JP2013542334A - 難燃繊維、ヤーンおよびこれらから作られた布 - Google Patents
難燃繊維、ヤーンおよびこれらから作られた布 Download PDFInfo
- Publication number
- JP2013542334A JP2013542334A JP2013530277A JP2013530277A JP2013542334A JP 2013542334 A JP2013542334 A JP 2013542334A JP 2013530277 A JP2013530277 A JP 2013530277A JP 2013530277 A JP2013530277 A JP 2013530277A JP 2013542334 A JP2013542334 A JP 2013542334A
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- JP
- Japan
- Prior art keywords
- flame retardant
- fiber
- fibers
- melamine
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 184
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 183
- 239000000835 fiber Substances 0.000 title claims abstract description 124
- 239000004744 fabric Substances 0.000 title claims abstract description 77
- 239000000654 additive Substances 0.000 claims abstract description 48
- 229920006012 semi-aromatic polyamide Polymers 0.000 claims abstract description 25
- 230000000996 additive effect Effects 0.000 claims description 37
- 101000576320 Homo sapiens Max-binding protein MNT Proteins 0.000 claims description 31
- 229920006121 Polyxylylene adipamide Polymers 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 29
- 229920000297 Rayon Polymers 0.000 claims description 25
- 239000002964 rayon Substances 0.000 claims description 25
- 229920000877 Melamine resin Polymers 0.000 claims description 16
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 229920000742 Cotton Polymers 0.000 claims description 14
- 239000004693 Polybenzimidazole Substances 0.000 claims description 12
- 229920002480 polybenzimidazole Polymers 0.000 claims description 12
- 229920000728 polyester Polymers 0.000 claims description 12
- -1 aliphatic diamines Chemical class 0.000 claims description 11
- 239000004760 aramid Substances 0.000 claims description 11
- 229920003235 aromatic polyamide Polymers 0.000 claims description 11
- 229910052736 halogen Inorganic materials 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 238000009987 spinning Methods 0.000 claims description 10
- 229920000388 Polyphosphate Polymers 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- 239000001205 polyphosphate Substances 0.000 claims description 9
- 235000011176 polyphosphates Nutrition 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 239000004745 nonwoven fabric Substances 0.000 claims description 8
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229920000433 Lyocell Polymers 0.000 claims description 6
- 229920002821 Modacrylic Polymers 0.000 claims description 6
- CGFYHILWFSGVJS-UHFFFAOYSA-N silicic acid;trioxotungsten Chemical compound O[Si](O)(O)O.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 CGFYHILWFSGVJS-UHFFFAOYSA-N 0.000 claims description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 5
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 5
- 244000025254 Cannabis sativa Species 0.000 claims description 5
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 5
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 5
- 241000208202 Linaceae Species 0.000 claims description 5
