JP2010525118A - 二酸化炭素の合成ガスへの接触水素化 - Google Patents
二酸化炭素の合成ガスへの接触水素化 Download PDFInfo
- Publication number
- JP2010525118A JP2010525118A JP2010504530A JP2010504530A JP2010525118A JP 2010525118 A JP2010525118 A JP 2010525118A JP 2010504530 A JP2010504530 A JP 2010504530A JP 2010504530 A JP2010504530 A JP 2010504530A JP 2010525118 A JP2010525118 A JP 2010525118A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- carbon dioxide
- synthesis gas
- hydrogen
- methane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6562—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
Description
混合酸化物触媒組成物である1%のLi−10%のCr−8%のMn−O/Al2O3を、アルミナ担体を表記の金属の硝酸塩の水溶液に含浸し、担体上に金属を析出させ、固体を単離し、その後、約4時間の期間で、約120℃で乾燥させ、約500℃でか焼することによって、製造した。触媒組成物の金属含有量は、X線回折および元素分析により決定し、1%のLi−10%のCr−8%のMn−O/Al2O3の表記の総組成に基づく質量%で表される。
実施例1に類似しているが、二酸化炭素がそれより少ない供給ガスについて、実験を行った。時間による触媒性能、および空気(酸素)を添加する効果をテストした。表2に収集されている結果は、反応装置を通る空気により、選択性およびSNにほとんど影響なく、触媒を再度活性化させ、二酸化炭素の転化率を回復できることを示している。
これらの実験において、3mlの触媒組成物の0.3%のPt−20%のCe−4%のMn−O/MgOが充填されたガラス管を適用した。それ以外は、実施例3と同様に実験を行った。結果が表4に示されている。
Claims (15)
- 水素、一酸化炭素および二酸化炭素を含有する合成ガス混合物を製造するプロセスであって、二酸化炭素および水素を含有するガス状供給混合物を触媒に接触させる工程を有してなり、前記触媒が、Mn酸化物と、Cr、Ni、La、Ce、W、およびPtからなる群より選択される少なくとも1つの元素の酸化物とから実質的になることを特徴とするプロセス。
- 前記触媒が、MnとLaの酸化物から実質的になることを特徴とする請求項1記載のプロセス。
- 前記触媒が、Cr、Ni、Ce、W、およびPtからなる群より選択される少なくとも1つの元素をさらに含むことを特徴とする請求項2記載のプロセス。
- 前記触媒が、少なくとも1種類のアルカリ金属またはアルカリ土類金属をさらに含むことを特徴とする請求項1から3いずれか1項記載のプロセス。
- 前記金属が、Li、K、CsおよびSrからなる群より選択されることを特徴とする請求項4記載のプロセス。
- 前記触媒が担体をさらに含有することを特徴とする請求項1から5いずれか1項記載のプロセス。
- 前記担体が、Al2O3、MgO、SiO2、TiO2およびZrO2からなる群より選択されることを特徴とする請求項6記載のプロセス。
- 前記接触工程が、300から900℃の温度、0.1から6MPaの圧力、および0.5から6秒の接触時間で行われることを特徴とする請求項1から7いずれか1項記載のプロセス。
- 前記供給混合物が、1から5までの比率で水素および二酸化炭素を含有することを特徴とする請求項1から8いずれか1項記載のプロセス。
- 前記合成ガス混合物が、0.1から3.0の化学量数を有することを特徴とする請求項1から9いずれか1項記載のプロセス。
- 前記供給混合物がアルカンをさらに含むことを特徴とする請求項1から10いずれか1項記載のプロセス。
- 前記アルカンがメタンであることを特徴とする請求項11記載のプロセス。
- 請求項1から12いずれか1項記載の二酸化炭素水素化工程およびメタン改質工程を有してなる、合成ガスの製造プロセス。
- 中間体または供給材料として合成ガス混合物を使用する化学生成物を製造するプロセスであって、請求項1から12いずれか1項記載の二酸化炭素水素化工程を有してなるプロセス
- メタノール製造、オレフィン合成、芳香族製造、オレフィンのヒドロホルミル化、メタノールのカルボニル化、またはオレフィンのカルボニル化であることを特徴とする請求項14記載のプロセス。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07008587 | 2007-04-27 | ||
EP07008587.3 | 2007-04-27 | ||
PCT/EP2008/003258 WO2008131898A1 (en) | 2007-04-27 | 2008-04-23 | Catalytic hydrogenation of carbon dioxide into syngas mixture |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010525118A true JP2010525118A (ja) | 2010-07-22 |
JP5592250B2 JP5592250B2 (ja) | 2014-09-17 |
Family
ID=38291211
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010504530A Expired - Fee Related JP5592250B2 (ja) | 2007-04-27 | 2008-04-23 | 二酸化炭素の合成ガスへの接触水素化 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8961829B2 (ja) |
EP (1) | EP2152409B1 (ja) |
JP (1) | JP5592250B2 (ja) |
