JP2013507324A - 窒化ホウ素ナノチューブ(bnnt)およびbnntポリマー複合体で製作されたエネルギー変換材料 - Google Patents
窒化ホウ素ナノチューブ(bnnt)およびbnntポリマー複合体で製作されたエネルギー変換材料 Download PDFInfo
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- JP2013507324A JP2013507324A JP2012534160A JP2012534160A JP2013507324A JP 2013507324 A JP2013507324 A JP 2013507324A JP 2012534160 A JP2012534160 A JP 2012534160A JP 2012534160 A JP2012534160 A JP 2012534160A JP 2013507324 A JP2013507324 A JP 2013507324A
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- boron nitride
- polyimide
- bnnt
- nitride nanotube
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- 239000002131 composite material Substances 0.000 title claims abstract description 15
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 title claims description 71
- 229920000642 polymer Polymers 0.000 title claims description 19
- 238000006243 chemical reaction Methods 0.000 title abstract description 9
- 239000000463 material Substances 0.000 title abstract description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title description 3
- 229920001721 polyimide Polymers 0.000 claims abstract description 47
- 239000004642 Polyimide Substances 0.000 claims abstract description 43
- 239000002071 nanotube Substances 0.000 claims description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 28
- 229910052582 BN Inorganic materials 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 24
- 239000002041 carbon nanotube Substances 0.000 claims description 20
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 19
- 239000002114 nanocomposite Substances 0.000 claims description 16
- 239000011159 matrix material Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 12
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 8
- 239000010931 gold Substances 0.000 claims description 8
- 229910052737 gold Inorganic materials 0.000 claims description 8
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- PVXRBSHBFJXTNM-UHFFFAOYSA-N 2,6-bis(3-aminophenoxy)benzonitrile Chemical compound NC1=CC=CC(OC=2C(=C(OC=3C=C(N)C=CC=3)C=CC=2)C#N)=C1 PVXRBSHBFJXTNM-UHFFFAOYSA-N 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 150000004985 diamines Chemical class 0.000 claims description 5
- 239000002033 PVDF binder Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 230000002194 synthesizing effect Effects 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- 125000006159 dianhydride group Chemical group 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- -1 polysiloxane Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 3
- 238000000576 coating method Methods 0.000 claims 3
- 239000011263 electroactive material Substances 0.000 abstract description 9
- 239000002109 single walled nanotube Substances 0.000 description 10
- 230000010287 polarization Effects 0.000 description 9
- 230000004044 response Effects 0.000 description 9
- 230000005684 electric field Effects 0.000 description 6
- 230000028161 membrane depolarization Effects 0.000 description 5
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 238000000527 sonication Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- XLOFNXVVMRAGLZ-UHFFFAOYSA-N 1,1-difluoroethene;1,1,2-trifluoroethene Chemical group FC(F)=C.FC=C(F)F XLOFNXVVMRAGLZ-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 241001289753 Graphium sarpedon Species 0.000 description 1
- 241001124569 Lycaenidae Species 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001746 electroactive polymer Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
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- H—ELECTRICITY
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- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/01—Manufacture or treatment
- H10N30/06—Forming electrodes or interconnections, e.g. leads or terminals
- H10N30/063—Forming interconnections, e.g. connection electrodes of multilayered piezoelectric or electrostrictive parts
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/01—Manufacture or treatment
- H10N30/09—Forming piezoelectric or electrostrictive materials
- H10N30/092—Forming composite materials
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/702—Piezoelectric or electrostrictive devices based on piezoelectric or electrostrictive fibres
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/704—Piezoelectric or electrostrictive devices based on piezoelectric or electrostrictive films or coatings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R29/00—Arrangements for measuring or indicating electric quantities not covered by groups G01R19/00 - G01R27/00
- G01R29/12—Measuring electrostatic fields or voltage-potential
- G01R29/14—Measuring field distribution
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/778—Nanostructure within specified host or matrix material, e.g. nanocomposite films
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- Y10T29/00—Metal working
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- Y10T29/49005—Acoustic transducer
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- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49117—Conductor or circuit manufacturing
- Y10T29/49124—On flat or curved insulated base, e.g., printed circuit, etc.
