JP2013522454A - 精製用残留分からの金属回収法 - Google Patents
精製用残留分からの金属回収法 Download PDFInfo
- Publication number
- JP2013522454A JP2013522454A JP2012555495A JP2012555495A JP2013522454A JP 2013522454 A JP2013522454 A JP 2013522454A JP 2012555495 A JP2012555495 A JP 2012555495A JP 2012555495 A JP2012555495 A JP 2012555495A JP 2013522454 A JP2013522454 A JP 2013522454A
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- recovery method
- molybdenum
- supernatant
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 54
- 239000002184 metal Substances 0.000 title claims abstract description 54
- 238000007670 refining Methods 0.000 title claims abstract description 7
- 238000011084 recovery Methods 0.000 title claims description 40
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 98
- 238000000034 method Methods 0.000 claims abstract description 89
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 49
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 40
- 239000011733 molybdenum Substances 0.000 claims abstract description 40
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 40
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 40
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000002002 slurry Substances 0.000 claims abstract description 22
- 239000010779 crude oil Substances 0.000 claims abstract description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- 238000001556 precipitation Methods 0.000 claims description 38
- 238000002386 leaching Methods 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 26
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims description 25
- 239000007787 solid Substances 0.000 claims description 25
- 239000006228 supernatant Substances 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 23
- -1 ammonium ions Chemical class 0.000 claims description 20
- 238000001914 filtration Methods 0.000 claims description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 15
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 238000003860 storage Methods 0.000 claims description 13
- 239000002699 waste material Substances 0.000 claims description 11
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 7
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 7
- 239000012065 filter cake Substances 0.000 claims description 7
- 239000000706 filtrate Substances 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
- 229940078487 nickel acetate tetrahydrate Drugs 0.000 claims description 4
- OINIXPNQKAZCRL-UHFFFAOYSA-L nickel(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Ni+2].CC([O-])=O.CC([O-])=O OINIXPNQKAZCRL-UHFFFAOYSA-L 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 238000005342 ion exchange Methods 0.000 claims description 3
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 3
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 239000000571 coke Substances 0.000 claims description 2
- 238000002485 combustion reaction Methods 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000005078 molybdenum compound Substances 0.000 claims description 2
- 150000002752 molybdenum compounds Chemical class 0.000 claims description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 2
- 230000001376 precipitating effect Effects 0.000 claims 5
- 239000007800 oxidant agent Substances 0.000 claims 4
