JP2012510562A - 分岐および星型分岐スチレンの重合体、短鎖重合体、ならびに付加物、それらの合成、それらの臭素化、およびそれらの使用 - Google Patents

分岐および星型分岐スチレンの重合体、短鎖重合体、ならびに付加物、それらの合成、それらの臭素化、およびそれらの使用 Download PDF

Info

Publication number
JP2012510562A
JP2012510562A JP2011539617A JP2011539617A JP2012510562A JP 2012510562 A JP2012510562 A JP 2012510562A JP 2011539617 A JP2011539617 A JP 2011539617A JP 2011539617 A JP2011539617 A JP 2011539617A JP 2012510562 A JP2012510562 A JP 2012510562A
Authority
JP
Japan
Prior art keywords
range
styrene
integer
brominated
independently
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
JP2011539617A
Other languages
English (en)
Japanese (ja)
Other versions
JP2012510562A5 (de
Inventor
レイマン，ウイリアム・ジエイ，ジユニア
コリシユ，チヤールズ・エイチ
マツク，アーサー・ジー
マツカーニイ，ジヨナサン・ピー
クマー，ゴビンダラジユル
ワン，ジユンツオ
モリス，ジヨージ
ゼー，ツオンシン
リウ，ボー
ジヨシ，ラビンドラ・アール
チユー，フーバー・ビー
ルーサー，ダグラス・ダブリユー
ホワイト，キンバリー・エム
Original Assignee
アルベマール・コーポレーシヨン
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by アルベマール・コーポレーシヨン filed Critical アルベマール・コーポレーシヨン
Publication of JP2012510562A publication Critical patent/JP2012510562A/ja
Publication of JP2012510562A5 publication Critical patent/JP2012510562A5/ja
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/005—Modified block copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C08F8/22—Halogenation by reaction with free halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/02—Halogenated hydrocarbons
    • C08K5/03—Halogenated hydrocarbons aromatic, e.g. C6H5-CH2-Cl
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/18—Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fireproofing Substances (AREA)
JP2011539617A 2008-12-02 2009-11-30 分岐および星型分岐スチレンの重合体、短鎖重合体、ならびに付加物、それらの合成、それらの臭素化、およびそれらの使用 Ceased JP2012510562A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11928508P 2008-12-02 2008-12-02
US61/119,285 2008-12-02
PCT/US2009/066132 WO2010065467A1 (en) 2008-12-02 2009-11-30 Branched and star-branched styrene polymers, telomers, and adducts, their synthesis, their bromination, and their uses

Publications (2)

Publication Number Publication Date
JP2012510562A true JP2012510562A (ja) 2012-05-10
JP2012510562A5 JP2012510562A5 (de) 2012-12-06

Family

ID=41790755

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2011539617A Ceased JP2012510562A (ja) 2008-12-02 2009-11-30 分岐および星型分岐スチレンの重合体、短鎖重合体、ならびに付加物、それらの合成、それらの臭素化、およびそれらの使用

Country Status (10)

