JP2015140326A - Fading inhibitor for dyed hair and fading prevention method using the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a fading inhibitor having an excellent fading prevention effect on the dyed hair, and to provide a fading prevention method for the hair using the same.SOLUTION: A fading inhibitor containing a lactone derivative represented by the following general formula (1) is used. The excellent fading prevention effect on the dyed hair can be exhibited by applying the fading inhibitor to the hair before dyeing, after dyeing, or with a hair dye and subjecting to a heat treatment. In the formula, n is 1 or 2, and R represents a straight or branched chain saturated or unsaturated hydrocarbon group of carbon number 9-22.

Description

  The present invention relates to an anti-fading agent for dyed hair containing a lactone derivative and an anti-fading method using the same.

In recent years, in addition to white hair dyeing, the number of people who are fashionably dyeing hair to a desired color has increased, and with the growing consumer awareness of hair dyeing, the technology of hair dyeing is advancing day by day. However, the problem that the dyed hair fades due to shampooing and daily hair damage has been one of the important issues.
As a method for improving such a problem, a method using a silicone derivative or highly polymerized silicone, a method using a specific polymer compound, a method using a specific diester compound, and the like have been proposed, but it is not necessarily sufficient. (For example, Patent Documents 1 to 4).

  The compound having the same structure as the lactone derivative of the present invention has already been disclosed to have a damage improving effect (Patent Document 5) and a sharpness improving effect (Patent Document 6). unknown.

Patent No. 4001340 JP-A-2005-008554 JP 2002-114642 A JP 2009-256280 A JP2012-062250 JP2012-219057

  An anti-fading agent having an excellent anti-fading effect on dyed hair and an anti-fading method using the same.

（ただし式中、ｎは１又は２であり、Ｒは炭素数９〜２２の直鎖又は分岐鎖の飽和又は不飽和炭化水素基を表す） As a result of intensive studies to solve the above problems, the present inventors have found that the lactone derivative represented by the following general formula (1) has an excellent anti-fading effect on dyed hair, The present invention has been completed. That is, it has been found that an anti-fading agent containing a lactone derivative represented by the following general formula (1) is applied to hair and subjected to heat treatment, thereby exhibiting an excellent anti-fading effect on dyed hair. Is.

(In the formula, n is 1 or 2, and R represents a linear or branched saturated or unsaturated hydrocarbon group having 9 to 22 carbon atoms)

  The anti-fading agent for hair of the present invention has an excellent anti-fading effect on dyed hair. Moreover, it is possible to prevent fading of dyed hair by using the method for preventing fading according to the present invention.

（ただし式中、ｎは１又は２であり、Ｒは炭素数９〜２２の直鎖又は分岐鎖の飽和又は不飽和炭化水素基を表す） The lactone derivative used in the present invention is a compound represented by the following general formula (1).

(In the formula, n is 1 or 2, and R represents a linear or branched saturated or unsaturated hydrocarbon group having 9 to 22 carbon atoms)

  R in the general formula (1) is not particularly limited as long as it is a linear or branched saturated or unsaturated hydrocarbon group having 9 to 22 carbon atoms, but is saturated hydrocarbon from the viewpoint of stability. It is preferably a group. Specifically, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group, heicosyl group, docosyl group and the like are preferable. Among these, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, eicosyl group, heicosyl group in terms of the availability of raw materials and the ease of synthesis A group is more preferable, and a decyl group, a tetradecyl group, and an octadecyl group are most preferable.

  The manufacturing method of the lactone derivative used for this invention is not specifically limited, It can manufacture by a well-known manufacturing method. For example, when n is 1, that is, a γ-lactone derivative, a method of mixing unsaturated fatty acids and a strong acid to isomerize an unsaturated bond and cyclize, or in the presence of a peroxide or an acid catalyst And a method of reacting acrylic acid with alcohol. When n is 2, that is, if it is a δ-lactone derivative, a 5-membered ring ketone compound is oxidized by reacting hydrogen peroxide and acetic acid, or 5-hydroxy contained in natural fats such as meadow foam oil. The method of cyclizing a fatty acid is mentioned. The lactone derivative of the present invention thus obtained may be used after being appropriately purified by extraction, deoxidation, washing with water, recrystallization, adsorption purification, distillation, column purification and the like.

  In the present invention, the dyed hair may be hair dyed by a generally used method, and is not particularly limited. For example, hair dyes using acid dyes, basic dyes, nitro dyes, or oxidation Examples thereof include hair dyed with a hair dye mainly composed of dye. According to the anti-fading method of the present invention, it is possible to exert an excellent anti-fading effect on hair dyed by such a method.

  The method for preventing discoloration of dyed hair according to the present invention is characterized in that an antifading agent containing a lactone derivative represented by the general formula (1) is applied to hair and subjected to heat treatment. For the heat treatment, a hair iron, a trowel, a digital permanent, a dryer or the like can be used. Heat treatment conditions are about 1 to 10 times at a set temperature of 60 to 180 ° C. for hair irons and irons, about 1 to 60 minutes at 60 to 120 ° C. for digital perms, and hot air for dryers 30 What is necessary is just to process for about 10 minutes for second.

  The anti-fading agent of the present invention may be applied to the hair before hair dyeing and subjected to heat treatment, or may be applied to the hair after hair dyeing and subjected to heat treatment. Or you may mix | blend with a hair dye, perform dyeing | staining and application | coating simultaneously, and may give heat processing after that.

  The method for applying the anti-fading agent of the present invention to the hair is not particularly limited as long as it can be uniformly applied to the hair, but is applied to the hair as it is, or it is applied to the hair after being dissolved or dispersed in a solvent or the like. Alternatively, it may be blended in a hair dyeing pretreatment agent, a hair dyeing treatment agent, a hair dyeing agent, etc. and applied to the hair.

  In the present invention, the hair dyeing pretreatment agent is not particularly limited as long as it is a composition that can be used by applying to the hair before dyeing, in addition to the anti-fading effect, such as dyeing improvement, stimulation mitigation, damage suppression, touch improvement, etc. It can be used in combination with a composition having both functions.

  In the present invention, the post-hair dyeing treatment agent is not particularly limited as long as it is a composition that can be used by applying to hair after hair dyeing. In addition to the effect of preventing discoloration, the composition has functions such as damage suppression and touch improvement. Can be used together.

  In the present invention, the hair dye is based on direct dyes such as acid dyes, basic dyes, and nitro dyes, and specifically includes hair manicure, hair color rinse, hair color treatment and the like. The dosage form of the hair dye of the present invention is not particularly limited, and it can be used in liquid, emulsion, solid, powdery cosmetics, jelly, gel, paste, mist, spray and the like.

  When blending the anti-fading agent of the present invention into a pre-dyeing agent, post-dyeing agent, or hair dye, the blending amount is not particularly limited, but is preferably 0.001 to 50% by weight, more preferably. 0.005 to 20% by weight.

