ES2530665T3 - Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc - Google Patents

Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc Download PDF

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Publication number
ES2530665T3
ES2530665T3 ES12708548T ES12708548T ES2530665T3 ES 2530665 T3 ES2530665 T3 ES 2530665T3 ES 12708548 T ES12708548 T ES 12708548T ES 12708548 T ES12708548 T ES 12708548T ES 2530665 T3 ES2530665 T3 ES 2530665T3
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Prior art keywords
radical
zinc
aromatic
aryl
composition
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ES12708548T
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English (en)
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Elke Westhoff
Peter Hoffmann
Bernadette Möller
Benedikt Schnier
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BASF Coatings GmbH
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BASF Coatings GmbH
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • B05D7/534—Base coat plus clear coat type the first layer being let to dry at least partially before applying the second layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/54—No clear coat specified
    • B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • C08G18/165—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22 covered by C08G18/18 and C08G18/24
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
    • C08G18/168—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
    • C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Abstract

Composición de agente de recubrimiento que contiene - por lo menos un componente (A) que tiene grupos polihidroxilo, - por lo menos un componente (B) que tiene grupos poliisocianato, - por lo menos un complejo de imidazol-carboxilato de zinc (D) que puede ser producido mediante reacción de por lo menos un biscarboxilato de Zn (II) con uno o varios imidazoles de la fórmula general (I)**Fórmula** donde R1 representa un radical hidrocarburo acíclico o cíclico, saturado o insaturado, un radical hidrocarburo aromático o un radical Rv-arilo, donde Rv representa un radical alquileno y arilo representa un radical aromático, y donde todos los radicales antes mencionados pueden contener heteroátomos, R2, R3 y R4 representan independientemente uno de otro hidrógeno, un radical hidrocarburo acíclico o cíclico, saturado o insaturado, un radical hidrocarburo aromático o un radical Rv-arilo, donde Rv representa un radical alquileno y arilo representa un radical aromático y donde todos los radicales antes mencionados pueden contener heteroátomos, con la condición de que se excluyen complejos de (1-metilimidazol)-bis(2-etilhexanoato) de zinc (D), los cuales son obtenibles por reacción de bis(2-etilhexanoato de zinc (II)) con 1-metilimidazol en una relación molar de 1 a <= 2,2, y - por lo menos un ácido carboxílico aromático (S) monomérico, en el cual el grupo carboxilo está en conjugación con un sistema de electrones pi.
ES12708548T 2011-03-18 2012-03-15 Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc Active ES2530665T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161453986P 2011-03-18 2011-03-18
EP11158846 2011-03-18
PCT/EP2012/054546 WO2012126796A1 (de) 2011-03-18 2012-03-15 Zink-imidazol-carboxylat-komplex katalysierte beschichtungsmittelzusammensetzung

Publications (1)

Publication Number Publication Date
ES2530665T3 true ES2530665T3 (es) 2015-03-04

Family

ID=45819217

Family Applications (1)

Application Number Title Priority Date Filing Date
ES12708548T Active ES2530665T3 (es) 2011-03-18 2012-03-15 Composición de agentes de recubrimiento catalizada por complejo de imidazol-carboxilato de zinc

Country Status (8)

Country Link
US (1) US9206330B2 (es)
EP (1) EP2686362B1 (es)
JP (1) JP6071993B2 (es)
AU (1) AU2012230533B2 (es)
BR (1) BR112013023578A2 (es)
ES (1) ES2530665T3 (es)
MX (1) MX2013010492A (es)
WO (1) WO2012126796A1 (es)

Families Citing this family (14)

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Publication number Priority date Publication date Assignee Title
MX341193B (es) * 2011-03-14 2016-08-11 Basf Coatings Gmbh Composicion de material de revestimiento de poliuretano, metodos de revestimiento de etapas multiples que utilizan estas composiciones de material de revestimiento, y tambien el uso de la composicion de material de revestimiento como material de revestimiento transparente y material de revestimiento pigmentado, y la aplicacion del metodo de revestimiento para dar un nuevo acabado automotriz y/o para el revestimiento de sustratos de plastico y/o de vehiculos utilitarios.
ES2527273T3 (es) * 2011-03-14 2015-01-22 Basf Coatings Gmbh Composición de agentes de recubrimiento de poliuretano, métodos de recubrimiento de varias etapas por empleo de estas composiciones de agentes de recubrimiento, así como el empleo de las composiciones de agentes de recubrimiento como laca clara y laca pigmentada o bien aplicación del método de recubrimiento, para el lacado de refacción de automóviles y/o para el recubrimiento de sustratos plásticos y/o vehículos utilitarios
US9340703B2 (en) * 2011-03-14 2016-05-17 Basf Coatings Gmbh Polyurethane coating agent composition, multistage coating method using said coating agent compositions, and use of the coating agent compositions as clear coating or pigmented coating material, and use of the coating method for automotive repair painting and/or for coating plastics substrates and/or of commercial vehicles
ES2646773T3 (es) * 2012-01-25 2017-12-15 Basf Coatings Gmbh Composición de material de recubrimiento catalizada por el complejo (1-metilimidazol)bis(2-etilhexanoato) de cinc
BR112015001335A2 (pt) 2012-07-25 2017-07-04 Basf Coatings Gmbh composição de material de revestimento não aquoso, uso da mesma, método de revestimento multiestágios e sistema de tinta efetivo e/ou colorido de multirrevestimento
EP2877512B1 (de) 2012-07-25 2017-08-09 BASF Coatings GmbH Polyurethan-beschichtungsmittelzusammensetzung und ihre verwendung, mehrstufige beschichtungsverfahren
EP2851379A1 (de) 2013-09-23 2015-03-25 BASF Coatings GmbH Beschichtungsmittelzusammensetzungen und daraus hergestelllte, bei niedrigen Temperaturen härtbare Beschichtungen und sowie deren Verwendung
EP2851403A1 (de) 2013-09-23 2015-03-25 BASF Coatings GmbH Beschichtungsmittelzusammensetzungen und daraus hergestellte, bei niedrigen temperaturen härtbare beschichtungen und sowie deren verwendung
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MX2021007735A (es) 2018-12-24 2021-08-05 Basf Coatings Gmbh Curado a baja temperatura de revestimientos a base de agua.
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EP4015547A1 (de) 2020-12-15 2022-06-22 Covestro Deutschland AG Nichtionisch hydrophilierte polyisocyanate, katalyse mit zink-komplexen

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Also Published As

Publication number Publication date
EP2686362B1 (de) 2015-01-14
US9206330B2 (en) 2015-12-08
AU2012230533A1 (en) 2013-09-19
JP6071993B2 (ja) 2017-02-01
AU2012230533B2 (en) 2014-08-28
WO2012126796A1 (de) 2012-09-27
MX2013010492A (es) 2013-10-17
JP2014510174A (ja) 2014-04-24
EP2686362A1 (de) 2014-01-22
BR112013023578A2 (pt) 2016-12-06
US20140162074A1 (en) 2014-06-12

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