JP2015515622A5 - - Google Patents
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- JP2015515622A5 JP2015515622A5 JP2015501794A JP2015501794A JP2015515622A5 JP 2015515622 A5 JP2015515622 A5 JP 2015515622A5 JP 2015501794 A JP2015501794 A JP 2015501794A JP 2015501794 A JP2015501794 A JP 2015501794A JP 2015515622 A5 JP2015515622 A5 JP 2015515622A5
- Authority
- JP
- Japan
- Prior art keywords
- transition metal
- carbon
- independently
- alkyl
- metal complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229910052723 transition metal Inorganic materials 0.000 claims description 21
- 150000003624 transition metals Chemical class 0.000 claims description 21
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 claims description 14
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 14
- 239000004020 conductor Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 4
- 238000001694 spray drying Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 12
- 125000001188 haloalkyl group Chemical group 0.000 claims 8
- 125000001475 halogen functional group Chemical group 0.000 claims 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 6
- 125000003118 aryl group Chemical group 0.000 claims 4
- 239000003446 ligand Substances 0.000 claims 4
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 4
- 239000012491 analyte Substances 0.000 claims 3
- 239000002041 carbon nanotube Substances 0.000 claims 2
- 229910021393 carbon nanotube Inorganic materials 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- 125000003396 thiol group Chemical class [H]S* 0.000 claims 2
- 125000004665 trialkylsilyl group Chemical group 0.000 claims 2
- 239000002109 single walled nanotube Substances 0.000 description 9
- 239000002131 composite material Substances 0.000 description 5
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 4
- 229920000123 polythiophene Polymers 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LAEBSQSRRMJULV-UHFFFAOYSA-N 2-azidoethylsulfanylbenzene Chemical compound [N-]=[N+]=NCCSC1=CC=CC=C1 LAEBSQSRRMJULV-UHFFFAOYSA-N 0.000 description 1
- 0 CCC(C)(C)*1=C(*)C=C(*)*1* Chemical compound CCC(C)(C)*1=C(*)C=C(*)*1* 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000004699 copper complex Chemical class 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261614834P | 2012-03-23 | 2012-03-23 | |
| US61/614,834 | 2012-03-23 | ||
| PCT/US2013/031851 WO2013184222A2 (en) | 2012-03-23 | 2013-03-15 | Ethylene sensor |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015515622A JP2015515622A (ja) | 2015-05-28 |
| JP2015515622A5 true JP2015515622A5 (https=) | 2018-06-21 |
| JP6359005B2 JP6359005B2 (ja) | 2018-07-18 |
Family
ID=49325454
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015501794A Expired - Fee Related JP6359005B2 (ja) | 2012-03-23 | 2013-03-15 | エチレンセンサー |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US9739737B2 (https=) |
| EP (1) | EP2828647B1 (https=) |
| JP (1) | JP6359005B2 (https=) |
| KR (1) | KR102137658B1 (https=) |
| CN (2) | CN104412100A (https=) |
| BR (1) | BR112014023454B1 (https=) |
| CA (1) | CA2868149C (https=) |
| IL (1) | IL234778B (https=) |
| MX (1) | MX373209B (https=) |
| WO (1) | WO2013184222A2 (https=) |
Families Citing this family (33)
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| BR112014023454B1 (pt) * | 2012-03-23 | 2022-01-11 | Massachusetts Institute Of Technology | Sensor de gás etileno, método de captação de etileno e método de produção de um sensor |
| CA2923427A1 (en) | 2013-09-06 | 2015-03-12 | Massachusetts Institute Of Technology | Devices and methods including a preconcentrator material for detection of analytes |
| EP3041597B1 (en) | 2013-09-06 | 2022-11-02 | Massachusetts Institute of Technology | Filter materials including functionalized cellulose |