- 238000004065 wastewater treatment Methods 0.000 claims 4
- 238000004090 dissolution Methods 0.000 claims 3
- 239000003125 aqueous solvent Substances 0.000 claims 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 claims 1
- 230000003472 neutralizing effect Effects 0.000 claims 1
- 239000012074 organic phase Substances 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 239000011343 solid material Substances 0.000 claims 1
- 229910001935 vanadium oxide Inorganic materials 0.000 claims 1
- 238000000605 extraction Methods 0.000 abstract description 10
- 150000002751 molybdenum Chemical class 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 description 43
- 150000002739 metals Chemical class 0.000 description 16
- 239000003921 oil Substances 0.000 description 14
- 230000003647 oxidation Effects 0.000 description 13
- 238000007254 oxidation reaction Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 10
- 239000002994 raw material Substances 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- FIXLYHHVMHXSCP-UHFFFAOYSA-H azane;dihydroxy(dioxo)molybdenum;trioxomolybdenum;tetrahydrate Chemical compound N.N.N.N.N.N.O.O.O.O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O FIXLYHHVMHXSCP-UHFFFAOYSA-H 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 6
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 6
- 238000004517 catalytic hydrocracking Methods 0.000 description 5
- 239000000295 fuel oil Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 4
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000007689 inspection Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229940078494 nickel acetate Drugs 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 230000008022 sublimation Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000010169 landfilling Methods 0.000 description 1
- 238000000622 liquid--liquid extraction Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 239000003471 mutagenic agent Substances 0.000 description 1
- 231100000707 mutagenic chemical Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000010909 process residue Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 description 1
- 239000011684 sodium molybdate Substances 0.000 description 1
- 235000015393 sodium molybdate Nutrition 0.000 description 1
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000003681 vanadium Chemical class 0.000 description 1
- 229910001456 vanadium ion Inorganic materials 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/30—Obtaining chromium, molybdenum or tungsten
- C22B34/34—Obtaining molybdenum
- C22B34/345—Obtaining molybdenum from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/04—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
- C22B23/026—Obtaining nickel or cobalt by dry processes from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/12—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/22—Obtaining vanadium
- C22B34/225—Obtaining vanadium from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
- C22B7/008—Wet processes by an alkaline or ammoniacal leaching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Treatment Of Sludge (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
【選択図】なし
Description
この工程は、一連の湿式金属抽出(製錬)法を使用して、重質減圧残油(VR)の触媒水素化分解により、残留分からモリブデン、バナジウム及びニッケルを回収し、金属含有量の低い残留炭素系生成物を残存させる。それぞれバナジウムをメタバナジン酸アンモニウム(AMV)として、モリブデンをヘプタモリブデン酸アンモニウム四水和物(AHM)として、ニッケルを酢酸ニッケル四水和物として回収する。
