JP2012214604A - 水素化精製触媒及び炭化水素油の製造方法 - Google Patents
水素化精製触媒及び炭化水素油の製造方法 Download PDFInfo
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- JP2012214604A JP2012214604A JP2011080572A JP2011080572A JP2012214604A JP 2012214604 A JP2012214604 A JP 2012214604A JP 2011080572 A JP2011080572 A JP 2011080572A JP 2011080572 A JP2011080572 A JP 2011080572A JP 2012214604 A JP2012214604 A JP 2012214604A
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Abstract
【解決手段】 本発明の水素化精製触媒は、固体酸性を有する非晶性複合金属酸化物を含む担体と、前記担体に担持された周期表第8族〜第10族の貴金属から選択される少なくとも一種の活性金属と、を含有してなる水素化精製触媒であって、水素化精製触媒は炭素原子を含む炭素質物質を含有し、水素化精製触媒における炭素質物質の含有量が炭素原子換算で0.05〜1質量%である。
【選択図】 なし
Description
分解率(%)=[(被処理ワックス単位質量中の沸点が360℃を超える炭化水素の質量)−(水素化分解生成物単位質量中の沸点が360℃を超える炭化水素の質量)]×100/(被処理ワックス単位質量中の沸点が360℃を超える炭化水素の質量)…(1)
<水素化精製触媒の調製>
粉末状のシリカジルコニア(シリカ単位/ジルコニア単位モル比が7)を60質量%と粉末状のアルミナを40質量%とを含有する組成物に水を加えて粘土状に混練し、ここに成型助剤としてデンプンを、シリカジルコニアとアルミナとの合計の質量に対して5質量%の割合で配合し、更に混練を行なって捏和物を調製した。この捏和物を押出成型により直径約1.5mm、長さ約3mmの円柱状に成型した。得られた成型体を120℃で3時間乾燥し、更に空気中、450℃で3時間焼成して担体を得た。この担体中に含まれるデンプン由来の炭素原子を含む残留物の含有量を、堀場製作所社製炭素・硫黄分析装置EMIA−920Vを用いて測定した結果、担体の質量を基準として1.1質量%であった。
上記により得られた水素化精製触媒を固定床流通式反応器に充填し、水素気流下、340℃で4時間の還元処理を行って触媒を活性化した。
<水素化精製触媒の調製>
触媒前駆体の焼成において、500℃における焼成時間を0.5時間とした以外は実施例1と同様の方法にて水素化精製触媒を得た。水素化精製触媒中の炭素質物質の含有量は炭素原子換算で0.3質量%であった。
上記により得られた水素化精製触媒を用いて、実施例1と同様にしてFT合成油由来の中間留分の水素化精製を行なった。C18異性体率が85%となる反応温度は338℃であり、軽油留分の収率は44質量%であった。また、前記気液分離器により分離された液体炭化水素中には、オレフィン分及び含酸素化合物は実質的に含まれていなかった。結果を表1に示す。
<水素化精製触媒の調製>
実施例1と同様にして触媒前駆体を調製した。この触媒前駆体を加熱炉内に仕込み、300℃まで昇温し、その後300〜400℃の間を10℃/hの昇温速度で昇温し、その後480℃にて0.5時間焼成することにより、水素化精製触媒を得た。水素化精製触媒中の炭素質物質の含有量は炭素原子換算で0.8質量%であった。
上記により得られた水素化精製触媒を用いて、実施例1と同様にしてFT合成油由来の中間留分の水素化精製を行なった。C18異性体率が85%となる反応温度は339℃であり、軽油留分の収率は44質量%であった。また、前記気液分離器により分離された液体炭化水素中には、オレフィン分及び含酸素化合物は実質的に含まれていなかった。結果を表1に示す。
<水素化精製触媒の調製>
実施例1と同様にして、シリカジルコニアとアルミナと水とデンプンから捏和物を調製し、この捏和物を成型し、これを乾燥して成型体を得た。この成型体を空気中、550℃で3時間焼成して担体を得た。この担体中に含まれるデンプン由来の炭素原子を含む残留物の含有量を実施例1と同様に測定したところ、炭素原子は検出されなかった(炭素原子換算の含有量が0.02質量%以下)。
上記により得られた水素化精製触媒を用いて、実施例1と同様にしてFT合成油由来の中間留分の水素化精製を行なった。C18異性体率が85%となる反応温度は337℃であり、軽油留分の収率は44質量%であった。また、前記気液分離器により分離された液体炭化水素中には、オレフィン分及び含酸素化合物は実質的に含まれていなかった。結果を表2に示す。
<水素化精製触媒の調製>
軽油留分に浸漬し、脱油処理を行った予備触媒の焼成において、450℃での焼成時間を0.8時間とした以外は実施例4と同様にして水素化精製触媒を得た。この水素化精製触媒中の炭素質物質の含有量は炭素原子換算で0.4質量%であった。
