JP2013533915A - 脂肪酸エステルにより可塑化した改良ポリウレタンシーリングフォーム組成物 - Google Patents
脂肪酸エステルにより可塑化した改良ポリウレタンシーリングフォーム組成物 Download PDFInfo
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- JP2013533915A JP2013533915A JP2013518787A JP2013518787A JP2013533915A JP 2013533915 A JP2013533915 A JP 2013533915A JP 2013518787 A JP2013518787 A JP 2013518787A JP 2013518787 A JP2013518787 A JP 2013518787A JP 2013533915 A JP2013533915 A JP 2013533915A
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- Prior art keywords
- isocyanate
- polyisocyanate
- component
- foam
- polyol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004814 polyurethane Substances 0.000 title description 6
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- 239000005056 polyisocyanate Substances 0.000 claims abstract description 60
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 33
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
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- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
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- 235000019774 Rice Bran oil Nutrition 0.000 description 1
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- 229910018540 Si C Inorganic materials 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
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- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- FAOMZVDZARKPFJ-UHFFFAOYSA-N WIN 18446 Chemical compound ClC(Cl)C(=O)NCCCCCCCCNC(=O)C(Cl)Cl FAOMZVDZARKPFJ-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
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- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
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- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 1
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- 238000009835 boiling Methods 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
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- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
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- 235000020971 citrus fruits Nutrition 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
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- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
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- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
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- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
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- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 description 1
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- 240000004308 marijuana Species 0.000 description 1
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- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
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- 238000005457 optimization Methods 0.000 description 1
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- 239000003346 palm kernel oil Substances 0.000 description 1
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- 150000004707 phenolate Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003003 phosphines Chemical group 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