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 235000009120 camo Nutrition 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 235000005607 chanvre indien Nutrition 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000011487 hemp Substances 0.000 claims description 5
- 239000005011 phenolic resin Substances 0.000 claims description 5
- 229920001568 phenolic resin Polymers 0.000 claims description 5
- 229920000927 poly(p-phenylene benzobisoxazole) Polymers 0.000 claims description 5
- 210000002268 wool Anatomy 0.000 claims description 5
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 claims description 4
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 244000241257 Cucumis melo Species 0.000 claims description 4
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 150000004984 aromatic diamines Chemical class 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 4
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 229920000393 Nylon 6/6T Polymers 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- XSAOTYCWGCRGCP-UHFFFAOYSA-K aluminum;diethylphosphinate Chemical compound [Al+3].CCP([O-])(=O)CC.CCP([O-])(=O)CC.CCP([O-])(=O)CC XSAOTYCWGCRGCP-UHFFFAOYSA-K 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 3
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 claims description 3
- UDATXMIGEVPXTR-UHFFFAOYSA-N 1,2,4-triazolidine-3,5-dione Chemical class O=C1NNC(=O)N1 UDATXMIGEVPXTR-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 2
- 239000004110 Zinc silicate Substances 0.000 claims description 2
- 239000005083 Zinc sulfide Substances 0.000 claims description 2
- CFUMBHCUWAMIBK-UHFFFAOYSA-N [B+3].[O-]B([O-])[O-] Chemical compound [B+3].[O-]B([O-])[O-] CFUMBHCUWAMIBK-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- 229940106691 bisphenol a Drugs 0.000 claims description 2
- YZYDPPZYDIRSJT-UHFFFAOYSA-K boron phosphate Chemical compound [B+3].[O-]P([O-])([O-])=O YZYDPPZYDIRSJT-UHFFFAOYSA-K 0.000 claims description 2
- 229910000149 boron phosphate Inorganic materials 0.000 claims description 2
- 239000002041 carbon nanotube Substances 0.000 claims description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- BEQVQKJCLJBTKZ-UHFFFAOYSA-M diphenylphosphinate Chemical compound C=1C=CC=CC=1P(=O)([O-])C1=CC=CC=C1 BEQVQKJCLJBTKZ-UHFFFAOYSA-M 0.000 claims description 2
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 2
- VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 235000019359 magnesium stearate Nutrition 0.000 claims description 2
- HHYXZVYUIJDJAH-UHFFFAOYSA-L magnesium;diethylphosphinate Chemical compound [Mg+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC HHYXZVYUIJDJAH-UHFFFAOYSA-L 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 150000007974 melamines Chemical class 0.000 claims description 2
- FMXPXIONARXTLI-UHFFFAOYSA-N methane;1,3,5-triazine-2,4,6-triamine Chemical compound C.NC1=NC(N)=NC(N)=N1.NC1=NC(N)=NC(N)=N1 FMXPXIONARXTLI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 2
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 2
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 125000003396 thiol group Chemical class [H]S* 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 claims description 2
