JP5214102B2 - Cosmetics for cleansing - Google Patents

Description

The present invention relates to a cleansing cosmetic composition, more particularly to useful cleansing cosmetic composition for you remove mascara cosmetic to form a coating film having excellent water.

In makeup cosmetics, it has been a long-standing challenge to maintain the initial finish for a long time. Recently, with respect to this problem, (see e.g., Patent Document 1) by using an acrylic resin emulsion, a technique for improving the makeup and water resistance that has been developed. With the development of this technology, the “raccoonization phenomenon” in which the mascara collapses due to sweat, etc., and the mascara pigment scatters around the eyes and the surroundings of the eyes become black has been resolved. However, it took a great deal of effort to remove the mascara once applied, and there was a case where a physical stimulus was applied to the periphery of the eye by this effort. This phenomenon remains a problem that remains even when mascara-specific cosmetics are developed. That is, there has been a demand for a makeup system that does not cause makeup collapse when using mascara and that can be removed safely and without much effort when it is desired to remove it.

  On the other hand, as means for removing makeup cosmetics having excellent water resistance, for example, liquid cleansing cosmetics using the solvent characteristics of alkylene glycol have been developed (see, for example, Patent Document 2). With such cosmetics, it can be easily removed if it is only a coating agent, but such cosmetics are also effective in the composite of wax, fats and oils such as mascara. I could not do it. The major cause is considered to be that the hydrophobicity of the resin inhibits the penetration of the cosmetic into the coating.

In addition, caprylic acid and / or capric acid polyhydric alcohol ester is used as an oily base material in cosmetics, in particular emulsified cosmetics, and for the purpose of improving spreading at the time of application in the cosmetics. that it has been formulated (see, for example, Patent Document 3, Patent Document 4, Patent Document 5, Patent Document 6, Patent Document 7). However, the use in the cleansing cosmetic composition for mascara removal to was not known, the cleansing cosmetic composition for mascara removed which contain such component, and contains an acrylic resin as a film-forming agent, emulsifier type Nor was it known to be suitable for dropping a mascara.

JP 2003-040734 A JP 2004-269404 A Japanese Patent Laying-Open No. 2005-053822 JP 2004-307353 A Japanese Patent Laid-Open No. 2004-210649 Japanese Patent Application Laid-Open No. 2004-075540 Special table 2003-500343 gazette

  The present invention has been made under such circumstances, and it is an object of the present invention to provide a technique that can safely remove an emulsified mascara having water resistance without taking great effort when it is desired to remove it. .

In view of such a situation, the present inventors have made intensive research efforts in search of a technology that can safely and safely drop emulsified mascara having water resistance without significant efforts. As a result, it has been found that a cosmetic containing a specific caprylic acid and / or a polyhydric alcohol ester of capric acid and an oil agent has such characteristics, and has completed the invention. That is, the present invention is as follows.
(1) A cleansing cosmetic for removing emulsified mascara containing an acrylic resin as a film forming agent, 1) propylene glycol ester or glycerin ester of caprylic acid and / or capric acid, and 2) acylated glutamic acid diester A cleansing cosmetic comprising 0.1 to 10% by mass .
(2) The propylene glycol ester or glycerin ester of caprylic acid and / or capric acid is propylene glycol dicaprylate, propylene glycol dicaprate, propylene glycol monocaprylate, di (caprylic acid / capric acid) propylene glycol and tri The cleansing cosmetic according to (1), wherein the cleansing cosmetic is selected from (caprylic acid / capric acid) glycerin.
(3) The cleansing cosmetic composition according to (1) or (2), further comprising an alkyl-modified carboxyvinyl polymer and / or a salt thereof and being in an emulsifier form.

  ADVANTAGE OF THE INVENTION According to this invention, when it is desired to remove the emulsification type mascara having water resistance, it is possible to provide a technique that can be removed safely and without great efforts.

(1) click Renjin grayed reduction粧料polyhydric alcohol esters present invention caprylic and / or capric acid must be agreed Sunari fraction of the present invention, propylene glycol esters or glycerol esters of caprylic and / or capric acid essential it characterized in that it contains as component. Propylene glycol or glycerin has a plurality of hydroxyl groups, but in the ester which is an essential component, all of the hydroxyl groups may form an ester, or some of the hydroxyl groups may remain free. The acyl group forming the ester is a capryloyl group or a caprynoyl group, but either one of the acyl groups can be bonded to one polyhydric alcohol, or both can be bonded (mixed ester). . As such propylene glycol ester or glycerin ester of caprylic acid and / or capric acid, for example, propylene glycol dicaprylate, propylene glycol dicaprate, propylene glycol monocaprylate, di (caprylic acid / capric acid) propylene glycol Or tri (caprylic acid / capric acid) glycerin can be preferably exemplified. Such propylene glycol ester or glycerin ester of caprylic acid and / or capric acid can be produced, for example, by reacting propylene glycol or glycerin with the corresponding acyl chloride in the presence of alkali. Such propylene glycol ester or glycerin ester of caprylic acid and / or capric acid already exists as a cosmetic raw material, and such a product can be purchased and used. Among such commercial products, in which preferable example, Ru tri (caprylate-caprate) glycerol der manufactured Cognis Japan Ltd. "Mirito Lumpur 318", di (caprylate-caprate) Propylene glycol "Mi litho Lumpur PC" is a propylene glycol monocaprylate manufactured by Nikko Chemicals Co., Ltd. "SEFSOL218" a propylene glycol dicaprylate "SEFSOL228" and the like. Such a component may contain only one species or may contain two or more species in combination. In the cleansing cosmetic composition of the present invention, such an ingredient acts on a complex made of an acrylic resin, a wax and a pigment, loosens its structure and makes it easy to release from the skin. The preferable content of such a component in the cleansing cosmetic of the present invention is 1 to 80% by mass, and more preferably 5 to 50% by mass.