Country Link
US (1) US8476373B2 (de)
EP (2) EP2479210A1 (de)
JP (1) JP2012510562A (de)
KR (1) KR20110100216A (de)
CN (1) CN102272176A (de)
CA (1) CA2744201A1 (de)
IL (1) IL213339A0 (de)
MX (1) MX2011005658A (de)
TW (1) TW201030020A (de)
WO (1) WO2010065467A1 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2694728T3 (es) 2007-06-07 2018-12-26 Albemarle Corporation Polímeros bromados de bajo peso molecular y su uso en formulaciones termoplásticas
US8993684B2 (en) 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
MX2011005659A (es) 2008-12-02 2011-06-16 Albemarle Corp Distribuciones de telomero derivadas de tolueno y estireno y retardantes de llama bromados producidos a partir de las mismas.
JP2012510539A (ja) 2008-12-02 2012-05-10 アルベマール・コーポレーシヨン トルエンおよびスチレンに由来するテロマー混合物の臭素化
JO3423B1 (ar) 2008-12-02 2019-10-20 Albemarle Corp مؤخرات لهب معالجة بالبروم و مواد مشتقه منها
US8476373B2 (en) 2008-12-02 2013-07-02 Albemarle Corporation Branched and star-branched styrene polymers, telomers, and adducts, their synthesis, their bromination, and their uses
JO3059B1 (ar) 2009-05-01 2017-03-15 Albemarle Corp معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض
TW201043651A (en) 2009-05-01 2010-12-16 Albemarle Corp Pelletized low molecular weight brominated aromatic polymer compositions
WO2011156091A1 (en) * 2010-06-09 2011-12-15 Albemarle Corporation Translucent or transparent flame retarded thermoplastic polymer compositions and brominated telomeric flame retardants
CN103998498A (zh) 2011-12-19 2014-08-20 陶氏环球技术有限责任公司 含溴化聚合阻燃剂的热固性聚氨酯泡沫
CN116134076A (zh) 2020-08-07 2023-05-16 雅宝公司 阻燃聚烯烃添加剂
CN112574333B (zh) * 2020-12-07 2022-04-29 山东京博中聚新材料有限公司 一种星形支化丁基橡胶的溴化工艺
CN117106109B (zh) * 2023-10-25 2024-06-04 山东海化集团有限公司 一种连续化制备溴化聚苯乙烯的方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1342101A (en) * 1970-01-15 1973-12-25 Lithium Corp Telomers
JPS4944115B1 (de) * 1968-11-26 1974-11-26
JPH02189307A (ja) * 1989-01-19 1990-07-25 Sanyo Chem Ind Ltd 平坦化材料
JPH0388803A (ja) * 1989-08-16 1991-04-15 Shell Internatl Res Maatschappij Bv 共役ジエン及びビニル芳香族化合物のコポリマーの製造方法
JPH05500827A (ja) * 1989-07-10 1993-02-18 エルフ　アトケム　ソシエテ　アノニム 星形共重合体とその製造方法
WO2007005233A1 (en) * 2005-06-30 2007-01-11 Albemarle Corporation Brominated styrenic polymers and their preparation

