JP2016027117A - 難燃性ゲルコート組成物および難燃性強化プラスティック成形物 - Google Patents
難燃性ゲルコート組成物および難燃性強化プラスティック成形物 Download PDFInfo
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- JP2016027117A JP2016027117A JP2015125392A JP2015125392A JP2016027117A JP 2016027117 A JP2016027117 A JP 2016027117A JP 2015125392 A JP2015125392 A JP 2015125392A JP 2015125392 A JP2015125392 A JP 2015125392A JP 2016027117 A JP2016027117 A JP 2016027117A
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- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- GUYMMHOQXYZMJQ-UHFFFAOYSA-N n-ethyl-3-methylaniline Chemical compound CCNC1=CC=CC(C)=C1 GUYMMHOQXYZMJQ-UHFFFAOYSA-N 0.000 description 1
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- GUSFEBGYPWJUSS-UHFFFAOYSA-N pentaazanium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O GUSFEBGYPWJUSS-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本発明による難燃性ゲルコート組成物において、ゲルコート樹脂成分(A)は、不飽和ポリエステル樹脂、ビニルエステル樹脂またはアクリル樹脂の単独或いはこれらの混合物に、顔料、体質顔料、揺変剤および硬化促進剤を適宜加えた液状熱硬化性樹脂組成物であることが好ましい。
ゲルコート用の不飽和ポリエステル樹脂としては、飽和酸が無水フタル酸、イソフタル酸、テレフタル酸、ヘット酸、こはく酸、アジピン酸、セバシン酸、テトラクロロ無水フタル酸、テトラブロモ無水フタル酸、シクロヘキサンジカルボン酸及びその無水物、テトラヒドロ無水フタル酸の内の一種から三種、不飽和酸にフマル酸、無水マレイン酸、イタコン酸の内の一種から三種、グリコール類がネオペンチルグリコール、プロピレングリコール、ジプロピレングリコール、エチレングリコール、ジエチレングリコール、ブタンジオール、ビスフェノールA、水素化ビスフェノールAの内の一種から三種をエステル化し、スチレンモノマー、メチルメタクリレートモノマーなどのビニルモノマーに溶解したものが一般的に使用される。
本発明による難燃性ゲルコート組成物を用いることによって、低発煙性および難燃性、耐クラック性、軽量性といった様々な特性を備えた鉄道車両や航空機用途に適したノンハロゲン・ノンアンチモンの強化プラスティック成形物を得ることができる。
A)材料
ゲルコート付強化プラスティック成形物作製用の材料として下記のものを用意した。
1)ゲルコート樹脂(色:ホワイト)
ゲルコート樹脂(1):イソフタル酸/プロピレングリコール系不飽和ポリエステル樹脂系ゲルコート(東罐マテリアル・テクノロジー社製、「3B−0012P」)
ゲルコート樹脂(2):アクリル系不飽和ポリエステル樹脂系ゲルコート(東罐マテリアル・テクノロジー社製、「NR−AC0012P」)
ゲルコート樹脂(3):イソフタル酸/ネオペンチルグリコール系不飽和ポリエステル樹脂系ゲルコート(東罐マテリアル・テクノロジー社製、「3F−0012P」)
ゲルコート樹脂(4):イソフタル酸/ネオペンチルグリコール系不飽和ポリエステル樹脂系ゲルコート(東罐マテリアル・テクノロジー社製、「3F−0012P」)に、軟質系不飽和ポリエステル樹脂(引っ張り弾性率:350MPa以下、引っ張り伸び率:50%以上)をゲルコート樹脂中25〜35重量%添加したもの(品番「3F−0012PA」)。
有機リン酸塩化合物:ADEKA社製、「アデカスタブFP−2200」
水酸化アルミニウム:昭和電工社製、「ハイジライトH−32」
3)強化プラスティック成形物のマトリックス
臭素付加不飽和ポリエステル樹脂:日本ユピカ社製、「ユピカFLH350R」
不飽和ポリエステル樹脂:ディーエイチ・マテリアル社製、「サンドーマFH−286」
4)強化プラスティック成形物成形用強化材
繊維補強材:「ガラスマット♯450」
5)ゲルコートおよび強化プラスティック成形物用の硬化剤
メチルエチルケトンパーオキサイド:日本油脂社製、「パーメックN」
B)成形物の作製
ゲルコート付強化プラスティック成形物を下記の方法で作製した。
C)燃焼試験
車両用材料燃焼試験(鉄道に関する技術上の基準を定める省令の解釈基準 第八十三条、車両の火災対策:国土交通省令)に従って、上記ゲルコート付強化プラスティック成形物の燃焼試験を行った。試験手順は下記の通りである。
1.図1に示す燃焼試験装置において、B5版(182mm×257mm)のサイズのテストピース(1)を基台(2)に対して角度45度で傾斜状に配置する。
2.傾斜状のテストピース(1)の下面中央から下の位置に配置された直径17.5mm×高さ7.1mmで厚さ0.8mmの円筒状の鉄製の燃焼皿(3)にエチルアルコール(0.5cc)を注ぎ込み、これを点火させる。テストピース(1)の下面中心から燃焼皿(3)の底面までの距離は25.4mm(1インチ)である。図1中、(4)は燃焼皿(3)を載せる受台で、コルク等の熱伝導率の低い材料でできている。(5)は受台(4)を基台(2)に支持する脚部である。