| WO2015178994A2 (en) * | 2014-03-02 | 2015-11-26 | Massachusetts Institute Of Technology | Gas sensors based upon metal carbon complexes |
| US12345680B1 (en) | 2014-03-13 | 2025-07-01 | Innosense Corporation | Modular chemiresistive sensor for real-time ethylene monitoring |
| WO2017025996A1 (ja) * | 2015-08-12 | 2017-02-16 | 株式会社 東芝 | 分子検出装置および分子検出方法 |
| WO2017042851A1 (ja) * | 2015-09-10 | 2017-03-16 | 株式会社 東芝 | 分子検出装置、分子検出方法、および有機物プローブ |
| JP2017166947A (ja) | 2016-03-16 | 2017-09-21 | 株式会社東芝 | ガス検出装置 |
| JP6682412B2 (ja) * | 2016-09-20 | 2020-04-15 | 株式会社東芝 | 分子検出装置 |
| US11257985B2 (en) * | 2016-12-05 | 2022-02-22 | Suzhou Lekin Semiconductor Co., Ltd. | Semiconductor element and sensing device having a light emitting unit and a sensor unit |
| TWI615611B (zh) * | 2016-12-20 | 2018-02-21 | 氣體偵測器 | |
| US11112394B2 (en) * | 2016-12-23 | 2021-09-07 | The Johns Hopkins University | Ethylenic compound sensor including an organic semiconductor |
| US10823691B2 (en) * | 2017-01-11 | 2020-11-03 | Winbond Electronics Corp. | Sensor, composite material and method of manufacturing the same |
| JP6612802B2 (ja) | 2017-03-21 | 2019-11-27 | 株式会社東芝 | 分子検出装置および分子検出方法 |
| WO2019074618A2 (en) * | 2017-09-18 | 2019-04-18 | Massachusetts Institute Of Technology | SENSORS COMPRISING REDOX-ACTIVE SELECTOR COMPLEXES |
| JP2019056602A (ja) | 2017-09-20 | 2019-04-11 | 株式会社東芝 | 分子検出装置および分子検出方法 |
| GB201715847D0 (en) * | 2017-09-29 | 2017-11-15 | Sumitomo Chemical Co | Gas Sensor |
| WO2019169476A1 (en) | 2018-03-03 | 2019-09-12 | Sawada James | Sensor and method for detecting combustible gas |
| JP2021518530A (ja) * | 2018-03-15 | 2021-08-02 | マサチューセッツ インスティテュート オブ テクノロジー | 化学抵抗性センサ及び検知方法 |
| JP2020008200A (ja) * | 2018-07-05 | 2020-01-16 | ダイキン工業株式会社 | 庫内環境制御システム |
| US12024530B2 (en) * | 2019-03-11 | 2024-07-02 | Carrier Corporation | Sensor for detecting gas analyte |
| US11788981B2 (en) * | 2019-03-11 | 2023-10-17 | Carrier Corporation | Sensor for detecting gas analyte |
| US10981941B2 (en) | 2019-03-11 | 2021-04-20 | Carrier Corporation | Metal complex as sensor compound for detecting gas analyte |
| DE102019002782A1 (de) * | 2019-04-16 | 2020-10-22 | Eberhard-Karls-Universität Tübingen | Gassensor und Verfahren zur selektiven Detektion von Acetylen und Ethylen |
| JP7283671B2 (ja) | 2019-11-14 | 2023-05-30 | 国立研究開発法人物質・材料研究機構 | アルケン検知ガスセンサ、及び、それを用いたシステム |
| EP3872487B1 (en) * | 2020-02-25 | 2022-10-05 | Carrier Corporation | Volatile alkene sensing device and method of using |
| EP4161280A1 (en) | 2020-06-07 | 2023-04-12 | Comestaag LLC | Selectively treating plant items |
| EP4161281A1 (en) | 2020-06-07 | 2023-04-12 | Comestaag LLC | Barrier coating compositions for perishables and methods, kits and coated items relating thereto |
| US11143641B1 (en) * | 2021-04-05 | 2021-10-12 | Vivante Health, Inc. | Gas sensor calibration method |
| WO2022239551A1 (ja) * | 2021-05-12 | 2022-11-17 | 国立研究開発法人産業技術総合研究所 | ガス検出装置 |
| RU209984U1 (ru) * | 2021-09-23 | 2022-03-24 | Федеральное Государственное Бюджетное Образовательное Учреждение Высшего Образования «Новосибирский Государственный Технический Университет» | Хеморезистивный газовый сенсор |
| CN113960121B (zh) * | 2021-10-26 | 2023-12-29 | 南京农业大学 | 可穿戴柔性传感器及其制备方法和监测水果成熟度方法 |
| KR102853303B1 (ko) * | 2022-11-11 | 2025-09-01 | 한국생산기술연구원 | 에틸렌 가스 측정용 센서 및 이의 제조 방법 |
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| US2648598A (en) * | 1950-06-27 | 1953-08-11 | Us Agriculture | Process for determination of ethylene in gases |
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| ATE409215T1 (de) * | 1998-05-05 | 2008-10-15 | Massachusetts Inst Technology | Emittierende polymere und vorrichtungen diese polymere enthaltend |