  The pre-dyeing agent, post-dyeing agent, or hair coloring compounded with the anti-fading agent of the present invention is generally added to hair cosmetics such as oily base, moisturizing agent, touch Improver, surfactant, polymer, thickener / gelator, solvent, propellant, antioxidant, reducing agent, oxidizing agent, preservative, antibacterial agent, chelating agent, pH adjuster, acid, alkali, powder The body, inorganic salts, vitamins and derivatives thereof, hair restoration agents, blood circulation promoters, stimulants, plant / animal / microbe extracts, fragrances, pigments, colorants, dyes, pigments, water, and the like can be blended.

  Examples of oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, ceralkyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexa Higher fatty acids such as cannic acid, anteisohenicosanoic acid, long-chain branched fatty acid, dimer acid, hydrogenated dimer acid, and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium salts, etc. And nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, solid Type hydrocarbons such as candelilla wax, carnauba wax, rice wax, wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, fisher Tropsch wax, polyethylene wax, waxes such as ethylene / propylene copolymer; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut Oil, hazelnut oil, cucumber oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran Vegetable oils such as oil, cacao butter, shea fat, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; animal properties such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle oil Fats and oils; animal waxes such as whale wax, lanolin, orange luffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine, Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids such as sphingomyelin, phospholipids such as phosphatidic acid, lysolecithin; hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, Phospholipid derivatives such as partially hydrogenated egg yolk phospholipids; cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytoster Sterols such as oleol and cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di-N-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl ), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl), N Acyl sarcosine alkyl esters such as lauroyl sarcosine isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phyto Sterol esters such as steryl, phytosteryl isostearate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; phospholipid / cholesterol complex, phospholipid / phytosterol complex, etc. Lipid complex; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl parmitate, octyldodecyl palmitate, cetyl octanoate, hexyl decyl octanoate, isotridecyl isononanoate, isononyl isononanoate, isononanoate Isotridecyl acid, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octeodecanoate Ludodecyl, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, lanolin fatty acid octyldodecyl, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isostearic acid hydrogenated castor oil, ethyl oleate, ethyl avocado oil, isopropyl myristate , Isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyl octyl sebacate, diisobutyl adipate, dioctyl succinate, triethyl citrate, etc. Monoalcohol carboxylic acid esters; cetyl lactate, diisostearyl malate, monoisostearyl Oxyacid esters such as acid hydrogenated castor oil; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri (caprylic / capric), tri (caprylic / capric / myristin) Acid / stearic acid) glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl behenate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, neopentyl glycol dioctanoate , Neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrtetraoctanoate Chill, hydrogenated rosin pentaerythrityl, triethylhexanoic acid ditrimethylolpropane, (isostearic acid / sebacic acid) ditrimethylolpropane, triethylhexanoic acid pentaerythrityl, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, diisostearic acid di Glyceryl, polyglyceryl tetraisostearate, polyglyceryl-10 nonaisostearate, deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate (ethylene glycol distearate) , Dineopentanoic acid 3-methyl-1,5-pentanediol, dineopentanoic acid 2,4-diethyl-1,5-pentane Polyhydric alcohol fatty acid esters such as ol; dimer dilinoleate diisopropyl, dimer dilinoleate diisostearyl, dimer dilinoleate di (isostearyl / phytosteryl), dimer dilinoleate (phytosteryl / behenyl), dimer dilinoleate (Phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleic acid dimer dilinoleyl, diisostearic dimer dilinoleyl, dimer dilinoleyl hydrogenated rosin condensate, dimer dilinoleic acid hydrogenated castor oil, hydroxyalkyl die Dimer acid or dimer diol derivative such as merlinoleyl ether; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), Lauri Acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), coconut oil Fatty acid alkanolamides such as fatty acid methylethanolamide (cocamidomethyl MEA); dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone , Diphenyldimethicone, phenyldimethicone, stearoxypropyldimethylamine, (aminoethylaminopropylmethicone / dimethicone) Polymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, amino-modified silicone such as aminopropyl dimethicone and amodimethicone, cation-modified silicone, polyether-modified silicone such as dimethicone copolyol, polyglycerin-modified silicone, sugar-modified silicone, carvone Acid-modified silicone, phosphoric acid-modified silicone, sulfuric acid-modified silicone, alkyl-modified silicone, fatty acid-modified silicone, alkyl ether-modified silicone, amino acid-modified silicone, peptide-modified silicone, fluorine-modified silicone, cation-modified and polyether-modified silicone, amino-modified and poly-modified Ether-modified silicone, alkyl-modified and polyether-modified silicone, polysiloxane-oxyalkylene copolymer Silicones such as body; perfluorodecane, perfluorooctane, fluorine-based oils such as perfluoropolyether may be mentioned as preferred.

  As the humectant / feel improver, glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc. (Eicosandioic acid / tetradecandioic acid) water-soluble esters such as polyglyceryl-10 and tetradecandioic acid polyglyceryl-10; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, maltitol; glucose, fructose, galactose Mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and maltosylation, Modified cyclodextrins such as hydroxyalkylation), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabinogalactan, dextrin, dextran, glycogen Sugars such as ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer, and derivatives thereof; hyaluronic acid, sodium hyaluronate; chondroitin sulfate sodium; mucoitin sulfate, caroline sulfate, kerato sulfate, dermatan sulfate; white jellyfish extract, white jellyfish Fucoidan; Tuberose polysaccharide, naturally-occurring polysaccharide; Organic acids such as citric acid, tartaric acid and lactic acid and salts thereof; Urea; 2-pyrrolidone-5-carboxylic acid and salts thereof such as sodium; Betaine (trimethylglycine) , Proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methio , Leucine, isoleucine, valine, tryptophan, histidine, taurine and other amino acids and their salts; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen-degrading peptide, hydrolyzed collagen, hydroxypropylammonium hydrolyzed collagen, elastin Degraded peptide, keratin degrading peptide, hydrolyzed keratin, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soy proteolytic peptide, wheat proteolytic peptide, hydrolyzed wheat protein, casein Protein peptides such as degraded peptides and acylated peptides and their derivatives; palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetrapep Acylated peptides such as tide; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesame lignan glycoside, glutathione, albumin, whey; choline chloride, phosphorylcholine; Animal and plant extract components such as placenta extract, aerostin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, Izayoi rose extract, yarrow extract, eucalyptus extract, and melilot extract Preferred are ceramides such as natural ceramides (types 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide, and sugar-ceramide-containing extract.

