JP2012523402A5 - - Google Patents
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- JP2012523402A5 JP2012523402A5 JP2012504075A JP2012504075A JP2012523402A5 JP 2012523402 A5 JP2012523402 A5 JP 2012523402A5 JP 2012504075 A JP2012504075 A JP 2012504075A JP 2012504075 A JP2012504075 A JP 2012504075A JP 2012523402 A5 JP2012523402 A5 JP 2012523402A5
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- JP
- Japan
- Prior art keywords
- formula
- ccl
- compound
- zinc
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000001875 compounds Chemical class 0.000 claims 9
- 125000006414 CCl Chemical group ClC* 0.000 claims 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N HF Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 4
- 239000011701 zinc Substances 0.000 claims 4
- 229910052725 zinc Inorganic materials 0.000 claims 4
- QDOXWKRWXJOMAK-UHFFFAOYSA-N Chromium(III) oxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims 3
- VKEIPALYOJMDAC-UHFFFAOYSA-N 3,3,3-trichloroprop-1-ene Chemical compound ClC(Cl)(Cl)C=C VKEIPALYOJMDAC-UHFFFAOYSA-N 0.000 claims 2
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- UTACNSITJSJFHA-UHFFFAOYSA-N 1,1,1,3-tetrachloropropane Chemical compound ClCCC(Cl)(Cl)Cl UTACNSITJSJFHA-UHFFFAOYSA-N 0.000 claims 1
- UQIKKIADJVUSNI-UHFFFAOYSA-N 1,1,3-trichloro-1-fluoropropane Chemical compound FC(Cl)(Cl)CCCl UQIKKIADJVUSNI-UHFFFAOYSA-N 0.000 claims 1
- WGABYHBTXHBSEI-UHFFFAOYSA-N 1,3-dichloro-1,1-difluoropropane Chemical compound FC(F)(Cl)CCCl WGABYHBTXHBSEI-UHFFFAOYSA-N 0.000 claims 1
- FIROAKDNSCQSTG-UHFFFAOYSA-N 3,3-dichloro-3-fluoroprop-1-ene Chemical compound FC(Cl)(Cl)C=C FIROAKDNSCQSTG-UHFFFAOYSA-N 0.000 claims 1
- ZPIFKCVYZBVZIV-UHFFFAOYSA-N 3-chloro-1,1,1-trifluoropropane Chemical compound FC(F)(F)CCCl ZPIFKCVYZBVZIV-UHFFFAOYSA-N 0.000 claims 1
- AQBMNBSTXOCKKZ-UHFFFAOYSA-N 3-chloro-3,3-difluoroprop-1-ene Chemical compound FC(F)(Cl)C=C AQBMNBSTXOCKKZ-UHFFFAOYSA-N 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000011368 organic material Substances 0.000 claims 1
Claims (14)
- 3,3,3‐トリフルオロプロペン(1243zf)を製造する方法であって、前記方法が化学式CX3CH2CH2XまたはCX3CH=CH2の化合物を、亜鉛/クロミア触媒の存在下でフッ化水素(HF)と接触させることを含み、式中、それぞれのXが独立してF、Cl、BrまたはIであるが、化学式CX3CH=CH2の化合物においては少なくとも1つのXがFではない、方法。
- XがFまたはClである、請求項1に記載の方法。
- 前記方法が、1,1,1,3‐テトラクロロプロパン(CCl 3 CH 2 CH 2 Cl、250fb)、1,1,3‐トリクロロ‐1‐フルオロプロパン(CCl 2 FCH 2 CH 2 Cl)、1,3‐ジクロロ‐1,1‐ジフルオロプロパン(CClF 2 CH 2 CH 2 Cl)、3‐クロロ‐1,1,1‐トリフルオロプロパン(CF 3 CH 2 CH 2 Cl、253fb)および1,1,1,3‐テトラフルオロプロパン(CF 3 CH 2 CH 2 F、254fb)から選択される化学式CX3CH2CH2Xの化合物を接触させることを含む、請求項1または2に記載の方法。
- 化学式CX3CH2CH2Xの前記化合物がCF3CH2CH2Cl(253fb)を含む、請求項1〜3のいずれか一項に記載の方法。
- 化学式CX3CH2CH2Xの前記化合物がCCl3CH2CH2Cl(250fb)を含む、請求項1〜4のいずれか一項に記載の方法。
- 3,3,3‐トリクロロプロペン(CCl 3 CH=CH 2 )、3,3‐ジクロロ‐3‐フルオロプロペン(CCl 2 FCH=CH 2 )および3‐クロロ‐3,3‐ジフルオロプロペン(CClF 2 CH=CH 2 )から選択される化学式CX 3 CH=CH 2 の化合物を接触させることを含む、請求項1または2に記載の方法。
- 化学式CX 3 CH=CH 2 の前記化合物が、3,3,3‐トリクロロプロペン(CCl 3 CH=CH 2 )である、請求項6に記載の方法。
- 前記方法が、約100℃〜約500℃、好ましくは約150℃〜約450℃の温度で行なわれる、請求項1〜7のいずれか一項に記載の方法。
- 前記方法が、0〜約30bara、好ましくは約1〜約20baraの圧力で行なわれる、請求項1〜8のいずれか一項に記載の方法。
- HF:有機物のモル比が、約1:1〜約100:1、好ましくは約3:1〜約50:1である、請求項1〜9のいずれか一項に記載の方法。
- 前記方法が気相中で行なわれる、請求項1〜10のいずれか一項に記載の方法。
- 前記方法が連続的または半連続的である、請求項1〜11のいずれか一項に記載の方法。
