JP2012505941A - テレフタル酸に基づくポリエステルポリオール - Google Patents
テレフタル酸に基づくポリエステルポリオール Download PDFInfo
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- JP2012505941A JP2012505941A JP2011531473A JP2011531473A JP2012505941A JP 2012505941 A JP2012505941 A JP 2012505941A JP 2011531473 A JP2011531473 A JP 2011531473A JP 2011531473 A JP2011531473 A JP 2011531473A JP 2012505941 A JP2012505941 A JP 2012505941A
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- Prior art keywords
- acid
- oil
- mol
- polyol
- polyester polyol
- Prior art date
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 229920005906 polyester polyol Polymers 0.000 title claims abstract description 28
- -1 aliphatic diols Chemical class 0.000 claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 47
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229920005862 polyol Polymers 0.000 claims abstract description 37
- 150000003077 polyols Chemical class 0.000 claims abstract description 32
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 19
- 239000000194 fatty acid Substances 0.000 claims abstract description 19
- 229930195729 fatty acid Natural products 0.000 claims abstract description 19
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 12
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000032050 esterification Effects 0.000 claims abstract description 11
- 238000005886 esterification reaction Methods 0.000 claims abstract description 11
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001991 dicarboxylic acids Chemical class 0.000 claims abstract description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 7
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 6
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims abstract description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005711 Benzoic acid Substances 0.000 claims abstract description 3
- 229920001283 Polyalkylene terephthalate Polymers 0.000 claims abstract description 3
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 claims abstract description 3
- 235000010233 benzoic acid Nutrition 0.000 claims abstract description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 45
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 27
- 239000011496 polyurethane foam Substances 0.000 claims description 27
- 239000003054 catalyst Substances 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 20
- 239000003063 flame retardant Substances 0.000 claims description 19
- 239000012948 isocyanate Substances 0.000 claims description 17
- 150000002513 isocyanates Chemical class 0.000 claims description 17
- 239000003921 oil Substances 0.000 claims description 17
- 235000019198 oils Nutrition 0.000 claims description 17
