JP2012523402A - 3,3,3‐トリフルオロプロペンの製造方法 - Google Patents
3,3,3‐トリフルオロプロペンの製造方法 Download PDFInfo
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- JP2012523402A JP2012523402A JP2012504075A JP2012504075A JP2012523402A JP 2012523402 A JP2012523402 A JP 2012523402A JP 2012504075 A JP2012504075 A JP 2012504075A JP 2012504075 A JP2012504075 A JP 2012504075A JP 2012523402 A JP2012523402 A JP 2012523402A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
本発明は、3,3,3‐トリフルオロプロペン(1243zf)を製造する方法であって、前記方法が化学式CX3CH2CH2XまたはCX3CH=CH2の化合物を、亜鉛/クロミア触媒の存在下でフッ化水素(HF)と接触させることを含み、式中、それぞれのXが独立してF、Cl、BrまたはIであるが、化学式CX3CH=CH2の化合物においては少なくとも1つのXがFではない、方法を提供する。
Description
30cm×0.5インチのInconnelチューブから作られた反応器に、性質上本質的に非晶質である6gの5.2%Zn/クロミア触媒を装入し、以下のように処理した。
最初に、250℃、3bargで48時間窒素(80ml/分)下で加熱することによって、触媒を乾燥させた。次に、HF(4ml/分)を窒素流へ導入し、温度を16時間で300℃に上昇することによって、触媒の予備フッ素化を始めた。最後の5時間の間、窒素流をゼロまで着実に減少させた。そして温度を380℃に25℃/hrで上昇し、380℃で7時間保持し、次いで250℃に25℃/hrで冷却した。
30cm×0.5インチのInconnelチューブから作られた反応器に、性質上本質的に非晶質であるクロミア触媒上の5.2重量%のZnを2.0g装入した。そして250℃で3時間、窒素(80ml/分)下で触媒を乾燥させた。HF(20ml/分)を窒素流に次いで導入し、触媒の予備フッ素化を開始した。反応器の排ガス中にHFが検出された時点で、反応器温度を250℃から370℃へ25℃/hrで上昇させて7時間保持し、その後200℃まで25℃/hrで冷却して戻した。
30cm×0.5インチのInconnelチューブから作られた反応器に、性質上本質的に非晶質であるクロミア触媒上の5.2重量%のZnを2.0g装入した。そして250℃で3時間、窒素(80ml/分)下で触媒を乾燥させた。そしてHF(20ml/分)を窒素流に導入し、触媒の予備フッ素化を開始した。反応器の排ガス中にHFが検出された時点で、反応器温度を250℃から370℃へ25℃/hrで上昇させて7時間保持し、その後200℃まで25℃/hrで冷却して戻した。
Claims (11)
- 3,3,3‐トリフルオロプロペン(1243zf)を製造する方法であって、前記方法が化学式CX3CH2CH2XまたはCX3CH=CH2の化合物を、亜鉛/クロミア触媒の存在下でフッ化水素(HF)と接触させることを含み、式中、それぞれのXが独立してF、Cl、BrまたはIであるが、化学式CX3CH=CH2の化合物においては少なくとも1つのXがFではない、方法。
- XがFまたはClである、請求項1に記載の方法。
- 前記方法が化学式CX3CH2CH2Xの化合物を接触させることを含む、請求項1または2に記載の方法。
- 化学式CX3CH2CH2Xの前記化合物がCF3CH2CH2Cl(253fb)を含む、請求項1〜3のいずれか一項に記載の方法。
- 化学式CX3CH2CH2Xの前記化合物がCCl3CH2CH2Cl(250fb)を含む、請求項1〜4のいずれか一項に記載の方法。
- 前記方法が、約100℃〜約500℃、好ましくは約150℃〜約450℃の温度で行なわれる、請求項1〜5のいずれか一項に記載の方法。
- 前記方法が、0〜約30bara、好ましくは約1〜約20baraの圧力で行なわれる、請求項1〜6のいずれか一項に記載の方法。
- HF:有機物のモル比が、約1:1〜約100:1、好ましくは約3:1〜約50:1である、請求項1〜7のいずれか一項に記載の方法。
- 前記方法が気相中で行なわれる、請求項1〜8のいずれか一項に記載の方法。
- 前記方法が連続的または半連続的である、請求項1〜9のいずれか一項に記載の方法。
- 所望により例を参照して、ここに記載されているようなあらゆる新規な方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0906191.2A GB0906191D0 (en) | 2009-04-09 | 2009-04-09 | Process |
GB0906191.2 | 2009-04-09 | ||
PCT/GB2010/000725 WO2010116150A1 (en) | 2009-04-09 | 2010-04-09 | Process for preparing 3,3,3-trifluoropropene |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2012523402A true JP2012523402A (ja) | 2012-10-04 |
JP2012523402A5 JP2012523402A5 (ja) | 2013-03-21 |
JP5816612B2 JP5816612B2 (ja) | 2015-11-18 |
Family
ID=40750388
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012504075A Expired - Fee Related JP5816612B2 (ja) | 2009-04-09 | 2010-04-09 | 3,3,3‐トリフルオロプロペンの製造方法 |
Country Status (11)
Country | Link |
---|---|
US (1) | US9096489B2 (ja) |
EP (1) | EP2417086B1 (ja) |
JP (1) | JP5816612B2 (ja) |
KR (1) | KR101731565B1 (ja) |
CN (1) | CN102388006B (ja) |
BR (1) | BRPI1008987A2 (ja) |
ES (1) | ES2555859T3 (ja) |
GB (1) | GB0906191D0 (ja) |