Family Cites Families (126)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2243543A (en) * 1938-10-14 1941-05-27 Us Rubber Co Parasiticide
US2757146A (en) * 1952-09-08 1956-07-31 Du Pont Pyrolysis polymers from p-methyl quaternary benzylammonium hydroxides
US2914489A (en) * 1956-01-10 1959-11-24 Du Pont Production of poly p-xylene polymers containing halogen
US2954412A (en) * 1957-01-10 1960-09-27 Huels Chemische Werke Ag Process for the preparation of dibenzylbenzenes
US3221068A (en) * 1962-03-01 1965-11-30 Union Carbide Corp Halogenated di-p-xylylenes
US3751384A (en) * 1963-03-13 1973-08-07 Exxon Organolithium-polyamine compositions
US3594396A (en) * 1963-03-13 1971-07-20 Arthur W Langer Jr Crystalline organolithium complexes containing silicon
US3541149A (en) * 1963-03-13 1970-11-17 Exxon Research Engineering Co Crystalline organolithium-tertiary chelating polyamine complexes
US3458586A (en) * 1964-04-13 1969-07-29 Exxon Research Engineering Co Linear alkyl aromatic compounds and their preparation
US3373135A (en) * 1964-12-01 1968-03-12 Kalk Chemische Fabrik Gmbh Shaped articles of self-extinguishing epoxy resins
NL126613C (de) 1966-03-25
US3372880A (en) * 1966-04-14 1968-03-12 Rexall Drug Chemical Process for the production of polymer powder
US3451988A (en) * 1966-10-25 1969-06-24 Exxon Research Engineering Co Polymerization catalyst and uses thereof
GB1174845A (en) 1967-08-25 1969-12-17 Shell Int Research The Polymerisation of Vinyl-Aromatic Compounds, and the Resulting Polyvinyl-Aromatic Compounds
DE1794072C3 (de) 1968-09-03 1975-09-25 Basf Ag, 6700 Ludwigshafen Schwerbrennbare Formmassen auf der Basis von Polymerisaten des Propylene
GB1051269A (de) * 1969-05-16
US3634548A (en) * 1969-08-11 1972-01-11 Gulf Research Development Co Polystyrene-ethylene graft copolymer
US3751501A (en) * 1970-01-15 1973-08-07 Lithium Corp Telomerization reactions utilizing liquid hydrocarbon solutions of certain organometallic complexes
US3725368A (en) * 1970-01-19 1973-04-03 Lithium Corp Preparation of polymers
US3668263A (en) * 1970-01-19 1972-06-06 Lithium Corp Organolithium polymerization initiators and use thereof in polymerization processes
US3742077A (en) * 1970-07-23 1973-06-26 Lithium Corp Method of preparing telomers utilizing as catalysts hydrocarbon-soluble organometallic complexes of metals of groups i and iia of the periodic table
US3850882A (en) * 1971-12-01 1974-11-26 Phillips Petroleum Co Flame retarded compositions and additive systems therefor
US4078019A (en) * 1972-11-24 1978-03-07 Exxon Research & Engineering Co. Process for polymer lithiation in graft polymerization
IT1025744B (it) * 1973-11-26 1978-08-30 Basf Ag Masse per formatura termopla stiche autoestinglenti
US4129705A (en) * 1975-02-02 1978-12-12 Compagnie Generale Des Etablissements Michelin Polymerization process
US4108921A (en) * 1975-03-28 1978-08-22 Exxon Research & Engineering Co. Process for polymer lithiation in graft polymerization
DE2515473C3 (de) * 1975-04-09 1987-01-22 Basf Ag, 6700 Ludwigshafen Flammwidrige, lineare Polyester
CA1054161A (en) * 1975-08-22 1979-05-08 Herbert Naarmann Manufacture of heat-stable brominated oligomers of monovinyl-aromatic compounds
DE2547498A1 (de) * 1975-10-23 1977-04-28 Huels Chemische Werke Ag Flammwidrige formmasse
US4311818A (en) * 1976-06-17 1982-01-19 Societe Chimique Des Charbonnages-Cdf. Chimie Bi- and Trifunctional organolithium initiators and applications thereof
US4134938A (en) * 1976-08-12 1979-01-16 Exxon Research & Engineering Co. Process for polymer lithiation in graft polymerization
DE2645711C3 (de) * 1976-10-09 1979-06-07 Basf Ag, 6700 Ludwigshafen Halogenhaltige Flammschutzmittel enthaltende Fasern und Fäden aus linearen, thermoplastischen Polyestern
US4041088A (en) * 1976-11-08 1977-08-09 Lithium Corporation Of America Recirculation telomerization process and its liquid telomers and liquid telomers produced thereby