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 claims description 2
- 239000011667 zinc carbonate Substances 0.000 claims description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 2
- 235000004416 zinc carbonate Nutrition 0.000 claims description 2
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 2
- 229940007718 zinc hydroxide Drugs 0.000 claims description 2
- 229910021511 zinc hydroxide Inorganic materials 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 2
- XSMMCTCMFDWXIX-UHFFFAOYSA-N zinc silicate Chemical compound [Zn+2].[O-][Si]([O-])=O XSMMCTCMFDWXIX-UHFFFAOYSA-N 0.000 claims description 2
- 235000019352 zinc silicate Nutrition 0.000 claims description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 2
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 claims description 2
- ZPEJZWGMHAKWNL-UHFFFAOYSA-L zinc;oxalate Chemical compound [Zn+2].[O-]C(=O)C([O-])=O ZPEJZWGMHAKWNL-UHFFFAOYSA-L 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- BHTBHKFULNTCHQ-UHFFFAOYSA-H zinc;tin(4+);hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Sn+4] BHTBHKFULNTCHQ-UHFFFAOYSA-H 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 238000007706 flame test Methods 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- IHSZURPWPOXDOF-UHFFFAOYSA-N [PH2](O)=O.C(C)[Ca]CC Chemical compound [PH2](O)=O.C(C)[Ca]CC IHSZURPWPOXDOF-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 125000005340 bisphosphate group Chemical group 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 239000012802 nanoclay Substances 0.000 claims 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 1
- 125000003003 spiro group Chemical group 0.000 claims 1
- 229920002302 Nylon 6,6 Polymers 0.000 abstract description 27
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- 239000012963 UV stabilizer Substances 0.000 description 2
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 2
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- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 150000008430 aromatic amides Chemical class 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- DRYHXHUXMMIMPH-UHFFFAOYSA-L calcium;diethylphosphinate Chemical compound [Ca+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DRYHXHUXMMIMPH-UHFFFAOYSA-L 0.000 description 1
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- 239000011248 coating agent Substances 0.000 description 1
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- 239000011258 core-shell material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
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- 230000001747 exhibiting effect Effects 0.000 description 1
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- 230000006698 induction Effects 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229920006131 poly(hexamethylene isophthalamide-co-terephthalamide) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
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- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
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- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
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- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
