JP2015535021A - 難燃性塗料及び難燃性基材 - Google Patents
難燃性塗料及び難燃性基材 Download PDFInfo
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Abstract
Description
(a)水性ポリウレタン樹脂と、
(b)複数のイソシアナト基を有するイソシアネート類化合物と、
(c)少なくとも1種の金属水酸化物と、
を含む。
該イソシアネート類化合物の該複数のイソシアナト基は、それぞれ該水性ポリウレタン樹脂及び該金属水酸化物と結合を生じる。
は、下記の化学式で表せる。
まず、予め水性ポリウレタン分子を含有する水溶液を調製しておき、次の反応を行う際、該水性ポリウレタン分子の水溶液内に脱イオン水を添加して希釈し、その後更に表面改質の水酸化アルミニウム微粒子(粒子径が1μm及び8μm)を添加し、均一に分散するまで攪拌して希釈混合水溶液となる。
本実施例の難燃性塗料の調製方法は、実施例1と類似し、まず、予め水性ポリウレタン分子を含有する水溶液を調製しておき、次の反応を行う際、次の反応を行う際、該水性ポリウレタン分子の水溶液内に脱イオン水を添加して希釈し、その後更に表面改質の水酸化アルミニウム微粒子(粒子径が8μm)及び更にリン系難燃剤(例えばポリリン酸アンモニウム)を添加し、均一に分散するまで攪拌して希釈混合水溶液となる。
本実施例の難燃性塗料の調製方法は、実施例1と類似し、まず、予め水性ポリウレタン分子を含有する水溶液を調製しておき、次の反応を行う際、該水性ポリウレタン分子の水溶液内に脱イオン水を添加して希釈する。ただし、該希釈水溶液内に表面改質の水酸化アルミニウム微粒子或いはリン系難燃剤を添加しない。
本実施例の難燃性塗料の調製方法は、実施例1と類似し、まず、予め水性ポリウレタン分子を含有する水溶液を調製しておき、次の反応を行う際、該水性ポリウレタン分子の水溶液内に脱イオン水を添加して希釈し、その後更に表面改質の水酸化アルミニウム微粒子(粒子径が8μm)及び更にリン系難燃剤(例えばポリリン酸アンモニウム)を添加し、均一に分散するまで攪拌して希釈混合水溶液とする。
本実施例の難燃性塗料の調製方法は、実施例1と類似し、まず、予め水性ポリウレタン分子を含有する水溶液を調製しておき、次の反応を行う際、該水性ポリウレタン分子の水溶液内に脱イオン水を添加して希釈し、その後更に表面改質の水酸化アルミニウム微粒子(粒子径が8μm)及び更にリン系難燃剤(例えばポリリン酸アンモニウム)を添加し、均一に分散するまで攪拌して希釈混合水溶液とする。
Claims (14)
- (a)水性ポリウレタン樹脂と、
(b)複数のイソシアナト基を有するイソシアネート類化合物と、
(c)少なくとも1種の金属水酸化物と、
を含む難燃性塗料であって、
前記イソシアネート類化合物の前記複数のイソシアナト基は、前記水性ポリウレタン樹脂及び前記金属水酸化物と結合を生じることを特徴とする難燃性塗料。 - 前記水性ポリウレタン樹脂と前記イソシアネート類化合物と前記金属水酸化物の固形重量比は、50:0.1〜1:20〜80であることを特徴とする請求項1に記載の難燃性塗料。
- リン系難燃剤を更に含むことを特徴とする請求項1に記載の難燃性塗料。
- 膨張黒鉛を更に含むことを特徴とする請求項1に記載の難燃性塗料。
- 前記水性ポリウレタン樹脂は、複数のスルホン酸基或いはカルボキシル基の親水基を有することを特徴とする請求項1に記載の難燃性塗料。
- 前記イソシアネート類化合物は、親水化改質を経たヘキサメチレンジイソシアネートのオリゴマーであることを特徴とする請求項1に記載の難燃性塗料。
- 前記金属水酸化物は、水酸化アルミニウム或いは水酸化マグネシウムであることを特徴とする請求項1に記載の難燃性塗料。
- 前記金属水酸化物の平均粒子径は、1〜15マイクロメートルであることを特徴とする請求項1に記載の難燃性塗料。
- 前記金属水酸化物の微粒子は、表面改質を経ることで複数のアミノ基を有することを特徴とする請求項8に記載の難燃性塗料。
- 金属粉或いは金網を更に含むことを特徴とする請求項1に記載の難燃性塗料。
- 薄物材料と、
前記薄物材料上に塗布された請求項1に記載の難燃性塗料と、
を含むことを特徴とする難燃性基材。 - 前記薄物材料は、布地、紙類或いはプラスチック製薄板から選ばれることを特徴とする請求項11に記載の難燃性基材。
- 前記布地は、綿布又はポリエチレンテレフタラート布であることを特徴とする請求項12に記載の難燃性基材。
- 前記プラスチック製薄板は、ポリプロピレン薄板であることを特徴とする請求項12に記載の難燃性基材。
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TW101141667 | 2012-11-08 | ||
TW101141667 | 2012-11-08 | ||
TW102140543 | 2013-11-07 | ||
TW102140543A TWI499648B (zh) | 2012-11-08 | 2013-11-07 | 阻燃塗料及阻燃基材 |
PCT/US2013/069221 WO2014074866A1 (en) | 2012-11-08 | 2013-11-08 | Flame-retardant coating material and flame-retardant substrate |
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JP2015535021A true JP2015535021A (ja) | 2015-12-07 |
JP6132928B2 JP6132928B2 (ja) | 2017-05-24 |
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EP (1) | EP2917274A4 (ja) |
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WO2021192767A1 (ja) * | 2020-03-27 | 2021-09-30 | 株式会社ユポ・コーポレーション | 水系難燃塗料組成物及び難燃熱可塑性樹脂フィルム |
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- 2013-11-08 EP EP13853205.6A patent/EP2917274A4/en not_active Withdrawn
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WO2021192767A1 (ja) * | 2020-03-27 | 2021-09-30 | 株式会社ユポ・コーポレーション | 水系難燃塗料組成物及び難燃熱可塑性樹脂フィルム |
Also Published As
Publication number | Publication date |
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US20150267121A1 (en) | 2015-09-24 |
TWI499648B (zh) | 2015-09-11 |
EP2917274A1 (en) | 2015-09-16 |
WO2014074866A1 (en) | 2014-05-15 |
JP6132928B2 (ja) | 2017-05-24 |
TW201418388A (zh) | 2014-05-16 |
EP2917274A4 (en) | 2016-06-22 |
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