JP2014122344A5 - - Google Patents
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- JP2014122344A5 JP2014122344A5 JP2013260212A JP2013260212A JP2014122344A5 JP 2014122344 A5 JP2014122344 A5 JP 2014122344A5 JP 2013260212 A JP2013260212 A JP 2013260212A JP 2013260212 A JP2013260212 A JP 2013260212A JP 2014122344 A5 JP2014122344 A5 JP 2014122344A5
- Authority
- JP
- Japan
- Prior art keywords
- lubricating oil
- dialkyl dithiophosphate
- group
- carbon atoms
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000010687 lubricating oil Substances 0.000 claims 32
- 229910052751 metal Inorganic materials 0.000 claims 9
- 239000002184 metal Substances 0.000 claims 9
- 150000003839 salts Chemical class 0.000 claims 9
- 239000000654 additive Substances 0.000 claims 8
- 230000000996 additive effect Effects 0.000 claims 8
- 125000004432 carbon atom Chemical group C* 0.000 claims 8
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 239000003607 modifier Substances 0.000 claims 6
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- -1 i-hexyl Chemical group 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 150000003138 primary alcohols Chemical class 0.000 claims 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 3
- 239000002199 base oil Substances 0.000 claims 3
- 239000003599 detergent Substances 0.000 claims 3
- 239000010705 motor oil Substances 0.000 claims 3
- 229910052698 phosphorus Inorganic materials 0.000 claims 3
- 239000011574 phosphorus Substances 0.000 claims 3
- 150000003333 secondary alcohols Chemical class 0.000 claims 3
- 229910052725 zinc Inorganic materials 0.000 claims 3
- 239000011701 zinc Substances 0.000 claims 3
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 239000002270 dispersing agent Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229920006395 saturated elastomer Polymers 0.000 claims 2
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims 1
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 claims 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims 1
- 239000005642 Oleic acid Substances 0.000 claims 1
- DIOYAVUHUXAUPX-KHPPLWFESA-N Oleoyl sarcosine Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-KHPPLWFESA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 239000002518 antifoaming agent Substances 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
Claims (28)
- 主要量の基油と少量の添加剤パッケージとを含んでなる潤滑油であって、該添加剤パッケージが、式Ｉ：
の、１種以上の摩擦修正剤を含んでなる潤滑油。 - 添加剤パッケージが少なくとも２種の摩擦修正剤を含んでなる、請求項１の潤滑油。
- 添加剤パッケージが少なくとも２種の、式Ｉの摩擦修正剤を含んでなる、請求項１の潤滑油。
- Ｒが約８〜約１８個の炭素原子をもつ、請求項１〜３のいずれか１項の潤滑油。
- Ｒが
- Ｒ1が約１０〜約１８個の炭素原子をもつ、請求項５の潤滑油。
- Ｒ2が水素またはメチル基である、請求項５の潤滑油。
- 添加剤パッケージが更に、清浄剤、分散剤、抗酸化剤、消泡剤、チタン含有化合物、リン含有化合物、粘度指数向上剤、流動点降下剤および希釈油よりなる群から選択される少なくとも１種の添加剤を含んでなる、請求項１〜７のいずれか１項の潤滑油。
- 更に、少なくとも１種の金属ジアルキル・ジチオホスフェート塩を含んでなる、請求項１〜８のいずれか１項の潤滑油。
- 少なくとも１種の金属ジアルキル・ジチオホスフェート塩が、以下の式：
により表される、少なくとも１種の亜鉛ジアルキル・ジチオホスフェートを含んでなる、請求項９の潤滑油。 - Ｒ’およびＲ”基がエチル、ｎ−プロピル、ｉ−プロピル、ｎ−ブチル、ｉ−ブチル、ｓｅｃ−ブチル、アミル、ｎ−ヘキシル、ｉ−ヘキシル、ｎ−オクチル、デシル、ドデシル、オクタデシル、２−エチルヘキシル、フェニル、ブチルフェニル、シクロヘキシル、メチルシクロペンチル、プロペニル、ブテニルから独立して選択される、請求項１０の潤滑油。
- 少なくとも１種の金属ジアルキル・ジチオホスフェート塩のアルキル基が、第一級アルコール、第二級アルコール、または第一級および第二級アルコールの混合物から誘導される、請求項９の潤滑油。
- 少なくとも１種の金属ジアルキル・ジチオホスフェート塩のアルキル基の１００モルパーセントが、第一級アルコールから誘導される、請求項９の潤滑油。
- 少なくとも一つの金属ジアルキル・ジチオホスフェート塩のアルキル基の少なくとも７５モルパーセントが、４−メチル−２−ペンタノールから誘導される、請求項９の潤滑油。
- 少なくとも１種の金属ジアルキル・ジチオホスフェート塩のアルキル基の８０モルパーセント超が、４−メチル−２−ペンタノールから誘導される、請求項９の潤滑油。
- 少なくとも２種の金属ジアルキル・ジチオホスフェート塩を含んでなり、第一の金属ジアルキル・ジチオホスフェート塩が第一級アルコールから誘導されるアルキル基を含んでなり、そして第二の金属ジアルキル・ジチオホスフェート塩が第二級アルコールから誘導されるアルキル基を含んでなる、請求項９の潤滑油。