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- D03—WEAVING
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- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
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- D—TEXTILES; PAPER
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-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D06M15/667—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain
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- D04H1/43832—Composite fibres side-by-side
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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-
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T442/696—Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Knitting Of Fabric (AREA)
Abstract
【選択図】 図4
Description
重合体 商標 溶融温度、℃
ナイロン6(非芳香族) 様々 220
ナイロン66(非芳香族) 様々 260
MXD6 MXD6 240
ナイロン6/6T Grivory 295
ポリフタルアミド(PPA) Zytel、LNP 300
ナイロン6T Arlen 310
ナイロン6I/6T Grivory 325
ポリアミドイミド Torlon 355
包含)、メラミンと燐酸の反応生成物(燐酸メラミン、ピロ燐酸メラミンおよびポリ燐酸メラミン(MPP)を包含)、メラミンの縮合生成物と燐の反応生成物(ポリ燐酸メラム、ポリ燐酸メレム、ポリ燐酸メロンを包含)、シアヌル酸メラミン(MC)、ジエチルホスフィン酸亜鉛(DEPZn)、ジエチルホスフィン酸アルミニウム(DEPAl)、ジエチルホスフィン酸カルシウム、ジエチルホスフィン酸マグネシウム、ビスフェノール−A ビス(ジフェニルホスフィネート)(BPADP)、レゾルシノールビス(2,6−ジキシレニルホスフェート)(RDX)、レゾルシノールビス(ジフェニルホスフェート)(RDP)、オキシ窒化燐、ホウ酸亜鉛、酸化亜鉛、錫酸亜鉛、ヒドロキシ錫酸亜鉛、硫化亜鉛、燐酸亜鉛、ケイ酸亜鉛、水酸化亜鉛、炭酸亜鉛、ステアリン酸亜鉛、ステアリン酸マグネシウム、八モリブデン酸アンモニウム、モリブデン酸メラミン、八モリブデン酸メラミン、メタホウ酸バリウム、フェロセン、燐酸ホウ素、ホウ酸ホウ素、水酸化マグネシウム、ホウ酸マグネシウム、水酸化アルミニウム、三水和アルミナ、グリコルリルおよび3−アミノ−1,2,4−トリアゾール−5−チオールのメラミン塩、カリウム、亜鉛および鉄のウラゾール塩、1,2−エタンジイル−4−4’−ビス−トリアゾリジン−3,5,ジオン、シリコーン、Mg、Al、Ti、Cr、Mn、Fe、Co、Ni、Cu、Zn、Zr、Mo、Sn、Sb、Ba、WおよびBiの酸化物、多面体オリゴマー状シルセスキオキサン、シリコタングステン酸(SiTA)、ホスホタングステン酸、タングステン酸のメラミン塩、直鎖、分枝もしくは環式ホスフェートもしくはホスホネート、スピロビスホスホネート、スピロビスホスフェートおよびナノ粒子、例えば炭素ナノチューブおよびナノ粘土(これらに限定するものでないが、モントモリロナイト、ハロイサイトおよびラポナイトが基になったナノ粘土を包含)が含まれ得る。
受けさせることも可能である。この上で考察したように、繊維に紡績する当該部分芳香族ポリアミドにまた追加的部分芳香族もしくは脂肪族重合体を含有させることも可能である。そのような繊維を紡績する時、2種以上のポリアミド重合体の混合物の混合を行った後に紡績を実施してヤーンを生じさせるか或は少なくとも1種の部分芳香族ポリアミド重合体と追加的部分芳香族ポリアミド重合体もしくは脂肪族重合体を2成分形態、例えば横並びまたはコア−シェル形態などで含有する多フィルムヤーンを生じさせることも可能である。
Flame Retardant Treatment’(2003)(引用することによって全体が本明細書に組み入れられる)に見られる。このような布は織布、編布および不織布であってもよい。不織布には、梳ウエブ、ウエット−レイまたはスパンボンド/メルトブローン工程で作られたそれらが含まれる。
着)との積層を受けさせることも可能である。
残炎は、“発火源を取り除いた後に材料が持続して燃えること”[情報源:ATSM D6413 Standard test Method for Flame Resistance of Textiles(Vertical Method)]を意味する。
Personnel Against Flash Fire]を意味する。
難燃性の測定をASTM D−6413 Standard Test Method
for Flame Resistance of Textiles(Vertical Test)に従って実施した。
ガラス繊維不織スクリムを前記重合体混合物の上下に置く。前記ガラス繊維スクリムは垂直燃焼試験中に炎から離れた所で重合体が収縮することも溶融することもないようにするものであり、それによって“付着物効果”が存在する可能性を予測することができる。そのスクリムの重量は最終的積層品の約7%である。成形温度を当該重合体の溶融温度より約25℃高い温度にする。
試験積層品の調製をこの上に示した技術を用いて実施した。実施例1の調製ではMXD6を用いるが難燃添加剤を用いない。実施例2の調製ではMXD6と10%(重量/重量)の量のMPP(ポリ燐酸メラミン)添加剤を用いる。実施例3の調製ではMXD6と10%(重量/重量)の量のMC(シアヌル酸メラミン)添加剤を用いる。実施例4の調製ではMXD6と10%(重量/重量)の量のDEPZn(ジエチルホスフィン酸亜鉛)添加剤を用いる。実施例5の調製ではMXD6と10%(重量/重量)の量のDEPAl(ジエチルホスフィン酸アルミニウム)を用いる。実施例6の調製ではMXD6と20%(重量/重量)の量のSiTA(シリコタングステン酸)を用いる。実施例7の調製ではMXD6と20%(重量/重量)の量のMC添加剤を用いる。結果を以下の表1に報告する。