- 229920001228 polyisocyanate Polymers 0.000 claims description 17
- 239000005056 polyisocyanate Substances 0.000 claims description 17
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 16
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 15
- 229920000570 polyether Polymers 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 10
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 10
- 125000005442 diisocyanate group Chemical group 0.000 claims description 9
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 8
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 8
- 239000004970 Chain extender Substances 0.000 claims description 8
- 239000004971 Cross linker Substances 0.000 claims description 8
- 239000005642 Oleic acid Substances 0.000 claims description 8
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 8
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 8
- 235000021313 oleic acid Nutrition 0.000 claims description 8
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 7
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 claims description 5
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 claims description 4
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 4
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- 239000004088 foaming agent Substances 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 claims description 4
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 4
- 229960003656 ricinoleic acid Drugs 0.000 claims description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 3
- 235000019483 Peanut oil Nutrition 0.000 claims description 3
- 239000000312 peanut oil Substances 0.000 claims description 3
- GWHCXVQVJPWHRF-KTKRTIGZSA-N (15Z)-tetracosenoic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCCCC(O)=O GWHCXVQVJPWHRF-KTKRTIGZSA-N 0.000 claims description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 claims description 2
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 claims description 2
- YWWVWXASSLXJHU-UHFFFAOYSA-N 9E-tetradecenoic acid Natural products CCCCC=CCCCCCCCC(O)=O YWWVWXASSLXJHU-UHFFFAOYSA-N 0.000 claims description 2
- 235000019489 Almond oil Nutrition 0.000 claims description 2
- 235000000832 Ayote Nutrition 0.000 claims description 2
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 claims description 2
- 240000004244 Cucurbita moschata Species 0.000 claims description 2
- 235000009854 Cucurbita moschata Nutrition 0.000 claims description 2
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 claims description 2
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 claims description 2