図2に示すように、リパルプ(再スラリー)貯槽過程1(a)に供給される原料(ライン1)には、真水(ライン2)が混合されて、スラリー(水と原料とを2対1の割合)が生成され、更に再生液(再生液貯槽(p)からのライン3)が混合される。
pHを7.9〜8.2に調整し、50℃以下の温度に加熱し、アンモニウムイオンを加えると、バナジウムは、メタバナジン酸アンモニウム(AMV)として沈殿する。10重量%を超える固体硫酸アンモニウム結晶(ライン13)を添加して、アンモニウムイオンを導入すると、最大割合でバナジウムは、確実に沈殿する。沈殿条件が満たされると、硫酸アンモニウムが加えられ、処理液は、冷水により10℃に冷却される。処理液の冷却により、収率を増加しかつバナジウムの滞留時間を激減させることができる。沈殿反応は、下式で行われる。
図2の沈澱槽(f)で、アルカリ溶液(ライン20から濃度50重量%の水酸化ナトリウムを混合する)に三酸化モリブデン(MoO3)が溶解されると、モリブデン酸陰イオン(MoO4 2-)が発生する。濃度50重量%の硫酸(ライン21)によりpHを4未満に低下すると、ヘプタモリブデン酸塩(Mo7O24 6-)が生成される。その後、固体硫酸アンモニウム(ライン22)の形態でアンモニウムイオンを添加すると、ヘプタモリブデン酸アンモニウム四水和物(AHM)としてモリブデンを沈澱・析出することができる。10重量%を超えて固体硫酸アンモニウムを添加して、最大割合で確実にモリブデンを沈殿させる必要がある。この沈殿工程は、温度に依存する。冷水(ライン12)で温度30℃から10℃に冷却すると、モリブデンの収率が増加しかつ滞留時間が減少する。沈殿反応は、下式の通りである。
浸出濾過過程1(c)(ライン10)から回収された炭素とニッケルは、リパルプ(再スリラー)貯槽過程2(i)に供給され、固体対液体比を1対2として真水(ライン31)が混合される。
Claims (24)
- 重質原油精製用残留分からバナジウム、ニッケル及びモリブデンを回収する方法において、
900℃以下の温度で残留分を熱分解しかつ燃焼して灰分を生成する工程と、
灰分を水性スラリーに転化する工程と、
スラリーからバナジウム、ニッケル及びモリブデン化合物を抽出する工程とを含むことを特徴とする回収法。 - 600℃を超える温度で燃焼工程を実施する請求項1に記載の回収法。
- アンモニウムイオンを使用して沈殿によりバナジウムとモリブデンを回収する工程を含む請求項1又は2に記載の回収法。
- 更に酸化マグネシウムにより浸出させかつ沈殿させて、水酸化ニッケルとしてニッケルを回収する工程を含む請求項1、2又は3に記載の回収法。
- (a) 過程(p)からの再生液と水とを加えて、灰分をスラリー化する工程と、
(b) 浸出領域で水性溶媒と酸化剤とを加えて、灰分を含むスラリーを浸出条件で処理する工程と、
(c) 液体と不溶性固形物を含む過程(b)の廃液を濾過領域に移送して、濾過ケークとして固体物質を回収する工程と、
(d) 水相及び有機相を含む過程(c)の上澄み液を混合沈澱領域に移して、上澄み液のpHを調整し、メタバナジン酸アンモニウムを沈殿させる工程と、
(e) 過程(d)の廃液を濾過領域に移して、メタバナジン酸アンモニウム固形物を除去する工程と、
(f) 過程(e)の上澄み液を混合沈澱領域に移送し、上澄み液のpHを調整して、ヘプタモリブデン酸アンモニウム四水和物を沈殿させる工程と、
(g) 過程(f)の廃液を濾過領域に移し、固形化したヘプタモリブデン酸アンモニウム四水和物を除去する工程と、
(h) 過程(g)の上澄み液を排水処理装置に移送し、精製装置から廃液を排出して廃棄処分する前に、微量金属及びアンモニウムを除去して、それら全てを過程(p)に再循環する工程と、
(i) 水を加えて過程(c)の濾過ケークをスラリー化する工程と、
(j) 浸出領域で酸化剤を加えて、不溶性固形物を含む過程(i)のスラリーを浸出条件で処理する工程と、
(k) 過程(j)の廃液を濾過領域に移して、固体コークス混在物を除去する工程と、
(l) 過程(k)の上澄みを混合沈澱領域に移し、溶液を中和して、水酸化ニッケルを沈殿させる工程と、
(m) 過程(l)の廃液を濾過領域に移して、固形化した水酸化ニッケルを分離する工程と、
(n) 水酸化ニッケルを含む過程(m)の不溶性固形物を溶解領域に移し、溶解条件に従って酢酸を加えて、生成物として酢酸ニッケル四水和物を得る工程と、
(o) 過程(m)の上澄み液を排水処理装置に移し、精製装置から廃液を排出して廃棄処分する前に、微量金属及びアンモニウムを除去して、それら全てを過程(p)に再循環する工程と、
(p) 過程(n)及び過程(h)から過程(a)まで再生液を再循環させる工程とを含む請求項4に記載の回収法。 - 過程(b)の浸出領域は、撹拌器を有する貯槽であり、
水性溶媒は、水酸化ナトリウムを含み、
酸化剤は、過酸化水素を含む請求項5に記載の回収法。 - 温度範囲60℃〜67℃、pH範囲7〜13で過程(b)の浸出反応を発生する請求項5又は6に記載の回収法。
- 過程(c)の濾過領域では、炭素、ニッケル、残留バナジウム及び残留モリブデンを含む濾過ケークである不溶性固形物から、豊富なバナジウムとモリブデンとを含む上澄み液を分離する工程と、
濾過ケークに対して1対1の割合で洗浄水を加えて、濾過ケークから伴入金属を除去する工程とを含む請求項5、6又は7に記載の回収法。 - 過程(d)の混合沈澱領域は、沈澱槽であり、
水酸化ナトリウム及び硫酸を加えて上澄み液のpHを調整する工程と、
硫酸アンモニウムのアンモニウムイオンを添加してメタバナジン酸アンモニウムを沈殿する工程とを含む請求項5〜8の何れか1項に記載の回収法。 - 温度範囲5℃〜10℃、pH範囲7.3〜8.5で過程(d)のメタバナジン酸アンモニウムの沈降反応を発生する工程を含む請求項5〜9の何れか1項に記載の回収法。
- メタバナジン酸アンモニウム濾過過程(e)により沈殿したメタバナジン酸アンモニウムから、(豊富なモリブデンと残留モリブデンを含む)上澄み液を分離する工程と、
メタバナジン酸アンモニウムケークに対して1対1の割合の洗浄水を加えて、伴入濾過液を除去する工程とを含む請求項5〜10の何れか1項に記載の回収法。 - 過程(f)の混合沈澱領域は、沈澱槽であり、
水酸化ナトリウム及び硫酸を加えて上澄み液のpHを調整する工程と、
硫酸アンモニウムのアンモニウムイオンを加えてヘプタモリブデン酸アンモニウム四水和物を沈殿させる工程とを含む請求項5〜11の何れか1項に記載の回収法。 - 温度範囲5℃〜50℃、pH範囲5.3〜7.1で過程(g)のヘプタモリブデン酸アンモニウム四水和物の沈降反応を発生する工程を含む請求項5〜12の何れか1項に記載の回収法。
- ヘプタモリブデン酸アンモニウム四水和物濾過過程(g)により沈殿したヘプタモリブデン酸アンモニウム四水和物から残留モリブデンと残留バナジウムを含む上澄み液を分離する工程と、
ヘプタモリブデン酸アンモニウム四水和物ケークに対して1対1の割合で洗浄水を加えて、伴入濾過液を除去する工程とを含む請求項5〜13の何れか1項に記載の回収法。 - 過程(h)の排水処理装置は、イオン交換装置であり、
水酸化ナトリウム及び硫酸を再生剤として使用する工程と、
廃液の濃度を2ppmに制限する工程とを含む請求項5〜14の何れか1項に記載の回収法。 - 過程(i)の濾過ケークは、炭素、ニッケル、残留バナジウム及び残留モリブデンを含む請求項5〜15の何れか1項に記載の回収法。
- 過程(j)の浸出領域は、撹拌器を有する貯槽であり、