上記により得られた水素化精製触媒を用いて、実施例1と同様にしてFT合成油由来の中間留分の水素化精製を行なった。C18異性体率が85%となる反応温度は339℃であり、軽油留分の収率は45質量%であった。また、前記気液分離器により分離された液体炭化水素中には、オレフィン分及び含酸素化合物は実質的に含まれていなかった。結果を表2に示す。
<水素化精製触媒の調製>
実施例1と同様にして触媒前駆体を調製した。この触媒前駆体を加熱炉内に仕込み、空気雰囲気下で、300℃まで昇温し、その後300〜400℃の間を10℃/hの昇温速度で昇温し、その後600℃にて0.5時間焼成することにより、水素化精製触媒を得た。この水素化精製触媒中の炭素質物質の含有量は炭素原子換算で0.03質量%であった。
上記により得られた水素化精製触媒を用いて、実施例1と同様にしてFT合成油由来の中間留分の水素化精製を行なった。C18異性体率が85%となる反応温度は334℃であり、軽油留分の収率は41質量%であった。また、前記気液分離器により分離された液体炭化水素中には、オレフィン分及び含酸素化合物は実質的に含まれていなかった。結果を表1に示す。
<水素化精製触媒の調製>
軽油留分に浸漬し、脱油処理を行った予備触媒の焼成を、昇温後470℃、2時間にて行なった以外は実施例4と同様の操作にて水素化精製触媒を得た。この水素化精製触媒中の炭素質物質の含有量は炭素原子換算で0.03質量%であった。
上記により得られた水素化精製触媒を用いて、実施例1と同様にしてFT合成油由来の中間留分の水素化精製を行なった。C18異性体率が85%となる反応温度は334℃であり、軽油留分の収率は41質量%であった。また、前記気液分離器により分離された液体炭化水素中には、オレフィン分及び含酸素化合物は実質的に含まれていなかった。結果を表2に示す。
<水素化精製触媒の調製>
軽油留分に浸漬し、脱油処理を行った予備触媒の焼成を、昇温後450℃、0.5時間にて行なった以外は実施例4と同様の操作にて水素化精製触媒を得た。この水素化精製触媒中の炭素質物質の含有量は炭素原子換算で1.5質量%であった。
上記により得られた水素化精製触媒を用いて、実施例1と同様にしてFT合成油由来の中間留分の水素化精製を行なった。C18異性体率が85%となる反応温度は341℃であり、軽油留分の収率は43質量%であった。また、前記気液分離器により分離された液体炭化水素中には、オレフィン分及び含酸素化合物は実質的に含まれていなかった。結果を表2に示す。
Claims (5)
- 固体酸性を有する非晶性複合金属酸化物を含む担体と、前記担体に担持された周期表第8族〜第10族の貴金属から選択される少なくとも一種の活性金属と、を含有してなる水素化精製触媒であって、
前記水素化精製触媒は、炭素原子を含む炭素質物質を含有し、
前記水素化精製触媒における前記炭素質物質の含有量が炭素原子換算で0.05〜1質量%である、水素化精製触媒。 - 前記非晶性複合金属酸化物が、シリカジルコニア、シリカアルミナ及びアルミナボリアから選択される少なくとも一種である、請求項1記載の水素化精製触媒。
- 前記活性金属が白金である、請求項1又は2記載の水素化精製触媒。
- 分子状水素の共存下、沸点が25〜360℃の範囲にある直鎖状脂肪族炭化水素を80質量%以上含み且つ沸点が150〜360℃の範囲にある直鎖状脂肪族炭化水素を20質量%以上含む原料油を、請求項1〜3のいずれか一項記載の水素化精製触媒に接触させる、炭化水素油の製造方法。
- 前記原料油が、フィッシャー・トロプシュ合成反応により得られる合成油である、請求項4記載の炭化水素油の製造方法。
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CA2831737C (en) | 2019-02-26 |
US20140326642A1 (en) | 2014-11-06 |
US9475036B2 (en) | 2016-10-25 |
MY162457A (en) | 2017-06-15 |
EP2692429A1 (en) | 2014-02-05 |
AP3496A (en) | 2015-12-31 |
CN107051427A (zh) | 2017-08-18 |
ZA201307561B (en) | 2014-07-30 |
BR112013025296B1 (pt) | 2020-12-01 |
EP2692429A4 (en) | 2014-09-10 |
AU2012233954B2 (en) | 2017-05-04 |
AP2013007191A0 (en) | 2013-10-31 |
BR112013025296A2 (pt) | 2016-12-13 |
EA028397B1 (ru) | 2017-11-30 |
JP5690634B2 (ja) | 2015-03-25 |
WO2012133316A1 (ja) | 2012-10-04 |
EA201391410A1 (ru) | 2014-03-31 |
CN103459015A (zh) | 2013-12-18 |
CA2831737A1 (en) | 2012-10-04 |
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