- OPGOLNDOMSBSCW-CLNHMMGSSA-N Fursultiamine hydrochloride Chemical compound Cl.C1CCOC1CSSC(\CCO)=C(/C)N(C=O)CC1=CN=C(C)N=C1N OPGOLNDOMSBSCW-CLNHMMGSSA-N 0.000 claims description 2
- 235000019487 Hazelnut oil Nutrition 0.000 claims description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 2
- 235000018330 Macadamia integrifolia Nutrition 0.000 claims description 2
- 240000000912 Macadamia tetraphylla Species 0.000 claims description 2
- 235000003800 Macadamia tetraphylla Nutrition 0.000 claims description 2
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 claims description 2
- XJXROGWVRIJYMO-SJDLZYGOSA-N Nervonic acid Natural products O=C(O)[C@@H](/C=C/CCCCCCCC)CCCCCCCCCCCC XJXROGWVRIJYMO-SJDLZYGOSA-N 0.000 claims description 2
- 244000090896 Nigella sativa Species 0.000 claims description 2
- 235000016698 Nigella sativa Nutrition 0.000 claims description 2
- 235000021319 Palmitoleic acid Nutrition 0.000 claims description 2
- 235000019497 Pistachio oil Nutrition 0.000 claims description 2
- 244000028344 Primula vulgaris Species 0.000 claims description 2
- 235000016311 Primula vulgaris Nutrition 0.000 claims description 2
- 235000009827 Prunus armeniaca Nutrition 0.000 claims description 2
- 244000018633 Prunus armeniaca Species 0.000 claims description 2
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- 235000005066 Rosa arkansana Nutrition 0.000 claims description 2
- 241000109365 Rosa arkansana Species 0.000 claims description 2
- 235000019486 Sunflower oil Nutrition 0.000 claims description 2
- HXWJFEZDFPRLBG-UHFFFAOYSA-N Timnodonic acid Natural products CCCC=CC=CCC=CCC=CCC=CCCCC(O)=O HXWJFEZDFPRLBG-UHFFFAOYSA-N 0.000 claims description 2
- UWHZIFQPPBDJPM-FPLPWBNLSA-M Vaccenic acid Natural products CCCCCC\C=C/CCCCCCCCCC([O-])=O UWHZIFQPPBDJPM-FPLPWBNLSA-M 0.000 claims description 2
- 235000021322 Vaccenic acid Nutrition 0.000 claims description 2
- 235000019498 Walnut oil Nutrition 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims description 2
- JAZBEHYOTPTENJ-JLNKQSITSA-N all-cis-5,8,11,14,17-icosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O JAZBEHYOTPTENJ-JLNKQSITSA-N 0.000 claims description 2
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- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 claims description 2
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- VZCCETWTMQHEPK-QNEBEIHSSA-N gamma-linolenic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/CCCCC(O)=O VZCCETWTMQHEPK-QNEBEIHSSA-N 0.000 claims description 2
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Abstract
a1)テレフタル酸に対して、50〜100モル%の、テレフタル酸、ジメチルテレフタレート、ポリアルキレンテレフタレート、及びこれらの混合物から選ばれる材料、
a2)0〜50モル%の、フタル酸、無水フタル酸、又はイソフタル酸、
a3)0〜50モル%の、1種以上のジカルボン酸、
を含む、10〜70モル%のジカルボン酸、