試験積層品の調製をこの上に示した技術を用いて実施した。比較実施例1の調製ではナイロン6,6を用いるが難燃添加剤を用いない。比較実施例2の調製ではナイロン6,6と10%(重量/重量)の量のMPP添加剤を用いる。比較実施例3の調製ではナイロン6,6と10%(重量/重量)の量のMC添加剤を用いる。比較実施例4の調製ではナイロン6,6と10%(重量/重量)の量のDEPZn添加剤を用いる。比較実施例5の調製ではナイロン6,6を用いるが難燃添加剤を用いない。結果を以下の表1に報告する。
以下の実施例では、難燃熱可塑性ヤーンをステープル紡績FRレーヨンヤーン(Lenzing FR)と組み合わせて編むことで管状布を生じさせた。その混合布の各ヤーンの含有量をそれぞれ約50パーセントにした。その布に燃焼試験を受けさせる前に繊維仕上げ剤および編み用油を除去しておいた。
0%(重量/重量)の難燃MXD6繊維と難燃レーヨン繊維の布混合物である。結果を以下の表2に報告する。
比較実施例6は、MPP添加剤含有量が5%(重量/重量)の難燃ナイロン6,6繊維と難燃レーヨン繊維の布混合物である。比較実施例7は、MPP添加剤含有量が10%(重量/重量)の難燃ナイロン6,6繊維と難燃レーヨン繊維の布混合物である。比較実施例8は、DEPAl添加剤含有量が10%(重量/重量)の難燃ナイロン6,6と難燃レーヨン繊維の布混合物である。結果を以下の表2に報告する。
Claims (26)
- 難燃繊維であって、部分芳香族ポリアミドおよび非ハロゲン系難燃添加剤を含有して成る難燃繊維。
- 前記部分芳香族ポリアミドが芳香族および脂肪族のジアミンおよび二酸の重合体もしくは共重合体を含んで成る請求項1記載の難燃繊維。
- 前記部分芳香族ポリアミドが更に芳香族ジアミン単量体および脂肪族二酸単量体も含んで成る請求項2記載の難燃繊維。
- 前記部分芳香族ポリアミドがMXD6である請求項1記載の難燃繊維。
- 前記非ハロゲン系難燃添加剤がメラミンの縮合生成物(メラム、メレムおよびメロンを包含)、メラミンと燐酸の反応生成物(燐酸メラミン、ピロ燐酸メラミンおよびポリ燐酸メラミン(MPP)を包含)、メラミンの縮合生成物と燐酸の反応生成物(ポリ燐酸メラム、ポリ燐酸メレム、ポリ燐酸メロンを包含)、シアヌル酸メラミン(MC)、ジエチルホスフィン酸亜鉛(DEPZn)、ジエチルホスフィン酸アルミニウム(DEPAl)、ジエチルホスフィン酸カルシウム、ジエチルホスフィン酸マグネシウム、ビスフェノール−Aビス(ジフェニルホスフィネート)(BPADP)、レゾルシノールビス(2,6−ジキシレニルホスフェート)(RDX)、レゾルシノールビス(ジフェニルホスフェート)(RDP)、オキシ窒化燐、ホウ酸亜鉛、酸化亜鉛、錫酸亜鉛、ヒドロキシ錫酸亜鉛、硫化亜鉛、燐酸亜鉛、ケイ酸亜鉛、水酸化亜鉛、炭酸亜鉛、ステアリン酸亜鉛、ステアリン酸マグネシウム、八モリブデン酸アンモニウム、モリブデン酸メラミン、八モリブデン酸メラミン、メタホウ酸バリウム、フェロセン、燐酸ホウ素、ホウ酸ホウ素、水酸化マグネシウム、ホウ酸マグネシウム、水酸化アルミニウム、三水和アルミナ、グリコルリルおよび3−アミノ−1,2,4−トリアゾール−5−チオールのメラミン塩、カリウム、亜鉛および鉄のウラゾール塩、1,2−エタンジイル−4−4’−ビス−トリアゾリジン−3,5,ジオン、シリコーン、Mg、Al、Ti、Cr、Mn、Fe、Co、Ni、Cu、Zn、Zr、Mo、Sn、Sb、Ba、WおよびBiの酸化物、多面体のオリゴマー状シルセスキオキサン、炭素ナノチューブ、ナノ粘土、シリコタングステン酸(SiTA)、ホスホタングステン酸、タングステン酸のメラミン塩、直鎖、分枝もしくは環式ホスフェートもしくはホスホネート、スピロビスホスホネート、スピロビスホスフェートおよびこれらの組み合わせから成る群より選択される請求項1記載の難燃繊維。
- 前記非ハロゲン系難燃添加剤がMPP、MC、DEPZn、DEPAlおよびこれらの組み合わせから成る群より選択される請求項1記載の難燃繊維。
- 前記非ハロゲン系難燃添加剤が重量で表して約5%から約10%の濃度で存在する請求項1−6の1項記載の難燃繊維。
- 難燃ステープル紡績ヤーンであって、請求項1−7の1項記載の少なくとも1種の難燃繊維を含有して成る難燃ステープル紡績ヤーン。
- 更に追加的繊維も含有して成る請求項8記載の難燃ステープル紡績ヤーン。
- 前記追加的繊維がセルロース、アラミド、フェノール樹脂、ポリエステル、酸化アクリル樹脂、モダクリル樹脂、メラミン、絹、亜麻、麻、羊毛、ポリ(p−フェニレンベンゾビスオキサゾール)(PBO)、ポリベンゾイミダゾール(PBI)およびポリスルホンアミド(PSA)繊維から成る群より選択される請求項9記載の難燃ステープル紡績ヤー
ン。 - 前記追加的繊維が難燃剤による処理を受けている請求項9−10の1項記載の難燃ステープル紡績ヤーン。
- 前記追加的繊維が綿、レーヨン、ポリエステルまたはリヨセルである請求項9記載の難燃ステープル紡績ヤーン。
- 難燃連続フィラメントヤーンであって、請求項1−7の1項記載の少なくとも1種の難燃繊維を含有して成りかつ前記難燃繊維が連続繊維である難燃連続フィラメントヤーン。
- 更に追加的連続フィラメント繊維も含有して成る請求項13記載の難燃連続フィラメントヤーン。
- 前記追加的連続フィラメント繊維がアラミド、フェノール樹脂、ポリエステル、酸化アクリル樹脂、モダクリル樹脂、メラミン、リヨセル、ポリ(p−フェニレンベンゾビスオキサゾール)(PBO)、ポリベンゾイミダゾール(PBI)およびポリスルホンアミド(PSA)繊維から成る群より選択される請求項14記載の難燃連続フィラメントヤーン。
- 前記追加的連続フィラメント繊維が難燃剤による処理を受けている請求項14−15の1項記載の難燃連続フィラメントヤーン。
- 請求項8−16の1項記載のヤーンを含有して成る布。
- 更に追加的ヤーンも含有して成る請求項17記載の布。
- 前記追加的ヤーンがセルロース、アラミド、フェノール樹脂、ポリエステル、酸化アクリル樹脂、モダクリル樹脂、メラミン、綿、絹、亜麻、麻、羊毛、レーヨン、リヨセル、ポリ(p−フェニレンベンゾビスオキサゾール)(PBO)、ポリベンゾイミダゾール(PBI)およびポリスルホンアミド(PSA)繊維から成る群より選択される繊維を含有して成る請求項18記載の布。
- 難燃不織布であって、請求項1−7の1項記載の難燃繊維を含有して成る難燃不織布。
- 前記不織布がスパンボンド、メルトブローンおよびこれらの組み合わせから成る群より選択される工程で作られたものである請求項20記載の難燃不織布。
- 少なくとも1種の繊維を含有して成る難燃布であって、前記繊維が部分芳香族ポリアミドおよび非ハロゲン系難燃添加剤を含有して成りかつ更に布が垂直燃焼試験で自己消化性を示す能力を有する難燃布。
- 少なくとも1種の繊維を含有して成る難燃布であって、前記繊維が部分芳香族ポリアミドおよび非ハロゲン系難燃添加剤を含有して成りかつ更に布が垂直燃焼試験で約60秒未満の残炎時間を示す能力を有する難燃布。
- 少なくとも1種の部分芳香族ポリアミド、少なくとも1種の脂肪族ポリアミドおよび少なくとも1種の非ハロゲン系難燃添加剤を含有して成る難燃繊維。
- 更に2番目の部分芳香族ポリアミドも含有して成る請求項24記載の難燃繊維。
- 前記少なくとも1種の部分芳香族ポリアミドがMXD6でありそして前記2番目の部分芳香族ポリアミドがナイロン6/6Tである請求項25記載の難燃繊維。
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Cited By (7)