酸化剤は、硫酸を含む請求項5〜16の何れか1項に記載の回収法。 - 温度範囲50℃〜60℃、pH範囲2.0〜3.0で過程(j)の浸出反応を発生し、99%を超える効率でニッケルを回収する請求項5〜17の何れか1項に記載の回収法。
- 浸出濾過過程(k)の不溶性炭素系生成物から、(豊富な硫酸ニッケル、残留未酸化バナジウム及び未酸化モリブデンを含む)上澄みを分離する工程と、
不溶性炭素系生成物に対して1対1の割合で洗浄水を加えて、伴入濾過液を除去する工程とを含む請求項5〜18の何れか1項に記載の回収法。 - 過程(l)の混合沈澱領域は、ニッケル沈澱槽であり、
水酸化ナトリウムを加えて、豊富なニッケルを含む溶液である上澄み液のpHを調整する工程と、
酸化マグネシウムスラリーを加えて水酸化ニッケルを沈殿する工程とを含む請求項5〜19の何れか1項に記載の回収法。 - 温度範囲20℃〜90℃、pH範囲7.5〜13で過程(l)の水酸化ニッケル沈殿反応を発生する工程を含む請求項5〜20の何れか1項に記載の回収法。
- 濾過過程(m)では、残留ニッケル、残留モリブデン及び残留バナジウムを含む上澄み液を、沈殿する水酸化ニッケルから分離する工程と、水酸化ニッケルケークに対して1対1の割合で洗浄水を加えて、伴入濾過液を除去する工程とを含む請求項5〜21の何れか1項に記載の回収法。
- 溶解領域は、乾燥ニッケル固形物に対して1対1の割合で水を貯蔵するニッケル再スラリー化貯槽であり、
酢酸を加えて、雰囲気温度かつpH範囲4.0〜4.5で最終生成物の酢酸ニッケル四水和物を生成する工程を含む請求項5〜22の何れか1項に記載の回収法。 - 過程(o)の排水処理装置は、イオン交換装置であり、
水酸化ナトリウム及び硫酸を再生剤として使用する工程と、
廃液の濃度を2ppmに制限する工程とを含む請求項5〜23の何れか1項に記載の回収法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1003578A GB2478332A (en) | 2010-03-04 | 2010-03-04 | Method of metals recovery from refinery residues |
GB1003578.0 | 2010-03-04 | ||
PCT/GB2011/050422 WO2011107802A2 (en) | 2010-03-04 | 2011-03-03 | Method of metals recovery from refinery residues |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2013522454A true JP2013522454A (ja) | 2013-06-13 |
Family
ID=42136444
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012555495A Pending JP2013522454A (ja) | 2010-03-04 | 2011-03-03 | 精製用残留分からの金属回収法 |
Country Status (14)
Country | Link |
---|---|
US (1) | US9273377B2 (ja) |
EP (1) | EP2542708A2 (ja) |
JP (1) | JP2013522454A (ja) |
KR (1) | KR20130026431A (ja) |
CN (1) | CN102971439B (ja) |
BR (1) | BR112012022247A2 (ja) |
CA (1) | CA2791636A1 (ja) |
CO (1) | CO6640287A2 (ja) |
CU (1) | CU24025B1 (ja) |
EC (1) | ECSP12012141A (ja) |
GB (1) | GB2478332A (ja) |
MX (1) | MX2012010208A (ja) |
RU (1) | RU2578891C2 (ja) |
WO (1) | WO2011107802A2 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7359181B2 (ja) | 2021-03-17 | 2023-10-11 | Jfeスチール株式会社 | 有価元素の回収方法 |
JP7359180B2 (ja) | 2021-03-17 | 2023-10-11 | Jfeスチール株式会社 | 有価元素の回収方法 |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20111763A1 (it) * | 2011-09-30 | 2013-03-31 | Francesco Corigliano | Processo estrattivo del vanadio e di separazione dal nichel nei residui petroliferi. |
CN102674483B (zh) * | 2012-05-14 | 2013-11-06 | 江门市芳源环境科技开发有限公司 | 一种用废电池正极材料制备球形氢氧化镍的方法 |
US8815185B1 (en) | 2013-03-04 | 2014-08-26 | Chevron U.S.A. Inc. | Recovery of vanadium from petroleum coke slurry containing solubilized base metals |
WO2015028398A1 (en) | 2013-08-26 | 2015-03-05 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of glycols |
KR101555832B1 (ko) | 2015-03-27 | 2015-09-25 | 케이씨코트렐 주식회사 | 중질유탈황(RHDS, Residual Hydro Desulfurization) 및 감압잔사유탈황(VRDS, Vacuum Residue Desulfurization) 공정에서의 폐촉매 통합 세정 장치 및 그 통합 세정 방법 |
EP3347499B1 (en) | 2015-09-07 | 2019-12-11 | Shell International Research Maatschappij B.V. | Process for recovering of metalls |
US10301705B2 (en) | 2016-04-01 | 2019-05-28 | Energy, Science And Technology Corporation | Method for producing electrolyte for vanadium batteries from oil sand waste |
CN106367601B (zh) * | 2016-08-31 | 2018-07-10 | 大连博融新材料股份有限公司 | 一种湿法处理燃油飞灰提取有价金属的方法 |
CN108117891B (zh) * | 2016-11-28 | 2020-05-19 | 中国石油化工股份有限公司 | 生物质微波热解定向气化的方法和系统 |
US20210388462A1 (en) * | 2018-12-11 | 2021-12-16 | Eni S.P.A. | Process for the selective recovery of transition metals from organic residues |