b)2〜30モル%の、1種以上の脂肪酸、及び/又は脂肪酸誘導体、及び/又は安息香酸、
c)10〜70モル%の、2〜18個の炭素原子を有する、1種以上の脂肪族ジオール、又は脂環式ジオール、又はこれらのアルコキシレート、
d)グリセロール、アルコキシル化されたグレセロール、トリメチロールプロパン、アルコキシル化されたトリメチロールプロパン、ペンタエリチリトール、及びアルコキシル化されたペンタエリチリトールから選ばれる、2〜50モル%の高−官能性ポリオール、
のエステル化生成物を含むポリエステルポリオールであって、
ポリエステルポリオール1kg当たり、少なくとも200ミリモル、好ましくは少なくとも500ミリモル、及び特に好ましくは少なくとも800ミリモルの、OH官能価が≧2.9のポリオールd)が反応するものであるポリエステルポリオール。
【選択図】なし
Description
a)以下の、
a1)テレフタル酸に対して、50〜100モル%の、テレフタル酸、ジメチルテレフタレート、ポリアルキレンテレフタレート、及びこれらの混合物から選ばれる材料、
a2)0〜50モル%の、フタル酸、無水フタル酸、又はイソフタル酸、
a3)0〜50モル%の、1種以上のジカルボン酸、
を含む、10〜70モル%、好ましくは20〜70モル%、及び特に好ましくは25〜50モル%のジカルボン酸組成物、
b)2〜30モル%、好ましくは3〜20モル%、特に好ましくは4〜15モル%の、脂肪酸、及び/又は1種以上の脂肪酸誘導体、及び/又は安息香酸、
c)10〜70モル%、好ましくは20〜60モル%、特に好ましくは25〜55モル%の、2〜18個の炭素原子を有する、1種以上の脂肪族ジオール、又は脂環式ジオール、又はこれらのアルコキシレート、
d)グリセロール、アルコキシル化されたグレセロール、トリメチロールプロパン、アルコキシル化されたトリメチロールプロパン、ペンタエリチリトール、及びアルコキシル化されたペンタエリチリトールから選ばれる、2〜50モル%、好ましくは2〜40のモル%、特に好ましくは2〜35モル%の高−官能性ポリオール、
のエステル化生成物を含むポリエステルポリオールであって、
ポリエステルポリオール1kg当たり、少なくとも200ミリモル、好ましくは少なくとも500ミリモル、及び特に好ましくは少なくとも800ミリモルの、OH官能価が≧2.9のポリオールd)が反応するものであるポリエステルポリオールによって達成される。
A)有機、及び/又は変性有機ジイソシアネート、及び/又はポリイソシアネートと、
B)成分B)が50質量%以下の更なるポオリエステルポリオールを含むことができる、本発明に記載された特定のポリエステルポリオール、
C)適切であれば、イソシアネートに対して反応性の基を少なくとも2個有する、ポリエーテルオール及び/又は更なる化合物、及び適切であれば、鎖延長剤、及び/又は架橋剤、
D)発泡剤、
E)触媒、及び適切であれば、
F)更なる補助剤、及び/又は添加剤、
G)難燃剤、
を反応させることにより、硬質ポリウレタンフォームを製造する方法をも提供する。
である。
種々のポリエステルオールが製造された:
一般的な方法
ジカルボン酸、脂肪族又は脂環式ジオール、又はこれらのアルコキシレート、及び高官能性ポリオールが、(機械的攪拌器、温度計、及び蒸留カラム、及び窒素注入チューブが備えられた)4リットルの丸底フラスコに導入された。触媒として40ppmのチタニウムテトラブチレートを加えた後、混合物を攪拌し、そして(解放された水を蒸留除去しつつ)240℃に加熱した。反応を200ミリバールで行った。これにより、酸価が≦1mgKOH/gのポリエステルオールが得られた。
894.8gの無水フタル酸、597.35gのオレイン酸、865.51gのジエチレングリコール、及び289.31gのグリセロールを、一般的な方法を使用して反応させた。これにより、OH官能価が2.2、及びヒドロキシル価が259mgKOH/gのポリエステルオールが得られた。
953.58gの無水フタル酸、545.65gのオレイン酸、884.79gのジエチレングリコール、及び266.81gのグリセロールを、一般的な方法を使用して反応させた。これにより、OH官能価が2.2、及びヒドロキシル価が237mgKOH/gのポリエステルオールが得られた。
ジメチルテレフタレートに基づき、及びヒドロキシル価が192mgKOH/gの、Invistaから市販されているポリエステルオール(Terate7541 LO)を使用した。
1428.51gのテレフタル酸、121.46gのオレイン酸、1460gのジエチレングリコール、及び57.69gのトリメチロールプロパンを、一般的な方法を使用して反応させた。これにより、OH官能価が2.0、及びヒドロキシル価が228mgKOH/gのポリエステルオールが得られた。
1468.53gのテレフタル酸、62.43gのオレイン酸、1500.9gのジエチレングリコール、及び40.7gのグリセロールを、一般的な方法を使用して反応させた。これにより、OH官能価が2.05、及びヒドロキシル価が238mgKOH/gのポリエステルオールが得られた。
1188.95gのテレフタル酸、404.36gのオレイン酸、1006.3gのジエチレングリコール、及び384.12gのトリメチロールプロパンを、一般的な方法を使用して反応させた。これにより、OH官能価が2.3、及びヒドロキシル価が246mgKOH/gのポリエステルオールが得られた。
1307.33gのテレフタル酸、444.57gのオレイン酸、897.73gのジエチレングリコール、及び362.34gのグリセロールを、一般的な方法を使用して反応させた。これにより、OH官能価が2.5、及びヒドロキシル価が239mgKOH/gのポリエステルオールが得られた。
硬質ポリウレタンフォームの製造(変形例1):
イソシアネート及びイソシアネートに対して反応性の化合物を、(ポリオール成分のイソシアネート成分に対する割合を100:190の一定の混合割合として、)発泡剤、触媒、及び他の全ての添加剤と一緒に、発泡した。各場合において、一定のファイバー時間(fiber time)を49+/−1秒、及び総合フォーム密度(overall form density)を33+/−0.5g/lに設定した。
