JP2014531036A5 - - Google Patents
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- Publication number
- JP2014531036A5 JP2014531036A5 JP2014537610A JP2014537610A JP2014531036A5 JP 2014531036 A5 JP2014531036 A5 JP 2014531036A5 JP 2014537610 A JP2014537610 A JP 2014537610A JP 2014537610 A JP2014537610 A JP 2014537610A JP 2014531036 A5 JP2014531036 A5 JP 2014531036A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- gas sensor
- anion
- sensor according
- ammonium cation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000007789 gas Substances 0.000 claims 25
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 9
- -1 mono-substituted ammonium Chemical class 0.000 claims 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 6
- 125000006575 electron-withdrawing group Chemical group 0.000 claims 6
- 229910052736 halogen Inorganic materials 0.000 claims 6
- 239000002608 ionic liquid Substances 0.000 claims 6
- 150000001450 anions Chemical class 0.000 claims 5
- 150000001412 amines Chemical class 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 4
- 239000003792 electrolyte Substances 0.000 claims 4
- 150000002367 halogens Chemical class 0.000 claims 4
- 125000001072 heteroaryl group Chemical group 0.000 claims 4
- 239000007787 solid Substances 0.000 claims 4
- 239000000654 additive Substances 0.000 claims 3
- 230000000996 additive effect Effects 0.000 claims 3
- 229910021529 ammonia Inorganic materials 0.000 claims 3
- 125000004429 atom Chemical group 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims 2
- 230000005595 deprotonation Effects 0.000 claims 2
- 238000010537 deprotonation reaction Methods 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000006259 organic additive Substances 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 claims 2
- QBNWRLIYIQMSEB-UHFFFAOYSA-N (4-methylphenyl)-oxomethanesulfonic acid Chemical compound CC1=CC=C(C(=O)S(O)(=O)=O)C=C1 QBNWRLIYIQMSEB-UHFFFAOYSA-N 0.000 claims 1
- JGTNAGYHADQMCM-UHFFFAOYSA-M 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F JGTNAGYHADQMCM-UHFFFAOYSA-M 0.000 claims 1
- XGMDYIYCKWMWLY-UHFFFAOYSA-N 2,2,2-trifluoroethanesulfonic acid Chemical compound OS(=O)(=O)CC(F)(F)F XGMDYIYCKWMWLY-UHFFFAOYSA-N 0.000 claims 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims 1
- PXACTUVBBMDKRW-UHFFFAOYSA-M 4-bromobenzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=C(Br)C=C1 PXACTUVBBMDKRW-UHFFFAOYSA-M 0.000 claims 1
- PXACTUVBBMDKRW-UHFFFAOYSA-N 4-bromobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C(Br)C=C1 PXACTUVBBMDKRW-UHFFFAOYSA-N 0.000 claims 1
- ZQQDQFWOUXWRMR-UHFFFAOYSA-N 4-methylbenzenesulfonic acid 4-nitrobenzenesulfonic acid Chemical compound Cc1ccc(cc1)S(O)(=O)=O.OS(=O)(=O)c1ccc(cc1)[N+]([O-])=O ZQQDQFWOUXWRMR-UHFFFAOYSA-N 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims 1
- DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 claims 1
- CNWONESORNTVSL-UHFFFAOYSA-N bis(2-hydroxyethyl)azanium;2,2,2-trifluoroacetate Chemical compound OCC[NH2+]CCO.[O-]C(=O)C(F)(F)F CNWONESORNTVSL-UHFFFAOYSA-N 0.000 claims 1