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---|---|---|---|---|
JP2014525521A (ja) * | 2011-09-02 | 2014-09-29 | インヴィスタ テクノロジーズ エスアエルエル | 部分芳香族ポリアミド繊維及び他の防炎繊維を含む防炎糸及び布地 |
CN105916735A (zh) * | 2014-01-17 | 2016-08-31 | 齐佩尔技术有限公司 | 热防护产品 |
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JP2018158959A (ja) * | 2017-03-22 | 2018-10-11 | 大日精化工業株式会社 | 難燃性マスターバッチ、難燃性樹脂組成物、及び難燃性繊維 |
JP2022515963A (ja) * | 2018-11-14 | 2022-02-24 | ローディア オペレーションズ | 難燃剤及びその調製プロセス |
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CN105386294A (zh) * | 2015-10-16 | 2016-03-09 | 辽宁石油化工大学 | 一种涤纶阻燃织物及其制作方法 |
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CN106757679A (zh) * | 2016-11-17 | 2017-05-31 | 安徽新盾消防设备有限公司 | 阻燃织物 |
WO2018098408A1 (en) * | 2016-11-28 | 2018-05-31 | Qed Labs, Inc. | Meltable intumescent flame retardant compositions |
CN106758168A (zh) * | 2016-12-01 | 2017-05-31 | 西南大学 | 基于纳米磷酸硼的阻燃涤纶织物制备方法 |
RU2641931C1 (ru) * | 2016-12-20 | 2018-01-23 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Волгоградский государственный технический университет" (ВолгГТУ) | Фторсодержащая полиамидная композиция с пониженной горючестью |
US20180220807A1 (en) * | 2017-02-09 | 2018-08-09 | Fosbrooke, Inc. | Flame retardant cover |
CN107237126B (zh) * | 2017-06-01 | 2019-11-15 | 成都海蓉特种纺织品有限公司 | 一种阻燃锦纶纺织品及其制备方法 |
CN107313168A (zh) * | 2017-08-31 | 2017-11-03 | 苏州英得福机电科技有限公司 | 一种环保复合型阻燃面料 |
EP3467162A1 (en) * | 2017-10-06 | 2019-04-10 | Lenzing Aktiengesellschaft | Flame retardant lyocell filament |
BR112020007709A2 (pt) * | 2017-10-20 | 2020-10-20 | Invista Textiles (U.K.) Limited | fibras têxteis de náilon de alta capacidade de suporte de carga com aditivo, fios e tecidos combinados dos mesmos |
US11311527B2 (en) | 2018-05-16 | 2022-04-26 | Forma Therapeutics, Inc. | Inhibiting mutant isocitrate dehydrogenase 1 (mIDH-1) |
EP3720442B1 (en) | 2018-05-16 | 2022-12-28 | Forma Therapeutics, Inc. | Inhibiting mutant idh-1 |
WO2019222551A1 (en) | 2018-05-16 | 2019-11-21 | Forma Therapeutics, Inc. | Solid forms of ((s)-5-((1-(6-chloro-2-oxo-1,2-dihydroquinolin-3-yl)ethyl)amino)-1-methyl-6-oxo-1,6-dihydropyridine-2-carbonitrile |
US11013733B2 (en) | 2018-05-16 | 2021-05-25 | Forma Therapeutics, Inc. | Inhibiting mutant isocitrate dehydrogenase 1 (mlDH-1) |
US11013734B2 (en) | 2018-05-16 | 2021-05-25 | Forma Therapeutics, Inc. | Treating patients harboring an isocitrate dehydrogenase-1 (IDH-1) mutation |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02127466A (ja) * | 1988-07-13 | 1990-05-16 | Basf Ag | 部分的芳香族コポリアミドを主体とする難燃性熱可塑性成形材料 |
JPH10280230A (ja) * | 1997-04-09 | 1998-10-20 | Mitsubishi Gas Chem Co Inc | ポリアミド繊維 |
JPH11513059A (ja) * | 1995-09-05 | 1999-11-09 | ビーエーエスエフ アクチェンゲゼルシャフト | メラミンシアヌレート及び前処理された繊維状充填剤を含有する防炎加工pa成形材料 |
JP2003105659A (ja) * | 2001-09-27 | 2003-04-09 | Mitsubishi Engineering Plastics Corp | 難燃性ポリアミド不織布 |
JP2007500803A (ja) * | 2003-07-28 | 2007-01-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 難燃性セルロース系繊維を含んでなる難燃性繊維混合物ならびにそれから製造される布および衣類 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01221537A (ja) | 1988-02-26 | 1989-09-05 | Teijin Ltd | 耐炎性繊維 |