79質量部の、実施例1及び2、又は比較例1及び2によるポリエステルオール、
6質量部の、ヒドロキシル官能価が2及びヒドロキシル価が200mgKOH/gの、エチレングリコール及びエチレンオキシドのエーテルからなるポリエーテルオール、
13質量部の、難燃性トリスクロロイソプロピルフォスフェイト(TCPP)、
2質量部の、安定剤Tegostab B8443(シリコーン−含有安定剤)、
15質量部の、ペンタンS80:20、
1.5質量部の水、
1.6質量部のカリウムアセテート(エチレングリコール中、47%質量濃度(strength by weight))、
1.2質量部の70%ビス(2−ジメチルアミノエチル)エーテル。
190質量部のポリマー性MDI(Lupranat(登録商標)M50,BASF SE,Ludwigshafen,DEより)。
圧痕試験を使用して硬化を測定した。この目的のために、(ポリスチレンカップ内で成分を混合した後、)半径が10mmの半球状の間端部を有する鋼製の圧子を、(万能試験機を使用して)フォームに10mmの深さに、2.5、3、4、5、6及び7分間、押し付けた。このために必要とされたNでの最大力が、フォームの硬化の測定(値)である。硬質ポリウレタンフォームの脆性の測定として、圧痕試験で、硬質フォームの表面が目視可能な割れ目領域を有する時点を測定した。
炎の高さをEN ISO 11925−2に従い測定した。結果を表2に示す。
硬質ポリウレタンフォームの製造(変形例2):
イソシアナート及びイソシアネートに対して反応性の成分を、発泡剤、触媒、及び全ての他の添加剤と一緒に、(ポリオール成分のイソシアネート成分に対する混合割合を一定の100:190として、)発泡させた。各場合において、一定のファイバー時間(fiber time)、49+/−1秒、及び総合フォーム密度、41+/−1g/lを設定した。
41.5質量部の、実施例1及び2、又は比較例2によるポリエステルオール、
20質量部の、(OHNが〜490mgKOH/gであり、及びポロピレンオキシドを開始分子としてスクロース/グリセロール混合物上に重付加させることによって製造された)ポリエーテルオール、
6質量部の、(OHNが〜160mgKOH/gであり、及びプロピレンをトリメチロールプロパン上に重付加させることにより製造された)ポリエーテルオール、
5質量部の、ヒドロキシル官能価が2及びヒドロキシル価が200mgKOH/gの、エチレングリコール及びエチレンオキシドのエーテルからなるポリエーテルオール、
25質量部の、難燃性トリスクロロイソプロピルフォスフェイト(TCPP)、
2.5質量部の、安定剤Niax Silicone L6635(シリコーン−含有安定剤)、
7.5質量部の、ペンタンS80:20、
2.0質量部の水、
1.5質量部のカリウムアセテート(エチレングリコール中、47%質量濃度(strength by weight))、
0.6質量部の、ビス(2−ジメチルアミノエチル)エーテル及びテトラメチルヘキサンジアミンの1:1混合物。
190質量部のポリマー性MDI(Lupranat(登録商標)M50,BASF SE,Ludwigshafen,DEより)。
更に、サンドイッチ要素を二重ベルト法を使用して製造した。水の含有量を、2質量部ではなく、2.6質量部に増加させ、及び7.5質量部ではなく、11質量部のペンタンを使用して、フォーム密度を30+/−1g/lに設定した。更に、ビス(2−ジメチルアミノエチル)エーテル及びテトラメチルヘキサンジアミンの1:1混合物の割合を変化させて、ファイバー時間(fiber time)を、49+/−1秒に設定した。
表面欠陥の頻度を評価するための試料を、二重ベルト法を使用して製造した。
処理の間、フォーム形成を試験することによって処理性を測定した。発泡剤の大きな泡(該泡は、フォーム表面を破裂させ、そして従ってこの開口部を裂くものである)が発生した場合、これらは「破裂」と称され、そして系(システム)は、問題のない方法で処理することができない。この不満足な挙動が観察されない場合、処理は「問題が無い」状態である。
実施例
硬質ポリウレタンフォームの製造(変形例3):
更に、硬質ポリウレタンの以下の製造に従う、二重ベルト法によって、テストプレートが製造された(変形例3)。
58質量部の、実施例、又は比較例によるポリエステルオール、
10質量部の、(ヒドロキシル官能価が2、及びヒドロキシル価が200mgKOH/gであり、及びエチレングリコール及びエチレンオキシドのエーテルから成る)ポリエーテルオール、
30質量部の、難燃性トリスクロロイソプロピルフォスフェイト(TCPP)、
2質量部の、安定剤Tegostab B 8443(シリコーン−含有安定剤)、
10質量部のn−ペンタン、
1.6質量部のギ酸(85%)、
2.0質量部のカリウムフィルメート(エチレングリコール中、36質量%濃度(strength))、
0.6質量部のビス(2−ジメチルアミノエチル)エーテル(ジプロピレングリコール中70質量%)。
170質量部のポリマー性MDI(Lupranat(登録商標)M50)。
Claims (8)
- a)以下の、
a1)テレフタル酸に対して、50〜100モル%の、テレフタル酸、ジメチルテレフタレート、ポリアルキレンテレフタレート、及びこれらの混合物から選ばれる材料、
a2)0〜50モル%の、フタル酸、無水フタル酸、又はイソフタル酸、
a3)0〜50モル%の、1種以上のジカルボン酸、
を含む、10〜70モル%のジカルボン酸組成物、
b)2〜30モル%の、1種以上の脂肪酸、及び/又は脂肪酸誘導体、及び/又は安息香酸、
c)10〜70モル%の、2〜18個の炭素原子を有する、1種以上の脂肪族ジオール、又は脂環式ジオール、又はこれらのアルコキシレート、
d)グリセロール、アルコキシル化されたグレセロール、トリメチロールプロパン、アルコキシル化されたトリメチロールプロパン、ペンタエリチリトール、及びアルコキシル化されたペンタエリチリトールから選ばれる、2〜50モル%の高−官能性ポリオール、
のエステル化生成物を含むポリエステルポリオールであって、