3.炎をテストピース(1)に接触させ、燃焼中及び燃焼後のテストピース(1)の状態を目視観察して、燃焼状態を判定する。
D)曲げ強度試験
前記ゲルコート層に対し、JIS K6911に準拠して、曲げ強度試験を行った。この結果を表2に示し、これをまとめたものを表3に示す。表3において、曲げひずみが1.5%未満であると柔軟性が不足していると判断できる。
ゲルコート硬化物の作製
下記の方法でゲルコート硬化物を作製した。
「NR−AC」:特殊ネオペンチルグリコールイソ系不飽和ポリエステル樹脂系(東罐マテリアル・テクノロジー社製、「NR−AC0012P」)
「3F」:ネオペンチルグリコールイソ系不飽和ポリエステル樹脂系(東罐マテリアル・テクノロジー社製、「3F−0012P」)
「FP2200」:有機リン酸塩化合物(ADEKA社製、「アデカスタブFP−2200」)
「水アル」:水酸化アルミニウム(昭和電工社製、「ハイジライトH−32」)
「3F−PA」:「3F−0012P」に、軟質系不飽和ポリエステル樹脂(引っ張り弾性率:350MPa以下、引っ張り伸び率:50%以上)をゲルコート樹脂中に25〜35重量%以上添加したもの
「オルソ系ホワイト(1C)」:(オルソ系不飽和ポリエステル樹脂系(東罐マテリアル・テクノロジー社製、「1C−0012P」)
「イソ系ホワイト(3A)」:(ネオペンチルグリコールイソ系不飽和ポリエステル樹脂系(東罐マテリアル・テクノロジー社製、「3A−0012P」)
「ビス系ホワイト(7B)」:(ビス系不飽和ポリエステル樹脂系(東罐マテリアル・テクノロジー社製、「7B−0012P」)。
Claims (4)
- (A)ゲルコート樹脂成分と、(B)リン酸またはポリリン酸とトリアジン環含有アミン化合物またはアンモニアとを反応させて得られる有機リン酸塩化合物成分とを含み、前記成分(A)100質量部に対して前記成分(B)が1〜70質量部含まれることを特徴とする難燃性ゲルコート組成物。
- 前記成分(B)は、下記一般式(1)で表される有機リン酸塩化合物である、請求項1に記載の難燃性ゲルコート組成物。
- 前記成分(A)は、不飽和ポリエステル樹脂、ビニルエステル樹脂またはアクリル樹脂の単独或いはこれらの混合物に、顔料、体質顔料、揺変剤および/または硬化促進剤を加えた液状熱硬化性樹脂組成物である、請求項1または2のいずれかに記載の難燃性ゲルコート組成物。
- 請求項1〜3のいずれかに記載の難燃性ゲルコート組成物からなるゲルコートを表面に有する強化プラスティック成形物。
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JP2019073662A (ja) * | 2017-10-19 | 2019-05-16 | Toyo Tire株式会社 | 鉄道車両用緩衝ゴム用ゴム組成物 |
JP2020069654A (ja) * | 2018-10-29 | 2020-05-07 | 東罐マテリアル・テクノロジー株式会社 | ゲルコート付き強化プラスチック成形物 |
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JPS5266588A (en) * | 1975-11-29 | 1977-06-02 | Hitachi Chem Co Ltd | Molded products of flame retardant unsaturated polyester resins |
JP2010070685A (ja) * | 2008-09-19 | 2010-04-02 | Mitsubishi Rayon Co Ltd | アクリルゾル組成物及びこれを用いた成形品 |
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- 2015-06-23 JP JP2015125392A patent/JP2016027117A/ja active Pending
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JPS5266588A (en) * | 1975-11-29 | 1977-06-02 | Hitachi Chem Co Ltd | Molded products of flame retardant unsaturated polyester resins |
JP2010070685A (ja) * | 2008-09-19 | 2010-04-02 | Mitsubishi Rayon Co Ltd | アクリルゾル組成物及びこれを用いた成形品 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2019073662A (ja) * | 2017-10-19 | 2019-05-16 | Toyo Tire株式会社 | 鉄道車両用緩衝ゴム用ゴム組成物 |
JP6993169B2 (ja) | 2017-10-19 | 2022-01-13 | ニッタ化工品株式会社 | 鉄道車両用緩衝ゴム用ゴム組成物 |
JP2020069654A (ja) * | 2018-10-29 | 2020-05-07 | 東罐マテリアル・テクノロジー株式会社 | ゲルコート付き強化プラスチック成形物 |
JP7202141B2 (ja) | 2018-10-29 | 2023-01-11 | Tomatec株式会社 | ゲルコート付き強化プラスチック成形物 |
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