JP2014511933A5 - - Google Patents
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- Publication number
- JP2014511933A5 JP2014511933A5 JP2014505552A JP2014505552A JP2014511933A5 JP 2014511933 A5 JP2014511933 A5 JP 2014511933A5 JP 2014505552 A JP2014505552 A JP 2014505552A JP 2014505552 A JP2014505552 A JP 2014505552A JP 2014511933 A5 JP2014511933 A5 JP 2014511933A5
- Authority
- JP
- Japan
- Prior art keywords
- weight
- material according
- support material
- copolymer
- maleic anhydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910021485 fumed silica Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000004609 Impact Modifier Substances 0.000 claims description 2
- 239000003607 modifier Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 8
- 229920001577 copolymer Polymers 0.000 claims 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 6
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 3
- 230000009477 glass transition Effects 0.000 claims 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- 239000012736 aqueous medium Substances 0.000 claims 2
- 239000004566 building material Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11163199.0 | 2011-04-20 | ||
| EP11163199A EP2514775A1 (en) | 2011-04-20 | 2011-04-20 | Maleic anhydride copolymers as soluble support material for fused deposition modelling (FDM) printer |
| PCT/EP2012/054306 WO2012143182A1 (en) | 2011-04-20 | 2012-03-13 | Maleic anhydride copolymers as soluble support material for fused deposition modelling (fdm) printer |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014511933A JP2014511933A (ja) | 2014-05-19 |
| JP2014511933A5 true JP2014511933A5 (enExample) | 2015-04-16 |
| JP5893128B2 JP5893128B2 (ja) | 2016-03-23 |
Family
ID=44560045
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014505552A Expired - Fee Related JP5893128B2 (ja) | 2011-04-20 | 2012-03-13 | 熱溶解積層方式（ｆｄｍ）プリンターのための可溶性の支持材料としての無水マレイン酸コポリマー |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8822590B2 (enExample) |
| EP (2) | EP2514775A1 (enExample) |
| JP (1) | JP5893128B2 (enExample) |
| KR (1) | KR20140009442A (enExample) |
| CN (1) | CN103380156B (enExample) |
| AU (1) | AU2012244499B2 (enExample) |
| BR (1) | BR112013023429B8 (enExample) |
| CA (1) | CA2833752C (enExample) |
| IL (1) | IL227363A (enExample) |
| RU (1) | RU2013151313A (enExample) |
| WO (1) | WO2012143182A1 (enExample) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9498593B2 (en) | 2013-06-17 | 2016-11-22 | MetaMason, Inc. | Customized medical devices and apparel |
| US9029058B2 (en) * | 2013-07-17 | 2015-05-12 | Stratasys, Inc. | Soluble support material for electrophotography-based additive manufacturing |
| US9745458B2 (en) | 2013-07-26 | 2017-08-29 | Hewlett-Packard Development Company, L.P. | Composite support material for three-dimensional printing |
| US10843401B2 (en) * | 2013-11-01 | 2020-11-24 | Kraton Polymers U.S. Llc | Fuse molded three dimensional article and a method for making the same |
