JP2014510174A5 - - Google Patents
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- Publication number
- JP2014510174A5 JP2014510174A5 JP2014500329A JP2014500329A JP2014510174A5 JP 2014510174 A5 JP2014510174 A5 JP 2014510174A5 JP 2014500329 A JP2014500329 A JP 2014500329A JP 2014500329 A JP2014500329 A JP 2014500329A JP 2014510174 A5 JP2014510174 A5 JP 2014510174A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- coating
- coating composition
- component
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 125000003118 aryl group Chemical group 0.000 claims description 17
- 239000005056 polyisocyanate Substances 0.000 claims description 10
- 229920001228 polyisocyanate Polymers 0.000 claims description 10
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 9
- 125000002947 alkylene group Chemical group 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 7
- 125000005842 heteroatom Chemical group 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 239000013638 trimer Substances 0.000 claims description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 3
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical class NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 3
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 claims description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000008199 coating composition Substances 0.000 claims 18
- 238000000576 coating method Methods 0.000 claims 16
- 239000011248 coating agent Substances 0.000 claims 13
- 239000010410 layer Substances 0.000 claims 9
- 239000003054 catalyst Substances 0.000 claims 7
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 6
- 125000002015 acyclic group Chemical group 0.000 claims 4
- 125000004122 cyclic group Chemical group 0.000 claims 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 4
- 239000000758 substrate Substances 0.000 claims 4
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims 4
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 239000000049 pigment Substances 0.000 claims 3
- 230000008439 repair process Effects 0.000 claims 3
- YQUVCSBJEUQKSH-UHFFFAOYSA-N 3,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(O)=C1 YQUVCSBJEUQKSH-UHFFFAOYSA-N 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 2
- 239000004033 plastic Substances 0.000 claims 2
- 239000002987 primer (paints) Substances 0.000 claims 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- IFNXAMCERSVZCV-UHFFFAOYSA-L zinc;2-ethylhexanoate Chemical compound [Zn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O IFNXAMCERSVZCV-UHFFFAOYSA-L 0.000 claims 2
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 claims 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims 1
- ZDFKSZDMHJHQHS-UHFFFAOYSA-N 2-tert-butylbenzoic acid Chemical compound CC(C)(C)C1=CC=CC=C1C(O)=O ZDFKSZDMHJHQHS-UHFFFAOYSA-N 0.000 claims 1
- BSYNRYMUTXBXSQ-FOQJRBATSA-N 59096-14-9 Chemical compound CC(=O)OC1=CC=CC=C1[14C](O)=O BSYNRYMUTXBXSQ-FOQJRBATSA-N 0.000 claims 1
- 239000005711 Benzoic acid Substances 0.000 claims 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- 239000007983 Tris buffer Substances 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 239000011247 coating layer Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- 239000004922 lacquer Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000003973 paint Substances 0.000 claims 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims 1
- 229920001225 polyester resin Polymers 0.000 claims 1
- 239000004645 polyester resin Substances 0.000 claims 1
- 229920000193 polymethacrylate Polymers 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 229960004889 salicylic acid Drugs 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- QAIYREPTUDZYMV-UHFFFAOYSA-L zinc;2-ethylhexanoate;1-methylimidazole Chemical compound [Zn+2].CN1C=CN=C1.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O QAIYREPTUDZYMV-UHFFFAOYSA-L 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Chemical group 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Chemical group 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- LUYHWJKHJNFYGV-UHFFFAOYSA-N 1,2-diisocyanato-3-phenylbenzene Chemical compound O=C=NC1=CC=CC(C=2C=CC=CC=2)=C1N=C=O LUYHWJKHJNFYGV-UHFFFAOYSA-N 0.000 description 1
- ZTNJGMFHJYGMDR-UHFFFAOYSA-N 1,2-diisocyanatoethane Chemical compound O=C=NCCN=C=O ZTNJGMFHJYGMDR-UHFFFAOYSA-N 0.000 description 1