CN111575478B (zh) * | 2019-02-18 | 2022-03-11 | 中国石油化工股份有限公司 | 一种重油中金属的分离方法 |
CN110453081A (zh) * | 2019-04-23 | 2019-11-15 | 湖北金洋冶金股份有限公司 | 一种含铅烟道灰预处理装置及方法 |
CN111014247B (zh) * | 2019-12-24 | 2021-04-02 | 青岛大学 | 一种重油悬浮床加氢固体废弃物的高值化利用工艺 |
US20220040629A1 (en) * | 2020-08-04 | 2022-02-10 | Honeywell International Inc. | Pitch destruction processes using thermal oxidation system |
CN114075625A (zh) * | 2020-08-18 | 2022-02-22 | 刘虎 | 一种炭黑中有价值金属的回收方法 |
CN114480857A (zh) * | 2020-10-27 | 2022-05-13 | 中国石油化工股份有限公司 | 一种气化灰渣中有价金属的回收方法 |
CN114426889B (zh) * | 2020-10-29 | 2023-10-10 | 中国石油化工股份有限公司 | 一种加氢裂化含钼尾渣的利用方法 |
CN114427029A (zh) * | 2020-10-29 | 2022-05-03 | 中国石油化工股份有限公司 | 一种实现金属分离回收的重油处理方法 |
CN113293297B (zh) * | 2020-11-16 | 2023-12-05 | 江苏瑞孚再生资源有限公司 | 渣油加氢废催化剂的多元素回收利用 |
CN114369718B (zh) * | 2021-12-17 | 2023-12-15 | 中核沽源铀业有限责任公司 | 一种双氧水分离钼合格液中夹带有机相的系统及方法 |
KR102496184B1 (ko) * | 2022-10-06 | 2023-02-06 | 한국지질자원연구원 | 적층형 세라믹콘덴서 공정 슬러지로부터 수산화니켈 및 황산니켈 회수방법 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4917397A (ja) * | 1972-04-14 | 1974-02-15 | ||
JPS52155102A (en) * | 1976-06-18 | 1977-12-23 | Taiwa Kk | Process for recovery of valuable metal from spent catalyst |
JPS5319118A (en) * | 1976-08-06 | 1978-02-22 | Baba Risaachi Inst Kk | Extraction of v and mo from oxidizing roasted ores containing same components |
JPH078808A (ja) * | 1990-10-30 | 1995-01-13 | Inst Fr Petrole | 使用済状態の精製用触媒の公害防止処理方法および金属の回収方法 |
JP2006241529A (ja) * | 2005-03-03 | 2006-09-14 | Taiheiyo Kinzoku Kk | ニッケル化合物またはコバルト化合物から硫黄などを除去する精製方法、フェロニッケルの製造方法 |
JP2009506880A (ja) * | 2005-07-29 | 2009-02-19 | シェブロン ユー.エス.エー. インコーポレイテッド | 廃触媒からの金属の回収方法 |
Family Cites Families (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4145397A (en) | 1976-08-06 | 1979-03-20 | Marubeni Corporation | Process for recovering molybdenum, vanadium, cobalt and nickel from roasted products of used catalysts from hydrotreatment desulfurization of petroleum |
US4178227A (en) | 1978-03-24 | 1979-12-11 | Exxon Research & Engineering Co. | Combination hydroconversion, fluid coking and gasification |
CA1156952A (en) * | 1979-06-08 | 1983-11-15 | Zacharia M. George | Formation of coke from heavy crude oils in the presence of calcium carbonate |
IT1130595B (it) | 1980-05-12 | 1986-06-18 | Stoppani Luigi Spa | Procedimento continuo per l'eleminazione di cromo da acque di rifiuto e la valrizzazione del cromo ricuperato |
US4432949A (en) | 1982-09-24 | 1984-02-21 | Chevron Research Company | Recovery of cobalt, molybdenum, nickel and vanadium from an aqueous ammonia and ammonium salt solution by precipitating vanadium and subsequent serial ion exchange |
US4514368A (en) | 1982-09-24 | 1985-04-30 | Chevron Research Company | Leaching nickel, cobalt, molybdenum, tungsten, and vanadium from spent hydroprocessing catalysts |
US4514369A (en) | 1982-09-24 | 1985-04-30 | Chevron Research Company | Recovery of cobalt, molybdenum, nickel, tungsten and vanadium from an aqueous ammonia and ammonium salt solution by coextracting molybdenum, tungsten and vanadium and sequential extraction of nickel and cobalt |
US4762812A (en) | 1983-08-29 | 1988-08-09 | Chevron Research Company | Heavy oil hydroprocess including recovery of molybdenum catalyst |
US4557821A (en) | 1983-08-29 | 1985-12-10 | Gulf Research & Development Company | Heavy oil hydroprocessing |