- RNZWSZDIXHZJJN-UHFFFAOYSA-O bis(cyanomethyl)azanium;nitrate Chemical compound [O-][N+]([O-])=O.N#CC[NH2+]CC#N RNZWSZDIXHZJJN-UHFFFAOYSA-O 0.000 claims 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- BSRDNMMLQYNQQD-UHFFFAOYSA-N iminodiacetonitrile Chemical compound N#CCNCC#N BSRDNMMLQYNQQD-UHFFFAOYSA-N 0.000 claims 1
- 125000002462 isocyano group Chemical group *[N+]#[C-] 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 125000005031 thiocyano group Chemical group S(C#N)* 0.000 claims 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102011085174.7 | 2011-10-25 | ||
| DE102011085174A DE102011085174A1 (de) | 2011-10-25 | 2011-10-25 | Elektrochemischer Gassensor mit einer ionischen Flüssigkeitals Elektrolyt zum Nachweis von Ammoniak und Aminen |
| DE102011087592A DE102011087592A1 (de) | 2011-12-01 | 2011-12-01 | Elektrochemischer Gassensor mit einer ionischen Flüssigkeit als Elektrolyt zum Nachweis von Ammoniak und Aminen |
| DE102011087592.1 | 2011-12-01 | ||
| PCT/EP2012/071141 WO2013060773A1 (en) | 2011-10-25 | 2012-10-25 | Electrochemical gas sensor with an ionic liquid as electrolyte for the detection of ammonia and amines |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014531036A JP2014531036A (ja) | 2014-11-20 |
| JP2014531036A5 true JP2014531036A5 (https=) | 2015-10-15 |
| JP6131261B2 JP6131261B2 (ja) | 2017-05-17 |
Family
ID=47146357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014537610A Active JP6131261B2 (ja) | 2011-10-25 | 2012-10-25 | アンモニア及びアミンを検出するための、電解質としてイオン液体を備えた電気化学式ガスセンサ |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9395323B2 (https=) |
| EP (1) | EP2776819B1 (https=) |
| JP (1) | JP6131261B2 (https=) |
| KR (1) | KR20140098083A (https=) |
| CN (1) | CN103890577B (https=) |
| AU (1) | AU2012330453B2 (https=) |
| CA (1) | CA2853374C (https=) |
| RU (1) | RU2617845C2 (https=) |
| WO (1) | WO2013060773A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3128627B2 (ja) | 1991-06-03 | 2001-01-29 | 東急建設株式会社 | 中空ＰＣａ柱 |
| RU2617845C2 (ru) | 2011-10-25 | 2017-04-28 | МСА Юроп ГмбХ | Электрохимический газовый датчик с ионной жидкостью в качестве электролита для обнаружения аммиака и аминов |
| DE102013014994A1 (de) | 2013-09-09 | 2015-03-12 | Dräger Safety AG & Co. KGaA | Elektrochemischer Gassensor, flüssiger Elektrolyt und Verwendung eines flüssigen Elektrolyten in einem elektrochemischen Gassensor |
| DE102014003316B4 (de) * | 2013-11-21 | 2019-07-25 | Dräger Safety AG & Co. KGaA | Elektrochemischer Sensor |
| DE102014007137A1 (de) * | 2014-05-16 | 2015-11-19 | Dräger Safety AG & Co. KGaA | Elektrode für einen elektronischen Gassensor, Herstellungsverfahren für eine Elektrode und Verwendung einer Elektrode |
| EP3115774B1 (en) | 2015-07-06 | 2020-05-06 | Stichting IMEC Nederland | Gas sensor with frequency measurement of impedance |
| DE102015012440B4 (de) * | 2015-09-28 | 2020-02-13 | Dräger Safety AG & Co. KGaA | Elektrochemischer Gasgenerator für Ammoniak unter Verwendung lonischer Flüssigkeiten und Verwendung des Gasgenerators |