- Y10T29/49155—Manufacturing circuit on or in base
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Abstract
【選択図】図1a
Description
[01]米国政府は、本発明についてのペイドアップ・ライセンス(paid-up license)、および、限定された状況において、航空宇宙局により与えられた共同契約No.NCC−1−02043の条項により規定されているような合理的な条件で、特許権者に対し他者にライセンスを供与するように求める権利を有する。
関連出願の相互参照
[02]本出願は、2009年10月13日提出の米国仮特許出願第61/278866号に由来する優先権を主張するものである。
[09]本発明の目的は、高性能エネルギー変換装置、例えばセンサーを、提供することである。
[11]本発明のさらに他の目的は、窒化ホウ素ナノチューブおよびBNNT/ポリイミド複合材料から製造される高性能エネルギー変換装置を提供することである。
[25]以下の詳細な説明は、現在考えられる最良の本発明の実施方法に関するものである。この説明は、限定的な意味で理解すべきではなく、本発明の態様の一般的原理を例示する目的でのみ行っている。
Claims (16)
- 窒化ホウ素ナノチューブナノ複合体フィルムを形成するための方法であって、
窒化ホウ素ナノチューブ溶液を、ポリマーおよびセラミックからなる群より選択されるマトリックスと組み合わせて、窒化ホウ素ナノチューブ/ポリイミド混合物を形成し;
窒化ホウ素ナノチューブ/ポリイミドナノ複合体フィルムを電気活性層として合成する、
ことを含む方法。 - マトリックスを、ジアミン、2,6−ビス(3−アミノフェノキシ)ベンゾニトリル((β−CN)APB)と、二無水物、ピロメリト酸二無水物(PMDA)から合成する、請求項1に記載の方法。
- マトリックスが、ポリフッ化ビニリデン、ポリフッ化ビニリデンコポリマー、ポリカーボネートおよびエポキシからなる群より選択されるポリマーである、請求項1に記載の方法。
- マトリックスが、ポリウレタンおよびポリシロキサンからなる群より選択される高弾性ポリマーである、請求項1に記載の方法。
- マトリックスが、二酸化ケイ素および酸化アルミニウムからなる群より選択されるセラミックである、請求項1に記載の方法。
- 窒化ホウ素ナノチューブ/ポリイミド混合物中の窒化ホウ素ナノチューブの濃度が0〜100重量%である、請求項1に記載の方法。
- さらに、窒化ホウ素ナノチューブ/ポリイミドナノ複合体フィルムを金属電極でコーティングする段階を含む、請求項1に記載の方法。
- 金属電極のための金属が、クロム、金およびそれらの混合物からなる群より選択される、請求項4に記載の方法。
- さらに、窒化ホウ素ナノチューブ/ポリイミドフィルムを柔軟電極でコーティングする段階を含む、請求項1に記載の方法。
- 柔軟電極が、カーボンナノチューブ、カーボンナノチューブシート、カーボンナノチューブ/ポリマー複合体、金粒子、銀粒子およびそれらの混合物からなる群より選択される、請求項9に記載の方法。
- 窒化ホウ素ナノチューブ/ポリマーナノ複合体フィルムを形成するための方法であって、
高温圧電性ポリイミドを合成し;
窒化ホウ素ナノチューブ溶液を高温圧電性ポリイミドと組み合わせ;
ポリマーをマトリックスとして用い;そして
窒化ホウ素ナノチューブ/ポリイミドナノ複合体フィルムを電気活性層として合成する、
ことを含む方法。 - ポリマーが二無水物、ピロメリト酸二無水物である、請求項11に記載の方法。
- 高温圧電性ポリイミドを、ジアミン、2,6−ビス(3−アミノフェノキシ)ベンゾニトリル((β−CN)APB)と、二無水物、ピロメリト酸二無水物(PMDA)から合成する、請求項11に記載の方法。
- 窒化ホウ素ナノチューブ/ポリイミド混合物中の窒化ホウ素ナノチューブの濃度が0〜100重量%である、請求項11に記載の方法。
- さらに、窒化ホウ素ナノチューブ/ポリイミドフィルムを金属電極でコーティングする段階を含む、請求項11に記載の方法。
- 金属が、クロム、金およびそれらの混合物からなる群より選択される、請求項11に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US27886609P | 2009-10-13 | 2009-10-13 | |
US61/278,866 | 2009-10-13 | ||
US12/925,047 | 2010-10-13 | ||
PCT/US2010/002737 WO2011046602A1 (en) | 2009-10-13 | 2010-10-13 | Energy conversion materials fabricated with boron nitride nanotubes (bnnts) and bnnt polymer composites |
US12/925,047 US10435293B2 (en) | 2009-10-13 | 2010-10-13 | Methods of manufacturing energy conversion materials fabricated with boron nitride nanotubes (BNNTs) and BNNT polymer composites |
Publications (2)
Publication Number | Publication Date |
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JP2013507324A true JP2013507324A (ja) | 2013-03-04 |