ポリエステルポリオール1kg当たり、少なくとも200ミリモル、好ましくは少なくとも500ミリモル、及び特に好ましくは少なくとも800ミリモルの、OH官能価が≧2.9のポリオールd)が反応するものであるポリエステルポリオール。 - ジカルボン酸組成物a)が、75モル%を超える、テレフタル酸a1)に基づく材料を含むことを特徴とする請求項1に記載のポリエステルポリオール。
- 脂肪族、又は脂環式ジオールc)が、エチレングリコール、ジエチレングリコール、プロピレングリコール、1,3−プロパンジオール、1,4−ブタンジオール、1,5−ペンタンジオール、1,6−ヘキサンジオール、2−メチル−1,3−プロパンジオール、及び3−メチル−1,5−ペンタンジオール、及びこれらのアルコキシレートから成る群から選ばれることを特徴とする請求項2に記載のポリエステルオール。
- 脂肪酸族ジオールが、ジエチレングリコールであることを特徴とする請求項3に記載のポリエステルオール。
- 脂肪酸、又は脂肪酸誘導体b2)が、再生可能な原料に基づく脂肪酸又は脂肪酸誘導体であり、及びヒマシ油、ポリヒドロキシ脂肪酸、リシノール酸、ヒドロキシ−変性油、ブドウ種油、ブラッククミン油、カボチャ核種油、ルリヂサ種油、大豆油、麦芽油、菜種油、向日葵油、ピーナッツ油、アプリコット核種油、ピスタチオ油、アーモンド油、オリーブオイル、マカダミアナッツ油、アボカド油、シーバックスロン油、セサミ油、大麻油、ヘーゼルナッツ油、サクラソウ油、野バラ油、ベニバナ油、くるみ油、
ミリストレイン酸、パルミトレイン酸、オレイン酸、バクセン酸、ペトロセリン酸、ガドレイン酸、エルカ酸、ネルボン酸、リノール酸、α−及びγ−リノール酸、ステアリドン酸、アラキドン酸、ティムノドン酸、クルパノドン酸、及びセルボン酸に基づくヒドロキシ−変性脂肪酸及び脂肪酸エステルから成る群から選ばれることを特徴とする請求項1〜4の何れか1項に記載のポリエステルオール。 - A)有機、及び/又は変性有機ジイソシアネート、及び/又はポリイソシアネートと、
B)成分B)が50質量%以下の更なるポオリエステルポリオールを含むことができる、請求項1に記載されたポリエステルポリオール、
C)適切であれば、ポリエーテルオール、及び/又はイソシアネートに対して反応性の基を少なくとも2個有する更なる化合物、及び適切であれば、鎖延長剤、及び/又は架橋剤、
D)発泡剤、
E)触媒、及び適切であれば、
F)更なる補助剤、及び/又は添加剤、
G)難燃剤、
を反応させることにより、硬質ポリウレタンフォームを製造する方法。 - 請求項6に記載の方法によって得ることができる硬質ポリウレタンフォーム。
- 硬質ポリウレタンフォームを製造するために、請求項1〜5の何れか1項に記載のポリエーテルポリオールを使用する方法。
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013538910A (ja) * | 2010-09-29 | 2013-10-17 | ダウ グローバル テクノロジーズ エルエルシー | 高官能価芳香族ポリエステル、高官能価芳香族ポリエステルを含むポリオールブレンド、およびそれから得られる生成物 |
JP2013545846A (ja) * | 2010-12-02 | 2013-12-26 | ビーエーエスエフ ソシエタス・ヨーロピア | 芳香族ジカルボン酸に基づくポリエステルポリオール |
KR20150027153A (ko) * | 2012-05-30 | 2015-03-11 | 바스프 에스이 | 경질 폴리우레탄 폼을 제조하기 위한 폴리에스테롤 |
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JP2017110142A (ja) * | 2015-12-18 | 2017-06-22 | Dic株式会社 | ポリエステルポリオール、コーティング材、及び包装材料 |
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Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102428120A (zh) * | 2009-05-19 | 2012-04-25 | 因温斯特技术公司 | 多元醇组合物,树脂共混物组合物,喷发组合物,及其各自的使用方法,及其各自的制备方法 |
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US10767073B2 (en) * | 2016-10-18 | 2020-09-08 | Ppg Industries Ohio, Inc. | Curable film-forming compositions containing hydroxyl functional, branched acrylic polymers and multilayer composite coatings |
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US11091652B2 (en) | 2017-01-25 | 2021-08-17 | Basf Se | Cold flexible polyurethane formulation |
EP3354671A1 (de) * | 2017-01-31 | 2018-08-01 | Covestro Deutschland AG | Verfahren zur herstellung von polyurethan (pur) und polyurethan/polyisocyanurat (pur/pir)- hartschaumstoffen |
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EP3581599A1 (de) | 2018-06-15 | 2019-12-18 | Covestro Deutschland AG | Thiocarbonat-haltige pur/pir-hartschäume und daraus erhaltene polyurethane |