| KR20160101998A (ko) * | 2013-12-18 | 2016-08-26 | 이네오스 스티롤루션 그룹 게엠베하 | 3-d 프린팅용의 비닐방향족/디엔 블록 공중합체에 기초한 몰딩 재료들의 용도 |
| US20160319120A1 (en) * | 2013-12-18 | 2016-11-03 | Ineos Styrolution Group Gmbh | Molding materials based on vinyl aromatic polymers for 3-d-printing |
| KR102215420B1 (ko) * | 2013-12-18 | 2021-02-15 | 이네오스 스티롤루션 그룹 게엠베하 | 3d 프린팅용의 비닐방향족 기반 몰딩 조성물 |
| CN105899591A (zh) | 2014-01-16 | 2016-08-24 | 陶氏环球技术有限责任公司 | 增材制造负载材料的回收 |
| JP6546179B2 (ja) * | 2014-01-16 | 2019-07-17 | ダウ グローバル テクノロジーズ エルエルシー | ３ｄ印刷用支持材料 |
| US9102099B1 (en) | 2014-02-05 | 2015-08-11 | MetaMason, Inc. | Methods for additive manufacturing processes incorporating active deposition |
| EP3107943B1 (en) * | 2014-02-19 | 2018-04-18 | Basf Se | Polymers as support material for use in fused filament fabrication |
| US9676159B2 (en) | 2014-05-09 | 2017-06-13 | Nike, Inc. | Method for forming three-dimensional structures with different material portions |
| WO2015195213A1 (en) * | 2014-06-16 | 2015-12-23 | Sabic Global Technologies B.V. | Process for additive manufacturing |
| CN104263150B (zh) * | 2014-09-10 | 2018-03-06 | 珠海天威飞马打印耗材有限公司 | 一种3d打印机及其工作台膜层的制备方法、涂覆在3d打印机工作台的涂料及其制备方法 |
| WO2016059987A1 (ja) * | 2014-10-14 | 2016-04-21 | 花王株式会社 | 三次元造形用可溶性材料 |
| JP6491467B2 (ja) * | 2014-10-14 | 2019-03-27 | 花王株式会社 | 三次元造形用可溶性材料 |
| JP5972335B2 (ja) | 2014-10-14 | 2016-08-17 | 花王株式会社 | 三次元造形用可溶性材料 |
| JP6568218B2 (ja) | 2014-12-23 | 2019-08-28 | ブリヂストン アメリカズ タイヤ オペレーションズ、 エルエルシー | 化学線硬化型高分子混合物、硬化高分子混合物、及び関連するプロセス |
| FR3030529B1 (fr) | 2014-12-23 | 2017-01-27 | Arkema France | Copolymere a blocs hydrosoluble et son utilisation comme materiau support pour impression 3d |
| WO2016205690A1 (en) | 2015-06-19 | 2016-12-22 | Stratasys, Inc. | Water dispersible polymer for use in additive manufacturing |
| EP3328930B1 (en) | 2015-07-27 | 2019-05-29 | Dow Global Technologies LLC | Method to additive manufacture biocompatible material and articles made by the method |
| WO2017020020A1 (en) * | 2015-07-30 | 2017-02-02 | Wildcat Dp Llc | Material and method for 3-d fabrication |
| WO2017048710A1 (en) | 2015-09-14 | 2017-03-23 | Carbon, Inc. | Light-curable article of manufacture with portions of differing solubility |
| US10647873B2 (en) | 2015-10-30 | 2020-05-12 | Carbon, Inc. | Dual cure article of manufacture with portions of differing solubility |
| KR102053481B1 (ko) * | 2015-11-03 | 2019-12-06 | 주식회사 엘지화학 | 3차원 조형물의 형성 방법 |
| US11049415B2 (en) | 2015-12-03 | 2021-06-29 | Dental Education Laboratories, Inc. | Anatomic apparatus and training system for remote and interactive hands-on surgical training |
| US11097531B2 (en) | 2015-12-17 | 2021-08-24 | Bridgestone Americas Tire Operations, Llc | Additive manufacturing cartridges and processes for producing cured polymeric products by additive manufacturing |
| CN108602048B (zh) | 2015-12-18 | 2022-02-18 | 坎特伯雷大学 | 分离介质 |
| US11045997B2 (en) * | 2015-12-24 | 2021-06-29 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| US10953595B2 (en) | 2015-12-24 | 2021-03-23 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| WO2017119218A1 (ja) * | 2016-01-05 | 2017-07-13 | コニカミノルタ株式会社 | 粉末材料、立体造形物の製造方法および立体造形装置 |