JP2703390B2 (ja) | 1990-06-11 | 1998-01-26 | 帝人株式会社 | 芳香族ポリアミド繊維布帛 |
CA2078626C (en) * | 1992-03-06 | 1999-04-27 | Gary W. Shore | Method for producing polyamide carpet fibers with improved flame retardancy |
BE1008947A3 (nl) * | 1994-12-01 | 1996-10-01 | Dsm Nv | Werkwijze voor de bereiding van condensatieproducten van melamine. |
RU2140472C1 (ru) * | 1996-05-15 | 1999-10-27 | Открытое акционерное общество "Научно-исследовательский институт нетканых материалов" | Огнезащитный нетканый материал |
US6225383B1 (en) * | 1997-05-26 | 2001-05-01 | Mitsubishi Engineering Plastic Corp. | Resin composition comprising polyamide resin |
JP2000303257A (ja) * | 1999-04-14 | 2000-10-31 | Unitika Ltd | 防炎性人工芝用ヤーン及び防炎性人工芝 |
JP2000328363A (ja) * | 1999-05-25 | 2000-11-28 | Nec Corp | 難燃性ポリアミド繊維 |
DE19933901A1 (de) * | 1999-07-22 | 2001-02-01 | Clariant Gmbh | Flammschutzmittel-Kombination |
JP2001234066A (ja) | 2000-02-24 | 2001-08-28 | Ube Ind Ltd | ポリアミド樹脂組成物 |
WO2002024991A1 (fr) * | 2000-09-20 | 2002-03-28 | Mitsubishi Engineering-Plastics Corporation | Filaments polyamides ignifugeants et leur utilisation |
JP2002173829A (ja) * | 2000-09-20 | 2002-06-21 | Mitsubishi Engineering Plastics Corp | 難燃性ポリアミド・フィラメント |
FR2851581B1 (fr) * | 2003-02-21 | 2007-04-06 | Rhodianyl | Fils, fibres, filaments et articles textiles ignifuges |
EP1618143A2 (fr) * | 2003-04-28 | 2006-01-25 | Rhodia Engineering Plastics Srl | Materiau thermoplastique comprenant des composes lamellaires nanometriques |
US20050159552A1 (en) | 2004-01-21 | 2005-07-21 | Reed Jon S. | Flame retarded fibers and filaments and process of production therefor |
CN1922252B (zh) | 2004-02-18 | 2011-06-15 | 亨斯迈先进材料(瑞士)有限公司 | 使用硅氧烷的阻燃剂组合物 |
WO2005105923A1 (ja) | 2004-04-28 | 2005-11-10 | Ube Industries, Ltd. | 難燃性樹脂組成物 |
WO2006001445A1 (ja) | 2004-06-29 | 2006-01-05 | Asahi Kasei Chemicals Corporation | 難燃性エポキシ樹脂組成物 |
US20080167404A1 (en) | 2004-07-01 | 2008-07-10 | Solvay Advanced Polymers, Llc | Aromatic Polyamide Composition and Article Manufactured Therefrom |
US7937924B2 (en) | 2005-11-16 | 2011-05-10 | Lorica International, Inc. | Fire retardant compositions and methods and apparatuses for making the same |
AU2007290499B2 (en) * | 2006-08-31 | 2012-07-05 | Southern Mills, Inc. | Flame resistant fabrics and garments made from same |
JP4934151B2 (ja) * | 2006-12-15 | 2012-05-16 | 帝人テクノプロダクツ株式会社 | ヘテロ環含有芳香族ポリアミド繊維及びその製造方法、並びに該繊維から構成された布帛及び該繊維により補強された繊維強化複合材料 |
FR2917738B1 (fr) | 2007-06-20 | 2010-11-05 | Rhodia Operations | Compositions thermoplastiques ignifugees |
JP5580057B2 (ja) | 2008-02-12 | 2014-08-27 | 帝人株式会社 | 難燃性樹脂組成物、難燃性繊維、難燃性布帛および耐熱性防護服 |
-
2011
- 2011-09-21 CN CN201610603136.0A patent/CN106591982B/zh active Active
- 2011-09-21 RU RU2013118576/05A patent/RU2596738C9/ru not_active IP Right Cessation
- 2011-09-21 WO PCT/US2011/052557 patent/WO2012040332A2/en active Application Filing
- 2011-09-21 BR BR112013006887-6A patent/BR112013006887B1/pt not_active IP Right Cessation
- 2011-09-21 CN CN201180045765.1A patent/CN103109002B/zh active Active
- 2011-09-21 US US13/825,209 patent/US10640893B2/en active Active
- 2011-09-21 MX MX2013003075A patent/MX355538B/es active IP Right Grant