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EP4011891A1 (de) | 2020-12-09 | 2022-06-15 | Covestro Deutschland AG | Verfahren zur herstellung von flammgeschützten pur/pir-hartschaumstoffen |
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EP4230670A1 (de) | 2022-02-18 | 2023-08-23 | Covestro Deutschland AG | Lagerstabile polyolformulierungen |
EP4269463A1 (de) | 2022-04-26 | 2023-11-01 | Covestro Deutschland AG | Dimensionsstabile offenzellige feinzellige polyurethan-hartschaumstoffe |
EP4275857A1 (de) | 2022-05-12 | 2023-11-15 | Covestro Deutschland AG | Werkzeug zur herstellung von schaumstoffen |
EP4286438A1 (de) | 2022-05-31 | 2023-12-06 | Covestro Deutschland AG | Komprimierter, offenzelliger, feinzelliger pur/pir-hartschaumstoff |
EP4379021A1 (en) | 2022-11-30 | 2024-06-05 | Covestro Deutschland AG | Pyrolysis of scrap, fiber reinforced polyurethane-poly(meth)acrylate composite material for recovery of recyclates |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62290723A (ja) * | 1986-05-30 | 1987-12-17 | インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− | ポリエステルポリオ−ル及びその製法 |
JPS63312312A (ja) * | 1986-04-23 | 1988-12-20 | ザ ダウ ケミカル カンパニ− | 活性水素組成物及び成形気泡ポリマ− |
JP2002540270A (ja) * | 1999-03-31 | 2002-11-26 | オキシド・エル・ピー | 芳香族ポリエステルポリオールの生成方法 |
JP2007297478A (ja) * | 2006-04-28 | 2007-11-15 | Kawasaki Kasei Chem Ltd | ポリエステルポリオール、それを用いたポリウレタンフォーム用組成物、及びポリウレタンフォーム |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3523093A (en) * | 1961-11-28 | 1970-08-04 | Paul Stamberger | Method of producing polyurethanes by reacting polyisocyanate with a preformed polymer resulting from polymerization of ethylenically unsaturated monomers |
GB1022434A (en) * | 1961-11-28 | 1966-03-16 | Union Carbide Corp | Improvements in and relating to polymers |
US3267050A (en) * | 1962-05-21 | 1966-08-16 | Union Carbide Corp | Foamed organic polyisocyanate-amine reaction products |
DE1251525B (ja) * | 1963-06-13 | |||
DE2850609A1 (de) * | 1978-11-22 | 1980-06-12 | Basf Ag | Verfahren zur herstellung von stabilen fuellstoff-polyol-dispersionen |
US4374209A (en) * | 1980-10-01 | 1983-02-15 | Interchem International S.A. | Polymer-modified polyols useful in polyurethane manufacture |
US4722803A (en) * | 1985-10-29 | 1988-02-02 | Stepan Company | Self-compatibilizing polyester polyol blends based on dimethyl terephthalate residues |
US5051528A (en) * | 1990-04-24 | 1991-09-24 | Eastman Kodak Company | Recovery process for ethylene glycol and dimethylterephthalate |
US5877255A (en) * | 1996-03-27 | 1999-03-02 | Sika Ag Vorm. Kaspar Winkler & Co. | Kind of polyhydroxyl compounds suitable for the polyurethane synthesis |
EP1058701B2 (en) * | 1998-02-23 | 2011-03-16 | Stepan Company | Low viscosity polyester polyols and methods for preparing same |