Preferred examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant. There is no restriction | limiting in particular in HLB of surfactant, It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB. Examples of preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroylglutamate; Cocoyl Glue Acyl amino acid salts such as sodium minate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine; polyoxyethylene alkyl ethers such as sodium laureth acetate Acetic acid salt; Succinic acid ester salt such as sodium lauroyl monoethanolamide succinate; Fatty acid alkanolamide ether carboxylate; Acyl lactate; Polyoxyethylene fatty amine sulfate; Fatty acid alkanolamide sulfate; Hardened coconut oil fatty acid sodium glyceryl sulfate Fatty acid glyceride sulfate such as alkylbenzene polyoxyethylene sulfate; α-olefin Olefin sulfonates such as sodium sulfonate; alkylsulfosuccinates such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate; disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, lauryl polypropylene glycol sulfosuccinic acid Alkyl ether sulfosuccinates such as sodium; alkylbenzene sulfonates such as sodium tetradecylbenzenesulfonate and tetraethanolamine tetraethanol; alkylnaphthalenesulfonates; alkanesulfonates; α-sulfo fatty acid methyl ester salts; Acyl isethionate; alkyl glycidyl ether sulfonate; alkyl sulfoacetate; laurethrin Alkyl ether phosphates such as sodium, sodium dilaureth phosphate, sodium trilaureth phosphate, sodium monooles phosphate; alkyl phosphate salts such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphate; fatty acid amide ether phosphorus Phospholipids such as phosphatidylglycerol, phosphatidylinositol, and phosphatidic acid; silicone anionic surfactants such as carboxylic acid-modified silicone, phosphate-modified silicone, and sulfate-modified silicone; and nonionic surfactants, laureth (Polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether), behenez (polyoxyethylene) Nbehenyl ethers), isosteares (polyoxyethylene isostearyl ethers), octyldecesses (polyoxyethylene octyldodecyl ethers) and other polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers; polyoxyethylene alkylphenyl ethers; Polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearate diester, poly Castor oil such as oxyethylene hydrogenated castor oil maleic acid and hydrogenated castor oil derivatives; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxy Polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxypropylene cetyl ether, polyoxyethylene polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene polyoxypropylene monobutyl ether, polyoxyethylene lanolin; Oxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene alkyl ethers such as polyoxyethylene / polyoxypropylene glycerin ether; polyoxyethylene / polyoxypropylene glycol; (poly) such as PPG-9 diglyceryl Glycerin polyoxypropylene glycol; glyceryl stearate, glyceryl isostearate, glyceryl palmitate, myristate group Glyceryl fatty acid partial esters such as ceryl, glyceryl oleate, glyceryl coconut fatty acid, mono-cotton oil fatty acid glycerin, glyceryl monoerucate, glyceryl sesquioleate, α, α'-oleic acid pyroglutamic acid glycerin, monostearic acid glycerin malic acid; Polyglyceryl stearate-2, 3, 4, 5, 6, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate, polyglyceryl decastearate-10, polyglyceryl isostearate -2, 3, 4, 5, 6, 8, 10, diglycostyl diisostearate (diglyceryl diisostearate), 3, 10, polyglyceryl-2 triisostearate, polyglyceryl tetraisostearate Ril-2, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate, 3,4, 5,6, 8,8, dioleate polyglyceryl-6, trioleate polyglyceryl-2, dekaoleic acid Polyglyceryl fatty acid esters such as polyglyceryl-10; ethylene glycol monofatty acid esters such as ethylene glycol monostearate; propylene glycol monofatty acid esters such as propylene glycol monostearate; pentaerythritol partial fatty acid esters; sorbitol partial fatty acid esters; maltitol moieties Fatty acid ester; maltitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monos Sorbitan fatty acid esters such as allate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; sucrose fatty acid ester, methyl glucoside fatty acid ester, trehalose undecylenate, etc. Partial derivatives of sugar derivatives; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides; lanolin alcohols; reduced lanolin; polyoxyethylene distearate, polyethylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene di- Polyoxyethylene fatty acid mono- and diesters such as oleate; polyoxyethylene propylene glycol fatty acid ester; polyoxyethylene Polyoxyethylene glycerin fatty acid esters such as polyoxyethylene monooleate such as polyglycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate; polyoxyethylene sorbitan monooleate, polyoxy Polyoxyethylene sorbitan fatty acid esters such as ethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol penta Polyoxyethylene sorbitol fatty acid esters such as oleate and polyoxyethylene sorbitol monostearate Polyoxyethylene methyl glucoside fatty acid ester; Polyoxyethylene alkyl ether fatty acid ester; Polyoxyethylene animal and vegetable oils such as polyoxyethylene sorbitol beeswax; Alkyl such as isostearyl glyceryl ether, chimyl alcohol, ceralkyl alcohol, batyl alcohol Glyceryl ethers; polyhydric alcohol alkyl ethers; polyoxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponins and sophorolipids; polyoxyethylene fatty acid amides; coconut oil Fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (laura) De MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), palm oil fatty acid methyl ethanolamide (cocamidomethyl) Fatty acid alkanolamides such as MEA); alkyldimethylamine oxides such as lauramine oxide, cocamamine oxide, stearamine oxide, and behenamine oxide; alkylethoxydimethylamine oxide; polyoxyethylene alkyl mercaptan; poly such as dimethicone copolyol Silicone such as ether-modified silicone, polysiloxane-oxyalkylene copolymer, polyglycerin-modified silicone, sugar-modified silicone Nonionic surfactants, etc .; for cationic surfactants, alkyltrimethylammonium chlorides such as behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, lauryltrimonium chloride; alkyls such as stearyltrimonium bromide Trimethylammonium bromides; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; fatty acid amidoamines and salts thereof such as stearamidepropyldimethylamine and stearamideethyldiethylamine; alkyl ether amines such as stearoxypropyldimethylamine; Salt or quaternary salt thereof; ethyl sulfate long chain branched fatty acid (12-31) aminopropylethyldimethylammonium, ethyl lanolin sulfate Fatty acid amide-type quaternary ammonium salts such as aminopropylethyldimethylammonium fatty acid; polyoxyethylene alkylamine and its salts or quaternary salts; alkylamine salts; fatty acid amidoguanidinium salts; alkyl etheraminemonium salts; Benzalkonium salts; benzethonium salts; pyridinium salts such as cetylpyridinium chloride; imidazolinium salts; alkylisoquinolinium salts; dialkyl morpholinium salts; polyamine fatty acid derivatives; Silicone-based cationic surfactants such as amino-modified silicone, cation-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone; Surfactants include N-alkyl-N, N-dimethylamino acid betaines such as lauryl betaine (lauryldimethylaminoacetic acid betaine); fatty acid amide alkyl-N, N-dimethylamino acid betaines such as cocamidopropyl betaine and lauramidopropyl betaine. Imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkylsulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate; phosphate-type betaines such as alkyldimethylaminoethanolphosphate; phosphatidylcholine , Phosphatidylethanolamine, phosphatidylserine, sphingomyelin and other sphingophospholipids, lysolecithin, hydrogenated soybean phospholipid, partially hydrogenated Phospholipids such as phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, and hydroxylated lecithin; silicone-based amphoteric surfactants; polymer surfactants such as polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum , Acrylic acid / methacrylic acid alkyl copolymer; and various silicone-based surfactants.

Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, chitin , Chitosan, agar, gypsum extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropi Cellulose, carboxymethylcellulose and its salts such as sodium, methylhydroxypropylcellulose, sodium cellulose sulfate, cellulose dialkyldimethylammonium sulfate, crystalline cellulose, cellulose powder such as cellulose powder; soluble starch, carboxymethyl starch, methylhydroxypropyl starch, Starch-based polymers such as methyl starch, starch derivatives such as hydroxypropyltrimonium chloride, octenyl succinate corn starch and aluminum; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), Vinyl pydridone-vinyl alcohol copolymer, polyvinyl methyl ether Polyethylene glycol, polypropylene glycol, polyoxyethylene / polyoxypropylene copolymer; amphoteric methacrylic acid such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer, etc. Ester copolymer; (Dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; Polyvinyl acetate partial saponification product, maleic acid copolymer; Vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; Kurylamide; Polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; acrylic acid / alkyl methacrylate Polymer: Cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, and acrylic acid such as polyquaternium-39・ Diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylic acid amide copolymer, polyquaternium Acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer such as 47, methacrylic acid choline ester polymer; cationized polysaccharides such as cationized oligosaccharide, cationized dextran, guar hydroxypropyltrimonium chloride; Polyethyleneimine; Cationic polymer; Polymer of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymer with butyl methacrylate copolymer; Acrylic resin emulsion, polyethyl acrylate emulsion, polyacrylalkyl ester emulsion, Polymer emulsions such as polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex; nitrocellulose; polyurethanes and various copolymers; various silicones Various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, Smoke-like silica (ultrafine silicic anhydride), aluminum magnesium silicate, magnesium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester It is mentioned as preferable.

Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate , Acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation flon; propellants such as LPG, dimethyl ether, carbon dioxide, and the like are preferable.

  Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned. Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

  Antibacterial agents or antiseptics include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane 1,2-alkanediols such as diol; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); salicylic acid; sodium benzoate; isothiazoline derivatives such as methyl chloroisothiazolinone and methylisothiazolinone; Dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzoyl chloride Luconium, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol; other phenols such as phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol , Photosensitizers, antibacterial zeolite, and silver ion are preferable, but when used as an antibacterial agent or antiseptic agent for antiseptic purposes, phenoxyethanol; 1 from the viewpoint of safety of cosmetics or skin external preparations; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol; alkyl glyceres such as 2-ethylhexyl glyceryl ether It is more preferred to use ethers.

  Examples of chelating agents include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.

  Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide, fine particles and ultrafine Titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silica), titanium mica, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, fine particle composite powder Body, gold, aluminum, etc., various sizes and shapes of inorganic powders, and these are treated with various surface treatment agents such as hydrogen silicone, cyclic hydrogen silicone, or other silane or titanium coupling agents Inorganic powders such as hydrophobized or hydrophilized powders; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, polyester powder, Benzoguanamine resin powder, polyethylene terephthalate, polymethyl Organic powders and surface-treated powders of various sizes and shapes, such as methacrylate powder, polyethylene terephthalate / aluminum / epoxy powder, urethane powder, silicone powder, Teflon (registered trademark) powder, organic-inorganic composite powder Is preferable. Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.

  Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt; Ascorbic acid fatty acid esters such as corobic acid tetraisopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate and ascorbyl dipalmitate, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and Ascorbic acid derivatives such as fatty acid esters and tocopheryl phosphate ascorbyl; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol acetate, tocopherol linoleate, tocopherol phosphate, tocopherol phosphate etc., tocotrienol, and other various vitamin derivatives Is preferable.

  Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, cephalanthin, vitamin E and nicotinic acid tocopherol, acetic acid tocopherol and other derivatives, γ-oryzanol, nicotinic acid, nicotinic acid amide, nicotinic acid benzyl Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives, stigmasterol or stigmasteranol, its glycosides, and minoxidil.

  As plant / animal / microbe extracts, Iris extract, Ashitaba extract, Asunaro extract, Asparagus extract, Avocado extract, Achacha extract, Almond extract, Altea extract, Arnica extract, Aloe extract, Apricot extract, Ginkgo biloba extract, Ginkgo biloba extract , Incheon extract, Fennel extract, Turmeric extract, Oolong tea extract, Peony extract, Ages extract, Echinacea leaf extract, Enmeo extract, Ogon extract, Oat extract, Auren extract, Barley extract, Panax ginseng extract, Hypericum extract, Odori extract , Dutch mustard extract, orange extract, dried sea water, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolysis Luc, Cascon extract, Chamomile extract, Oil-soluble chamomile extract, Carrot extract, Kawara mugi extract, Oat extract, Calcade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Cyprid extract, Quina extract, Cucumber extract, Kiri leaf extract, Guanosine, guava extract, cucumber extract, gardenia extract, kumazasa extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, Gentian pepper extract, tea Extract, yeast extract, kokuboku extract, coffee extract, burdock extract, rice extract, rice fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, Lagen, Cowberry extract, Saishin extract, Psycho extract, Saitai extract, Saffron extract, Salvia extract, Salmon extract, Sasa extract, Hawthorn extract, Sansha extract, Salamander extract, Shiitake extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Shimosukeso Extract, jatoba extract, peonies extract, ginger cucumber extract, ginger root extract, white birch extract, white jellyfish extract, horsetail extract, stevia extract, stevia fermented product, west river willow extract, horse chestnut extract, hawthorn extract, elderberry extract, yarrow extract , Mint extract, sage extract, mallow extract, nematode extract, essence extract, Sakuhakuhi extract, Diou extract, Dai Extract, peanut extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, tea tea extract, red pepper extract, red snapper extract, red snapper extract, red spruce extract, red spruce extract, tomato Extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, bacmond extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietalia extract, hyacinth extract, bisabolol, cypress extract, bifidobacteria extract, Loquat extract, dandelion extract, burdock extract, bukkuri extract, butcher bloom extract, grape extract, grape seed extract, propolis, loofah extract, Safflower extract, peppermint extract, body extract, button extract, hop extract, squid extract, pine extract, maroonnier extract, mizubasho extract, mukuroji extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, yukinoshita extract, yuzu extract, lily extract, Yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, litchi extract, lettuce extract, lemon extract, forsythia extract, forsythia extract, rose extract, rosemary extract, roman chamomile extract, royal jelly Extracts such as an extract and a bitumen extract are preferred.