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| US6105416A (en) * | 1998-10-16 | 2000-08-22 | Geo-Centers, Inc. | Ethylene monitoring and control system |
| EP1263887A1 (en) * | 2000-02-04 | 2002-12-11 | Massachusetts Institute Of Technology | Insulated nanoscopic pathways, compositions and devices of the same |
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| US7318908B1 (en) * | 2001-11-01 | 2008-01-15 | The Board Of Trustees Of The Leland Stanford Junior University | Integrated nanotube sensor |
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| KR20040054801A (ko) * | 2001-11-26 | 2004-06-25 | 소니 인터내셔널(유로파) 게엠베하 | 실온에 근접한 온도에서 조작 및 제조되는, 1ｄ 반도체재료의 화학 감지 재료로서의 용도 |
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| JP2010025719A (ja) * | 2008-07-18 | 2010-02-04 | Sharp Corp | 化学物質センシング素子、化学物質センシング装置、及び、化学物質センシング素子の製造方法 |
| JP2010038840A (ja) * | 2008-08-07 | 2010-02-18 | Sharp Corp | 化学物質センシング素子、化学物質センシング装置、表面修飾カーボンナノ構造体の製造方法、及び、化学物質センシング素子の製造方法 |
| US10105875B2 (en) * | 2008-08-21 | 2018-10-23 | Cam Holding Corporation | Enhanced surfaces, coatings, and related methods |
| JP2010106898A (ja) | 2008-10-29 | 2010-05-13 | Bando Chem Ind Ltd | Ｖリブドベルト |
| JP5062695B2 (ja) * | 2008-10-29 | 2012-10-31 | シャープ株式会社 | 化学物質センシング素子、ならびにこれを備えたガス分析装置および呼気分析装置、ならびに化学物質センシング素子を用いたアセトン濃度検出方法 |
| WO2010123482A2 (en) * | 2008-12-12 | 2010-10-28 | Massachusetts Institute Of Technology | High charge density structures, including carbon-based nanostructures and applications thereof |
| WO2010106898A1 (ja) * | 2009-03-16 | 2010-09-23 | シャープ株式会社 | 化学物質センシング装置およびそれを備える化学物質センシングシステム |
| JP4744618B2 (ja) * | 2009-04-13 | 2011-08-10 | シャープ株式会社 | ガス成分検出装置 |
| JP2011080798A (ja) * | 2009-10-05 | 2011-04-21 | Sharp Corp | 化学物質センシング素子の製造方法 |
| US20110124113A1 (en) * | 2009-11-25 | 2011-05-26 | Abdul-Majeed Azad | Methods and devices for detecting unsaturated compounds |
| KR20110100361A (ko) * | 2010-03-04 | 2011-09-14 | 전자부품연구원 | 유해 가스 검출 센서 및 검출 방법 |
| WO2012012537A1 (en) * | 2010-07-20 | 2012-01-26 | Ohmx Corporation | Novel chemistry used in biosensors |
| BR112014023454B1 (pt) * | 2012-03-23 | 2022-01-11 | Massachusetts Institute Of Technology | Sensor de gás etileno, método de captação de etileno e método de produção de um sensor |
| US10545093B2 (en) * | 2013-04-06 | 2020-01-28 | Massachusetts Institute Of Technology | Selective detection of alkenes or alkynes |
| WO2015178994A2 (en) * | 2014-03-02 | 2015-11-26 | Massachusetts Institute Of Technology | Gas sensors based upon metal carbon complexes |
| WO2019074618A2 (en) | 2017-09-18 | 2019-04-18 | Massachusetts Institute Of Technology | SENSORS COMPRISING REDOX-ACTIVE SELECTOR COMPLEXES |
| WO2021167693A2 (en) | 2020-02-18 | 2021-08-26 | Massachusetts Institute Of Technology | Ethylene sensor |
-
2013
- 2013-03-15 BR BR112014023454-0A patent/BR112014023454B1/pt not_active IP Right Cessation
- 2013-03-15 JP JP2015501794A patent/JP6359005B2/ja not_active Expired - Fee Related
- 2013-03-15 US US13/832,430 patent/US9739737B2/en active Active
- 2013-03-15 MX MX2014011421A patent/MX373209B/es active IP Right Grant
- 2013-03-15 CN CN201380023698.2A patent/CN104412100A/zh active Pending
- 2013-03-15 CN CN201911012248.9A patent/CN111103330A/zh active Pending
- 2013-03-15 EP EP13800766.1A patent/EP2828647B1/en active Active
- 2013-03-15 CA CA2868149A patent/CA2868149C/en active Active
- 2013-03-15 KR KR1020147029641A patent/KR102137658B1/ko not_active Expired - Fee Related
- 2013-03-15 WO PCT/US2013/031851 patent/WO2013184222A2/en not_active Ceased
-
2014
- 2014-09-22 IL IL234778A patent/IL234778B/en active IP Right Grant
-
2017
- 2017-08-18 US US15/681,313 patent/US12345669B2/en active Active
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