JP5848706B2 JP5848706B2 (ja) | 2016-01-27 |
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Application Number | Title | Priority Date | Filing Date |
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JP2012534160A Active JP5848706B2 (ja) | 2009-10-13 | 2010-10-13 | 窒化ホウ素ナノチューブ(bnnt)およびbnntポリマー複合体で製作されたエネルギー変換材料 |
Country Status (6)
Country | Link |
---|---|
US (1) | US10435293B2 (ja) |
EP (1) | EP2489064A4 (ja) |
JP (1) | JP5848706B2 (ja) |
KR (1) | KR101810700B1 (ja) |
CA (1) | CA2777666C (ja) |
WO (1) | WO2011046602A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013535002A (ja) * | 2010-05-07 | 2013-09-09 | ナショナル・インスティチュート・オブ・エアロスペース・アソシエイツ | 放射線遮蔽用の窒化ホウ素および窒化ホウ素ナノチューブ材料 |
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US10435293B2 (en) | 2009-10-13 | 2019-10-08 | National Institute Of Aerospace Associates | Methods of manufacturing energy conversion materials fabricated with boron nitride nanotubes (BNNTs) and BNNT polymer composites |
JP2013535002A (ja) * | 2010-05-07 | 2013-09-09 | ナショナル・インスティチュート・オブ・エアロスペース・アソシエイツ | 放射線遮蔽用の窒化ホウ素および窒化ホウ素ナノチューブ材料 |
JP2013538887A (ja) * | 2010-07-26 | 2013-10-17 | ナショナル・インスティチュート・オブ・エアロスペース・アソシエイツ | 窒化ホウ素ナノチューブを用いて製造される高運動エネルギーの貫通物遮蔽材料 |
US10607742B2 (en) | 2011-05-09 | 2020-03-31 | National Institute Of Aerospace Associates | Radiation shielding materials containing hydrogen, boron and nitrogen |
KR20190032388A (ko) * | 2016-07-20 | 2019-03-27 | 비엔엔티 엘엘씨 | 폴리머를 이용한 붕소 질화막 나노튜브의 가스 상 코팅 |
JP2019528372A (ja) * | 2016-07-20 | 2019-10-10 | ビイエヌエヌティ・エルエルシイ | 窒化ホウ素ナノチューブのポリマーでの気相コーティング |
JP7007357B2 (ja) | 2016-07-20 | 2022-01-24 | ビイエヌエヌティ・エルエルシイ | 窒化ホウ素ナノチューブのポリマーでの気相コーティング |
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JP2021526595A (ja) * | 2019-05-09 | 2021-10-07 | ネイール テクノロジー | 窒化ホウ素ナノチューブが分散された高分子複合圧電材料の製造方法及び装置、並びにその方法により製造される高分子複合圧電材料 |
KR20210111477A (ko) * | 2020-03-03 | 2021-09-13 | 한국과학기술연구원 | 산화아연-질화붕소나노튜브 복합체 필름 및 이의 제조 방법 |
KR102398007B1 (ko) * | 2020-03-03 | 2022-05-16 | 한국과학기술연구원 | 산화아연-질화붕소나노튜브 복합체 필름 및 이의 제조 방법 |
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KR101810700B1 (ko) | 2017-12-19 |
KR20120095889A (ko) | 2012-08-29 |
US20110192016A1 (en) | 2011-08-11 |
EP2489064A4 (en) | 2014-02-19 |
CA2777666A1 (en) | 2011-04-21 |
EP2489064A1 (en) | 2012-08-22 |
US10435293B2 (en) | 2019-10-08 |
WO2011046602A1 (en) | 2011-04-21 |
JP5848706B2 (ja) | 2016-01-27 |
CA2777666C (en) | 2021-01-05 |
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