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- ATOUXIOKEJWULN-UHFFFAOYSA-N 1,6-diisocyanato-2,2,4-trimethylhexane Chemical compound O=C=NCCC(C)CC(C)(C)CN=C=O ATOUXIOKEJWULN-UHFFFAOYSA-N 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- ICLCCFKUSALICQ-UHFFFAOYSA-N 1-isocyanato-4-(4-isocyanato-3-methylphenyl)-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(C=2C=C(C)C(N=C=O)=CC=2)=C1 ICLCCFKUSALICQ-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- XXKOQQBKBHUATC-UHFFFAOYSA-N cyclohexylmethylcyclohexane Chemical compound C1CCCCC1CC1CCCCC1 XXKOQQBKBHUATC-UHFFFAOYSA-N 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161453986P | 2011-03-18 | 2011-03-18 | |
| EP11158846.3 | 2011-03-18 | ||
| EP11158846 | 2011-03-18 | ||
| US61/453,986 | 2011-03-18 | ||
| PCT/EP2012/054546 WO2012126796A1 (de) | 2011-03-18 | 2012-03-15 | Zink-imidazol-carboxylat-komplex katalysierte beschichtungsmittelzusammensetzung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014510174A JP2014510174A (ja) | 2014-04-24 |
| JP2014510174A5 true JP2014510174A5 (enExample) | 2015-04-09 |
| JP6071993B2 JP6071993B2 (ja) | 2017-02-01 |
Family
ID=45819217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014500329A Expired - Fee Related JP6071993B2 (ja) | 2011-03-18 | 2012-03-15 | 亜鉛−イミダゾール−カルボキシレート錯体により触媒反応された被覆剤組成物 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9206330B2 (enExample) |
| EP (1) | EP2686362B1 (enExample) |
| JP (1) | JP6071993B2 (enExample) |
| AU (1) | AU2012230533B2 (enExample) |
| BR (1) | BR112013023578A2 (enExample) |
| ES (1) | ES2530665T3 (enExample) |
| MX (1) | MX2013010492A (enExample) |
| WO (1) | WO2012126796A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2686360B1 (de) * | 2011-03-14 | 2016-10-12 | BASF Coatings GmbH | Polyurethan-beschichtungsmittelzusammensetzung, mehrstufige beschichtungsverfahren unter verwendung dieser beschichtungsmittelzusammensetzungen sowie die verwendung der beschichtungsmittelzusammensetzung als klarlack und pigmentierter lack bzw. anwendung des beschichtungsverfahrens für die automobilreparaturlackierung und/oder für die beschichtung von kunststoffsubstraten und/oder nutzfahrzeugen |
| PL2686361T3 (pl) * | 2011-03-14 | 2015-04-30 | Basf Coatings Gmbh | Poliuretanowa kompozycja środków powłokowych, wieloetapowe sposoby powlekania przy użyciu tych kompozycji środków powłokowych oraz zastosowanie kompozycji środków powłokowych jako lakieru bezbarwnego i lakieru pigmentowanego lub zastosowanie sposobu powlekania do renowacyjnego lakierowania samochodów i/lub do powlekania podłoży z tworzywa sztucznego i/lub pojazdów użytkowych |
| US9139751B2 (en) * | 2011-03-14 | 2015-09-22 | Basf Coatings Gmbh | Polyurethane coating material composition, multistage coating methods using these coating material compositions, and also the use of the coating material composition as clearcoat material and pigmented coating material, and application of the coating method for automotive refinish and/or for the coating of plastics substrates and/or of utility vehicles |
| KR20140119157A (ko) * | 2012-01-25 | 2014-10-08 | 바스프 코팅스 게엠베하 | 아연 (1-메틸이미다졸)비스(2-에틸헥사노에이트) 착물 촉매화 코팅 물질 조성물 |
| WO2014016026A1 (de) | 2012-07-25 | 2014-01-30 | Basf Coatings Gmbh | Polyurethan-beschichtungsmittelzusammensetzung und ihre verwendung, mehrstufige beschichtungsverfahren |
| WO2014016019A1 (de) | 2012-07-25 | 2014-01-30 | Basf Coatings Gmbh | Polyurethan-beschichtungsmittelzusammensetzung, mehrstufige beschichtungsverfahren |
| EP2851379A1 (de) | 2013-09-23 | 2015-03-25 | BASF Coatings GmbH | Beschichtungsmittelzusammensetzungen und daraus hergestelllte, bei niedrigen Temperaturen härtbare Beschichtungen und sowie deren Verwendung |
| EP2851403A1 (de) | 2013-09-23 | 2015-03-25 | BASF Coatings GmbH | Beschichtungsmittelzusammensetzungen und daraus hergestellte, bei niedrigen temperaturen härtbare beschichtungen und sowie deren verwendung |
| JPWO2015087920A1 (ja) * | 2013-12-12 | 2017-03-16 | 関西ペイント株式会社 | 塗料組成物 |
| EP2910612A1 (de) | 2014-02-20 | 2015-08-26 | BASF Coatings GmbH | Beschichtungsmittelzusammensetzungen und daraus hergestellte Beschichtungen und sowie deren Verwendung |
| EP3466998A4 (en) | 2016-05-26 | 2020-01-15 | Sekisui Chemical Co., Ltd. | POLYURETHANE COMPOSITION |
| JP7532375B2 (ja) | 2018-12-24 | 2024-08-13 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 水性コーティングの低温硬化 |
| CN113825782B (zh) * | 2019-04-18 | 2024-01-09 | 陶氏环球技术有限责任公司 | 粘合剂组合物 |
| EP4015547A1 (de) | 2020-12-15 | 2022-06-22 | Covestro Deutschland AG | Nichtionisch hydrophilierte polyisocyanate, katalyse mit zink-komplexen |
