Systems |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1419604A1 (de) * | 1961-06-12 | 1969-05-14 | Bergwerksverband Gmbh | Verwendung fluessiger hochsiedender aromatischer Kohlenwasserstoffe als Waermeuebertragungsmittel |
SE456742B (sv) * | 1980-07-18 | 1988-10-31 | Mitsubishi Oil Co | Komposition laemplig foer mekanisk krafoeverfoering och anvaendning av komposition i samband med drivanordningar av traktionstyp |
US4371726A (en) * | 1981-02-13 | 1983-02-01 | Nippon Steel Chemical Co., Ltd. | Composition suitable for mechanical power transmission and process for operating traction drives |
JPH088010B2 (ja) * | 1986-09-04 | 1996-01-29 | 日本石油化学株式会社 | 電気絶縁油組成物 |
DE3729526A1 (de) | 1987-09-03 | 1989-03-16 | Nasser Kamilia | Vorrichtung zur dehydrierung von fluessigen hydriden |
US7101530B2 (en) | 2003-05-06 | 2006-09-05 | Air Products And Chemicals, Inc. | Hydrogen storage by reversible hydrogenation of pi-conjugated substrates |
JP2005138024A (ja) * | 2003-11-06 | 2005-06-02 | Sekisui Chem Co Ltd | 水素化芳香族化合物からの脱水素反応用触媒とその触媒を利用した水素製造方法 |
JP2006248814A (ja) | 2005-03-09 | 2006-09-21 | Hitachi Ltd | 水素供給装置および水素供給方法 |
JP4483901B2 (ja) | 2007-06-29 | 2010-06-16 | 株式会社日立製作所 | エンジンシステム |
DE102007039478A1 (de) * | 2007-08-21 | 2009-02-26 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Wasserstoffgenerator sowie Verfahren zur Erzeugung von Wasserstoff |
JP4523978B2 (ja) * | 2008-03-28 | 2010-08-11 | 株式会社日立製作所 | エンジンシステム |
DE102008034221A1 (de) | 2008-07-23 | 2010-01-28 | Bayerische Motoren Werke Aktiengesellschaft | Kraftstoffversorgungseinrichtung für ein mit Wasserstoff betreibbares Kraftfahrzeug |
CN101575257B (zh) | 2009-06-16 | 2012-06-13 | 华东师范大学 | 一种以甲苯为储氢剂的催化加氢方法 |
CN102101645A (zh) * | 2009-12-16 | 2011-06-22 | 中国科学院大连化学物理研究所 | 一种硼氢化钠水解制氢系统 |
-
2012
- 2012-11-28 DE DE102012221809.2A patent/DE102012221809A1/de not_active Withdrawn
-
2013
- 2013-10-23 ES ES13780357T patent/ES2696080T3/es active Active
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- 2015-05-27 US US14/722,443 patent/US10450194B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57172992A (en) * | 1981-02-13 | 1982-10-25 | Nippon Steel Chem Co Ltd | Lubricating oil for power transmission means |
JPS6087231A (ja) * | 1983-09-23 | 1985-05-16 | アトーシュム | ポリアリールアルカンオリゴマー組成物及びその製造法 |
JP2007269522A (ja) * | 2006-03-30 | 2007-10-18 | Chiyoda Corp | 水素の貯蔵輸送システム |
US20080260630A1 (en) * | 2007-04-16 | 2008-10-23 | Air Products And Chemicals, Inc. | Autothermal Hydrogen Storage and Delivery Systems |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2019532455A (ja) * | 2016-08-17 | 2019-11-07 | ペズ,ギド,ピー | 電気化学的エネルギー変換及び貯蔵のためのシステム及び方法 |
JP7084375B2 (ja) | 2016-08-17 | 2022-06-14 | ペズ,ギド,ピー | 電気化学的エネルギー変換及び貯蔵のためのシステム及び方法 |
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KR101954305B1 (ko) | 2019-03-05 |
DE102012221809A1 (de) | 2014-05-28 |
KR101992255B1 (ko) | 2019-06-24 |
AU2013351445A1 (en) | 2015-07-16 |
EP2925669B1 (de) | 2018-10-31 |
KR20180030735A (ko) | 2018-03-23 |
BR112015012183B1 (pt) | 2022-01-11 |
AU2013351445B2 (en) | 2017-04-06 |
CA2892228C (en) | 2020-09-08 |
BR112015012183A8 (pt) | 2019-10-01 |
JP6280559B2 (ja) | 2018-02-14 |
WO2014082801A1 (de) | 2014-06-05 |
US10450194B2 (en) | 2019-10-22 |
BR112015012183A2 (ja) | 2017-08-22 |
CA2892228A1 (en) | 2014-06-05 |
CN104812698A (zh) | 2015-07-29 |
ES2696080T3 (es) | 2019-01-14 |
KR20150097558A (ko) | 2015-08-26 |
EP2925669A1 (de) | 2015-10-07 |
CN104812698B (zh) | 2017-12-15 |
US20150266731A1 (en) | 2015-09-24 |
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