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- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000034563 regulation of cell size Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- LVPSBELIABHESA-UHFFFAOYSA-L zinc;n,n-dibutylcarbamothioate Chemical compound [Zn+2].CCCCN(C([O-])=S)CCCC.CCCCN(C([O-])=S)CCCC LVPSBELIABHESA-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
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Abstract
Description
(a)前記ポリイソシアネート成分はイソシアネート末端プレポリマー及び1種以上の脂肪酸の少なくとも1種のアルキルエステルの混合物を含み、イソシアネート含有分が約8〜約14質量%であり、そしてブルックフィールド粘度が25℃で5000cps以下であり、
(b)前記硬化剤成分は平均官能価が少なくとも約1.8であるイソシアネート反応性材料を含み、該イソシアネート反応性材料は水、少なくとも1種のポリオール、又は、水と少なくとも1種のポリオールとの両方を含み、そして
(c)もし前記硬化剤成分が水を含まないならば、反応混合物は少なくとも1種の他の発泡剤を含む、
方法である。
HzN−[(CHR’−CHR”−O−)a−(CH2)x−OH]y(II)
を有し、式中、yは少なくとも1であり、z+yは3であり、R’及びR”は、独立に、水素、エチル又はメチルであり、xは1〜4の数値であり、aは1又は2であり、ただしa×yは2以下である。このタイプの特に好ましいアルカノールアミンは、2−(2−アミノエトキシ)エタノール及び2(2−(2−アミノエトキシル)エトキシ)エタノールである。
(b)トリアルキルホスフィン及びジアルキルベンジルホスフィンなどの第三級ホスフィン、
(c)Be、Mg、Zn、Cd、Pd、Ti、Zr、Sn、As、Bi、Cr、Mo、Mn、Fe、Co及びNiなどの金属とアセチルアセトン、ベンゾイルアセトン、トリフルオロアセチルアセトン、アセト酢酸エチルなどから得ることができるものなどの各種金属のキレート、
(d)塩化第二鉄、塩化第二スズ、塩化第一スズ、三塩化アンチモン、硝酸ビスマス及び塩化ビスマスなどの強酸の酸性金属塩、
(e)アルカリ金属及びアルカリ土類金属水酸化物、アルコキシド及びフェノキシドなどの強塩基、
(f)Ti(OR)4、Sn(OR)4及びAl(OR)3(式中、Rはアルキル又はアリールである)などの各種金属のアルコラート及びフェノラート、及び、アルコラートとカルボン酸、β−ジケトン及び2−(N,N−ジアルキルアミノ)アルコールとの反応生成物、
(g)アルカリ金属、アルカリ土類金属、Al、Sn、Pb、Mn、Co、Ni及びCuなどの各種金属の有機酸塩、例えば、酢酸ナトリウム、オクタン酸第一スズ、オレイン酸第一スズ、オクチル酸鉛、ナフテン酸マンガン及びナフテン酸コバルトなどの金属乾燥剤を含む、ならびに、
(h)四価のスズ、三価及び五価のAs、Sb及びBiの有機金属誘導体ならびに鉄及びコバルトの金属カルボニル、
が挙げられる。
1000の当量のポリ(プロピレンオキシド)ジオール24.36部、ブタノール2.33部、イソシアネート官能価が3.2でありそしてイソシアネート当量が138であるポリマーMDI40.56部、オルガノシリコーン界面活性剤0.35部及びダイズメチルエステル(Bunge North Americaより入手)32.4部を混合することによりイソシアネート末端プレポリマーを調製する。この混合物を窒素下に加熱しそして70℃で一定のイソシアネート濃度まで攪拌し、可塑化したプレポリマー組成物を形成する。この生成物はイソシアネート含有分が10質量%であり、プレポリマー自体のイソシアネート含有分は約14.9質量%である。この生成物を例1と指定する。
さらなる比較のために、プレポリマー組成物をダイズ油、パーム油及びキャノーラ油を可塑剤として用いて行う。植物油は、各場合に、プレポリマーから急速に相分離する。
一連の可塑化したポリイソシアネート(例7〜12及び比較サンプルD〜F)を例1に関して記載したのと同一の一般手順で製造するが、これらの場合に、ポリイソシアネートは2.7の官能価であり、134の当量のポリマーMDIである。配合の詳細を表3に提供する。
一連の可塑化したポリイソシアネート(例13〜18及び比較サンプルG〜I)を例7〜12に関して記載したのと同一の一般手順で製造するが、これらの場合に、ポリオールは500の当量のポリ(プロピレンオキシド)ジオールである。配合の詳細を表5に提供する。
一連の可塑化したポリイソシアネート(例19〜24及び比較サンプルJ、K及びL)を例7〜12に関して記載したのと同一の一般手順で製造するが、これらの場合に、ポリオールは216の当量のポリ(プロピレンオキシド)ジオールである。配合の詳細を表7に提供する。
ポリイソシアネート成分の例5、11、17及び23からポリウレタンフォームを製造する。ポリイソシアネート成分2.88gを、水64%、触媒34.95%、増粘剤0.55%及び臭気制御剤0.5%を含む混合物0.12gとクリーミングが観測されるまで手動混合し、その後、周囲温度で自由起泡させる。硬化したサンプルを最少露光で4ヶ月間老化し、その後、視覚的に評価する。
ポリイソシアネート成分の例5から調製されるフォームサンプルはある程度の黄変を示し、そのことは可塑剤のある程度の分離が起こったことを示している。ポリイソシアネート成分の例23から調製されたフォームサンプルも非相溶性のある程度の証拠を示す。ポリイソシアネート成分の例11及び17から調製されるフォームサンプルは非相溶性の兆候を殆ど示さず、そして同様の量のフタレート可塑剤を用いて製造されるフォームと視覚的に同様である。
約216の当量の二官能ポリ(プロピレンオキシド)ホモポリマー10.65部、n−ブタノール2.55部、ダイズメチルエステル(Soygold 1000)20部、フタル酸ジイソノニル20部、オルガノシリコーン界面活性剤0.8部及びポリマーMDI45部から、例1に記載される一般手順においてプレポリマーを製造する。可塑化したプレポリマーは25℃での粘度が1120cpsである。
上記のフォームスクリーン評価に関して記載した一般手順でプレポリマーからフォームを製造する。フォームの起泡時間は約数秒であり、ゲル化時間は7秒であり、不粘着時間は約8秒である。フォーム密度は1.90ポンド/立方フィート(約30.4kg/m3)である。
約432の当量の二官能ポリ(プロピレンオキシド)ホモポリマー9.43部、約1652の当量の三官能EO/POコポリマー3.6部、n−ブタノール3.23部、ダイズメチルエステル(Soygold 1000)30部、1種以上のオルガノシリコーン界面活性剤1部及びポリマーMDI52.73部から、例1に記載される一般手順においてプレポリマーを製造する。
上記のフォームスクリーン評価に関して記載した一般手順でプレポリマーからフォームを製造する。フォームのタックフリー時間は約7秒であり、フォーム密度は1.4ポンド/立方フィート(lb/ft3)である。組成及び結果を表9に示す。
Claims (18)