- 2011-09-21 CA CA 2812453 patent/CA2812453A1/en not_active Abandoned
- 2011-09-21 EP EP11827445.5A patent/EP2619358B1/en active Active
- 2011-09-21 KR KR1020137010160A patent/KR101920504B1/ko active IP Right Grant
- 2011-09-21 JP JP2013530277A patent/JP6076907B2/ja active Active
- 2011-09-23 TW TW100134435A patent/TWI625434B/zh active
- 2011-09-23 TW TW106133284A patent/TW201802312A/zh unknown
-
2013
- 2013-03-10 IL IL225148A patent/IL225148B/en active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02127466A (ja) * | 1988-07-13 | 1990-05-16 | Basf Ag | 部分的芳香族コポリアミドを主体とする難燃性熱可塑性成形材料 |
JPH11513059A (ja) * | 1995-09-05 | 1999-11-09 | ビーエーエスエフ アクチェンゲゼルシャフト | メラミンシアヌレート及び前処理された繊維状充填剤を含有する防炎加工pa成形材料 |
JPH10280230A (ja) * | 1997-04-09 | 1998-10-20 | Mitsubishi Gas Chem Co Inc | ポリアミド繊維 |
JP2003105659A (ja) * | 2001-09-27 | 2003-04-09 | Mitsubishi Engineering Plastics Corp | 難燃性ポリアミド不織布 |
JP2007500803A (ja) * | 2003-07-28 | 2007-01-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 難燃性セルロース系繊維を含んでなる難燃性繊維混合物ならびにそれから製造される布および衣類 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014525521A (ja) * | 2011-09-02 | 2014-09-29 | インヴィスタ テクノロジーズ エスアエルエル | 部分芳香族ポリアミド繊維及び他の防炎繊維を含む防炎糸及び布地 |
US9683315B2 (en) | 2011-09-02 | 2017-06-20 | Invista North America Sarl | Flame resistant yarns and fabrics including partially aromatic polyamide fiber and other flame resistant fibers |
CN105916735A (zh) * | 2014-01-17 | 2016-08-31 | 齐佩尔技术有限公司 | 热防护产品 |
JP2018522147A (ja) * | 2015-07-06 | 2018-08-09 | ピービーアイ・パフォーマンス・プロダクツ・インコーポレーテッド | ホスホン酸化pbi繊維 |
JP2020097814A (ja) * | 2015-07-06 | 2020-06-25 | ピービーアイ・パフォーマンス・プロダクツ・インコーポレーテッド | ホスホン酸化pbi繊維 |
JP7015854B2 (ja) | 2015-07-06 | 2022-02-03 | ピービーアイ・パフォーマンス・プロダクツ・インコーポレーテッド | ホスホン酸化pbi繊維 |
JP2018158959A (ja) * | 2017-03-22 | 2018-10-11 | 大日精化工業株式会社 | 難燃性マスターバッチ、難燃性樹脂組成物、及び難燃性繊維 |
JP2022515963A (ja) * | 2018-11-14 | 2022-02-24 | ローディア オペレーションズ | 難燃剤及びその調製プロセス |
JP7323749B2 (ja) | 2018-11-14 | 2023-08-09 | エナジー ソリューションズ(ユーエス)エルエルシー | 難燃剤及びその調製プロセス |
US11873587B2 (en) | 2019-03-28 | 2024-01-16 | Southern Mills, Inc. | Flame resistant fabrics |
US11891731B2 (en) | 2021-08-10 | 2024-02-06 | Southern Mills, Inc. | Flame resistant fabrics |
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CA2812453A1 (en) | 2012-03-29 |
TW201802312A (zh) | 2018-01-16 |
US10640893B2 (en) | 2020-05-05 |
JP6076907B2 (ja) | 2017-02-08 |
CN106591982B (zh) | 2020-10-27 |
TWI625434B (zh) | 2018-06-01 |
IL225148B (en) | 2019-06-30 |
CN103109002B (zh) | 2018-07-06 |
RU2596738C2 (ru) | 2016-09-10 |
CN103109002A (zh) | 2013-05-15 |
BR112013006887A2 (pt) | 2017-05-23 |
BR112013006887B1 (pt) | 2020-12-08 |
EP2619358A2 (en) | 2013-07-31 |
MX355538B (es) | 2018-04-20 |
KR101920504B1 (ko) | 2018-11-20 |
WO2012040332A2 (en) | 2012-03-29 |
MX2013003075A (es) | 2013-04-05 |
KR20130098371A (ko) | 2013-09-04 |
WO2012040332A3 (en) | 2012-06-21 |
EP2619358B1 (en) | 2018-02-21 |
RU2596738C9 (ru) | 2016-11-10 |
CN106591982A (zh) | 2017-04-26 |
US20130244527A1 (en) | 2013-09-19 |
EP2619358A4 (en) | 2016-05-18 |
RU2013118576A (ru) | 2014-10-27 |
TW201229338A (en) | 2012-07-16 |
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