US4710486A (en) | 1983-08-29 | 1987-12-01 | Chevron Research Company | Process for preparing heavy oil hydroprocessing slurry catalyst |
FR2553680B1 (fr) | 1983-10-25 | 1987-09-18 | Inst Francais Du Petrole | Catalyseurs a base de sulfures de metaux du groupe viii et du groupe vib, pour les reactions d'hydrotraitement des coupes d'hydrocarbures contenant du soufre |
US4544533A (en) | 1984-11-26 | 1985-10-01 | Chevron Research Company | Recovering vanadium values from ammonium bicarbonate solution using heat, sulfuric acid, and ammonium sulfate |
US4668483A (en) | 1986-05-12 | 1987-05-26 | Gte Products Corporation | Process for recovery of chromium |
DE3710021A1 (de) | 1987-03-30 | 1988-10-20 | Veba Oel Entwicklungs Gmbh | Verfahren zur hydrierenden konversion von schwer- und rueckstandsoelen |
CA1296670C (en) | 1988-04-15 | 1992-03-03 | Anil K. Jain | Use of antifoam to achieve high conversion in hydroconversion of heavy oils |
US5124024A (en) | 1989-11-20 | 1992-06-23 | Nova Husky Research Corporation | Method for extending hydroconversion catalyst life |
CA2117155C (en) * | 1993-03-15 | 2003-12-02 | Michael R. Woolery | Separation and recovery of metal values from natural bitumen ash |
US6033637A (en) * | 1996-12-25 | 2000-03-07 | Kashima-Kita, Electric Power Corporation | Method for treating combustion ashes |
JP3665918B2 (ja) * | 1997-05-14 | 2005-06-29 | バブコック日立株式会社 | 石油系燃焼灰の処理方法 |
US6153155A (en) * | 1997-12-31 | 2000-11-28 | Exxon Research And Engineering Company | Recovery of the transition metal component of catalyst used in heavy feed hydroconversion |
US6511937B1 (en) | 1999-10-12 | 2003-01-28 | Exxonmobil Research And Engineering Company | Combination slurry hydroconversion plus solvent deasphalting process for heavy oil upgrading wherein slurry catalyst is derived from solvent deasphalted rock |
JP3831805B2 (ja) * | 1999-12-28 | 2006-10-11 | 太平洋セメント株式会社 | 石油系燃焼灰の処理方法 |
RU2198941C2 (ru) * | 2000-08-08 | 2003-02-20 | Закрытое акционерное общество "Техноген" | Способ переработки материала, преимущественно содержащего никель, кобальт, молибден, ванадий в неорганической, например оксидной, основе |
JP3780359B2 (ja) * | 2000-11-30 | 2006-05-31 | 太平洋セメント株式会社 | 石油系燃焼灰の処理方法 |
EP1350832A4 (en) | 2000-11-30 | 2004-12-01 | Jgc Corp | METHOD FOR REFINING PETROLEUM |
US20030102250A1 (en) | 2001-12-04 | 2003-06-05 | Michael Siskin | Delayed coking process for producing anisotropic free-flowing shot coke |
JPWO2003072275A1 (ja) * | 2002-02-27 | 2005-06-16 | 鹿島北共同発電株式会社 | 石油系燃焼灰の湿式処理方法 |
JP2005060777A (ja) * | 2003-08-13 | 2005-03-10 | Kashima Kita Electric Power Corp | ニッケル水酸化物含有スラリーからのニッケル水酸化物の分離方法 |
US7214309B2 (en) | 2004-09-10 | 2007-05-08 | Chevron U.S.A. Inc | Process for upgrading heavy oil using a highly active slurry catalyst composition |
US20060058174A1 (en) | 2004-09-10 | 2006-03-16 | Chevron U.S.A. Inc. | Highly active slurry catalyst composition |
ITMI20042446A1 (it) | 2004-12-22 | 2005-03-22 | Eni Spa | Procedimento per la conversione di cariche pesantyi quali i greggi pesanti e i residui di distillazione |
CA2630365C (en) | 2005-11-23 | 2010-03-16 | Pedro Pereira-Almao | Ultradispersed catalyst compositions and methods of preparation |
