JP2012164661A5 - - Google Patents
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- JP2012164661A5 JP2012164661A5 JP2012033774A JP2012033774A JP2012164661A5 JP 2012164661 A5 JP2012164661 A5 JP 2012164661A5 JP 2012033774 A JP2012033774 A JP 2012033774A JP 2012033774 A JP2012033774 A JP 2012033774A JP 2012164661 A5 JP2012164661 A5 JP 2012164661A5
- Authority
- JP
- Japan
- Prior art keywords
- layer
- equivalent thickness
- plane equivalent
- iron
- layers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Claims (1)
- ナノスコピック触媒粒子を担持した微細構造化担体ウィスカを含むナノ構造化要素を含んで成る燃料電池カソード触媒であって、
前記ナノスコピック触媒粒子が、第１および第２の層の交互堆積によって製造され、
真空堆積によって形成された前記第１の層が白金を含み、
真空堆積によって形成された前記第２の層が、鉄と、マンガンである第２の金属との合金または均質混合物であり、
前記第２の層における前記第２の金属に対する鉄の原子数比が０．０１〜１０であり、
前記第２の層に対する前記第１の層の平面相当厚さの比が０．３〜５であり、
前記第１および第２の層の平均二層平面相当厚さが１０ｎｍ未満であり、
前記平面相当厚さは、層の全質量が、表面として同じ投影面積を覆う平面にわたり均一に分散したと仮定して算出されるものである、
燃料電池カソード触媒。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/674,594 | 2003-09-29 | ||
| US10/674,594 US7419741B2 (en) | 2003-09-29 | 2003-09-29 | Fuel cell cathode catalyst |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006528009A Division JP5209206B2 (ja) | 2003-09-29 | 2004-08-27 | 燃料電池カソード触媒 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012164661A JP2012164661A (ja) | 2012-08-30 |
| JP2012164661A5 true JP2012164661A5 (ja) | 2013-02-14 |
| JP5385415B2 JP5385415B2 (ja) | 2014-01-08 |
Family
ID=34376891
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006528009A Active JP5209206B2 (ja) | 2003-09-29 | 2004-08-27 | 燃料電池カソード触媒 |
| JP2012033774A Expired - Fee Related JP5385415B2 (ja) | 2003-09-29 | 2012-02-20 | 燃料電池カソード触媒 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006528009A Active JP5209206B2 (ja) | 2003-09-29 | 2004-08-27 | 燃料電池カソード触媒 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7419741B2 (ja) |
| EP (1) | EP1667793B1 (ja) |
| JP (2) | JP5209206B2 (ja) |
| KR (1) | KR20060131733A (ja) |
| CN (1) | CN1859976A (ja) |
| AT (1) | ATE397490T1 (ja) |
| CA (1) | CA2539965A1 (ja) |
| DE (1) | DE602004014287D1 (ja) |
| WO (1) | WO2005035123A2 (ja) |
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|---|---|---|---|---|
| US7572534B2 (en) * | 2004-09-20 | 2009-08-11 | 3M Innovative Properties Company | Fuel cell membrane electrode assembly |
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| US7968488B2 (en) | 2006-04-18 | 2011-06-28 | Southwest Research Institute | Two-dimensional composite particle adapted for use as a catalyst and method of making same |
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| KR20090063441A (ko) | 2007-12-14 | 2009-06-18 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
| JP5196988B2 (ja) | 2007-12-21 | 2013-05-15 | スリーエム イノベイティブ プロパティズ カンパニー | インク組成物、その製造方法、そのインク組成物を用いて形成した電極触媒層及びこれらの用途 |
| JP5342824B2 (ja) | 2008-07-25 | 2013-11-13 | 株式会社東芝 | 触媒層担持基板の製造方法、触媒層担持基板、膜電極複合体、および燃料電池 |
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| JP6143663B2 (ja) | 2013-12-19 | 2017-06-07 | 株式会社東芝 | 多孔質触媒層、その製造方法、膜電極接合体および電気化学セル |
| US9468909B2 (en) * | 2014-06-27 | 2016-10-18 | Ford Global Technologies, Llc | Metal oxide stabilized platinum-based ORR catalyst |
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| KR20170095296A (ko) | 2014-12-15 | 2017-08-22 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 막 전극 접합체 |
| EP3303657B1 (en) | 2015-05-26 | 2023-06-28 | 3M Innovative Properties Company | Oxygen evolution catalyst electrodes, and methods of making and using the same |
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| KR102543281B1 (ko) | 2017-04-03 | 2023-06-16 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 물 전해 장치 |