| US10449713B2 (en) | 2016-01-25 | 2019-10-22 | Te Connectivity Corporation | Article and method of forming an article |
| US20190143582A1 (en) | 2016-05-04 | 2019-05-16 | Covestro Deutschland Ag | Copolycarbonate as a supporting material in 3-d printing |
| CN109789632A (zh) | 2016-09-12 | 2019-05-21 | 沙特基础工业全球技术公司 | 用于增材制造工艺的牺牲高热支架材料 |
| EP3532267B1 (en) | 2016-10-27 | 2023-03-01 | Bridgestone Americas Tire Operations, LLC | Processes for producing cured polymeric products by additive manufacturing |
| JP6990594B2 (ja) * | 2017-02-07 | 2022-01-12 | 株式会社日本触媒 | 水性樹脂組成物 |
| CN110730800B (zh) | 2017-05-26 | 2022-08-19 | 无限材料解决方案有限公司 | 水性聚合物组合物 |
| WO2018227094A1 (en) | 2017-06-08 | 2018-12-13 | Buchanan Stephen L | Tooth or tooth replica holding sleeve for use with an paex locator |
| JP2019064258A (ja) * | 2017-09-28 | 2019-04-25 | 花王株式会社 | 三次元造形用可溶性材料 |
| WO2019065824A1 (ja) * | 2017-09-28 | 2019-04-04 | 花王株式会社 | 三次元造形用可溶性材料 |
| EP3694939A1 (en) | 2017-10-10 | 2020-08-19 | Stratasys, Inc. | Water-dispersible thermoplastic material comprising sulfonated copolymer for use in additive manufacturing |
| FR3074181B1 (fr) | 2017-11-28 | 2020-11-06 | Arkema France | Composition copolymerique hydrosoluble a ph neutre |
| CN111670105B (zh) * | 2018-02-02 | 2022-06-07 | 三菱化学株式会社 | 三维造型用材料、三维造型用细丝、该细丝的卷绕体和三维打印机用盒 |
| EP3755785A1 (en) | 2018-02-22 | 2020-12-30 | The Procter & Gamble Company | Methods for making unit dose articles |
| WO2020077127A1 (en) * | 2018-10-10 | 2020-04-16 | Stratasys, Inc. | Water dispersible sulfonated thermoplastic copolymer for use in additive manufacturing |
| FR3088327B1 (fr) | 2018-11-08 | 2021-11-05 | Arkema France | Composition copolymerique hydrosoluble |
| US20210178661A1 (en) * | 2019-12-17 | 2021-06-17 | Ticona Llc | Three-Dimensional Printing System Employing A Toughened Polyarylene Sulfide Composition |
| EP3865302B1 (en) * | 2020-02-14 | 2024-08-14 | iSQUARED AG | Copolymer for use in a digital manufacturing process |
| US12371581B2 (en) | 2020-03-25 | 2025-07-29 | Infinite Material Solutions, Llc | High performance water soluble polymer compositions |
| US20230271379A1 (en) * | 2020-08-06 | 2023-08-31 | Signify Holding B.V. | Continuous hollow tube printing using fdm |
| US12157800B2 (en) | 2021-04-12 | 2024-12-03 | Stratasys, Inc. | Method for underwater processing of water-dispersible materials |
| KR20240123438A (ko) | 2021-04-19 | 2024-08-13 | 자빌 인코퍼레이티드 | 개선된 적층 제조 분리 지지 재료 |
| FR3124420B1 (fr) * | 2021-06-23 | 2024-09-27 | Arkema France | Utilisation de copolymères multi blocs en tant que matériau sacrificiel dans un procédé d’impression 3D |
| WO2024076464A1 (en) | 2022-10-03 | 2024-04-11 | Jabil Inc. | Additive manufactured article comprising a grafted aliphatic polyketone, filament and powder |