(2) cleansing cosmetic composition of the cleansing cosmetic composition of the Invention The present invention is characterized by containing a acylated glutamic acid diester to the component and below. Cleansing cosmetics are used to remove powder-containing cosmetics such as skin oil stains and makeup cosmetics, but the cleansing cosmetics of the present invention are powder-containing cosmetics that are difficult to remove normal cleansing cosmetics. Excellent in removing the material. As such powder-containing cosmetics that are difficult to remove normal cleansing cosmetics, mascara in which powder and a film forming agent are mixed can be mentioned. This often involves a dedicated cleansing cosmetic that is exclusively used to remove mascara . Such special cleansing cosmetics are usually not usable for other cleansing purposes and are not versatile.
The cleansing cosmetic composition of the present invention can be used as a normal cleansing cosmetic composition, and has a characteristic of also having an action of removing the cosmetic composition that is difficult to remove.

The cleansing cosmetic of the present invention can be applied as long as it has the constitution of the characteristics of the present invention as long as it is a dosage form generally known for cleansing cosmetics. water-in-oil emulsifier type, oil formulations, wax dosage forms, lotions dosage form, any such gels forms are applicable. A particularly preferred dosage form is an oil-in-water emulsifier form. This is because the cosmetic to be removed forms a matrix that also has a hydrophilic portion, and in order to loosen this structure, both the aqueous component and the oily component must be present.

In the cleansing cosmetic composition of the present invention, in addition to the essential components, optional ingredients that are generally known in the production of cosmetic products can be contained within a range that does not impair the effects of the present invention. Examples of such components include oily bases, moisturizers, feel improvers, surfactants, polymers, thickening / gelling agents, solvents, propellants, antioxidants, reducing agents, oxidizing agents, preservatives. Agent, antibacterial agent, chelating agent, pH adjuster, acid, alkali, powder, inorganic salt, ultraviolet absorber, whitening agent, vitamins and derivatives thereof, anti-inflammatory agent, anti-inflammatory agent, hair growth agent, blood circulation promoter , Stimulant, hormones, anti-wrinkle agent, anti-aging agent, squeeze agent, cooling sensation agent, warming sensation agent, wound healing promoter, stimulation mitigation agent, analgesic agent, cell activator, plant / animal / microbe extract, antipruritic agent It is desirable to contain one or more selected from agents, exfoliants / solubilizers, antiperspirants, refreshers, astringents, enzymes, nucleic acids, fragrances, pigments, colorants, dyes, pigments, and water. By including the specific polyhydric alcohol ester of the present invention or the oil agent of the present invention and one or more selected from these, functions necessary for cosmetics or external preparations for skin can be exhibited better. it can. The amount of these components varies depending on the type of component, but is preferably 0.0001 to 99.9% by weight per component, more preferably 0.001 to 99% by weight per component. . In the cosmetics and skin external preparations of the present technology, two or more kinds of ingredients that are known to be used in other cosmetics or skin external preparations are usually blended, but the combination, blending ratio and blending amount are publicly known. It is possible to make it contain by the combination of these, a compounding ratio and a compounding quantity. The specific polyhydric alcohol ester of the present invention or the oil agent of the present invention and the blending ratio of these components per component vary depending on the type of the component, the type of cosmetic or skin external preparation, and the general form. For the specific polyhydric alcohol ester of the present invention or the oil agent of the present invention, the weight ratio is preferably in the range of 1: 1000 to 1: 0.0001, respectively.