CN1247656C (zh) * | 2003-08-07 | 2006-03-29 | 烟台万华聚氨酯股份有限公司 | 一种聚酯多元醇与其改性原料的生产工艺和用途 |
CN1803878A (zh) * | 2005-12-22 | 2006-07-19 | 辽阳东辰聚氨酯有限公司 | 生产聚氨酯泡沫、聚异氰脲酸酯泡沫及聚氨酯胶粘剂的聚酯多元醇及制备工艺 |
US7560526B2 (en) * | 2006-03-21 | 2009-07-14 | Oxid, L.P. | Polyol with high cyclopentane solubility |
CN101265323A (zh) * | 2007-03-16 | 2008-09-17 | 张鹏飞 | 聚酯多元醇 |
-
2009
- 2009-10-13 MX MX2011003903A patent/MX2011003903A/es active IP Right Grant
- 2009-10-13 BR BRPI0920168A patent/BRPI0920168A2/pt not_active Application Discontinuation
- 2009-10-13 JP JP2011531473A patent/JP5735920B2/ja active Active
- 2009-10-13 PL PL09783986T patent/PL2340269T3/pl unknown
- 2009-10-13 US US13/124,217 patent/US20110201716A1/en not_active Abandoned
- 2009-10-13 PT PT97839864T patent/PT2340269E/pt unknown
- 2009-10-13 WO PCT/EP2009/063358 patent/WO2010043624A2/de active Application Filing
- 2009-10-13 CA CA2739845A patent/CA2739845C/en active Active
- 2009-10-13 KR KR1020117011024A patent/KR101722273B1/ko active IP Right Review Request
- 2009-10-13 CN CN200980150589.0A patent/CN102245668B/zh active Active
- 2009-10-13 EP EP09783986A patent/EP2340269B1/de active Active
- 2009-10-13 SI SI200930423T patent/SI2340269T1/sl unknown
- 2009-10-13 ES ES09783986T patent/ES2391811T3/es active Active
-
2012
- 2012-12-04 HR HRP20120999AT patent/HRP20120999T1/hr unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63312312A (ja) * | 1986-04-23 | 1988-12-20 | ザ ダウ ケミカル カンパニ− | 活性水素組成物及び成形気泡ポリマ− |
JPS62290723A (ja) * | 1986-05-30 | 1987-12-17 | インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− | ポリエステルポリオ−ル及びその製法 |
JP2002540270A (ja) * | 1999-03-31 | 2002-11-26 | オキシド・エル・ピー | 芳香族ポリエステルポリオールの生成方法 |
JP2007297478A (ja) * | 2006-04-28 | 2007-11-15 | Kawasaki Kasei Chem Ltd | ポリエステルポリオール、それを用いたポリウレタンフォーム用組成物、及びポリウレタンフォーム |
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Also Published As
Publication number | Publication date |
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WO2010043624A2 (de) | 2010-04-22 |
ES2391811T3 (es) | 2012-11-30 |
KR20110090930A (ko) | 2011-08-10 |
US20110201716A1 (en) | 2011-08-18 |
PL2340269T3 (pl) | 2013-02-28 |
CA2739845A1 (en) | 2010-04-22 |
PT2340269E (pt) | 2012-12-05 |
MX2011003903A (es) | 2011-04-28 |
JP5735920B2 (ja) | 2015-06-17 |
CN102245668A (zh) | 2011-11-16 |
CA2739845C (en) | 2016-08-16 |
WO2010043624A3 (de) | 2010-12-09 |
SI2340269T1 (sl) | 2013-01-31 |
BRPI0920168A2 (pt) | 2015-12-29 |
KR101722273B1 (ko) | 2017-03-31 |
EP2340269B1 (de) | 2012-09-05 |
HRP20120999T1 (hr) | 2012-12-31 |
CN102245668B (zh) | 2014-04-09 |
EP2340269A2 (de) | 2011-07-06 |
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