  As perfumes, acetyl cedrene, amylcinnamaldehyde, allyl amyl glycolate, β-ionone, iso-Esuper, isobutyl quinoline, Iris oil, Iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, auranthiol, galac solid, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile , Isobornyl acetate, geranyl acetate, dimethylbenzyl carvinyl acetate, styrylyl acetate, cedolyl acetate, terpinel acetate, pt-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, vinegar Linalyl, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citronellal, Cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascon, damassenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, Tripral, Nellore, Nonanal, 2,6-Nonadienol, Nonalactone, Patchouli alcohol, Vanilla absolute , Vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitglen oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian valsum, vetiver oil, vetiverol, peppermint oil, Pepper oil, heliotropin, red 223, red 225, red 226, red 227, red 228, yh red 230-1, red 230-2, red 231, red 232, red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505, Red 506, Orange 201, Orange 203, Orange 204 , Orange 205, Orange 206, Orange 207, Orange 401, Orange 402, Orange 403, Yellow 201, Yellow 202-1, Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow Legal dyes such as 404, Yellow 405, Yellow 406, Yellow 407, Yellow 5; Other acid dyes such as Acid Red 14; Bases such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow Dyes: HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2, Basic Blue 26, etc. Disperse dyes; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (Bengara) and iron titanate; inorganic brown pigments such as γ-iron oxide; yellow iron oxide and ocher Inorganic yellow pigments such as black iron oxide and low-order titanium oxide inorganic black pigments such as man Inorganic purple pigments such as violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium oxide coated mica, titanium oxide coated bismuth oxychloride, Pearl pigments such as titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil; metal powder pigments such as aluminum powder, copper powder and gold; surface treatment inorganic and metal powder pigments; red 201 and red 202 , Red 204, red 205, red 220, red 226, red 228, red 405, orange 203, orange 204, yellow 205, yellow 401, blue 404, red 3, red 104, Red 106, Red 227, Red 230, Red 401 Organic pigments such as zirconium, barium or aluminum lakes such as red No. 505, orange No. 205, yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, green No. 3 and blue No. 1; surface-treated organic pigments; Anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsanthin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, cochineal, shikonin and other naphthoquinones, bixins, flavones, betacyanidine, henna, hemoglobin, Natural pigments / dyes such as lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol , Resorcin 1-naphthol, 2,6-oxidative dye intermediates and couplers of diaminopyridine and the like, and the like salts thereof; autoxidation dye indoline and the like; dihydroxyacetone may be mentioned as preferred.

  Preferred examples of water include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and clustered water.

  In addition to these, cosmetic raw material standards, blending ingredient standard by cosmetic varieties, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), quasi-drug raw material standards, Japanese pharmacopoeia, pharmaceutical additives Ingredients listed in standards, official food additives, etc., and Japanese and foreign patent publications and patent publications (including publications and republications) in which the international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the ingredients described, in known combinations, blending ratios and blending amounts.

EXAMPLES Hereinafter, although this invention is demonstrated in detail using an Example, this invention is not limited to these Examples. In this example, the infrared absorption spectrum was measured using IRAffinity-1 manufactured by Shimadzu Corporation. The ¹ H-NMR spectrum was measured using JNM-AL (300 MHz) manufactured by JEOL Ltd. and deuterated methanol as a solvent.

Synthesis Example 1 Synthesis of γ-ercalactone (4-hydroxydocosanoic acid γ-lactone) In a 200 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 16.9 g (0.0500 mol) of erucic acid, 10.1 g (0.100 mol) of sulfuric acid was charged and reacted at 85 ° C. for 6 hours under a nitrogen atmosphere. The obtained reaction solution was charged with 50 g of water, 118 g of heptane, 4% sodium hydroxide, the target product was extracted into a heptane phase, deoxidized with 2% sodium hydroxide solution, and washed with water three times. The heptane phase was concentrated under reduced pressure to obtain 3.4 g of the objective compound as a solid. The obtained solid was a white solid (infrared absorption spectrum (KBr tablet method): 2918, 2851, 1753, 1468, 1188 cm ⁻¹ ). It was subjected to structural confirmed by ^{1 H-NMR} spectrum for the compound was confirmed to be a compound represented by the following general formula (assignment numbers of the ^{1 H-NMR} spectrum in the formula, attribution Table 1 Showing).

Synthesis Example 2 Synthesis of γ-stearolactone (4-hydroxyoctadecanoic acid γ-lactone) To a 200 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube, oleic acid (trade name, LUNAC O-LL, manufactured by Kao Corporation) was prepared. -V) 14.1 g (0.0500 mol) of concentrated sulfuric acid and 10.1 g (0.100 mol) of concentrated sulfuric acid were charged and reacted at 85 ° C. for 6 hours in a nitrogen atmosphere. 50 g of water, 99 g of heptane, and 4% sodium hydroxide were charged into the resulting reaction solution, and the target product was extracted into a heptane phase. After deoxidation with 2% sodium hydroxide solution, washing with water was performed three times. The heptane phase was concentrated under reduced pressure to obtain 2.6 g of the objective compound as a solid. The obtained solid was a white solid (infrared absorption spectrum (KBr tablet method) 2920, 2851, 1753, 1470, 1190 cm ⁻¹ ). It was subjected to structural confirmed by ^{1 H-NMR} spectrum for the compound was confirmed to be a compound represented by the following general formula (assignment numbers of the ^{1 H-NMR} spectrum in the formula, attribution Table 2 Showing).

  The hair oil which mix | blended the synthesis example 1, the synthesis example 2, or (delta) -tetradecanolactone (made by Wako Pure Chemical Industries) which is a lactone derivative of this invention with the composition of Table 3 was produced.

<Anti-fading effect of hair dyed with hair manicure (pretreatment)>
Using hair oils of Examples 1 to 3 and Comparative Example 1 in Table 3 as pre-dyeing agents, the anti-fading effect of hair dyed with hair nail polish was evaluated. The test was performed as follows and the results are listed in Table 4.

(Fabric production)
After uniformly applying 0.2 g of the hair oil of Example 1 to a hair bundle of human white hair (1 g × 10 cm, manufactured by Beaulux Co., Ltd.), it was dried with cold air from a dryer to obtain a hair bundle A1. Further, the hair bundle A1 was heat-treated with warm air from a dryer for 3 minutes to obtain a hair bundle B1. Similarly, hair bundles A2 and B2 using the hair oil of Example 2, hair bundles A3 and B3 using the hair oil of Example 3, and hair bundles A4 and B4 using the hair oil of Comparative Example 1 were produced. About each produced hair bundle, 0.6g of commercially available hair manicure (Kao company make, Brone hair manicure natural black) was apply | coated, and it was left to stand at about 25 degreeC for 60 minutes, Then, it wash | cleaned by 3% laureth sulfate Na aqueous solution. About each dyed hair bundle, the fading prevention effect was evaluated from the color difference of the hair before and after washing using the method described below.

(Evaluation method of anti-fading effect)
The hue (L ^* , a ^* , b ^* value) of each hair bundle produced above was measured with a color difference meter (Nippon Denshoku ZE6000) (before washing). After the measurement, each hair bundle was immersed in a 3% aqueous laureth sulfate solution heated to 40 ° C. for 30 minutes, and then the color of the hair bundle rinsed and dried with running water was measured again with a color difference meter (after washing). The color difference ΔE ^* of the hair bundle before and after washing was calculated and the anti-fading effect was evaluated according to the following evaluation criteria (ΔE ^* = {(ΔL ^* ) ² + (Δa ^* ) ² + (Δb ^* ) ² } ^{1 / 2} ).

Evaluation criteria ○: ΔE ^* is 0 or more and less than 3.0 ··· There is almost no color difference (there is little discoloration)
Δ: ΔE ^* is 3.0 or more and less than 6.0 ... there is a little difference in color (there is a slight discoloration)
×: ΔE ^* is 6.0 or more ············· There is a considerable color difference (amber color is large)

<Anti-fading effect of hair dyed with hair manicure (post treatment)>
Using hair oils of Examples 1 to 3 and Comparative Example 1 in Table 3 as post-dyeing treatment agents, the effect of preventing discoloration of hair dyed with hair manicure was evaluated. The test was performed as follows and the results are listed in Table 5.