- 前記亜鉛/クロミア触媒が、有機物およびHFの総合重量に基づき、約0.01〜約50重量%、好ましくは約0.1〜約30%の量で存在する、請求項1〜12のいずれか一項に記載の方法。
- 前記亜鉛/クロミア触媒は非晶質であるか、または該触媒の0.1〜50重量%が1つ以上のクロムの結晶性化合物および/または1つ以上の亜鉛の結晶性化合物の形態にある、請求項1〜13のいずれか一項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0906191.2A GB0906191D0 (en) | 2009-04-09 | 2009-04-09 | Process |
GB0906191.2 | 2009-04-09 | ||
PCT/GB2010/000725 WO2010116150A1 (en) | 2009-04-09 | 2010-04-09 | Process for preparing 3,3,3-trifluoropropene |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2012523402A JP2012523402A (ja) | 2012-10-04 |
JP2012523402A5 true JP2012523402A5 (ja) | 2013-03-21 |
JP5816612B2 JP5816612B2 (ja) | 2015-11-18 |
Family
ID=40750388
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012504075A Expired - Fee Related JP5816612B2 (ja) | 2009-04-09 | 2010-04-09 | 3,3,3‐トリフルオロプロペンの製造方法 |
Country Status (11)
Country | Link |
---|---|
US (1) | US9096489B2 (ja) |
EP (1) | EP2417086B1 (ja) |
JP (1) | JP5816612B2 (ja) |
KR (1) | KR101731565B1 (ja) |
CN (1) | CN102388006B (ja) |
BR (1) | BRPI1008987A2 (ja) |
ES (1) | ES2555859T3 (ja) |
GB (1) | GB0906191D0 (ja) |
MX (1) | MX339991B (ja) |
PL (1) | PL2417086T3 (ja) |
WO (1) | WO2010116150A1 (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102001912A (zh) * | 2010-10-24 | 2011-04-06 | 浙江衢化氟化学有限公司 | 一种合成3,3,3-三氟丙烯的方法 |
CN103717560B (zh) * | 2011-07-26 | 2016-04-27 | 大金工业株式会社 | 用于制备2,3,3,3-四氟丙烯的方法 |
WO2014010750A1 (en) * | 2012-07-10 | 2014-01-16 | Daikin Industries, Ltd. | Process for producing fluorine-containing olefin |
CN104844415A (zh) * | 2015-05-26 | 2015-08-19 | 南京都乐制冷设备有限公司 | 一种三氟丙烯回收装置及回收方法 |
GB201509323D0 (en) * | 2015-05-29 | 2015-07-15 | Mexichem Fluor Sa De Cv | Process |
GB2540427B (en) | 2015-07-17 | 2017-07-19 | Mexichem Fluor Sa De Cv | Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf) |
GB2540421C (en) | 2015-07-17 | 2018-11-14 | Mexichem Fluor Sa De Cv | Process for preparing 245cb from 243db |
GB2540428B (en) | 2015-07-17 | 2017-09-13 | Mexichem Fluor Sa De Cv | Process for preparing 3,3,3-trifluoropropene |
FR3055221B1 (fr) | 2016-08-29 | 2023-12-15 | Arkema France | Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse |
JP2024515192A (ja) * | 2021-04-19 | 2024-04-05 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | 3,3,3-トリフルオロプロペン(1243zf)を含有する組成物並びに当該組成物の製造及び使用方法 |
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-
2009
- 2009-04-09 GB GBGB0906191.2A patent/GB0906191D0/en not_active Ceased
-
2010
- 2010-04-09 ES ES10717715.6T patent/ES2555859T3/es active Active
- 2010-04-09 US US13/256,077 patent/US9096489B2/en active Active
- 2010-04-09 WO PCT/GB2010/000725 patent/WO2010116150A1/en active Application Filing
- 2010-04-09 JP JP2012504075A patent/JP5816612B2/ja not_active Expired - Fee Related
- 2010-04-09 CN CN201080011409.3A patent/CN102388006B/zh not_active Expired - Fee Related
- 2010-04-09 BR BRPI1008987A patent/BRPI1008987A2/pt not_active Application Discontinuation
- 2010-04-09 EP EP10717715.6A patent/EP2417086B1/en not_active Not-in-force
- 2010-04-09 MX MX2011009426A patent/MX339991B/es active IP Right Grant
- 2010-04-09 KR KR1020117023530A patent/KR101731565B1/ko active IP Right Grant
- 2010-04-09 PL PL10717715T patent/PL2417086T3/pl unknown
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