- 更に、少なくとも１種の分散剤を含んでなる、請求項１〜１６のいずれか１項の潤滑油。
- 更に少なくとも１種の清浄剤を含んでなる、請求項１〜１７のいずれか１項の潤滑油。
- 潤滑油がエンジン油である、請求項１〜１８のいずれか１項の潤滑油組成物。
- 約０．０５〜約２．０重量％の１種以上の式Ｉの摩擦修正剤を含んでなる、請求項１の潤滑油。
- 約０．１〜約２．０重量％の１種以上の式Ｉの摩擦修正剤を含んでなる、請求項１の潤滑油。
- 約０．５〜約２．０重量％の１種以上の式Ｉの摩擦修正剤を含んでなる、請求項１の潤滑油。
- 少なくとも９０％の飽和度を有し、グループＩＩ、グループＩＩＩ、グループＩＶ、及び、グループＶ、並びにこれらの混合物から選択される主要量の基油を含む、請求項１の潤滑油。
- 約５０〜約１０００ｐｐｍのリンを含むエンジン油である、請求項１の潤滑油。
- 添加剤パッケージが、オレオイルサルコシンと２−アミノ−２−（ヒドロキシメチル）プロパン−１，３−ジオールの反応生成物を含む、請求項１の潤滑油。
- 添加剤パッケージが、オレイン酸と２−アミノ−２−（ヒドロキシメチル）プロパン−１，３−ジオールの反応生成物を含む、請求項１の潤滑油。
- 約５０〜約１０００ｐｐｍのリンを含むエンジン油であって、少なくとも９０％の飽和度を有し、グループＩＩ、グループＩＩＩ、グループＩＶ、及び、グループＶ、並びにこれらの混合物から選択される主要量の基油、並びに、カルシウム含有清浄剤を含む、請求項２１の潤滑油。
- 更に、亜鉛ジアルキル・ジチオホスフェートを含む、請求項２７の潤滑油。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/725,482 | 2012-12-21 | ||
| US13/725,482 US9550955B2 (en) | 2012-12-21 | 2012-12-21 | Friction modifiers for lubricating oils |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014122344A JP2014122344A (ja) | 2014-07-03 |
| JP2014122344A5 true JP2014122344A5 (ja) | 2016-03-10 |
Family
ID=49916892
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013260212A Withdrawn JP2014122344A (ja) | 2012-12-21 | 2013-12-17 | 潤滑油のための摩擦修正剤 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9550955B2 (ja) |
| EP (1) | EP2746370B1 (ja) |
| JP (1) | JP2014122344A (ja) |
| KR (1) | KR20140081747A (ja) |
| CN (1) | CN103881788A (ja) |
| BR (1) | BR102013032934A2 (ja) |
| CA (1) | CA2836679A1 (ja) |
| SG (1) | SG2013094743A (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2017011143A (es) | 2015-03-04 | 2017-11-28 | Huntsman Petrochemical Llc | Modificadores de friccion organicos novedosos. |
| WO2016183207A1 (en) | 2015-05-11 | 2016-11-17 | Northwestern University | Cyclen friction modifiers for boundary lubrication |
| US10323205B2 (en) * | 2016-05-05 | 2019-06-18 | Afton Chemical Corporation | Lubricant compositions for reducing timing chain stretch |
| US10443558B2 (en) * | 2017-01-18 | 2019-10-15 | Afton Chemical Corporation | Lubricants with calcium and magnesium-containing detergents and their use for improving low-speed pre-ignition and for corrosion resistance |
| US20190002784A1 (en) * | 2017-06-30 | 2019-01-03 | Chevron Oronite Company Llc | Low viscosity engine oils containing isomerized phenolic-based detergents |
| CN111936605B (zh) | 2017-11-30 | 2022-10-11 | 胜牌许可和知识产权有限公司 | 用于车用机油的摩擦改进剂 |
| WO2022043891A1 (en) * | 2020-08-26 | 2022-03-03 | Eni S.P.A. | Friction reducing additives and process for preparing the same |
| CN113293044A (zh) * | 2021-05-26 | 2021-08-24 | 长沙望城石油化工有限公司 | 一种长效抗磨减摩剂组合物及润滑脂及加工油 |
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| RU2012108102A (ru) | 2009-08-05 | 2013-09-10 | Басф Се | Смазочная композиция |
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| CN102329681A (zh) | 2011-09-05 | 2012-01-25 | 王琴 | 齿轮润滑添加剂 |
-
2012
- 2012-12-21 US US13/725,482 patent/US9550955B2/en active Active
-
2013
- 2013-12-13 CA CA2836679A patent/CA2836679A1/en not_active Abandoned
- 2013-12-17 JP JP2013260212A patent/JP2014122344A/ja not_active Withdrawn
- 2013-12-20 SG SG2013094743A patent/SG2013094743A/en unknown
- 2013-12-20 BR BRBR102013032934-7A patent/BR102013032934A2/pt active Search and Examination
- 2013-12-20 KR KR1020130160691A patent/KR20140081747A/ko not_active Application Discontinuation
- 2013-12-20 EP EP13199054.1A patent/EP2746370B1/en active Active
- 2013-12-23 CN CN201310716569.3A patent/CN103881788A/zh active Pending
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