These additive components will be described in more detail. Examples of the oily base other than the specific polyhydric alcohol ester of the present invention or the oil of the present invention include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, Higher alcohols such as chimyl alcohol, ceralkyl alcohol, batyl alcohol, hexyl decanol, isostearyl alcohol, 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearin Acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, palmitooleic acid, oleic acid, linoleic acid, linolein Higher fatty acids such as erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexadecanoic acid, antiisohenicosanoic acid, long-chain branched fatty acid, dimer acid, hydrogenated dimer acid, and aluminum salts, calcium salts, magnesium salts thereof, Metal soaps such as zinc salts and potassium salts, and nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane , Olive-derived squalane, squalene, petroleum jelly, solid paraffin and other carbides; candelilla wax, carnauba wax, rice wax, wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, my Waxes such as croccrystallin wax, petrolatum, Fischer-Tropsch wax, polyethylene wax, ethylene propylene copolymer; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose Oil, wheat germ oil, macadamia nut oil, hazelnut oil, cucumber nut oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, Vegetable oils such as soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef fat, milk fat, horse fat, egg yolk oil, mink oil , Animal oils such as turtle oil; whale wax, lanolin, orange Animal waxes such as fee oil; liquid lanolin, reduced lanolin, adsorbed lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid ( Lanolins such as cetyl lanolyl ester; phospholipids such as lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin, phosphatidic acid, lysolecithin; hydrogenated soybean phospholipid Phospholipid derivatives such as partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid; cholesterol, dihydrocholesterol Lanosterol, dihydro lanosterol, phytosterols, sterol such as cholate; sapogenins; saponins; acid cholesteryl, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteric oleate Le, N - lauroyl sarcosinate isopropyl etc. acyl sarcosine alkyl Esters such as esters, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, phytosteryl isostearate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl Phospholipid / cholesterol complex, phospholipid / phytostero Lipid complexes such as octyldodecyl myristate, hexyl decyl myristate, octyl dodecyl isostearate, cetyl paritate, octyl dodecyl palmitate, cetyl octoate, hexyldecyl octoate, isotridecyl isononanoate, isononanoyl isononanoate, Octyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldodecyl neodecanoate, oleyl oleate, octyl dodecyl oleate, octyldodecyl ricinoleate, octyldodecyl lanolinate, hexyldecyl dimethyloctanoate Octyldodecyl erucate, isostearic acid hydrogenated castor oil, ethyl oleate, avocado oil , Isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate Monoalcohol carboxylic acid esters such as triethyl citrate; oxyacid esters such as cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, Glyceryl diisostearate, tri (caprylic acid / capric acid) glyceryl, tri (caprylic acid / capric acid / myristic acid / stearin) ) Glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl behenate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, neopentylglycol dioctanoate, neopentyl glycol dicaprate Pentyl glycol, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, triethylhexanoic acid ditrimethylolpropane (isostearic acid / Sebacic acid) ditrimethylolpropane, pentaerythrityl triethylhexanoate, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythri Chill, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl-10 nonaisostearate, deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate ( Polyhydric alcohol fatty acid esters such as ethylene glycol distearate; diisopropyl dimerolinoleate, diisostearyl dimerdilinoleate, dimerdilinoleate di (isostearyl / phytosteryl), dimerlinoleic acid (phytosteryl / behenyl), Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleic acid dimer dilinoleyl, diisosteare Dimer acid or dimer diol derivative such as dimer dilinoleyl acid, dimer dilinoleic hydrogenated rosin condensate, dimer dilinoleic acid hydrogenated castor oil, hydroxyalkyl dimer dilinoleyl ether; palm oil fatty acid monoethanolamide (cocamide) MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA) ), Fatty acid alkanolamides such as palmitic acid diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamide methyl MEA); dimethicone ( Methylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, stearoxypropyldimethylamine, (aminoethylamino) Propylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, amino-modified silicone such as aminopropyl dimethicone and amodimethicone, cation-modified silicone, polyether-modified silicone such as dimethicone copolyol, polyglycerin-modified silicone, Sugar-modified silicone, carboxylic acid-modified silicone, phosphoric acid-modified silicone, sulfuric acid-modified silicone, alkyl-modified silicone Ricone, fatty acid modified silicone, alkyl ether modified silicone, amino acid modified silicone, peptide modified silicone, fluorine modified silicone, cationic modified and polyether modified silicone, amino modified and polyether modified silicone, alkyl modified and polyether modified silicone, polysiloxane Preferred examples include silicones such as oxyalkylene copolymers; and fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether.

As the humectant / feel improver, glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc. Sugars such as sorbitol, xylitol, erythritol, mannitol, maltitol; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid , Glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin and modified cyclodextrins such as maltosylation, hydroxyalkylation, etc.), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabino Sugars and derivatives thereof such as galactan, dextrin, dextran, glycogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer; hyaluronic acid, hyal Sodium ronate; sodium chondroitin sulfate; mucoitin sulfate, caroline sulfate, keratosulfate, dermatan sulfate; white jellyfish extract, white jellyfish polysaccharide; fucoidan; tuberose polysaccharide, naturally-occurring polysaccharide; organic acids such as citric acid, tartaric acid, lactic acid and the like Urea; 2-pyrrolidone-5-carboxylic acid and its sodium salt; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine , Glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and other amino acids and salts thereof; collagen, fish Collagen, atelocollagen, gelatin, elastin, collagen degrading peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin degrading peptide, keratin degrading peptide, hydrolyzing keratin, conchiolin degrading peptide, hydrolyzing conchiolin, silk proteolytic peptide, hydrolyzing Degraded silk, lauroyl hydrolyzed silk sodium, soy proteolytic peptide, wheat proteolytic peptide, hydrolyzed wheat protein, casein degrading peptide, acylated peptide, and other peptide peptides; palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetra Acylated peptides such as peptides; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hipotauri , Sesame lignan glycoside, glutathione, albumin, whey; choline chloride, phosphorylcholine; placenta extract, aerostin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, liquorice extract, comfrey extract, silk extract, Animal and plant extract ingredients such as Izayoi rose extract, Achillea millefolium extract, Eucalyptus extract, Merirot extract, natural ceramide (type 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide and Ceramides such as sugar-ceramide-containing extracts are preferred.