CN (1) | CN101678329B (ja) |
EA (1) | EA016492B9 (ja) |
WO (1) | WO2008131898A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015044926A (ja) * | 2013-08-28 | 2015-03-12 | 独立行政法人産業技術総合研究所 | 炭化水素製造方法及び炭化水素製造装置 |
WO2019230854A1 (ja) * | 2018-05-29 | 2019-12-05 | 積水化学工業株式会社 | 触媒、二酸化炭素還元方法、及び二酸化炭素還元装置 |
WO2021186663A1 (ja) * | 2020-03-19 | 2021-09-23 | 株式会社日立製作所 | 一酸化炭素製造装置及び一酸化炭素製造システム |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0814053D0 (en) * | 2008-08-01 | 2008-09-10 | Johnson Matthey Plc | Process |
EA020700B1 (ru) * | 2008-12-17 | 2015-01-30 | Сауди Бейсик Индастриз Корпорейшн | Способ увеличения содержания монооксида углерода в синтез-газе |
CN102513102A (zh) * | 2011-11-22 | 2012-06-27 | 北京化工大学 | 一种二氧化钛负载钌催化剂的制备方法及其应用 |
US8962702B2 (en) * | 2011-12-08 | 2015-02-24 | Saudi Basic Industries Corporation | Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use |
WO2013135663A1 (de) | 2012-03-13 | 2013-09-19 | Bayer Intellectual Property Gmbh | Verfahren zur reduktion von kohlendioxid bei hohen temperaturen an mischmetalloxid-katalysatoren umfassend edelmetalle |
WO2013135662A1 (de) | 2012-03-13 | 2013-09-19 | Bayer Intellectual Property Gmbh | Verfahren zur reduktion von kohlendioxid bei hohen temperaturen an mischmetalloxidkatalysatoren |
AU2013231342A1 (en) | 2012-03-13 | 2014-10-16 | Bayer Intellectual Property Gmbh | Method for producing CO and/or H2 in an alternating operation between two operating modes |
WO2013190500A2 (en) | 2012-06-21 | 2013-12-27 | Saudi Basic Industries Corporation | Process for producing a synthesis gas mixture |
US8551434B1 (en) | 2012-06-29 | 2013-10-08 | Saudi Basic Industries Corporation | Method of forming a syngas mixture |
WO2014070419A2 (en) * | 2012-10-31 | 2014-05-08 | Physical Shockwave Industrial Applications, Llc | Process and apparatus for supersonic collision shockwave reaction mechanism making chemical compounds |
CN103183346B (zh) * | 2012-12-13 | 2014-12-17 | 浙江海洋学院 | 一种逆水煤气变换催化剂用于逆水煤气变换反应的方法 |
WO2014141198A1 (en) * | 2013-03-14 | 2014-09-18 | Johnson Matthey Public Limited Company | Cerium-modified manganese octahedral molecular sieves as catalysts for selective catalytic reduction |
US9695365B2 (en) | 2013-07-31 | 2017-07-04 | Saudi Basic Industries Corporation | Process for the production of olefins through FT based synthesis |
EP3027716A2 (en) | 2013-07-31 | 2016-06-08 | Saudi Basic Industries Corporation | A process for the production of olefins through fischer-tropsch based synthesis |
CN105683141A (zh) * | 2013-10-29 | 2016-06-15 | 沙特基础工业公司 | 合成气的二氧化碳加氢方法及该过程与合成气转化过程的结合 |
EP3080037A1 (en) | 2013-11-11 | 2016-10-19 | Saudi Basic Industries Corporation | Method for hydrogenation of co2 in adiabatic metal reactors |
CN105899648A (zh) | 2014-01-06 | 2016-08-24 | 沙特基础工业公司 | 用于合成气的二氧化碳氢化的方法 |
