JP2010539337A - 銀ポリアミン錯体の還元による銀球の調製 - Google Patents
銀ポリアミン錯体の還元による銀球の調製 Download PDFInfo
- Publication number
- JP2010539337A JP2010539337A JP2010526006A JP2010526006A JP2010539337A JP 2010539337 A JP2010539337 A JP 2010539337A JP 2010526006 A JP2010526006 A JP 2010526006A JP 2010526006 A JP2010526006 A JP 2010526006A JP 2010539337 A JP2010539337 A JP 2010539337A
- Authority
- JP
- Japan
- Prior art keywords
- silver
- solvent
- solution
- polyamine
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 56
- 239000004332 silver Substances 0.000 title claims abstract description 56
- 229920000768 polyamine Polymers 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title description 4
- 230000009467 reduction Effects 0.000 title description 3
- 239000002245 particle Substances 0.000 claims abstract description 55
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 18
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 claims abstract description 8
- 235000010350 erythorbic acid Nutrition 0.000 claims abstract description 8
- 229940026239 isoascorbic acid Drugs 0.000 claims abstract description 8
- 239000000084 colloidal system Substances 0.000 claims abstract description 7
- 230000001681 protective effect Effects 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 32
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 23
- 239000002904 solvent Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 9
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 9
- 229920002873 Polyethylenimine Polymers 0.000 claims description 8
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical group [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 8
- 239000003638 chemical reducing agent Substances 0.000 claims description 7
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 6
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 6
- 229960005070 ascorbic acid Drugs 0.000 claims description 5
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 5
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims description 3
- 239000011668 ascorbic acid Substances 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 150000003077 polyols Chemical group 0.000 claims description 3
- CIWBSHSKHKDKBQ-MVHIGOERSA-N D-ascorbic acid Chemical compound OC[C@@H](O)[C@@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-MVHIGOERSA-N 0.000 claims description 2
- 235000000069 L-ascorbic acid Nutrition 0.000 claims description 2
- 239000002211 L-ascorbic acid Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 125000003916 ethylene diamine group Chemical group 0.000 claims 1
- 239000011368 organic material Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 20
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000000635 electron micrograph Methods 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000010944 silver (metal) Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 150000003378 silver Chemical class 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- XXFXYGWNAPCELD-UHFFFAOYSA-N 2-aminoethanol;silver Chemical class [Ag].NCCO XXFXYGWNAPCELD-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003985 ceramic capacitor Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000000445 field-emission scanning electron microscopy Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010946 fine silver Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000007540 photo-reduction reaction Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- NBYLLBXLDOPANK-UHFFFAOYSA-M silver 2-carboxyphenolate hydrate Chemical compound C1=CC=C(C(=C1)C(=O)O)[O-].O.[Ag+] NBYLLBXLDOPANK-UHFFFAOYSA-M 0.000 description 1
- -1 silver amine Chemical class 0.000 description 1
- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 description 1
- 229940019931 silver phosphate Drugs 0.000 description 1
- 229910000161 silver phosphate Inorganic materials 0.000 description 1
- OGFYIDCVDSATDC-UHFFFAOYSA-N silver silver Chemical compound [Ag].[Ag] OGFYIDCVDSATDC-UHFFFAOYSA-N 0.000 description 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 1
- 229910000367 silver sulfate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/06—Metallic powder characterised by the shape of the particles
- B22F1/065—Spherical particles
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US96017007P | 2007-09-19 | 2007-09-19 | |
| PCT/US2008/077061 WO2009039401A2 (en) | 2007-09-19 | 2008-09-19 | Preparation of silver spheres by the reduction of silver polyamine complexes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010539337A true JP2010539337A (ja) | 2010-12-16 |
| JP2010539337A5 JP2010539337A5 (enExample) | 2011-09-29 |
Family
ID=40282470
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010526006A Pending JP2010539337A (ja) | 2007-09-19 | 2008-09-19 | 銀ポリアミン錯体の還元による銀球の調製 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8292986B2 (enExample) |
| EP (1) | EP2190614A2 (enExample) |
| JP (1) | JP2010539337A (enExample) |
| KR (1) | KR101229687B1 (enExample) |