Preferred examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant. There is no restriction | limiting in particular in HLB of surfactant, It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB.
Examples of preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroylglutamate; Cocoyl Glue Acyl amino acid salts such as sodium minate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine; polyoxyethylene alkyl ethers such as sodium laureth acetate Acetic acid salt; Succinic acid ester salt such as sodium lauroyl monoethanolamide succinate; Fatty acid alkanolamide ether carboxylate; Acyl lactate; Polyoxyethylene fatty amine sulfate; Fatty acid alkanolamide sulfate; Hardened coconut oil fatty acid sodium glyceryl sulfate Fatty acid glyceride sulfate such as alkylbenzene polyoxyethylene sulfate; α-olefin Olefin sulfonates such as sodium sulfonate; alkylsulfosuccinates such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate; disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, lauryl polypropylene glycol sulfosuccinic acid Alkyl ether sulfosuccinates such as sodium; alkylbenzene sulfonates such as sodium tetradecylbenzenesulfonate and tetraethanolamine tetraethanol; alkylnaphthalenesulfonates; alkanesulfonates; α-sulfo fatty acid methyl ester salts; Acyl isethionate; alkyl glycidyl ether sulfonate; alkyl sulfoacetate; laurethrin Alkyl ether phosphates such as sodium, sodium dilaureth phosphate, sodium trilaureth phosphate, sodium monooles phosphate; alkyl phosphate salts such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphate; fatty acid amide ether phosphorus Acid salts; phospholipids such as phosphatidylglycerol, phosphatidylinositol, and phosphatidic acid; silicone-based anionic surfactants such as carboxylic acid-modified silicone, phosphate-modified silicone, and sulfate-modified silicone;
Nonionic surfactants include laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether), behenes (polyoxyethylene behenyl ether), isosteares (poly Polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers such as oxyethylene isostearyl ether), octyldecesses (polyoxyethylene octyldodecyl ether); polyoxyethylene alkylphenyl ether; polyoxyethylene hydrogenated castor oil, poly Oxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil mono Polyglutamic acid monoisostearic acid diester, castor oil and hardened castor oil derivatives such as polyoxyethylene hydrogenated castor oil maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene lanolin; Lanolin; polyoxyethylene / polyoxypropylene cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene・ Polyoxyethylene such as polyoxypropylene glycerin ether ・ Polyoxypropylene alkyl ether; Polyoxyethylene Polyoxypropylene glycol; (poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; glyceryl stearate, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, glyceryl palm oil fatty acid, mono cottonseed oil fatty acid Glycerin fatty acid partial esters such as glycerin, glyceryl monoerucate, glyceryl sesquioleate, glycerin α, α'-oleic acid pyroglutamate, glyceryl monostearate, malic acid monostearate; polyglyceryl-2 stearate, 3, 4, 4 , 6, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate, polyglyceryl decastearate-10, polyglyceryl isostearate -2, 3, 4, 5, 6, 8, 10, diglycostyl diisostearate (diglyceryl diisostearate), 3, 10, polyglyceryl triisostearate, polyglyceryl tetraisostearate -2, deglycisostearate polyglyceryl-10, oleic acid polyglyceryl-2, the same 3, the same 4, the same 6, the same 8, the same 10, the dioleic acid polyglyceryl-6, the trioleic acid polyglyceryl-2, the dekaoleic acid polyglyceryl Polyglycerol fatty acid ester such as -10; ethylene glycol mono fatty acid ester such as ethylene glycol monostearate; propylene glycol mono fatty acid ester such as propylene glycol monostearate; pentaerythritol partial fatty acid ester; sorbitol Maltitol partial fatty acid ester; maltitol partial fatty acid ester; maltitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, penta Sorbitan fatty acid esters such as 2-ethylhexyl diglycerol sorbitan and tetra-2-ethylhexyl diglycerol sorbitan; Sucrose fatty acid esters, methyl glucoside fatty acid esters, sugar derivatives partial esters such as undecylenic acid trehalose; alkyls such as caprylyl glucoside Alkyl polyglycoside; Lanolin alcohol; Reduced lanolin; Polyoxyethylene distearate, Polyethylene glycol di Polyoxyethylene fatty acid mono- and diesters such as isostearate, polyoxyethylene monooleate, polyoxyethylene dioleate; polyoxyethylene propylene glycol fatty acid ester; polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoiso Polyoxyethylene glycerin fatty acid esters such as stearate and polyoxyethylene glycerol triisostearate; polyoxyethylene glycerin fatty acid esters such as polyoxyethylene monooleate; polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate , Polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol Polyoxyethylene sorbitol fatty acid esters such as monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid ester; polyoxyethylene alkyl ether fatty acid Esters; Polyoxyethylene animal and vegetable oils and fats such as polyoxyethylene sorbitol beeswax; Alkyl glyceryl ethers such as isostearyl glyceryl ether, chimyl alcohol, ceralkyl alcohol, and batyl alcohol; Polyhydric alcohol alkyl ether; Polyoxyethylene alkylamine; Tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; saponin, sophoro Natural surfactants such as Pid; polyoxyethylene fatty acid amide; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide Fatty acid alkanolamides such as (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA) Alkyl dimethyl amine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, and behenamine oxide; alkyl ethoxy dimethyl amine oxide Xoxide; polyoxyethylene alkyl mercaptan; polyether-modified silicone such as dimethicone copolyol, polysiloxane-oxyalkylene copolymer, polyglycerin-modified silicone, silicone-based nonionic surfactant such as sugar-modified silicone, etc .;
Cationic surfactants include behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, lauryltrimonium chloride and other alkyltrimethylammonium chlorides; stearyltrimonium bromide and other alkyltrimethylammonium bromides; distearyldimonium chloride, Dialkyldimethylammonium chlorides such as dicocodimonium chloride; fatty acid amidoamines and salts thereof such as stearamidepropyldimethylamine and stearamideethyldiethylamine; alkyl etheramines such as stearoxypropyldimethylamine and salts or quaternary salts thereof; Chain-branched fatty acid (12-31) aminopropylethyldimethylammonium, ethyl sulfate lanolin fatty acid aminopropylethyldi Fatty acid amide type quaternary ammonium salts such as tilammonium; polyoxyethylene alkylamine and its salts or quaternary salts; alkylamine salts; fatty acid amidoguanidinium salts; alkyl etheraminemonium salts; Benzethonium salts; pyridinium salts such as cetylpyridinium chloride; imidazolinium salts; alkylisoquinolinium salts; dialkyl morpholinium salts; polyamine fatty acid derivatives; Silicone-based cationic surfactants such as modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone;
In amphoteric surfactants, N-alkyl-N, N-dimethylamino acid betaines such as lauryl betaine (lauryldimethylaminoacetic acid betaine); fatty acid amide alkyl-N, N-dimethylamino acids such as cocamidopropyl betaine and lauramidopropyl betaine Betaines; imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkylsulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate; phosphate-type betaines such as alkyldimethylaminoethanol phosphate; Sphingophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphingomyelin, lysolecithin, hydrogenated soybean phospholipid, partially hydrogenated Soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipids, phospholipids such as hydroxylated lecithin; silicone amphoteric surfactants;
Among the polymeric surfactants, polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, acrylic acid / alkyl methacrylate copolymer; various silicone surfactants are preferable.

Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, chitin , Chitosan, agar, gypsum extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropi Cellulose, carboxymethylcellulose and its salts such as sodium, methylhydroxypropylcellulose, sodium cellulose sulfate, cellulose dialkyldimethylammonium sulfate, crystalline cellulose, cellulose powder such as cellulose powder; soluble starch, carboxymethyl starch, methylhydroxypropyl starch, Starch-based polymers such as methyl starch, starch derivatives such as hydroxypropyltrimonium chloride, octenyl succinate corn starch and aluminum; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), Vinyl pydridone-vinyl alcohol copolymer, polyvinyl methyl ether Polyethylene glycol, polypropylene glycol, polyoxyethylene / polyoxypropylene copolymer; amphoteric methacrylic acid such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer, etc. Ester copolymer; (Dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; Polyvinyl acetate partial saponification product, maleic acid copolymer; Vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; Kurylamide; Polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; acrylic acid / alkyl methacrylate Polymer: Cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, and acrylic acid such as polyquaternium-39・ Diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylic acid amide copolymer, polyquaternium Acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer such as 47, methacrylic acid choline ester polymer; cationized polysaccharides such as cationized oligosaccharide, cationized dextran, guar hydroxypropyltrimonium chloride; Polyethyleneimine; Cationic polymer; Polymer of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymer with butyl methacrylate copolymer; Acrylic resin emulsion, polyethyl acrylate emulsion, polyacrylalkyl ester emulsion, Polymer emulsions such as polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex; nitrocellulose; polyurethanes and various copolymers; various silicones Various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, Smoke-like silica (ultrafine silicic anhydride), aluminum magnesium silicate, magnesium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester It is mentioned as preferable.

  Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate , Acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation flon; propellants such as LPG, dimethyl ether, carbon dioxide, and the like are preferable.

  Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned. Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

Preservatives and antibacterial agents include hydroxybenzoic acid such as methylparaben, ethylparaben, propylparaben, and butylparaben and salts or esters thereof; salicylic acid; sodium benzoate; phenoxyethanol; 1,2-pentanediol, 1,2-hexane 1,2-diols such as diols; isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; imidazolinium urea; dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides , Quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, Kichioru; phenol, isopropyl phenol, cresol, thymol, p-chlorophenol, phenylphenol, other phenols such as phenylphenol sodium; phenylethyl alcohol, photosensitive Motorui, be mentioned as antibacterial zeolite, silver ion. Examples of chelating agents include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.

  Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide, fine particles and ultrafine Titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silica), titanium mica, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, fine particle composite powder Body, gold, aluminum, etc., various sizes and shapes of inorganic powders, and these are treated with various surface treatment agents such as hydrogen silicone, cyclic hydrogen silicone, or other silane or titanium coupling agents Inorganic powders such as hydrophobized or hydrophilized powders; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, polyester powder, Benzoguanamine resin powder, polyethylene terephthalate, polymethyl Organic powders and surface-treated powders of various sizes and shapes, such as methacrylate powder, polyethylene terephthalate / aluminum / epoxy powder, urethane powder, silicone powder, Teflon (registered trademark) powder, organic-inorganic composite powder Is preferable. Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.