- ポリイソシアネート成分を、硬化剤成分及びポリイソシアネートと水又はポリオールとの反応のための少なくとも1種の触媒と混合すること、得られた混合物を乗物部材又は断熱パネルのキャビティー中に分配すること、及び、前記キャビティーを少なくとも部分的に充填する、バルク密度が0.5〜5ポンド/立方フィート(20〜80kg/m3)であるフォームを形成するように硬化するのに十分な条件下に混合物を付すことを含む、乗物部材又は断熱パネルをシールし又は遮断(insulate)するための方法であって、
(a)前記ポリイソシアネート成分はイソシアネート末端プレポリマー及び1種以上の脂肪酸の少なくとも1種のアルキルエステルの混合物を含み、イソシアネート含有分が約8〜約14質量%であり、そしてブルックフィールド粘度が25℃で5000cps以下であり、
(b)前記硬化剤成分は平均官能価が少なくとも約1.8であるイソシアネート反応性材料を含み、該イソシアネート反応性材料は水、少なくとも1種のポリオール、又は、水と少なくとも1種のポリオールとの両方を含み、そして
(c)もし前記硬化剤成分が水を含まないならば、反応混合物は少なくとも1種の他の発泡剤を含む、
方法。 - 前記ポリイソシアネート成分は1種以上の疎水性誘発性界面活性剤をさらに含む、請求項1記載の方法。
- 硬化したフォームは20%以下の24時間吸水率を有する、請求項2記載の方法。
- 前記ポリイソシアネート成分はブルックフィールド粘度が25℃で2000cps以下である、請求項1記載の方法。
- 前記脂肪酸は12〜20個の炭素原子を有する直鎖モノカルボン酸である、請求項1記載の方法。
- 前記脂肪酸は植物油又は動物性脂肪の構成成分の脂肪酸の混合物である、請求項5記載の方法。
- 前記脂肪酸はダイズ油の構成成分の脂肪酸の混合物である、請求項6記載の方法。
- 成分b)は水を含む、請求項1〜7のいずれか1記載の方法。
- 成分b)は水及び少なくとも1種のポリオールを含む、請求項1〜8のいずれか1記載の方法。
- 成分b)は少なくとも1種の触媒を含む、請求項1〜9のいずれか1記載の方法。
- (a)ポリマーMDIと、二官能ポリ(プロピレンオキシド)ホモポリマー又は少なくとも85質量%のプロピレンオキシドと15質量%以下のエチレンオキシドとの二官能コポリマーのイソシアネート末端反応生成物、ここで、前記ホモポリマー又はコポリマーは分子量が約400〜2200である、及び、(b)1種以上の脂肪酸の少なくとも1種のアルキルエステルを含む、ポリイソシアネート組成物であって、該ポリイソシアネート組成物はイソシアネート含有分が約8〜約14質量%であり、そしてブルックフィールド粘度が25℃で5000cps以下である、ポリイソシアネート組成物。
- 1種以上の疎水性誘発性界面活性剤をさらに含む、請求項11記載の組成物。
- 前記ポリイソシアネート成分はブルックフィールド粘度が25℃で2000cps以下である、請求項11記載の組成物。
- 前記脂肪酸は12〜20個の炭素原子を有する直鎖モノカルボン酸である、請求項11記載の組成物。
- 前記脂肪酸は植物油又は動物性脂肪の構成成分の脂肪酸の混合物である、請求項14記載の組成物。
- 前記脂肪酸はダイズ油の構成成分の脂肪酸の混合物である、請求項15記載の組成物。
- 前記二官能ホモポリマー又はコポリマーは分子量が400〜1500である、請求項11〜16のいずれか1記載の組成物。
- 平均官能価が少なくとも約1.8であるイソシアネート反応性材料を含み、該イソシアネート反応性材料が水、少なくとも1種のポリオール、又は、水と少なくとも1種のポリオールとの両方を含む硬化剤と、請求項11又は12記載の組成物の反応生成物を含むフォーム。
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2011
- 2011-07-05 EP EP11738341.4A patent/EP2591030A1/en not_active Withdrawn
- 2011-07-05 KR KR1020137003245A patent/KR20130041189A/ko not_active Application Discontinuation
- 2011-07-05 US US13/806,123 patent/US20130241098A1/en not_active Abandoned
- 2011-07-05 BR BR112013000367A patent/BR112013000367A2/pt not_active IP Right Cessation
- 2011-07-05 WO PCT/US2011/042956 patent/WO2012006282A1/en active Application Filing
- 2011-07-05 CN CN201180033974.4A patent/CN103003324B/zh not_active Expired - Fee Related
- 2011-07-05 JP JP2013518787A patent/JP5824043B2/ja not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017503102A (ja) * | 2014-01-17 | 2017-01-26 | ロイヤル アドヒーシブ アンド シーランツ カナダ エルティーディーRoyal Adhesives & Sealants Canada Ltd. | 耐荷重性構造のためのフーチング基礎におけるポリウレタンフォーム |
US10364544B2 (en) | 2014-01-17 | 2019-07-30 | Royal Adhesives & Sealants Canada Ltd. | Polyurethane foam in foundation footings for load-bearing structures |
JP2018510256A (ja) * | 2015-02-03 | 2018-04-12 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンHenkel AG & Co. KGaA | 低表面エネルギーフィルムを接着するためのポリウレタン接着剤 |
US11015094B2 (en) | 2015-02-03 | 2021-05-25 | Henkel IP & Holding GmbH | Polyurethane adhesives for bonding low surface energy films |
Also Published As
Publication number | Publication date |
---|---|
EP2591030A1 (en) | 2013-05-15 |
CN103003324B (zh) | 2015-02-25 |
JP5824043B2 (ja) | 2015-11-25 |
US20130241098A1 (en) | 2013-09-19 |
KR20130041189A (ko) | 2013-04-24 |
BR112013000367A2 (pt) | 2017-05-16 |
CN103003324A (zh) | 2013-03-27 |
WO2012006282A1 (en) | 2012-01-12 |
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