| CN (1) | CN101795794A (enExample) |
| WO (1) | WO2009039401A2 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2281646A1 (en) | 2009-07-02 | 2011-02-09 | Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO | Method and kit for manufacturing metal nanoparticles and metal-containing nanostructured composite materials |
| CN102211206B (zh) * | 2011-05-25 | 2013-09-18 | 华东微电子技术研究所合肥圣达实业公司 | 一种钛酸钡基半导体陶瓷欧姆电极浆料用超细球形银粉的制备方法 |
| EP3467809B1 (en) | 2013-03-12 | 2021-07-21 | Arizona Board of Regents, a Body Corporate of the State of Arizona acting for and on behalf of Arizona State University | Image processing of dendritic structures used in tags as physical unclonable function for anti-counterfeiting |
| CN105290417A (zh) * | 2014-06-17 | 2016-02-03 | 中国科学院大连化学物理研究所 | 一种可高度分散在有机体系中的纳米银的合成方法 |
| WO2016073910A1 (en) | 2014-11-07 | 2016-05-12 | Arizona Board Of Regents On Behalf Of Arizona State University | Information coding in dendritic structures and tags |
| EP3639188A4 (en) | 2017-06-16 | 2021-03-17 | Arizona Board of Regents on behalf of Arizona State University | POLARIZED SCANNING OF DENDRITIC IDENTIFICATORS |
| US10472528B2 (en) | 2017-11-08 | 2019-11-12 | Eastman Kodak Company | Method of making silver-containing dispersions |
| US10851257B2 (en) | 2017-11-08 | 2020-12-01 | Eastman Kodak Company | Silver and copper nanoparticle composites |
| US20210198769A1 (en) * | 2017-12-04 | 2021-07-01 | Greene Lyon Group, Inc. | Silver recovery |
| US11598015B2 (en) | 2018-04-26 | 2023-03-07 | Arizona Board Of Regents On Behalf Of Arizona State University | Fabrication of dendritic structures and tags |
| CN108746656B (zh) * | 2018-06-15 | 2021-11-26 | 威海职业学院 | 用于金刚石制品的预合金粉及其制备方法 |
| US20200130066A1 (en) * | 2018-10-25 | 2020-04-30 | Zhi ZHAO | Photochemical synthesis of dendritic silver particles |
| EP4420017A4 (en) | 2021-10-18 | 2025-02-05 | Arizona Board of Regents on behalf of Arizona State University | AUTHENTICATION OF IDENTIFIERS BY LIGHT SCATTERING |
| CN119304200B (zh) * | 2024-09-27 | 2025-09-09 | 中船黄冈贵金属有限公司 | 一种高球形度超细银粉及其制备方法和应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004100013A (ja) * | 2002-09-12 | 2004-04-02 | Mitsui Mining & Smelting Co Ltd | 低凝集性銀粉並びにその低凝集性銀粉の製造方法及びその低凝集性銀粉を用いた導電性ペースト |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5389122A (en) * | 1993-07-13 | 1995-02-14 | E. I. Du Pont De Nemours And Company | Process for making finely divided, dense packing, spherical shaped silver particles |
| US5292359A (en) * | 1993-07-16 | 1994-03-08 | Industrial Technology Research Institute | Process for preparing silver-palladium powders |
| US7718094B2 (en) * | 2004-06-18 | 2010-05-18 | The Research Foundation Of State University Of New York | Preparation of metallic nanoparticles |
| US8349393B2 (en) * | 2004-07-29 | 2013-01-08 | Enthone Inc. | Silver plating in electronics manufacture |
| US20060130700A1 (en) * | 2004-12-16 | 2006-06-22 | Reinartz Nicole M | Silver-containing inkjet ink |
| WO2006076613A2 (en) * | 2005-01-14 | 2006-07-20 | Cabot Corporation | Metal nanoparticle compositions |
| US7291292B2 (en) * | 2005-08-26 | 2007-11-06 | E.I. Du Pont De Nemours And Company | Preparation of silver particles using thermomorphic polymers |
| JP4839767B2 (ja) | 2005-10-14 | 2011-12-21 | 東洋インキScホールディングス株式会社 | 金属微粒子分散体の製造方法、該方法で製造された金属微粒子分散体を用いた導電性インキ、および導電性パターン。 |
| US7625637B2 (en) * | 2006-05-31 | 2009-12-01 | Cabot Corporation | Production of metal nanoparticles from precursors having low reduction potentials |
| US7648557B2 (en) * | 2006-06-02 | 2010-01-19 | E. I. Du Pont De Nemours And Company | Process for making highly dispersible spherical silver powder particles and silver particles formed therefrom |
-
2008
- 2008-09-19 CN CN200880107447A patent/CN101795794A/zh active Pending
- 2008-09-19 JP JP2010526006A patent/JP2010539337A/ja active Pending
- 2008-09-19 KR KR1020107008303A patent/KR101229687B1/ko not_active Expired - Fee Related
- 2008-09-19 EP EP08832691A patent/EP2190614A2/en not_active Withdrawn
- 2008-09-19 WO PCT/US2008/077061 patent/WO2009039401A2/en not_active Ceased
- 2008-09-19 US US12/234,341 patent/US8292986B2/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004100013A (ja) * | 2002-09-12 | 2004-04-02 | Mitsui Mining & Smelting Co Ltd | 低凝集性銀粉並びにその低凝集性銀粉の製造方法及びその低凝集性銀粉を用いた導電性ペースト |
Non-Patent Citations (1)
| Title |
|---|
| EDUARDO VILLEGAS ORTEGA、DIMITRIOS BERK: "Precipitation of Silver Powders in the Presence of Ethylenediamine Tetraacetic Acid", IND ENG CHEM RES, vol. 45, no. 6, JPN6013021312, 15 March 2006 (2006-03-15), US, pages 1863 - 1868, ISSN: 0002524304 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009039401A2 (en) | 2009-03-26 |
| US20090071292A1 (en) | 2009-03-19 |
| CN101795794A (zh) | 2010-08-04 |
| US8292986B2 (en) | 2012-10-23 |
| EP2190614A2 (en) | 2010-06-02 |
| KR20100068447A (ko) | 2010-06-23 |
| KR101229687B1 (ko) | 2013-02-05 |
| WO2009039401A3 (en) | 2009-09-17 |
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