| WO2023157942A1 (ja) * | 2022-02-18 | 2023-08-24 | 関西ペイント株式会社 | 塗料組成物及び塗膜形成方法 |
| US20250161886A1 (en) * | 2023-08-02 | 2025-05-22 | The Board Of Regents Of The University Of Oklahoma | Zinc imidazole salicylaldoxime-based adsorptive membranes for removal of metal ions from aqueous solutions |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2434185A1 (de) | 1974-07-16 | 1976-02-05 | Bayer Ag | Verfahren zur herstellung von amidin-metall-komplexen |
| DE2835451C2 (de) | 1978-08-12 | 1985-10-24 | Saarbergwerke AG, 6600 Saarbrücken | Verfahren zum Verfestigen von Kohle und/oder Gestein im Bergbau |
| EP0249201A3 (en) | 1986-06-10 | 1989-07-19 | Union Carbide Corporation | High solids sag resistant cycloaliphatic epoxy coatings containing low molecular weight high tg organic polymeric sag resisting additives |
| NO170944C (no) | 1987-01-24 | 1992-12-30 | Akzo Nv | Fortykkede, vandige preparater, samt anvendelse av slike |
| US5084541A (en) | 1988-12-19 | 1992-01-28 | American Cyanamid Company | Triazine crosslinking agents and curable compositions |
| US4939213A (en) | 1988-12-19 | 1990-07-03 | American Cyanamid Company | Triazine crosslinking agents and curable compositions containing the same |
| JPH032288A (ja) * | 1989-05-30 | 1991-01-08 | Hitachi Chem Co Ltd | ポリウレタン塗料の硬化速度の制御方法 |
| DE4310414A1 (de) | 1993-03-31 | 1994-10-06 | Basf Lacke & Farben | Verfahren zur Herstellung einer zweischichtigen Decklackierung auf einer Substratoberfläche |
| DE4310413A1 (de) | 1993-03-31 | 1994-10-06 | Basf Lacke & Farben | Nichtwäßriger Lack und Verfahren zur Herstellung einer zweischichtigen Decklackierung |
| TW328955B (en) | 1993-05-14 | 1998-04-01 | Cytec Tech Corp | Process for preparing bis- or tris-carbamate functional 1,3,5-triazines, substantially halogen contamination free crosslinker compositions and new bis-or tris-carbamate functional 1,3,5-triazines |
| WO1997012945A1 (en) | 1995-10-06 | 1997-04-10 | Cabot Corporation | Aqueous thixotropes for waterborne systems |
| JPH09125000A (ja) * | 1995-11-01 | 1997-05-13 | Asahi Chem Ind Co Ltd | 上塗り塗料及び塗装方法 |
| AU6801298A (en) * | 1997-06-05 | 1998-12-10 | Rohm And Haas Company | Coating compositions having extended pot life and shortened cure time and combination of chemicals used therein |
| US6046270A (en) | 1998-10-14 | 2000-04-04 | Bayer Corporation | Silane-modified polyurethane resins, a process for their preparation and their use as moisture-curable resins |
| ES2280235T3 (es) | 1999-07-30 | 2007-09-16 | Ppg Industries Ohio, Inc. | Composiciones de recubrimiento que tienen resistencia al rayado mejorada, sustratos recubiertos y metodos relacionados con los mismos. |
| JP2002212499A (ja) * | 2001-01-22 | 2002-07-31 | Nippon Paint Co Ltd | 熱硬化性艶消し粉体塗料組成物 |
| DE10132938A1 (de) | 2001-07-06 | 2003-01-16 | Degussa | Nichtwässriges, wärmehärtendes Zweikomponenten-Beschichtungsmittel |
| DE10244142A1 (de) | 2002-09-23 | 2004-04-01 | Henkel Kgaa | Stabile Polyurethansysteme |
| DE602004004561T2 (de) | 2003-03-18 | 2007-11-15 | Tosoh Corp. | Katalysatorzusammensetzung für die Herstellung von Polyurethanharz und Verfahren zu ihrer Herstellung |
| US6992149B2 (en) | 2004-02-12 | 2006-01-31 | Basf Corporation | Use of carbamate-modified aminoplast resins to improve the appearance and performance of powder coatings |
| US7485729B2 (en) | 2004-08-12 | 2009-02-03 | King Industries, Inc. | Organometallic compositions and coating compositions |
| US20060036007A1 (en) | 2004-08-12 | 2006-02-16 | King Industries, Inc. | Organometallic compositions and coating compositions |
| US20100279005A1 (en) * | 2007-12-20 | 2010-11-04 | E.I. Du Pont De Nemours And Company | Process for producing a multilayer coating |
| DE102008026341A1 (de) | 2008-05-07 | 2009-11-12 | Bayer Materialscience Ag | Katalysatoren zur Synthese von Polyurethanen |
-
2012
- 2012-03-15 BR BR112013023578A patent/BR112013023578A2/pt not_active IP Right Cessation
- 2012-03-15 MX MX2013010492A patent/MX2013010492A/es not_active Application Discontinuation
- 2012-03-15 ES ES12708548T patent/ES2530665T3/es active Active
- 2012-03-15 AU AU2012230533A patent/AU2012230533B2/en not_active Ceased
- 2012-03-15 WO PCT/EP2012/054546 patent/WO2012126796A1/de not_active Ceased
- 2012-03-15 EP EP12708548.8A patent/EP2686362B1/de not_active Not-in-force
- 2012-03-15 JP JP2014500329A patent/JP6071993B2/ja not_active Expired - Fee Related
- 2012-03-15 US US14/006,024 patent/US9206330B2/en not_active Expired - Fee Related
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