Examples of ultraviolet absorbers include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoic acid ethyl ester. Benzoic acid-based ultraviolet absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid Salicylic acid-type purple such as sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate Line absorber: Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p- Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-
p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), cyclohexyl-p-methoxycinnamate, ethyl-α-cyano- Cinnamic acid-based UV absorbers such as β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocrine), glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, ferulic acid and its derivatives 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2; -Hydroxy-4-methoxybenzo Enone (oxybenzone-3), 2-hydroxy-4-methoxy-4′-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4′-phenyl- Benzophenone ultraviolet absorbers such as benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone; 3- (4′-methylbenzylidene) -d, l-camphor , 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2′-hydroxy-5-methylphenylbenzotriazole; 2- (2′-hydroxy-5′-t-octyl) Phenyl) benzotriazole; 2- (2′-hydroxy-5′-) Dibenzalazine; dianisoylmethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyl Triazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 1- (3,4-dimethoxyphenyl) -4,4-dimethyl-1 , 3-pentanedione, dimethoxybenzylidenedioxoimidazolidinepropionate 2-ethylhexyl, etc. hydantoin derivatives, phenylbenzimidazole sulfonic acid, terephthalylidene dicamphulsulfonic acid, drometrizol trisiloxane, anthranilate methyl, rutin And its derivatives, oryzanol and its derivatives are preferred.

  Examples of whitening agents include hydroquinone glycosides such as arbutin and α-arbutin and esters thereof; ascorbic acid phosphate salts such as ascorbic acid, sodium ascorbate phosphate and magnesium ascorbate phosphate, ascorbic acid Ascorbic acid fatty acid esters such as tetraisopalmitic acid ester, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucosides such as ascorbic acid-2-glucoside and fatty acid esters thereof, ascorbic acid sulfate ester, tocopheryl ascorbyl phosphate Ascorbic acid derivatives such as kojic acid, ellagic acid, tranexamic acid and its derivatives, ferulic acid and its derivatives, placenta extract, glutathione, oryzanol, butylreso Shinoru, oil-soluble Kamomiraekisu, oil-soluble licorice extract, Nishikawa willow extract, be mentioned as saxifrage extract, and the like plant extracts are preferred.

Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt; Ascorbic acid fatty acid esters such as corobic acid tetraisopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate and ascorbyl dipalmitate, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and Ascorbic acid derivatives such as fatty acid esters and tocopheryl phosphate ascorbyl; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol acetate, tocopherol linoleate, tocopherol phosphate, tocopherol phosphate etc., tocotrienol, and other various vitamin derivatives Is preferable.

  Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract A plant extract such as a koji leaf extract is preferable. Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, cephalanthin, vitamin E and nicotinic acid tocopherol, acetic acid tocopherol and other derivatives, γ-oryzanol, nicotinic acid, nicotinic acid amide, nicotinic acid benzyl Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives, stigmasterol or stigmasteranol, its glycosides, and minoxidil. Preferred hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Other remedies such as anti-wrinkle agents, anti-aging agents, squeeze agents, cooling sensations, warming sensation agents, wound healing promoters, irritation relievers, analgesics, cell activators include retinols, retinoic acids, retinoin Acid tocopheryl; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, α- or such as hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl β-hydroxy acids and derivatives thereof; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; creatine; ceramides, sphingosines; caffeine, xanthine and the like; and coenzyme Q10, carotene, lycopene, astaxanthin Antioxidants and active oxygen scavengers such as catechins; flavones such as quercetin; Flavones; gallic acid and ester sugar derivatives; polyphenols such as tannin, sesamin, protoanthocyanidin, chlorogenic acid, apple polyphenol; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; Licorice extract-related substances such as glabrizine, glabrene, liquiritin, isoliquiritin; lactoferrin; gingerol; fragrance substances such as menthol, camphor, cedrol and derivatives thereof; capsaicin, vanillin, and derivatives; A complex of a physiologically active substance and cyclodextrins is preferable.