CN106133118B (zh) | 2014-04-03 | 2018-03-23 | 沙特基础工业公司 | 使用co2转化甲烷蒸汽重整合成气的方法 |
CN105080564B (zh) * | 2014-05-14 | 2017-09-15 | 中国石油化工股份有限公司 | 用于二氧化碳转化制一氧化碳的催化剂及其使用方法 |
WO2017085594A2 (en) * | 2015-11-16 | 2017-05-26 | Sabic Global Technologies B.V. | Process and catalyst for conversion of co2 to syngas for a simultaneous production of olefins and methanol |
CN106881084B (zh) * | 2015-12-10 | 2019-04-30 | 中国科学院大连化学物理研究所 | 一种用于逆水煤气变换反应贵金属催化剂及其制备和应用 |
RU2632701C1 (ru) * | 2016-06-21 | 2017-10-09 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) | Способ получения синтез-газа из CO2 |
WO2018002771A1 (en) * | 2016-06-28 | 2018-01-04 | Sabic Global Technologies B.V. | Methods for producing olefins from light hydrocarbons |
WO2018020343A1 (en) * | 2016-07-25 | 2018-02-01 | Sabic Global Technologies B.V. | Process for producing an oxo-synthesis syngas composition by high-pressure hydrogenation over a chromium oxide/aluminum supported catalyst |
WO2018047032A2 (en) * | 2016-09-08 | 2018-03-15 | Sabic Global Technologies B.V. | Process for selective conversion of hydrocarbons to c2 fraction and syngas composition |
CN106883084A (zh) * | 2017-03-07 | 2017-06-23 | 王亚壮 | 一种新型合成甲烷的方法及系统 |
CN108622855A (zh) * | 2017-03-15 | 2018-10-09 | 单岩崑 | 一种天然气催化氧化制备合成气的方法 |
CN107021453B (zh) * | 2017-04-20 | 2019-10-11 | 西南化工研究设计院有限公司 | 一种烯烃氢甲酰化反应中氢气和一氧化碳的生产工艺 |
WO2018219992A1 (de) | 2017-06-02 | 2018-12-06 | Basf Se | Verfahren zur kohlenstoffdioxid-hydrierung in gegenwart eines nickel- und magnesiumspinellhaltigen katalysators |
WO2018219986A1 (de) | 2017-06-02 | 2018-12-06 | Basf Se | Verfahren zur kohlenstoffdioxid-hydrierung in gegenwart eines iridium- und/oder rhodiumhaltigen katalysators |
RU2660139C1 (ru) * | 2017-11-28 | 2018-07-05 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Способ получения синтез-газа из CO2 |
RU2668863C1 (ru) * | 2017-12-11 | 2018-10-03 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) | Способ получения синтез-газа из CO2 |
CN108160104B (zh) * | 2017-12-22 | 2021-02-12 | 中国科学院上海高等研究院 | 一种用于二氧化碳一步加氢制备芳烃的催化剂及其制备方法和应用 |
WO2019236983A1 (en) * | 2018-06-08 | 2019-12-12 | Sabic Global Technologies B.V. | Method for conversion of methane to ethylene |
CN111170817B (zh) * | 2020-01-17 | 2022-09-23 | 太原理工大学 | 一种高稳定性和高选择性的甲醇制芳烃催化反应工艺 |
DE102020101054A1 (de) * | 2020-01-17 | 2021-07-22 | Linde Gmbh | Verfahren und Anlage zur Herstellung eines oder mehrerer Olefine |
US20230183587A1 (en) | 2020-06-01 | 2023-06-15 | Shell Usa, Inc. | A process and reactor for converting carbon dioxide into carbon monoxide, involving a catalyst |
CA3219199A1 (en) * | 2021-05-07 | 2022-11-10 | Enerkem Inc. | Optimizing carbon monoxide production from heterogeneous feedstock |
US11827521B2 (en) | 2021-12-14 | 2023-11-28 | Industrial Technology Research Institute | Method for selectively chemically reducing CO2 to form CO |