DE2651435C3 (de) 1976-11-11 1980-11-27 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols
DE2703419B1 (de) * 1977-01-28 1978-02-02 Basf Ag Flammwidrig ausgeruestete polyamid- formmassen
DE2727483A1 (de) 1977-06-18 1979-01-11 Basf Ag Selbstverloeschende thermoplastische formmassen
DE2756375A1 (de) 1977-12-17 1979-07-05 Basf Ag Flammschutzmittelkonzentrat fuer thermoplaste
DE3006448A1 (de) * 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von mischungen aus bromierten polystyrolen und bromierten aromatischen verbindungen
US4268705A (en) * 1980-03-21 1981-05-19 Phillips Petroleum Company Addition of monomer in production of liquid polymers
JPS5919577B2 (ja) * 1980-08-25 1984-05-07 日本エラストマ−株式会社 耐衝撃性ポリスチレンの製造方法
FR2498193B1 (fr) * 1981-01-19 1986-03-21 Poudres & Explosifs Ste Nale Nouvelles associations de bases resultant de la combinaison d'un alkyl ou aryl lithien avec un amidure ou un hydrure alcalin, procede de polymerisation les utilisant et produit obtenu
IT1195303B (it) * 1981-12-22 1988-10-12 Anic Spa Iniziatori anionici multifunzionali e loro impiego
US4463135A (en) * 1982-10-25 1984-07-31 The Goodyear Tire & Rubber Company Process for the functionalization of polystyrene resins
IL72857A (en) 1984-09-05 1989-12-15 Yeda Res & Dev Halogen-containing telomers
IT1186743B (it) * 1985-07-01 1987-12-16 Eniricerche Spa Metodo per la terminazione di polimeri ottenuti per polimerizzazione anionica di monomeri dienici e/o vinilaromatici e composti adatti allo scopo
IT1206738B (it) * 1985-07-01 1989-05-03 Eniricerche Spa Metodo per la terminazione di polimeri viventi ottenuti per polimerizzazione anionica di monomeri dienici e/o vinilaromatici e composti adatti allo scopo.
US4636540A (en) * 1985-07-08 1987-01-13 Atlantic Richfield Company Purification of polymer solutions
US4755573A (en) * 1985-11-15 1988-07-05 General Electric Company Cationic polymerization of bromoalkenyl aromatic compounds with aromatic chain transfer agent, and products
US4753745A (en) * 1985-12-30 1988-06-28 The Lubrizol Corporation Methylene linked aromatic pour point depressant
IT1213077B (it) * 1986-06-05 1989-12-07 Eniricerche Spa Composti stabilizzanti polimerici e procedimento per la loro preparazione.
CA1297628C (en) 1987-01-28 1992-03-17 David C. Sanders Aromatic bromination of polystyrene using bromine as the reaction solvent
US4883846A (en) * 1987-04-20 1989-11-28 The Dow Chemical Company Anionic polymerization of purified monovinylidene aromatic monomer feed stock
US4829135A (en) * 1987-12-29 1989-05-09 Mobil Oil Corporation Multi-stage anionic dispersion homopolymerization to form microparticles with narrow size distribution
FR2629085B1 (fr) 1988-03-24 1992-09-04 Atochem Procede de fabrication de polybutadiene et preparation de resine vinylaromatique choc a partir de polybutadiene
US5112897A (en) * 1989-06-06 1992-05-12 Ferro Corporation High impact polystyrene containing low molecular weight brominated polystyrene
US5112898A (en) * 1989-06-06 1992-05-12 Ferro Corporation High impact polystyrene containing low molecular weight brominated polystyrene
AU5833890A (en) 1989-06-06 1991-01-07 Ferro Corporation High impact polystyrene containing low molecular weight brominated polystyrene
US4975496A (en) * 1989-08-10 1990-12-04 The Dow Chemical Company Process for brominating aromatic resins
US4950721A (en) * 1989-10-03 1990-08-21 Exxon Chemical Patents Inc. Ion-exchange reactions for polymeric alkali metal carboxylates
CA2047256C (en) * 1990-07-30 2002-03-05 Saadat Hussain Process for decabromodiphenylalkane predominant product
KR940003782B1 (ko) * 1991-09-03 1994-05-03 주식회사 럭키 스티렌계 난연수지의 제조방법
US5196622A (en) * 1991-11-22 1993-03-23 Phillips Petroleum Company Alkene addition process
US5198594A (en) * 1991-11-27 1993-03-30 Amoco Corporation Alkylation of alkylaromatics promoted by sonicated alkali metal