| NL2036419B1 (en) | 2023-12-04 | 2025-06-13 | Tectonic 3D Swip B V | Fused deposition modeling method and method to dissolve a high temperature polycarbonate support used in this method |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU463914B2 (en) | 1971-09-22 | 1975-08-07 | Dow Chemical Company, The | Impact resistant polymers ofa resinous copolymer ofan alkenyl aromatic. monomer and unsaturated dicarboxylic anhydride |
| DE3034171A1 (de) * | 1980-09-11 | 1982-05-06 | Basf Ag, 6700 Ludwigshafen | Alkaliloesliche harze auf basis von copolymerisaten aus monoolefinisch ungesaettigten carbonsaeuren und durch aromaten substituierten (alpha) -olefinen und ihre verwendung als harzkomponente in polymerdispersionen |
| JPH0260909A (ja) * | 1988-08-26 | 1990-03-01 | Nippon Oil & Fats Co Ltd | 熱硬化型水溶性樹脂及びその硬化物 |
| US5121329A (en) | 1989-10-30 | 1992-06-09 | Stratasys, Inc. | Apparatus and method for creating three-dimensional objects |
| JPH075302A (ja) * | 1993-06-15 | 1995-01-10 | Tosoh Corp | マイクロ集光レンズ形成用感光性組成物 |
| US5503785A (en) | 1994-06-02 | 1996-04-02 | Stratasys, Inc. | Process of support removal for fused deposition modeling |
| US6228923B1 (en) * | 1997-04-02 | 2001-05-08 | Stratasys, Inc. | Water soluble rapid prototyping support and mold material |
| US6070107A (en) * | 1997-04-02 | 2000-05-30 | Stratasys, Inc. | Water soluble rapid prototyping support and mold material |
| US7754807B2 (en) | 1999-04-20 | 2010-07-13 | Stratasys, Inc. | Soluble material and process for three-dimensional modeling |
| HK1043087B (zh) | 1999-04-20 | 2007-12-28 | 斯特拉塔西斯公司 | 可溶材料和三维模型的加工方法 |
| JP4148733B2 (ja) * | 2002-09-02 | 2008-09-10 | リコープリンティングシステムズ株式会社 | 三次元積層造形法とその装置 |
| EP1648945A4 (en) | 2003-07-24 | 2008-06-25 | Nova Chem Inc | STYRENE RESIN COMPOSITION AND ARTICLES PRODUCED THEREFROM |
| JP2006111710A (ja) * | 2004-10-14 | 2006-04-27 | Nof Corp | 無水マレイン酸（共）重合体の製造方法、無水マレイン酸（共）重合体、及びその加水分解物 |
| CN100387419C (zh) * | 2006-01-16 | 2008-05-14 | 南京师范大学 | 采用逐层喷涂方式制作三维物体的方法 |
| CN100340388C (zh) * | 2006-03-03 | 2007-10-03 | 南京师范大学 | 制作三维物体和支撑的打印成型方法 |
| US8246888B2 (en) | 2008-10-17 | 2012-08-21 | Stratasys, Inc. | Support material for digital manufacturing systems |
-
2011
- 2011-04-20 EP EP11163199A patent/EP2514775A1/en not_active Withdrawn
-
2012
- 2012-03-13 EP EP12708835.9A patent/EP2699611B1/en active Active
- 2012-03-13 RU RU2013151313/04A patent/RU2013151313A/ru not_active Application Discontinuation
- 2012-03-13 US US13/982,431 patent/US8822590B2/en active Active
- 2012-03-13 CA CA2833752A patent/CA2833752C/en active Active
- 2012-03-13 WO PCT/EP2012/054306 patent/WO2012143182A1/en not_active Ceased
- 2012-03-13 BR BR112013023429A patent/BR112013023429B8/pt not_active IP Right Cessation
- 2012-03-13 AU AU2012244499A patent/AU2012244499B2/en not_active Ceased
- 2012-03-13 CN CN201280009711.4A patent/CN103380156B/zh not_active Expired - Fee Related
- 2012-03-13 JP JP2014505552A patent/JP5893128B2/ja not_active Expired - Fee Related
- 2012-03-13 KR KR1020137026041A patent/KR20140009442A/ko not_active Withdrawn
-
2013
- 2013-07-07 IL IL227363A patent/IL227363A/en active IP Right Grant