(Fabric production)
After applying 0.6 g of commercially available hair nail polish (manufactured by Kao Corporation, Brone Hair Nail Polish Natural Black) to a hair bundle of human white hair (1 g × 10 cm, manufactured by Beaulux), left at about 25 ° C. for 60 minutes, then 3% Washed with sodium laureth sulfate. After 0.2 g of the hair oil of Example 1 was uniformly applied to the dyed hair bundle, it was dried with cold air from a dryer to obtain a hair bundle C1. Further, the C1 hair bundle was heat-treated with warm air from a dryer for 3 minutes to obtain a hair bundle D1. In the same manner, hair bundles C2 and D2 were produced using the hair oil of Example 2, hair bundles C3 and D3 were produced using the hair oil of Example 3, and hair bundles C4 and D4 were produced using the hair oil of Comparative Example 1. About each produced hair bundle, the fading prevention effect was evaluated from the color difference of the hair before and behind washing | cleaning using the above-mentioned method.

<Anti-fading effect of hair dyed by hair color treatment (pretreatment)>
The hair oils of Examples 1 to 3 and Comparative Example 1 in Table 3 were used as hair dyeing pretreatment agents, and the anti-fading effect of hair dyed by hair color treatment was evaluated. The test was performed as follows and the results are listed in Table 6.

(Fabric production)
After uniformly applying 0.2 g of the hair oil of Example 1 to a hair bundle of human white hair (1 g × 10 cm, manufactured by Beaulux), it was dried with cold air from a dryer to obtain a hair bundle E1. Further, the hair bundle E1 was heat-treated with warm air from a dryer for 3 minutes to obtain a hair bundle F1. In the same manner, hair bundles E2 and F2 using the hair oil of Example 2, hair bundles E3 and F3 using the hair oil of Example 3, and hair bundles E4 and F4 using the hair oil of Comparative Example 1 were produced. About each hair bundle produced, 0.6 g of a commercially available hair color treatment (Siero Color Treatment Natural Black manufactured by Hoyu Co., Ltd.) was applied, left at about 25 ° C. for 60 minutes, and then rinsed with running water until no color appeared. About each dyed hair bundle, the anti-fading effect was evaluated from the color difference of the hair before and after washing using the above-described method.

<Anti-fading effect of hair dyed by hair color treatment (post-treatment)>
Using hair oils of Examples 1 to 3 and Comparative Example 1 in Table 3 as post-dyeing treatment agents, the anti-fading effect of hair dyed by hair color treatment was evaluated. The test was conducted as follows and the results are listed in Table 7.

(Fabric production)
After applying 0.6g of a commercially available hair color treatment (Ciel Color Treatment Natural Black, manufactured by Hoyu Co., Ltd.) to a hair bundle of human white hair (1g x 10cm, manufactured by Beaulux), the color is Rinse with running water until it stops. The hair oil of Example 1 was added to the dyed hair bundle. After 2 g was uniformly applied, it was dried with cold air from a dryer to obtain a hair bundle G1. In addition, the hair bundle G1 was heat-treated with warm air from a dryer for 3 minutes to obtain a hair bundle H1. In the same manner, hair bundles G2 and H2 were produced using the hair oil of Example 2, hair bundles G3 and H3 were produced using the hair oil of Example 3, and hair bundles G4 and H4 were produced using the hair oil of Comparative Example 1. About each produced hair bundle, the fading prevention effect was evaluated from the color difference of the hair before and behind washing | cleaning using the above-mentioned method.

<Anti-fading effect of hair dyed with oxidative hair dye (pretreatment)>
The hair oils of Examples 1 to 3 and Comparative Example 1 in Table 3 were used as hair dyeing pretreatment agents, and the anti-fading effect of hair dyed with an oxidative hair dye was evaluated. The test was conducted as follows and the results are listed in Table 8.

(Fabric production)
After uniformly applying 0.2 g of the hair oil of Example 1 to a hair bundle of human white hair (1 g × 10 cm, manufactured by Beaulux), it was dried with cold air from a dryer to obtain a hair bundle J1. Further, the hair bundle of J1 was heat-treated with warm air from a dryer for 3 minutes to obtain a hair bundle K1. Similarly, hair bundles J2 and K2 were produced using the hair oil of Example 2, hair bundles J3 and K3 were produced using the hair oil of Example 3, and hair bundles J4 and K4 were produced using the hair oil of Comparative Example 1. About each produced hair bundle, 0.6g of commercially available oxidative hair dye (Rasana hair color by Yamasaki Co., Ltd.) was apply | coated, and it was left to stand at about 25 degreeC for 30 minutes, Then, it wash | cleaned by 3% laureth sulfate Na aqueous solution. About each dyed hair bundle, the anti-fading effect was evaluated from the color difference of the hair before and after washing using the above-described method.

<Anti-fading effect of hair dyed with oxidative hair dye (post treatment)>
Using hair oils of Examples 1 to 3 and Comparative Example 1 in Table 3 as post-dyeing agents, the anti-fading effect of hair dyed with an oxidative hair dye was evaluated. The test was performed as follows and the results are listed in Table 9.

(Fabric production)
After applying 0.6 g of a commercially available oxidative hair dye (Rasana Hair Color, manufactured by Yamasaki Co., Ltd.) to a hair bundle of human white hair (1 g × 10 cm, manufactured by Beaulux Co., Ltd.) and leaving it at about 25 ° C. for 30 minutes, 3% laureth Washed with aqueous sodium sulfate. After 0.2 g of the hair oil of Example 1 was uniformly applied to the dyed hair bundle, it was dried with cold air from a dryer to obtain a hair bundle L1. In addition, the hair bundle of L1 was heat-treated with warm air from a dryer for 3 minutes to obtain a hair bundle M1. Similarly, hair bundles L2 and M2 using the hair oil of Example 2, hair bundles L3 and M3 using the hair oil of Example 3, and hair bundles L4 and M4 using the hair oil of Comparative Example 1 were produced. About each produced hair bundle, the fading prevention effect was evaluated from the color difference of the hair before and behind washing | cleaning using the above-mentioned method.

From the above results, the anti-fading agent of the present invention is applied to the hair dyed with hair manicure, hair color treatment and oxidative hair dye before or after dyeing. It has been found that by performing the heat treatment, an excellent anti-fading effect is exhibited as compared with the case where the anti-fading agent is not blended or the case where no heat treatment is performed.

<Anti-fading effect of hair dyed with hair color treatments containing anti-fading agent>
A hair color treatment having the composition shown in Table 10 and incorporating the anti-fading agent of the present invention was prepared (Example 4). For comparison, a hair color treatment containing no anti-fading agent of the present invention was prepared (Comparative Example 2). About the hair dye | stained using these hair color treatments, the fading prevention effect was evaluated as follows. The results are also shown in Table 10.