EP0554675A1 (de) * 1992-01-31 1993-08-11 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polymeren des para-Xylylens und von diesem abgeleiteten Derivaten
US6025450A (en) * 1992-10-02 2000-02-15 Bridgestone Corporation Amine containing polymers and products therefrom
US5625017A (en) * 1992-10-19 1997-04-29 Bridgestone Corporation Process for preparing a polymer using lithium initiator prepared by in situ preparation
IL109251A (en) * 1993-04-07 1999-05-09 Great Lakes Chemical Corp Bromine-converted diphenylalcane products, processes for their preparation and anti-flame formulation containing them
US5687090A (en) * 1994-09-01 1997-11-11 Aspen Technology, Inc. Polymer component characterization method and process simulation apparatus
WO1996011227A1 (en) * 1994-10-05 1996-04-18 Great Lakes Chemical Corporation Continuous bromination process and products thereof
JPH08188622A (ja) * 1995-01-13 1996-07-23 Tosoh Corp 臭素化ポリスチレン低分子量体の製造方法
DE19516593C2 (de) 1995-05-05 2001-07-05 Koenig & Bauer Ag Non-Stop-Einrichtung
DE19516563A1 (de) 1995-05-05 1996-11-07 Basf Ag Verfahren zur Herstellung von Styrol-Oligomeren und deren Verwendung als Schmiermittel in Thermoplasten
US5534592A (en) * 1995-09-22 1996-07-09 The Goodyear Tire & Rubber Company High performance blend for tire treads
CA2190302A1 (en) 1995-11-22 1997-05-23 Gregory George Smith Process for preparing vulcanizable elastomeric compounds from granular elastomer blends and elastomeric articles manufactured therefrom
DE19618678A1 (de) * 1996-05-09 1997-11-13 Basf Ag Verfahren zur Herstellung von Polystyrol durch kontinuierliche anionische Polymerisation
US5637650A (en) * 1996-06-14 1997-06-10 Ferro Corporation Brominated polysytrene having improved thermal stability and color and process for the preparation thereof
US6518368B2 (en) * 1996-06-14 2003-02-11 Albemarle Corporation Brominated polystyrene having improved thermal stability and color and process for the preparation thereof
US5723549A (en) 1996-06-14 1998-03-03 Ferro Corporation Process for the preparation of brominated polystyrene having improved color characteristics
US6326439B1 (en) * 1996-09-26 2001-12-04 Albemarle Corporation Process for brominating polystyrenic resins
US6521714B2 (en) * 1996-09-26 2003-02-18 Albemarle Corporation Brominated polystyrenic resins
US5767203A (en) * 1996-09-26 1998-06-16 Albemarle Corporation Process for brominated styrenic polymers
US5677390A (en) * 1996-09-26 1997-10-14 Albemarle Corporation Process for brominating polystyrenic resins
US5686538A (en) * 1996-09-26 1997-11-11 Albemarle Corporation Process for brominating polystyrenic resins
US6133381A (en) 1996-09-26 2000-10-17 Albelmarle Corporation Brominated polystyrenic flame retardants
US6235844B1 (en) * 1996-09-26 2001-05-22 Albemarle Corporation Brominated polystyrenic resins
US6232408B1 (en) * 1996-09-26 2001-05-15 Albemarle Corporation Brominated polstyrenic resins
US6235831B1 (en) * 1996-09-26 2001-05-22 Albemarle Corporation Polymer compositions containing brominated polystyrenic resins
CA2265642C (en) * 1996-09-26 2006-03-14 Albemarle Corporation Process for brominated styrenic polymers
US6232393B1 (en) * 1996-09-26 2001-05-15 Albemarle Corporation Polymers flame retarded with brominated polystyrenic resins
US5728782A (en) * 1996-12-06 1998-03-17 Union Carbide Chemicals & Plastics Technology Corporation Gas phase anionic polymerization of dienes and vinyl-substituted aromatic compounds
AU5813498A (en) * 1997-01-08 1998-08-03 Hercules Incorporated Fluorinated solid acids as catalysts for the preparation of hydrocarbon resins
US6008283A (en) * 1997-03-20 1999-12-28 Great Lakes Chemical Corporation Oligomeric flame retardant additive
DE19754504A1 (de) * 1997-12-09 1999-06-10 Basf Ag Verfahren zur Herstellung von Erdalkalidiorganylverbindungen
WO1999051650A1 (en) * 1998-04-07 1999-10-14 The Dow Chemical Company Improved syndiotactic vinylidene aromatic polymerization process