US7943036B2 (en) | 2009-07-21 | 2011-05-17 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US8048292B2 (en) | 2005-12-16 | 2011-11-01 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US8435400B2 (en) | 2005-12-16 | 2013-05-07 | Chevron U.S.A. | Systems and methods for producing a crude product |
US8372266B2 (en) | 2005-12-16 | 2013-02-12 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
RU2374344C2 (ru) * | 2006-06-27 | 2009-11-27 | Товарищество с ограниченной ответственностью "Научно-производственное объединение "Ванадий-катализатор" | Способ переработки ванадийсодержащего сырья |
FR2910352B1 (fr) | 2006-12-21 | 2010-10-08 | Inst Francais Du Petrole | Procede d'hydroconversion en phase slurry de charges hydrocarbonees lourdes et ou de charbon utilisant un catalyseur supporte |
US7674369B2 (en) | 2006-12-29 | 2010-03-09 | Chevron U.S.A. Inc. | Process for recovering ultrafine solids from a hydrocarbon liquid |
FR2913691B1 (fr) | 2007-03-16 | 2010-10-22 | Inst Francais Du Petrole | Procede d'hydroconversion de charges hydrocarbonees lourdes en reacteur slurry en presence d'un catalyseur a base d'heteropolyanion |
US7737068B2 (en) | 2007-12-20 | 2010-06-15 | Chevron U.S.A. Inc. | Conversion of fine catalyst into coke-like material |
MX2010005883A (es) | 2007-11-28 | 2010-06-09 | Chevron Usa Inc | Proceso para recuperar metales base a partir de un catalizador utilizando hidroprocesamiento. |
GB2456537A (en) * | 2008-01-17 | 2009-07-22 | Grimley Smith Associates | Process for vanadium recovery from residues |
US20090023965A1 (en) | 2008-05-01 | 2009-01-22 | Intevep, S.A. | Dispersed metal sulfide-based catalysts |
US8298509B2 (en) | 2008-05-19 | 2012-10-30 | Intevep, S.A. | Electro-gasification process using pre-treated pet-coke |
EP2328995A4 (en) | 2008-09-18 | 2012-05-30 | Chevron Usa Inc | SYSTEMS AND METHODS FOR PRODUCING A GROSS PRODUCT |
US8080154B2 (en) | 2008-12-30 | 2011-12-20 | Chevron U.S.A. Inc. | Heavy oil upgrade process including recovery of spent catalyst |
RU2412022C1 (ru) | 2009-11-05 | 2011-02-20 | Юрий Михайлович Ермаков | Регулируемая державка |
US8679322B2 (en) | 2009-11-24 | 2014-03-25 | Intevep, S.A. | Hydroconversion process for heavy and extra heavy oils and residuals |
US8636967B2 (en) | 2010-01-21 | 2014-01-28 | Intevep, S.A. | Metal recovery from hydroconverted heavy effluent |
-
2010
- 2010-03-04 GB GB1003578A patent/GB2478332A/en not_active Withdrawn
-
2011
- 2011-03-03 RU RU2012142128/02A patent/RU2578891C2/ru not_active IP Right Cessation
- 2011-03-03 WO PCT/GB2011/050422 patent/WO2011107802A2/en active Application Filing
- 2011-03-03 BR BR112012022247A patent/BR112012022247A2/pt not_active IP Right Cessation
- 2011-03-03 CN CN201180022158.3A patent/CN102971439B/zh not_active Expired - Fee Related
- 2011-03-03 EP EP11713504A patent/EP2542708A2/en not_active Withdrawn
- 2011-03-03 MX MX2012010208A patent/MX2012010208A/es active IP Right Grant
- 2011-03-03 JP JP2012555495A patent/JP2013522454A/ja active Pending
- 2011-03-03 US US13/582,479 patent/US9273377B2/en not_active Expired - Fee Related
- 2011-03-03 KR KR20127025872A patent/KR20130026431A/ko not_active Application Discontinuation
- 2011-03-03 CA CA 2791636 patent/CA2791636A1/en not_active Abandoned
-
2012
- 2012-09-04 CU CU20120131A patent/CU24025B1/es active IP Right Grant
- 2012-09-04 EC ECSP12012141 patent/ECSP12012141A/es unknown