Plant / animal / microbe extracts include iris extract, ashitaba extract, asunalo extract, asparagus extract, avocado extract, achacha extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo biloba extract , Incheon extract, Fennel extract, Turmeric extract, Oolong tea extract, Peony extract, Ages extract, Echinacea leaf extract, Enmeo extract, Ogon extract, Oat extract, Auren extract, Barley extract, Panax ginseng extract, Hypericum extract, Odori extract , Dutch mustard extract, orange extract, dried sea water, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolysis Luc, Cascon extract, Chamomile extract, Oil-soluble chamomile extract, Carrot extract, Kawara mugi extract, Oat extract, Calcade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Cyprid extract, Quina extract, Cucumber extract, Kiri leaf extract, Guanosine, guava extract, cucumber extract, gardenia extract, kumazasa extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, Gentian pepper extract, tea Extract, yeast extract, kokuboku extract, coffee extract, burdock extract, rice extract, rice fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, Lagen, Cowberry extract, Saishin extract, Psycho extract, Saitai extract, Saffron extract, Salvia extract, Salmon extract, Sasa extract, Hawthorn extract, Sansha extract, Salamander extract, Shiitake extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Shimosukeso Extract, jatoba extract, peonies extract, ginger cucumber extract, ginger root extract, white birch extract, white jellyfish extract, horsetail extract, stevia extract, stevia fermented product, west river willow extract, horse chestnut extract, hawthorn extract, elderberry extract, yarrow extract , Mint extract, sage extract, mallow extract, nematode extract, essence extract, Sakuhakuhi extract, Diou extract, Dai Extract, peanut extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, tea tea extract, red pepper extract, red snapper extract, red snapper extract, red spruce extract, red spruce extract, tomato Extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, bacmond extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietalia extract, hyacinth extract, bisabolol, cypress extract, bifidobacteria extract, Loquat extract, dandelion extract, burdock extract, bukkuri extract, butcher bloom extract, grape extract, grape seed extract, propolis, loofah extract, Safflower extract, peppermint extract, body extract, button extract, hop extract, squid extract, pine extract, maroonnier extract, mizubasho extract, mukuroji extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, yukinoshita extract, yuzu extract, lily extract, Yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, litchi extract, lettuce extract, lemon extract, forsythia extract, forsythia extract, rose extract, rosemary extract, roman chamomile extract, royal jelly Extracts such as an extract and a bitumen extract are preferred.

  Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor, and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenol sulfonate. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like. Preferred nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium.

As perfumes, acetyl cedrene, amylcinnamaldehyde, allyl amyl glycolate, β-ionone, iso-Esuper, isobutyl quinoline, Iris oil, Iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, auranthiol, galac solid, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile , Isobornyl acetate, geranyl acetate, dimethylbenzyl carvinyl acetate, styrylyl acetate, cedolyl acetate, terpinel acetate, pt-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, acetic acid Linalyl, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citronellal, Cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylus resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascon, damassenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, Tripral, Nellore, Nonanal, 2,6-Nonadienol, Nonalactone, Patchouli alcohol, Vanilla absolute, Vanillin Basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitglen oil, hexylcinnamaldehyde, cis-3-hexenol, perubalsum, vetiver oil, vetiverol, peppermint oil, pepper oil, Heliotropin, bergamot oil, benzylbenzoate, borneol, milresinoid, musk ketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menton, eucalyptus oil, β-yonone, lime oil, lavender oil, D-limonene Synthetic and natural fragrances such as linalool, rillar, rigliall, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, various essential oils, and various blended fragrances are also preferred. As mentioned.

As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230 No. 1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505, red 506, orange 201, orange 203, orange 204, orange 205, orange 206, orange 207, orange 401, orange 402, orange 403, yellow 201, yellow 202- No. 1, yellow 202-2, yellow 203, yellow 204, yellow 205, yellow 4, yellow 401, yellow 402, yellow 403-1, yellow 404, yellow 405, yellow 406 Legal dyes such as Yellow No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Base dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4- Nitro dyes such as hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2, and Basic Blue 26; disperse dyes; inorganic white such as titanium dioxide and zinc oxide Pigments: Inorganic red pigments such as iron oxide (Bengara) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and loess; Black iron oxide, low-order titanium oxide, etc. Inorganic pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium oxide coated mica; Titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, pearl pigments such as fish scale foil; gold such as aluminum powder, copper powder, gold Surface treated inorganic and metal powder pigments: Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204 No., Yellow 205, Yellow 401, Blue 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Organic pigments such as zirconium, barium or aluminum lake such as yellow 5, yellow 202, yellow 203, green 3 and blue 1; surface treatment organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene , Catenal, capsanthin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, cochinie Natural pigments and dyes such as naphthoquinones such as shikonin, bixin, flavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, Or intermediates and couplers of oxidation dyes such as p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and their salts; autooxidation of indoline, etc. Type dyes; dihydroxyacetone is preferred.

  Preferred examples of water include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and clustered water.

In addition to these, cosmetic raw material standards, blending ingredient standard by cosmetic varieties, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and
Handbook), ingredients listed in the Quasi-drug Raw Material Standards, Japanese Pharmacopoeia, Pharmaceutical Additive Standards, Food Additives Official Code, etc., and Japanese and foreign patents whose international patent classification IPC belongs to the classification of A61K7 Including known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., in known combinations, blending ratios, and blending quantities, such as ingredients described in publications and patent publications (including publications and republications) Is possible.

As described above, the present invention contains an acylated glutamic acid diester. Acylated glutamic acid diesters include N-lauroyl-L-glutamate di (cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamic acid di (phytosteryl / Behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl) and the like. Among these components, particularly preferred is N-lauroyl-L-glutamate di (octyldodecyl / Phytosteryl). This product is sold by Ajinomoto Co., Inc. as “El Dew PS203” and is easily available. Such a component is particularly excellent in the action of dissolving a lipophilic part and a highly solid part in a matrix made by a cosmetic containing a powder and a resin. To achieve such a effect, such components Ru contained 0.1 to 10 mass% relative to the total amount of the cosmetic. In the case of an emulsifier form, it is preferable to contain an alkyl-modified carboxyvinyl polymer and / or a salt thereof because the cleansing action can be enhanced. Preferable examples of the alkyl-modified carboxyvinyl polymer include “Carbopol 1382”, “Pemlen TR-1”, “Pemlen TR-2” and the like sold by Goodrich. The salts include alkali metal salts such as sodium salt and potassium salt, alkaline earth metal salts such as calcium and magnesium, organic amine salts such as ammonium salt, triethanolamine salt and triethylamine salt, lysine salt and arginine salt. Preferred examples include basic amino acid salts such as Such a component may contain only one species or may contain two or more species in combination. The preferable content of this component in the cleansing cosmetic of the present invention is 0.01 to 0.5% by mass.