US6093211A (en) * 1998-04-09 2000-07-25 Aspen Technology, Inc. Polymer property distribution functions methodology and simulators
KR20000019517A (ko) 1998-09-12 2000-04-15 이정국 스티렌 다이머 및 스티렌 트리머의 용출이 되지 않는 식품포장재용 고순도 폴리스티렌 및 그의 제조방법
US6821456B2 (en) 1998-09-22 2004-11-23 Albemarle Corporation Granular polymer additives and their preparation
US6355194B1 (en) * 1999-03-22 2002-03-12 Xerox Corporation Carrier pelletizing processes
US6313230B1 (en) * 1999-09-21 2001-11-06 Industrial Technology Research Institute Catalyst composition for hydrogenation of conjugated diene based synthetic rubbers
US6759498B2 (en) * 2000-05-08 2004-07-06 Asahi Kadei Kabushiki Kaisha Process for producing styrene resin reduced in content of low-molecular ingredient
JP2001341246A (ja) 2000-06-05 2001-12-11 Asahi Kasei Corp スチレン系樹脂積層シート
EP1288260A1 (de) 2001-08-29 2003-03-05 Albemarle Corporation Flammengeschützte Zusammensetzungen
DE10218161A1 (de) 2002-04-23 2003-11-13 Basf Ag Initiatorzusammensetzung und Verfahren zur anionischen Polymerisation
CN1290871C (zh) * 2002-05-10 2006-12-20 Ps日本株式会社 苯乙烯－基聚合物树脂及其组合物
US6657028B1 (en) * 2002-08-01 2003-12-02 Albemarle Corporation Anionic polymerization process
KR100471716B1 (ko) * 2002-08-03 2005-03-10 금호석유화학 주식회사 연속식 음이온 중합에 의한 내충격 비닐 방향족 고분자의제조방법
EP1644420A2 (de) * 2003-06-20 2006-04-12 Scimed Life Systems, Inc. Endgruppenverschlossene polymerketten und produkte davon
US7202296B2 (en) * 2003-12-19 2007-04-10 Albemarle Corporation Flame retardant compositions and their use
US20050209408A1 (en) * 2004-03-17 2005-09-22 Lee Hyung-Jae Star-shaped polymer, multiple star polymer and their preparation methods
MXPA06013323A (es) * 2004-05-20 2007-02-02 Albemarle Corp Polimeros estirenicos anionicos bromados, en forma de pellas y su preparacion y uso.
EP1805232B1 (de) * 2004-09-30 2009-12-30 Chemtura Corporation Verbesserte bromstyrol-polymere mit kontrolliertem molekülgewicht
US7351777B2 (en) 2005-03-30 2008-04-01 Moore Eugene R Retarded anionic polymerization of vinyl aromatic monomers using insoluble or heterogeneous retardants
CN100369941C (zh) 2005-05-17 2008-02-20 北京化工大学 一种氢化苯乙烯类热塑性弹性体及其制备方法
KR100827335B1 (ko) * 2005-10-06 2008-05-06 주식회사 엘지화학 그라프트 공중합체 및 이의 제조방법
BRPI0620898A2 (pt) * 2005-12-21 2011-11-29 Albemarle Corp preparo de resinas ou polìmeros estirênicos bromados
HUE025498T2 (hu) 2006-07-20 2016-04-28 Albemarle Corp Eljárási technológia brómozott sztirolpolimerek visszanyerésére reakcióelegyekbõl, amelyekben képzõdtek és/vagy ezen elegyek átalakítása pelletekké vagy granulátumokká vagy pasztillákká
EP2094458A1 (de) 2006-11-28 2009-09-02 Albemarle Corporation Umwandlung eines bromierten anionischen styrolpolymers in eine härtere und grössere form zur lagerung, zum versand und zur verwendung
ES2694728T3 (es) 2007-06-07 2018-12-26 Albemarle Corporation Polímeros bromados de bajo peso molecular y su uso en formulaciones termoplásticas
JP5498486B2 (ja) 2008-06-06 2014-05-21 アルベマール・コーポレーシヨン 低分子量臭素化ポリマー、それらの製作プロセス、および熱可塑性配合物におけるそれらの使用
MX2011005659A (es) 2008-12-02 2011-06-16 Albemarle Corp Distribuciones de telomero derivadas de tolueno y estireno y retardantes de llama bromados producidos a partir de las mismas.
US8476373B2 (en) 2008-12-02 2013-07-02 Albemarle Corporation Branched and star-branched styrene polymers, telomers, and adducts, their synthesis, their bromination, and their uses
JP2012510539A (ja) 2008-12-02 2012-05-10 アルベマール・コーポレーシヨン トルエンおよびスチレンに由来するテロマー混合物の臭素化
JO3423B1 (ar) 2008-12-02 2019-10-20 Albemarle Corp مؤخرات لهب معالجة بالبروم و مواد مشتقه منها
SG175155A1 (en) 2009-05-01 2011-11-28 Albemarle Corp Pelletized low molecular weight brominated aromatic polymer compositions
JO3059B1 (ar) 2009-05-01 2017-03-15 Albemarle Corp معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض
TW201043651A (en) 2009-05-01 2010-12-16 Albemarle Corp Pelletized low molecular weight brominated aromatic polymer compositions

