JP2012519217A5 - - Google Patents
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- Publication number
- JP2012519217A5 JP2012519217A5 JP2011551457A JP2011551457A JP2012519217A5 JP 2012519217 A5 JP2012519217 A5 JP 2012519217A5 JP 2011551457 A JP2011551457 A JP 2011551457A JP 2011551457 A JP2011551457 A JP 2011551457A JP 2012519217 A5 JP2012519217 A5 JP 2012519217A5
- Authority
- JP
- Japan
- Prior art keywords
- slurry process
- carried out
- porosity
- molecular weight
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 4
- 239000002002 slurry Substances 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 2
- 239000000155 melt Substances 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- 238000004438 BET method Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000003247 decreasing Effects 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims 1
- 229910052753 mercury Inorganic materials 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 238000007613 slurry method Methods 0.000 claims 1
- 239000011949 solid catalyst Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
Claims (5)
- ６０〜１２０℃の範囲の温度において２以上の重合段階で行い、かかる２以上の重合段階の少なくとも２つを分子量調整剤の異なる濃度下で行い、（Ａ）Ｔｉ、Ｍｇ、ハロゲンを含み、少なくとも０．３ｃｍ３／ｇの水銀法によって測定される１μｍ以下の半径を有する細孔による多孔度（ＰＦ）、１００ｍ２／ｇより低いＢＥＴ法によって測定される表面積、及び８〜３５μｍの平均直径を有する固体触媒成分、及び（Ｂ）有機アルミニウム化合物を接触させることによって得られる生成物を含む触媒系の存在下で行う、２５より大きいＡＳＴＭ−１２３８によるメルトフロー比Ｆ／Ｐを有するエチレンポリマーを製造するためのスラリー法。
- 触媒成分（Ａ）の多孔度（ＰＦ）が０．４〜１ｃｍ３／ｇの範囲である、請求項１に記載のスラリー法。
- ２以上の連続撹拌タンク反応器内で行う、請求項１に記載のスラリー法。
- 減少する分子量調整剤の濃度を有する直列に接続されている３つの連続撹拌タンク反応器内で行う、請求項１に記載のスラリー法。
- メルトフロー比Ｆ／Ｐが２８を超える、請求項１に記載のスラリー法。
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09153872 | 2009-02-27 | ||
| EP09153872.8 | 2009-02-27 | ||
| US20953309P | 2009-03-06 | 2009-03-06 | |
| US61/209,533 | 2009-03-06 | ||
| PCT/EP2010/051844 WO2010097305A1 (en) | 2009-02-27 | 2010-02-15 | Multistage process for the polymerization of ethylene |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015121731A Division JP6050436B2 (ja) | 2009-02-27 | 2015-06-17 | エチレンを重合するための多段階方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012519217A JP2012519217A (ja) | 2012-08-23 |
| JP2012519217A5 true JP2012519217A5 (ja) | 2013-07-11 |
| JP5837424B2 JP5837424B2 (ja) | 2015-12-24 |
Family
ID=42046259
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011551457A Active JP5837424B2 (ja) | 2009-02-27 | 2010-02-15 | エチレンを重合するための多段階方法 |
| JP2015121731A Active JP6050436B2 (ja) | 2009-02-27 | 2015-06-17 | エチレンを重合するための多段階方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015121731A Active JP6050436B2 (ja) | 2009-02-27 | 2015-06-17 | エチレンを重合するための多段階方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8557931B2 (ja) |
| EP (1) | EP2401308B1 (ja) |
| JP (2) | JP5837424B2 (ja) |
| KR (1) | KR101711811B1 (ja) |
| CN (1) | CN102333798B (ja) |
| BR (1) | BRPI1008916B1 (ja) |
| RU (1) | RU2522439C2 (ja) |
| WO (1) | WO2010097305A1 (ja) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20130008644A (ko) * | 2006-03-30 | 2013-01-22 | 토탈 리서치 앤드 테크놀로지 펠루이 | 소량의 소거제 존재하의 에틸렌 슬러리 중합 방법 |
| US10138310B2 (en) * | 2010-08-24 | 2018-11-27 | Equistar Chemicals, Lp | Preparation of LLDPE resins and films having low gels |
| DE102012109612A1 (de) | 2011-10-13 | 2013-04-18 | Samsung Electronics Co., Ltd. | Nichtflüchtige Speichervorrichtung, Programmierungsverfahren für nichtflüchtige Speichervorrichtungen und Speichersystem, das eine nichtflüchtiger Speichervorrichtung umfasst |
| WO2014016318A1 (en) | 2012-07-27 | 2014-01-30 | Total Research & Technology Feluy | Process for preparing a polyethylene resin |
| EP2746299A1 (en) | 2012-12-19 | 2014-06-25 | Basell Poliolefine Italia S.r.l. | Multistage process for the polymerization of ethylene |
| FR3004849B1 (fr) * | 2013-04-23 | 2015-04-10 | Legrand France | Commutateur electrique a touche de commande monostable |