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| WO2019193461A1 (en) | 2018-04-04 | 2019-10-10 | 3M Innovative Properties Company | Catalyst comprising pt, ni, and cr |
| CN111954950A (zh) * | 2018-04-04 | 2020-11-17 | 3M创新有限公司 | 包含Pt、Ni和Ta的催化剂 |
| WO2019195046A1 (en) | 2018-04-04 | 2019-10-10 | Steinbach Andrew J L | Catalyst |
| US20210008528A1 (en) | 2018-04-04 | 2021-01-14 | 3M Innovative Properties Company | Catalyst comprising pt, ni, and ru |
| CN112042022A (zh) | 2018-04-13 | 2020-12-04 | 3M创新有限公司 | 催化剂 |
| US11476470B2 (en) | 2018-04-13 | 2022-10-18 | 3M Innovative Properties Company | Catalyst |
| US11955645B2 (en) | 2018-04-13 | 2024-04-09 | 3M Innovative Properties Company | Catalyst |
| US11560632B2 (en) | 2018-09-27 | 2023-01-24 | 3M Innovative Properties Company | Membrane, membrane electrode assembly, and water electrolyzer including the same |
| EP3895238A1 (en) | 2018-12-13 | 2021-10-20 | 3M Innovative Properties Company | Catalyst |
| EP3899100B1 (en) | 2018-12-19 | 2023-01-25 | 3M Innovative Properties Company | Water electrolyzers |
| CN110085875B (zh) * | 2019-04-19 | 2022-06-17 | 同济大学 | 一种缓解含合金催化层衰减的多层催化层及其制备方法 |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3969545A (en) | 1973-03-01 | 1976-07-13 | Texas Instruments Incorporated | Light polarizing material method and apparatus |
| DE2616662C2 (de) | 1976-04-15 | 1984-02-02 | Dornier System Gmbh, 7990 Friedrichshafen | Verfahren zur herstellung einer selektiven solarabsorberschicht auf aluminium |
| US4155781A (en) | 1976-09-03 | 1979-05-22 | Siemens Aktiengesellschaft | Method of manufacturing solar cells, utilizing single-crystal whisker growth |
| US4252843A (en) | 1977-02-18 | 1981-02-24 | Minnesota Mining And Manufacturing Company | Process for forming a microstructured transmission and reflectance modifying coating |
| US4209008A (en) | 1977-07-26 | 1980-06-24 | United Technologies Corporation | Photon absorbing surfaces and methods for producing the same |
| US4252865A (en) | 1978-05-24 | 1981-02-24 | National Patent Development Corporation | Highly solar-energy absorbing device and method of making the same |
| US4340276A (en) | 1978-11-01 | 1982-07-20 | Minnesota Mining And Manufacturing Company | Method of producing a microstructured surface and the article produced thereby |
| US4316944A (en) | 1980-06-18 | 1982-02-23 | United Technologies Corporation | Noble metal-chromium alloy catalysts and electrochemical cell |
| US4396643A (en) | 1981-06-29 | 1983-08-02 | Minnesota Mining And Manufacturing Company | Radiation absorbing surfaces |
| US5079107A (en) | 1984-06-07 | 1992-01-07 | Giner, Inc. | Cathode alloy electrocatalysts |
| US4568598A (en) | 1984-10-30 | 1986-02-04 | Minnesota Mining And Manufacturing Company | Article with reduced friction polymer sheet support |
| US4812352A (en) | 1986-08-25 | 1989-03-14 | Minnesota Mining And Manufacturing Company | Article having surface layer of uniformly oriented, crystalline, organic microstructures |
| US5039561A (en) | 1986-08-25 | 1991-08-13 | Minnesota Mining And Manufacturing Company | Method for preparing an article having surface layer of uniformly oriented, crystalline, organic microstructures |
| JPH01210035A (ja) | 1988-02-18 | 1989-08-23 | Tanaka Kikinzoku Kogyo Kk | 白金触媒とその製造方法 |
| US5176786A (en) | 1988-07-13 | 1993-01-05 | Minnesota Mining And Manufacturing Company | Organic thin film controlled molecular epitaxy |
| US5138220A (en) | 1990-12-05 | 1992-08-11 | Science Applications International Corporation | Field emission cathode of bio-molecular or semiconductor-metal eutectic composite microstructures |