| JP6694645B2 (ja) * | 2016-03-01 | 2020-05-20 | 国立研究開発法人産業技術総合研究所 | 塩基性ガス吸収剤及び塩基性ガス分離回収方法 |
| JP7391540B2 (ja) | 2019-05-31 | 2023-12-05 | 浜松ホトニクス株式会社 | 匂いセンサ及び匂い検出方法 |
| CN115711928A (zh) * | 2022-11-09 | 2023-02-24 | 郑州炜盛电子科技有限公司 | 柔性电解质及其制备方法与应用 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3841622A1 (de) | 1988-12-10 | 1990-06-13 | Draegerwerk Ag | Elektrochemische messzelle zur amperometrischen bestimmung von ammoniak und dessen derivate |
| US6248224B1 (en) | 1999-05-12 | 2001-06-19 | Mst Analytics Inc. | Toxic sensor and method of manufacture |
| RU25226U1 (ru) * | 2002-01-23 | 2002-09-20 | Общество с ограниченной ответственностью "ВЗОР" | Электрохимический датчик |
| US7060169B2 (en) | 2002-08-14 | 2006-06-13 | Mst Technology Gmbh | Electrochemical cell for gas sensor |
| GB0407908D0 (en) | 2004-04-07 | 2004-05-12 | Univ York | Ionic liquids |
| JP4838134B2 (ja) * | 2004-09-03 | 2011-12-14 | 日産自動車株式会社 | プロトン伝導体およびそれを用いた燃料電池 |
| JP4597622B2 (ja) * | 2004-09-27 | 2010-12-15 | 根本特殊化学株式会社 | 電気化学式ガスセンサ |
| DE102005020719B3 (de) | 2005-05-04 | 2006-09-14 | Drägerwerk AG | Offner elektrochemischer Sensor |
| JP2008064578A (ja) * | 2006-09-06 | 2008-03-21 | Horiba Ltd | イオン液体特性測定方法 |
| GB0704972D0 (en) | 2007-03-15 | 2007-04-25 | Varney Mark S | Neoteric room temperature ionic liquid gas sensor |
| DE102008044240B4 (de) * | 2008-12-01 | 2013-12-05 | Msa Auer Gmbh | Elektrochemischer Gassensor mit einer ionischen Flüssigkeit als Elektrolyt, welche mindestens ein Mono-, Di- oder Trialkylammonium-Kation enthält |
| DE102008044239A1 (de) | 2008-12-01 | 2010-06-10 | Msa Auer Gmbh | Elektrochemischer Gassensor mit einer in einem Feststoff auf SiO2-Basis absorbierten ionischen Flüssigkeit als Elektrolyt mit organischen und/oder metallorganischen und/oder anorganischen Zusätzen |
| DE102008044238A1 (de) | 2008-12-01 | 2010-06-10 | Msa Auer Gmbh | Elektrochemischer Gassensor mit einer ionischen Flüssigkeit als Elektrolyt, welche organische und/oder metallorganische und/oder anorganische Zusätze aufweist |
| CA2745236C (en) | 2008-12-01 | 2019-03-26 | Msa Auer Gmbh | Electrochemical gas sensors with ionic liquid electrolyte systems |
| DE102010063626A1 (de) | 2010-12-21 | 2012-06-21 | Henkel Ag & Co. Kgaa | Geschirrspülmittelkompaktate |
| RU2617845C2 (ru) | 2011-10-25 | 2017-04-28 | МСА Юроп ГмбХ | Электрохимический газовый датчик с ионной жидкостью в качестве электролита для обнаружения аммиака и аминов |
-
2012
- 2012-10-25 RU RU2014120795A patent/RU2617845C2/ru active
- 2012-10-25 EP EP12783553.6A patent/EP2776819B1/en active Active
- 2012-10-25 CN CN201280052362.4A patent/CN103890577B/zh active Active
- 2012-10-25 AU AU2012330453A patent/AU2012330453B2/en active Active
- 2012-10-25 CA CA2853374A patent/CA2853374C/en active Active
- 2012-10-25 WO PCT/EP2012/071141 patent/WO2013060773A1/en not_active Ceased
- 2012-10-25 US US14/354,011 patent/US9395323B2/en active Active
- 2012-10-25 JP JP2014537610A patent/JP6131261B2/ja active Active
- 2012-10-25 KR KR20147013382A patent/KR20140098083A/ko not_active Ceased
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