- 2012-10-01 CO CO12171900A patent/CO6640287A2/es unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4917397A (ja) * | 1972-04-14 | 1974-02-15 | ||
JPS52155102A (en) * | 1976-06-18 | 1977-12-23 | Taiwa Kk | Process for recovery of valuable metal from spent catalyst |
JPS5319118A (en) * | 1976-08-06 | 1978-02-22 | Baba Risaachi Inst Kk | Extraction of v and mo from oxidizing roasted ores containing same components |
JPH078808A (ja) * | 1990-10-30 | 1995-01-13 | Inst Fr Petrole | 使用済状態の精製用触媒の公害防止処理方法および金属の回収方法 |
JP2006241529A (ja) * | 2005-03-03 | 2006-09-14 | Taiheiyo Kinzoku Kk | ニッケル化合物またはコバルト化合物から硫黄などを除去する精製方法、フェロニッケルの製造方法 |
JP2009506880A (ja) * | 2005-07-29 | 2009-02-19 | シェブロン ユー.エス.エー. インコーポレイテッド | 廃触媒からの金属の回収方法 |
Non-Patent Citations (1)
Title |
---|
JPN6015038897; 渡部陽一 他1名: '使用済脱硫触媒からのモリブデン,バナジウムの分離・回収' 環境資源工学会シンポジウム「リサイクル設計と分離精製技術」資料集 Vol.16th, 20080220, Page.39-44 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7359181B2 (ja) | 2021-03-17 | 2023-10-11 | Jfeスチール株式会社 | 有価元素の回収方法 |
JP7359180B2 (ja) | 2021-03-17 | 2023-10-11 | Jfeスチール株式会社 | 有価元素の回収方法 |
Also Published As
Publication number | Publication date |
---|---|
KR20130026431A (ko) | 2013-03-13 |
CU20120131A7 (es) | 2013-04-19 |
CA2791636A1 (en) | 2011-09-09 |
GB201003578D0 (en) | 2010-04-21 |
ECSP12012141A (es) | 2013-05-31 |
WO2011107802A2 (en) | 2011-09-09 |
US20130078167A1 (en) | 2013-03-28 |
CO6640287A2 (es) | 2013-03-22 |
RU2578891C2 (ru) | 2016-03-27 |
RU2012142128A (ru) | 2014-04-10 |
EP2542708A2 (en) | 2013-01-09 |
CN102971439A (zh) | 2013-03-13 |
MX2012010208A (es) | 2012-10-03 |
BR112012022247A2 (pt) | 2016-10-25 |
WO2011107802A3 (en) | 2011-10-27 |
US9273377B2 (en) | 2016-03-01 |
CN102971439B (zh) | 2015-01-14 |
CU24025B1 (es) | 2014-07-30 |
GB2478332A (en) | 2011-09-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2013522454A (ja) | 精製用残留分からの金属回収法 | |
JP5232833B2 (ja) | 水素化分解された重質排出物から金属を回収する金属回収法 | |
KR100615773B1 (ko) | 소모된 촉매로부터 알칼리 침출에 의한 몰리브덴 및바나듐 금속의 회수방법 | |
JP5020954B2 (ja) | 廃触媒からの金属の回収方法 | |
JP3703813B2 (ja) | 有価金属の分離回収方法 | |
US8282897B2 (en) | Process for recovering boehmite and y-AI2O3 from spent hydroprocessing catalysts | |
WO2012065191A2 (en) | Method for recovering molybdenum, vanadium, nickel, cobalt and aluminum from spent catalysts | |
Marafi et al. | Refinery waste: the spent hydroprocessing catalyst and its recycling options | |
US20210077950A1 (en) | Method of Processing Sulfur-Bearing Wastes from Refineries and Upgraders | |
CA1210746A (en) | Recovering metal compounds from used catalysts obtained from hydroprocessing hydrocarbon feedstocks | |
Marafi et al. | Utilization of waste spent hydroprocessing catalyst: development of a process for full recovery of deposited metals and alumina support | |
WO1995001461A1 (en) | Method for extracting metals from catalysts on the basis of al2o¿3? | |
CN112746171A (zh) | 一种不同类型失活加氢催化剂组合处理方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20131211 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150119 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150303 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150601 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150929 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20151203 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160209 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20160920 |