MX (1) | MX339991B (ja) |
PL (1) | PL2417086T3 (ja) |
WO (1) | WO2010116150A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015525201A (ja) * | 2012-07-10 | 2015-09-03 | ダイキン工業株式会社 | 含フッ素オレフィンの製造方法 |
JP2018520180A (ja) * | 2015-07-17 | 2018-07-26 | メキシケム フロー エセ・ア・デ・セ・ヴェ | 3,3,3−トリフルオロプロペンの調製方法 |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102001912A (zh) * | 2010-10-24 | 2011-04-06 | 浙江衢化氟化学有限公司 | 一种合成3,3,3-三氟丙烯的方法 |
CN103717560B (zh) * | 2011-07-26 | 2016-04-27 | 大金工业株式会社 | 用于制备2,3,3,3-四氟丙烯的方法 |
CN104844415A (zh) * | 2015-05-26 | 2015-08-19 | 南京都乐制冷设备有限公司 | 一种三氟丙烯回收装置及回收方法 |
GB201509323D0 (en) * | 2015-05-29 | 2015-07-15 | Mexichem Fluor Sa De Cv | Process |
GB2540427B (en) | 2015-07-17 | 2017-07-19 | Mexichem Fluor Sa De Cv | Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf) |
GB2540421C (en) | 2015-07-17 | 2018-11-14 | Mexichem Fluor Sa De Cv | Process for preparing 245cb from 243db |
FR3055221B1 (fr) | 2016-08-29 | 2023-12-15 | Arkema France | Compositions de catalyseurs d'oxyfluorure ou de fluorure de chrome, leur preparation et leur utilisation dans des procedes en phase gazeuse |
WO2022225830A1 (en) * | 2021-04-19 | 2022-10-27 | The Chemours Company Fc, Llc | Compositions containing 3,3,3-trifluoropropene (1243zf) and methods for making and using the compositions |
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2009
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-
2010
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- 2010-04-09 WO PCT/GB2010/000725 patent/WO2010116150A1/en active Application Filing
- 2010-04-09 MX MX2011009426A patent/MX339991B/es active IP Right Grant
- 2010-04-09 KR KR1020117023530A patent/KR101731565B1/ko active IP Right Grant
- 2010-04-09 CN CN201080011409.3A patent/CN102388006B/zh not_active Expired - Fee Related
- 2010-04-09 JP JP2012504075A patent/JP5816612B2/ja not_active Expired - Fee Related
- 2010-04-09 ES ES10717715.6T patent/ES2555859T3/es active Active
- 2010-04-09 US US13/256,077 patent/US9096489B2/en active Active
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- 2010-04-09 PL PL10717715T patent/PL2417086T3/pl unknown
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015525201A (ja) * | 2012-07-10 | 2015-09-03 | ダイキン工業株式会社 | 含フッ素オレフィンの製造方法 |
JP2018520180A (ja) * | 2015-07-17 | 2018-07-26 | メキシケム フロー エセ・ア・デ・セ・ヴェ | 3,3,3−トリフルオロプロペンの調製方法 |
Also Published As
Publication number | Publication date |
---|---|
MX2011009426A (es) | 2011-09-28 |
WO2010116150A1 (en) | 2010-10-14 |
US20120071699A1 (en) | 2012-03-22 |
EP2417086A1 (en) | 2012-02-15 |
GB0906191D0 (en) | 2009-05-20 |
EP2417086B1 (en) | 2015-11-04 |
ES2555859T3 (es) | 2016-01-11 |
BRPI1008987A2 (pt) | 2016-03-22 |
JP5816612B2 (ja) | 2015-11-18 |
PL2417086T3 (pl) | 2016-04-29 |
CN102388006A (zh) | 2012-03-21 |
MX339991B (es) | 2016-06-21 |
KR101731565B1 (ko) | 2017-05-11 |
US9096489B2 (en) | 2015-08-04 |
KR20120026030A (ko) | 2012-03-16 |
CN102388006B (zh) | 2016-01-13 |
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