(Fabric production)
Applying 0.6 g of the hair color treatment of Example 4 or Comparative Example 2 to a hair bundle of human white hair (1 g × 10 cm, manufactured by Beaulux), leaving it at about 25 ° C. for 60 minutes, and running water until no color appears. Rinse. The rinsed hair bundle was dried with hot air from a dryer and heat-treated. About the produced hair | bristle bundle, the fading prevention effect was evaluated from the color difference of the hair before and behind washing | cleaning using the above-mentioned method.

From the above results, it was found that the hair color treatment in which the anti-fading agent of the present invention was blended exhibited an excellent anti-fading effect as compared with the case without blending.

Example 5 Hair dye pretreatment agent A hair dye pretreatment agent having the following formulation was prepared. By applying this pretreatment agent to the hair before dyeing and heating, excellent dyeability and anti-fading effect were obtained. Moreover, the hair was prevented from being entangled during washing, and the hair was given elasticity and unity.

Component Blending amount (% by weight)
--------------------------------------
Part A Compound of Synthesis Example 1 0.5
Dimethicone (2cs) 4.0
Diisopropyl sebacate 0.5
Ethanol 15.0
Part B Cyclopentasiloxane 10.0
Dimethiconol 1.0
Camellia oil 0.5
Cyclohexanedicarboxylic acid bisethoxydiglycol 0.2
(Neosolu-Aquorio: Nippon Seika)
Isodecyl neopentanoate 3.0
Phenyltrimethicone 3.0
Caprylyl Methicone 1.0
Dimethicone (2cs) Total amount to be 100 Perfume Suitable amount ------------------------------------ −
(Preparation method)
Part A is mixed and dissolved in advance. Each raw material of part B was weighed, heated to about 70 ° C. and dissolved uniformly, and then part A was added, followed by cooling with stirring.

Example 6 Hair dye pretreatment agent A hair dye pretreatment agent having the following formulation was prepared. By applying this pretreatment agent to the hair before dyeing and heating, excellent dyeability and anti-fading effect were obtained. Moreover, the hair was prevented from being entangled during washing, and the hair was given elasticity and unity.

Component Blending amount (% by weight)
------------------------------------
Part A Compound of Synthesis Example 1 0.05
Distearyldimonium chloride 0.6
Behentrimonium chloride 0.3
Propanediol 8.0
Phytosterol 0.1
Purified water 20.0
Part B Ethanol 15.0
Glycerin 2.0
Phenoxyethanol 0.5
Part C glycosyl trehalose 0.3
Benzoic acid Na 0.2
EDTA-2Na 0.05
Hydrolyzed hydrogenated starch 0.3
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A other than purified water was heated to about 80 ° C. and added to purified water heated to 80 ° C. while stirring with a homomixer to prepare a mixed solution. Part B and part C were taken and heated to about 60 ° C. to make it uniform. The part B was added to the part C to make it uniform, and then cooled. Part A was added at around 40 ° C. to make it uniform.

Example 7 Hair dyeing post-treatment agent A hair dyeing post-treatment agent having the following formulation was prepared. This post-treatment agent was excellent in the effect of preventing fading of the dyed hair, prevented tangling of the hair during washing, and imparted firmness and unity to the hair.

Component Blending amount (% by weight)
--------------------------------------
Compound of Synthesis Example 2 10.0
Olive oil 5.5
Macadamia nut oil 4.5
Dimethicone (50cs) 3.5
Ethyl hexyl methoxycinnamate 2.0
Ethylparaben 0.05
Lanolin fatty acid octyldodecyl 1.0
(YOFCO FE-1SS: Nippon Seika)
Macadamia nut fatty acid phytosteryl 0.2
(Plandool-MAS: Nippon Seika)
Ethyl oleate 3.0
Avocado oil fatty acid ethyl 2.0
Methylheptyl isostearate 3.0
Japanese radish seed oil 1.0
Cetyl lactate 1.0
Ascorbyl tetrahexyldecanoate 0.01
Squalane 3.0
Tocopherol acetate 0.05
Isododecane Total amount of 100 --------------------------------------
(Preparation method)
Each raw material was weighed, heated to about 70 ° C. and dissolved uniformly, and then cooled with stirring.

Example 8 Hair dyeing post-treatment agent A hair dyeing post-treatment agent having the following formulation was prepared. This post-treatment agent was excellent in anti-fading effect of the dyed hair, imparted a moderate moist feeling, cohesion, and harshness to the hair, and suppressed undulation and entanglement. Moreover, the effect lasted even after washing.

Component Blending amount (% by weight)
------------------------------------
Part A stealtrimonium chloride (70%) 0.8
Cetrimonium chloride (70%) 0.2
Stearyl alcohol 5.5
Isopropyl palmitate 1.0
Sunflower seed oil 0.5
Cottonseed oil 0.5
Dimethicone (1 million cs) 0.1
Dimethicone (10cs) 1.0
Glycerol monostearate1.0
Dimer linoleic acid Dimer linoleyl 40% MCT solution 0.3
(LUSPLAN SR-DM4: Nippon Seika)

Part B Purified water Amount to be 100 in total Propynyl iodide butylcarbamate 0.01
Part C Compound of Synthesis Example 1 0.05
Dicocodimonium chloride 1.5
Quotanium-33 (Cation NH: Nippon Seika) 0.5
DPG 7.0
Cholesterol 0.05
Purified water 20.0
------------------------------------
(Preparation method)
Part C other than purified water was heated to about 80 ° C. and added to purified water heated to 80 ° C. while stirring with a homomixer to prepare a mixed solution. Part A and part B were taken and heated to about 60 ° C. to make it uniform. While stirring, part B was added to part A and cooled. C part was added at around 40 ° C. to make it uniform.

Example 9 Hair Nail Polish A hair nail polish having the following formulation was prepared. This hair manicure has excellent dyeability and anti-fading effect, imparts a moist and harsh feel to the hair, and suppresses undulation and entanglement. Moreover, the effect was that the lasting effect was exhibited by blowing with a dryer after washing.

Component Blending amount (% by weight)
------------------------------------
Part A Compound of Synthesis Example 1 0.5
Diethyl sebacate 1.5
Ethanol 10.0
B part purple 401 0.2
Black 401 0.1
Orange 205 0.1
Red 102 0.1
Citric acid 2.0
Benzyl alcohol 8.0
Ethanol 10.0
Part C Purified water Amount of total 100 (Ammonium acryloyldimethyltaurate / VP) Copolymer 3.0
Glycolic acid 2.0
------------------------------------
(Preparation method)
A part and C part were mixed and made uniform. After stirring to Part B and adding to Part C and mixing uniformly, Part A was added at about 40 ° C. and mixed uniformly.

Example 10 Hair nail polish A hair nail polish having the following formulation was prepared. This hair manicure has excellent dyeability and anti-fading effect, imparts a moist and harsh feel to the hair, and suppresses undulation and entanglement. Moreover, the effect was that the lasting effect was exhibited by blowing with a dryer after washing.