WO2024000397A1 (en) * | 2022-06-30 | 2024-01-04 | Bp P.L.C. | Integrated fischer-tropsch processes using nickel reverse water-gas shift catalysts |
WO2024000353A1 (en) * | 2022-06-30 | 2024-01-04 | Bp P.L.C. | Integrated fischer-tropsch processes using manganese reverse water-gas shift catalysts |
WO2024000343A1 (en) * | 2022-06-30 | 2024-01-04 | Bp P.L.C. | Nickel catalysts for reverse water-gas shift processes |
WO2024000381A1 (en) * | 2022-06-30 | 2024-01-04 | Bp P.L.C | Integrated fischer-tropsch processes using gold reverse water-gas shift catalysts |
WO2024000403A1 (en) * | 2022-06-30 | 2024-01-04 | Bp P.L.C. | Integrated fischer-tropsch processes using palladium and platinum reverse water-gas shift catalysts |
WO2024000370A1 (en) * | 2022-06-30 | 2024-01-04 | Bp P.L.C | Manganese catalysts for reverse water-gas shift processes |
WO2024003843A1 (en) * | 2022-06-30 | 2024-01-04 | Bp P.L.C. | Manganese catalysts for reverse water-gas shift and integrated fischer-tropsch processes |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS635034A (ja) * | 1986-06-26 | 1988-01-11 | Agency Of Ind Science & Technol | 一酸化炭素の変換方法 |
JP2000169411A (ja) * | 1998-12-08 | 2000-06-20 | Jgc Corp | ジメチルエーテルの製造装置及びその方法 |
JP2002324567A (ja) * | 2001-02-09 | 2002-11-08 | General Motors Corp <Gm> | 燃料電池システムで使用するための結合された水ガスシフト反応器/二酸化炭素吸着器 |
WO2005026093A1 (en) * | 2003-09-17 | 2005-03-24 | Korea Institute Of Science And Technology | Method for the production of dimethyl ether |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1719867A (en) * | 1925-04-27 | 1929-07-09 | Commercial Solvents Corp | Process for the production of carbon monoxide |
GB335632A (en) * | 1929-07-02 | 1930-10-02 | British Celanese | Improvements in or relating to the treatment of mixtures containing carbon dioxide and hydrogen for the purpose of reducing or eliminating hydrogen content, and to the formation of carbon monoxide therefrom |
US3479149A (en) | 1963-09-10 | 1969-11-18 | Mobil Oil Corp | Process for reducing carbon dioxide with hydrogen to carbon monoxide |
IT1065295B (it) * | 1976-12-23 | 1985-02-25 | Snam Progetti | Processo per la produzione di dimetil etere e catalizzatore utilizzabile in detto processo |
IT1169281B (it) * | 1981-12-02 | 1987-05-27 | Assoreni & Snamprogetti Spa | Sistema catalitico e procedimento per la produzione di miscele di metanolo ed alcoli superiori |
FR2546154B1 (fr) * | 1983-05-20 | 1986-11-07 | Rhone Poulenc Chim Base | Procede pour l'obtention de co a partir d'une source carbonee par reduction par l'hydrogene et dispositif pour sa mise en oeuvre et application |
GB2168718B (en) | 1984-10-29 | 1988-06-29 | Humphreys & Glasgow Ltd | Process for the production of synthesis gas and its utilisation |