| US5336558A (en) | 1991-06-24 | 1994-08-09 | Minnesota Mining And Manufacturing Company | Composite article comprising oriented microstructures |
| US5338430A (en) * | 1992-12-23 | 1994-08-16 | Minnesota Mining And Manufacturing Company | Nanostructured electrode membranes |
| US5593934A (en) | 1993-12-14 | 1997-01-14 | Tanaka Kikinzoku Kogyo K.K. | Platinum alloy catalyst |
| CA2117158C (fr) | 1994-03-07 | 1999-02-16 | Robert Schulz | Alliages nanocristallins a base de nickel et usage de ceux-ci pour le transport et le stockage de l'hydrogene |
| EP0815273B1 (en) | 1995-02-02 | 2001-05-23 | Hydro-Quebec | NANOCRYSTALLINE Mg-BASED MATERIALS AND USE THEREOF FOR THE TRANSPORTATION AND STORAGE OF HYDROGEN |
| JP3874380B2 (ja) * | 1996-08-26 | 2007-01-31 | エヌ・イーケムキャット株式会社 | 空格子点型格子欠陥を有するカーボン担持白金スケルトン合金電極触媒 |
| US5872074A (en) | 1997-01-24 | 1999-02-16 | Hydro-Quebec | Leached nanocrystalline materials process for manufacture of the same, and use thereof in the energetic field |
| US6136412A (en) | 1997-10-10 | 2000-10-24 | 3M Innovative Properties Company | Microtextured catalyst transfer substrate |
| US5879827A (en) | 1997-10-10 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Catalyst for membrane electrode assembly and method of making |
| US5879828A (en) | 1997-10-10 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Membrane electrode assembly |
| US5910378A (en) | 1997-10-10 | 1999-06-08 | Minnesota Mining And Manufacturing Company | Membrane electrode assemblies |
| US6300000B1 (en) | 1999-06-18 | 2001-10-09 | Gore Enterprise Holdings | Fuel cell membrane electrode assemblies with improved power outputs and poison resistance |
| US6482763B2 (en) * | 1999-12-29 | 2002-11-19 | 3M Innovative Properties Company | Suboxide fuel cell catalyst for enhanced reformate tolerance |
| US20010031338A1 (en) * | 2000-04-26 | 2001-10-18 | Sil Han | Box reinforcing sheet with self-stick layer |
| US6663998B2 (en) | 2001-04-05 | 2003-12-16 | The Technical University Of Denmark (Dtu) | Anode catalyst materials for use in fuel cells |
| US6703068B2 (en) * | 2001-12-19 | 2004-03-09 | 3M Innovative Properties Company | Amine oxide coating compositions |
| US6465041B1 (en) * | 2001-12-19 | 2002-10-15 | 3M Innovative Properties Company | Method of making gas diffusion layers for electrochemical cells |
| US20030134178A1 (en) * | 2001-12-21 | 2003-07-17 | 3M Innovative Properties Company | Precompressed gas diffusion layers for electrochemical cells |
| WO2003073542A2 (en) | 2002-02-27 | 2003-09-04 | Symyx Technologies, Inc. | Full cell electrocatalyst of pt-ni-mn/fe |
| US20070082814A1 (en) * | 2005-10-12 | 2007-04-12 | 3M Innovative Properties Company | Ternary nanocatalyst and method of making |
| JP5674373B2 (ja) * | 2010-07-30 | 2015-02-25 | 富士フイルム株式会社 | 洗浄組成物、これを用いた洗浄方法及び半導体素子の製造方法 |
-
2003
- 2003-09-29 US US10/674,594 patent/US7419741B2/en not_active Expired - Fee Related
-
2004
- 2004-08-27 EP EP04782374A patent/EP1667793B1/en not_active Not-in-force
- 2004-08-27 CN CNA2004800282534A patent/CN1859976A/zh active Pending
- 2004-08-27 DE DE602004014287T patent/DE602004014287D1/de active Active
- 2004-08-27 KR KR1020067006012A patent/KR20060131733A/ko not_active Application Discontinuation
- 2004-08-27 WO PCT/US2004/027878 patent/WO2005035123A2/en active Application Filing
- 2004-08-27 JP JP2006528009A patent/JP5209206B2/ja active Active
- 2004-08-27 CA CA002539965A patent/CA2539965A1/en not_active Abandoned
- 2004-08-27 AT AT04782374T patent/ATE397490T1/de not_active IP Right Cessation
-
2012
- 2012-02-20 JP JP2012033774A patent/JP5385415B2/ja not_active Expired - Fee Related