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4944115B1 (de) * 1968-11-26 1974-11-26
GB1342101A (en) * 1970-01-15 1973-12-25 Lithium Corp Telomers
JPH02189307A (ja) * 1989-01-19 1990-07-25 Sanyo Chem Ind Ltd 平坦化材料
JPH05500827A (ja) * 1989-07-10 1993-02-18 エルフ　アトケム　ソシエテ　アノニム 星形共重合体とその製造方法
JPH0388803A (ja) * 1989-08-16 1991-04-15 Shell Internatl Res Maatschappij Bv 共役ジエン及びビニル芳香族化合物のコポリマーの製造方法
WO2007005233A1 (en) * 2005-06-30 2007-01-11 Albemarle Corporation Brominated styrenic polymers and their preparation
JP2009500470A (ja) * 2005-06-30 2009-01-08 アルベマール・コーポレーシヨン 臭素化スチレン系ポリマーおよびこれらの製造

Also Published As

Publication number Publication date
MX2011005658A (es) 2014-01-17
CA2744201A1 (en) 2010-06-10
EP2361269A1 (de) 2011-08-31
IL213339A0 (en) 2011-07-31
EP2479210A1 (de) 2012-07-25
WO2010065467A8 (en) 2011-08-04
WO2010065467A1 (en) 2010-06-10
KR20110100216A (ko) 2011-09-09
TW201030020A (en) 2010-08-16
CN102272176A (zh) 2011-12-07
US8476373B2 (en) 2013-07-02
US20110224320A1 (en) 2011-09-15

Similar Documents

Publication Publication Date Title
JP2012510562A (ja) 分岐および星型分岐スチレンの重合体、短鎖重合体、ならびに付加物、それらの合成、それらの臭素化、およびそれらの使用
JP6231731B2 (ja) 臭素化難燃剤およびその前駆体
KR101593236B1 (ko) 저분자량의 브롬화 중합체 및 열가소성 배합물에서 이들의 용도
EP2288628B1 (de) Niedermolekulare bromierte polymere, verfahren zu ihrer herstellung und ihre verwendung in thermoplastischen formulierungen
CN102224122B (zh) 甲苯和苯乙烯衍生的调聚物分布物及由其制备的溴化阻燃剂
US8642821B2 (en) Bromination of telomer mixtures derived from toluene and styrene
US9914830B2 (en) Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20121022

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20121022

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20140221

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20140319

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20140619

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20141217

A045 Written measure of dismissal of application [lapsed due to lack of payment]

Free format text: JAPANESE INTERMEDIATE CODE: A045

Effective date: 20150422