The cleansing cosmetic composition of the present invention can be produced by treating the essential components and optional components according to a conventional method.

Hereinafter, the present invention will be described in more detail with reference to examples, but it goes without saying that the present invention is not limited to such examples .

<Example 1>
According to the formulation shown below, was created cleanse cosmetic of the present invention. That is, b, and stirred at 80 ° C. The components of B and C, gradually b was added to i, and neutralized with Ha Thereafter, stirring cooled, the cleansing cosmetic composition is a cleansing cosmetic composition of the present invention 1 (Oil-in-water emulsifier form) was obtained.

<Test Example 1>
The cleansing effect of cleansing cosmetic 1 was investigated using the following mascara. That is, after preparing a brush and weighing it, 100 mg of mascara was applied to the hair bundle part, allowed to stand for 20 minutes, and then rubbed with cut cotton while blending with 200 mg of cleansing cosmetic, to remove the mascara. The hair removed by this action was collected, washed with a brush and then left to stand in a constant temperature room for 24 hours and dried, and then weighed. The cosmetic residual rate (%) was calculated from the formula (mass of writing brush + 100 mg-mass of writing brush and hair after treatment). Comparative Example was substituted for "SEFSOL218" of cleansing cosmetics 1 in squalane 1, comparison was replaced with "Erude oxalic PS203" Example 2 is also prepared in the same manner, it was evaluated. Table 2 shows the mascara formulation used in the test. The results are shown in Table 3. From this, it can be seen that the cleansing cosmetic of the present invention is excellent in removing makeup of a powder-containing cosmetic that contains a resin and powder, such as mascara.

<Test Example 2>
Using the same sample as in Test Example 1, the application location of mascara was changed to a 2 cm × 4 cm region on the inner side of the forearm, and the makeup removal function was evaluated. The amount of mascara applied was 40 mg, and the amount of cleansing cosmetic was 40 mg. After rubbing, washing with an aqueous facial cleanser, wiping with a towel, leaving to stand for 10 minutes, color difference from the untreated site (“Color Difference Meter” manufactured by Konica Minolta; ΔE) and TEWL (“Tevameter” Integral) (Manufactured by company; transcutaneously dissipated water content) was measured. The results are shown in Table 4. From this, it can be seen that the cleansing cosmetic of the present invention can remove mascara without damaging the skin barrier function.

<Reference Example 1>
In the same manner as in Example 1, a cleansing cosmetic 2 was produced according to the formulation in Table 5. Was evaluated by the method of Test Example 1, the cosmetic residual ratio thereof was 9.5%, it was found that those who contain "Erude oxalic PS203" is preferred.

<Example 2>
In the same manner as in Example 1, a cleansing cosmetic 3 was produced according to the formulation in Table 6. Was evaluated by the method of Test Example 1, the cosmetic residual ratio thereof was 5.2%, it was found that the same effect even "mi litho Lumpur 318".

<Example 3>
In the same manner as in Example 1, a cleansing cosmetic 4 was produced according to the formulation in Table 7. Was evaluated by the method of Test Example 1, the cosmetic residual ratio thereof was 6.2%, it was found that the same effect even "mi litho Lumpur PC".

<Example 4>
In the same manner as in Example 1, a cleansing cosmetic 5 was produced according to the formulation in Table 8. When evaluated by the method of Test Example 1, the cosmetic residual ratio was 4.9%, and it was found that “SEFSOL228” also exhibited the same effect.

<Example 5>
According to Table 9 below, cleansing cosmetic 6 in oil dosage form was produced. That is, cleansing cosmetic 6 was obtained by heating and stirring the prescription ingredients at 80 ° C. and stirring and cooling. When evaluated by the method of Test Example 2, ΔE was 0.43, TEWL was 16.3, and it was found that the effects of the present invention can be obtained even in an oil dosage form.

The present invention can be applied to cleansing cosmetics.

Claims (3)

A cleansing cosmetic for removing emulsified mascara containing an acrylic resin as a film forming agent, comprising 1) propylene glycol ester or glycerin ester of caprylic acid and / or capric acid, and 2) acylated glutamic acid diester 0.1 A cleansing cosmetic comprising 10 to 10% by mass .   The propylene glycol ester or glycerin ester of caprylic acid and / or capric acid is propylene glycol dicaprylate, propylene glycol dicaprate, propylene glycol monocaprylate, di (caprylic acid / capric acid) propylene glycol and tri (caprylic acid). The cleansing cosmetic according to claim 1, wherein the cleansing cosmetic is selected from capric acid) glycerin.   The cleansing cosmetic composition according to claim 1 or 2, further comprising an alkyl-modified carboxyvinyl polymer and / or a salt thereof and being in an emulsifier form.