Component Blending amount (% by weight)
------------------------------------
Part A Compound of Synthesis Example 2 0.01
Cyclopentasiloxane 0.99
Ethanol 10.0
B part purple 401 0.1
Black 401 0.1
Orange 205 0.09
Green 204 0.01
Yellow 403 0.005
Blue 1 0.05
EDTA-2Na 0.1
Lactic acid 3.0
Ethyl lactate 1.0
γ-Caprolactone 3.0
Ethanol 10.0
Part C Purified water Total amount of 100 (hydroxyethyl acrylate / acryloyldimethyltaurine Na) copolymer
1.0
Stearoxypropyl methylcellulose 0.8
PEG-90M 0.1
------------------------------------
(Preparation method)
A part and C part were mixed and made uniform. After stirring to Part B and adding to Part C and mixing uniformly, Part A was added at about 40 ° C. and mixed uniformly.

Example 11 Hair Color Treatment A hair color treatment having the following formulation and not washed off was prepared. This hair color treatment was excellent in dyeability and hair discoloration preventing effect. Moreover, the effect was that the lasting effect was exhibited by blowing with a dryer after washing.

Component Blending amount (% by weight)
--------------------------------------
Part A Compound of Synthesis Example 1 0.1
Cetanol 3.9
Part B Cyclohexanedicarboxylic acid bisethoxydiglycol 1.0
(Neosolu-Aquorio: Nippon Seika)
Dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl /
Behenyl) (Plandool-H: Nippon Seika) 0.5
Cetrimonium chloride (25%) 2.5
Quotanium-33 (cation NH: Nippon Seika) 0.3
Caprylyl glucoside (50%) 0.3
(Sucraft AG-8: Nippon Seika)
Hydrogenated lecithin / soybean sterol complex 0.5
(Phytocompo-PP: Nippon Seika)
Lanolin 1.0
Glycerin 4.0
Setes-7 1.0
Isostearyl alcohol 0.3
Rice bran oil 0.5
Dimethicone (50cs) 0.5
Dimethicone (6cs) 0.5
Hydrogenated polydecene 0.1
Macadamia nut fatty acid ethyl 1.0
Tocopherol 0.05
Phenoxyethanol 0.3
Part C purified water 10.0
Ethanol 10.0
Hydrolyzed conchiolin 0.1
Panthenol 0.1
Hyaluronic acid crosspolymer Na 0.01
Polyquaternium-49 0.2
Polyquaternium-7 0.4
White jellyfish polysaccharide 1% solution (Tremoist-SL: Nippon Seika) 5.0
PCA-Na 0.1
Gardenia extract 0.05
Part D Purified water Total amount of 100 Basic Blue 99 0.1
Basic tea 16 0.13
HC Blue 2 0.05
HC yellow 2 0.03
HC red 3 0.1
--------------------------------------
(Preparation method)
Part A, which had been uniformly mixed in advance, was added to part B and heated to about 80 ° C. to dissolve (part E). In a separate container, part D was heated to about 80 ° C. and dissolved. While stirring D part to E part, it was gradually added and mixed uniformly, and then rapidly cooled (part F). C part was added to F part which became about 40 ° C. to make it uniform.

Example 12 Hair Color Treatment A hair color treatment having the following formulation was prepared. This treatment has excellent dyeability and anti-fading effect, imparts a moist and firm feeling to the hair, and suppresses undulation and entanglement. The effect was sustained after shampooing by blowing with a dryer after applying the treatment.

Component Blending amount (% by weight)
--------------------------------------
Part A Compound of Synthesis Example 1 0.3
Stearyl alcohol 3.0
Part B steartrimonium chloride (70%) 1.5
Glyceryl stearate 1.0
Cocamidomethyl MEA 1.0
YOFCO CLE-S (Nippon Seika) 0.5
Lauroyl glutamate (octyldodecyl / phytosteryl / behenyl)
(Plandool-LG1: Nippon Seika) 0.3
Shea fat 0.5
Dimethicone (50cs) 2.0
Phenoxyethanol 0.5
Cocamidomethyl MEA 0.5
Part C Hydroxyethylcellulose 0.5
Purified water A total of 100 parts D
BG 1.0
Basic yellow 57 0.1
Basic red 76 0.05
HC Blue 2 0.15
HC yellow 4 0.03
Ammonium carbonate 0.8
HC red 3 0.01
Gardenia Blue 0.05
4-Hydroxypropylamino-3-nitrophenol 0.05
Purified water 20.0
--------------------------------------
(Preparation method)
Part A, which had been uniformly mixed in advance, was added to part B and heated to about 80 ° C. to dissolve (part E). In a separate container, part C was heated to about 80 ° C. and dissolved. The part C was gradually added to the part E with stirring and mixed uniformly, and then rapidly cooled (part F). D part was added to F part which became about 40 ° C. to make it uniform.

Example 13 Hair dyeing post-treatment agent A hair dyeing post-treatment agent having the following formulation was prepared. This post-treatment agent was excellent in fading prevention effect and damage care effect of dyed hair, and suppressed waviness and entanglement of hair and improved combing. The effect was sustained after shampooing by blowing with a dryer after applying the treatment.

Component Blending amount (% by weight)
--------------------------------------
Part A Compound of Synthesis Example 1 2.0
Camellia oil 2.0
Part B steartrimonium chloride 0.6
Stearyl alcohol 1.5
Myristyl alcohol 0.3
Cetyl ethylhexanoate 0.5
PG 3.0
Phenoxyethanol 0.2
Part A Amodimethicone 1.0
Glycine 0.05
Glutamic acid 0.05
Proline 0.1
Betaine 0.3
(Eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10 1.0
(Neosolu-AquaS: Nippon Seika)
Purified water 10.0
Part D Guar hydroxypropyltrimonium chloride 0.2
Glycerin 2.0
Lactic acid 0.05
Purified water Total amount of 100 --------------------------------------
(Preparation method)
Part A, which had been uniformly mixed in advance, was added to part B and heated to about 70 ° C. to dissolve (part E). In a separate container, part D was heated to about 80 ° C. and dissolved. While stirring D part to E part, it was gradually added and mixed uniformly, and then rapidly cooled (part F). C part was added to F part which became about 40 ° C. to make it uniform.

Claims (8)

An anti-fading agent for dyed hair, which contains a lactone derivative represented by the following general formula (1).

(In the formula, n is 1 or 2, and R represents a linear or branched saturated or unsaturated hydrocarbon group having 9 to 22 carbon atoms)   A method for preventing discoloration of dyed hair, which comprises applying the antifading agent according to claim 1 to hair and performing heat treatment.   A method for preventing discoloration of dyed hair, which comprises applying the anti-fading agent according to claim 1 to hair before the hair dyeing treatment and applying heat treatment.   A method for preventing discoloration of dyed hair, which comprises applying the anti-fading agent according to claim 1 to hair after hair dyeing and applying heat treatment.   A method for preventing discoloration of dyed hair, which comprises applying a hair dye containing the discoloration preventing agent according to claim 1 to the hair and applying heat treatment thereto.   A hair dyeing pretreatment agent comprising the anti-fading agent according to claim 1.   A hair dyeing post-treatment agent comprising the antifading agent according to claim 1.   A hair dye containing the anti-fading agent according to claim 1.