| WO2016023973A1 (en) | 2014-08-14 | 2016-02-18 | Basell Polyolefine Gmbh | Multi-reactor slurry polymerization processes with high ethylene purity |
| KR101686178B1 (ko) * | 2014-11-25 | 2016-12-13 | 롯데케미칼 주식회사 | 높은 내환경 응력 균열성 및 우수한 가공성을 갖는 폴리올레핀 수지의 제조 방법 |
| CN105985490A (zh) * | 2015-02-16 | 2016-10-05 | 中国石油天然气股份有限公司 | 耐热聚乙烯共聚物的制备方法及耐热聚乙烯共聚物、管材 |
| BR102016009378B1 (pt) | 2016-04-27 | 2021-04-20 | Braskem S.A. | Catalisador heterogêneo de múltiplos sítios, e, processos de preparação do catalisador heterogêneo de múltiplos sítios e de obtenção de poliolefin |
| EP3732215B8 (en) | 2017-12-26 | 2022-04-27 | Dow Global Technologies LLC | Dual reactor solution process for the production of multimodal ethylene-based polymer |
| JP7394056B2 (ja) | 2017-12-26 | 2023-12-07 | ダウ グローバル テクノロジーズ エルエルシー | マルチモーダルエチレン系ポリマーおよび低密度ポリエチレン（ｌｄｐｅ）を含む組成物 |
| JP7278286B2 (ja) | 2017-12-26 | 2023-05-19 | ダウ グローバル テクノロジーズ エルエルシー | 靭性が改善された多峰性エチレン系ポリマー組成物 |
| EP3732216B1 (en) | 2017-12-26 | 2023-04-19 | Dow Global Technologies LLC | Process for the production of multimodal ethylene-based polymers |
| SG11202005777XA (en) | 2017-12-26 | 2020-07-29 | Dow Global Technologies Llc | Multimodal ethylene-based polymer processing systems and methods |
| CN110016090A (zh) * | 2018-01-08 | 2019-07-16 | 李化毅 | 一种连续制备聚烯烃的方法及其制备得到的聚烯烃 |
| CN115181202B (zh) * | 2021-04-02 | 2023-12-26 | 中国石油天然气股份有限公司 | 乙烯连续聚合方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT969340B (it) * | 1972-09-13 | 1974-03-30 | Montedison Spa | Catalizzatori per la polimerizza zione delle olefine a polimeri in forma sferica |
| US3953414A (en) * | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
| GB1577512A (en) * | 1977-06-18 | 1980-10-22 | Nippon Oil Co Ltd | Olefin polymerization |
| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| CA1162700A (en) * | 1981-01-30 | 1984-02-21 | Kiyoshi Kawai | Process for producing ethylene polymers |
| JPH078890B2 (ja) * | 1985-07-25 | 1995-02-01 | 三井石油化学工業株式会社 | オレフインの連続重合法 |
| JPH06104693B2 (ja) | 1986-01-06 | 1994-12-21 | 東邦チタニウム株式会社 | オレフイン類重合用触媒 |
| FI80055C (fi) | 1986-06-09 | 1990-04-10 | Neste Oy | Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner. |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| JP2879347B2 (ja) | 1989-10-02 | 1999-04-05 | チッソ株式会社 | オレフィン重合用触媒の製法 |
| IT1243188B (it) * | 1990-08-01 | 1994-05-24 | Himont Inc | Composizioni poliolefiniche elastoplastiche |
| IT1256648B (it) * | 1992-12-11 | 1995-12-12 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| BE1007653A3 (fr) | 1993-10-26 | 1995-09-05 | Fina Research | Procede de production de polyethylene ayant une distribution large de poids moleculaire. |
| BR9804806A (pt) | 1997-03-29 | 1999-08-17 | Montell Technology Company Bv | Adutos de alcool-dicloreto de magnesio processo para sua prepara-Æo e componentes de catalisadores obtidos a partir deles |
| US7696287B2 (en) * | 2004-02-13 | 2010-04-13 | Total Petrochemicals Research Feluy | Catalyst grain size |
| JP2010513625A (ja) * | 2006-12-20 | 2010-04-30 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用の触媒成分及びそれから得られる触媒 |
| KR20090101192A (ko) * | 2006-12-22 | 2009-09-24 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 및 그로부터 수득된 촉매 |
-
2010
- 2010-02-15 JP JP2011551457A patent/JP5837424B2/ja active Active
- 2010-02-15 RU RU2011139324/04A patent/RU2522439C2/ru not_active IP Right Cessation
- 2010-02-15 EP EP10704142.8A patent/EP2401308B1/en active Active
- 2010-02-15 KR KR1020117019990A patent/KR101711811B1/ko active IP Right Grant
- 2010-02-15 CN CN201080009693.0A patent/CN102333798B/zh active Active
- 2010-02-15 WO PCT/EP2010/051844 patent/WO2010097305A1/en active Application Filing
- 2010-02-15 US US13/201,202 patent/US8557931B2/en active Active
- 2010-02-15 BR BRPI1008916-0A patent/BRPI1008916B1/pt active IP Right Grant
-
2015
- 2015-06-17 JP JP2015121731A patent/JP6050436B2/ja active Active
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