US4654458A (en) * | 1985-09-26 | 1987-03-31 | Amoco Corporation | Conversion of a lower alkane |
US5068057A (en) * | 1989-06-12 | 1991-11-26 | Eastman Kodak Company | Conversion of carbon dioxide to carbon monoxide |
US5346679A (en) | 1991-08-15 | 1994-09-13 | Agency Of Industrial Science & Technology | Method for reduction of carbon dioxide, catalyst for the reduction, and method for production of the catalyst |
DK169615B1 (da) | 1992-12-10 | 1994-12-27 | Topsoe Haldor As | Fremgangsmåde til fremstilling af carbonmonoxidrig gas |
JP2847018B2 (ja) | 1993-06-25 | 1999-01-13 | 株式会社コスモ総合研究所 | 二酸化炭素還元反応触媒 |
MY131526A (en) * | 1993-12-27 | 2007-08-30 | Shell Int Research | A process for the preparation of carbon monoxide and/or hydrogen |
KR0138587B1 (ko) | 1994-08-19 | 1998-05-01 | 김은영 | 새로운 메탄올 합성방법 |
US6303092B1 (en) | 1995-04-10 | 2001-10-16 | Air Products And Chemicals, Inc. | Process for operating equilibrium controlled reactions |
EP1153660A3 (en) | 1997-06-18 | 2002-01-09 | ExxonMobil Chemical Patents Inc. | Conversion of synthesis gas to lower olefins using modified molecular sieves |
DE19929281A1 (de) * | 1999-06-25 | 2000-12-28 | Basf Ag | Verfahren und Katalysator zur Herstellung von C¶2¶-Oxygenaten aus Synthesegas |
FR2806073B1 (fr) | 2000-03-07 | 2002-06-07 | Air Liquide | Procede de production de monoxyde de carbone par retroconversion inverse avec un catalyseur adapte |
DE60100918T2 (de) | 2000-04-27 | 2004-05-13 | Haldor Topsoe A/S | Verfahren zur Herstellung eines wasserstoffreichen Gases |
WO2004058395A2 (en) * | 2002-12-20 | 2004-07-15 | Honda Giken Kogyo Kabushiki Kaisha | Platinum-ruthenium containing catalyst formulations for hydrogen generation |
ATE548324T1 (de) * | 2003-02-05 | 2012-03-15 | Haldor Topsoe As | Verfahren zur aufbereitung von synthesegas |
US7022306B1 (en) * | 2003-03-21 | 2006-04-04 | Uop Llc | Process for the production of hydrogen |
CA2539666C (en) * | 2005-03-24 | 2011-06-28 | University Of Regina | Catalysts for hydrogen production |
-
2008
- 2008-04-23 CN CN200880013889XA patent/CN101678329B/zh not_active Expired - Fee Related
- 2008-04-23 JP JP2010504530A patent/JP5592250B2/ja not_active Expired - Fee Related
- 2008-04-23 EA EA200901458A patent/EA016492B9/ru not_active IP Right Cessation
- 2008-04-23 US US12/450,818 patent/US8961829B2/en not_active Expired - Fee Related
- 2008-04-23 EP EP08735374.4A patent/EP2152409B1/en not_active Not-in-force
- 2008-04-23 WO PCT/EP2008/003258 patent/WO2008131898A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS635034A (ja) * | 1986-06-26 | 1988-01-11 | Agency Of Ind Science & Technol | 一酸化炭素の変換方法 |
JP2000169411A (ja) * | 1998-12-08 | 2000-06-20 | Jgc Corp | ジメチルエーテルの製造装置及びその方法 |
JP2002324567A (ja) * | 2001-02-09 | 2002-11-08 | General Motors Corp <Gm> | 燃料電池システムで使用するための結合された水ガスシフト反応器/二酸化炭素吸着器 |
WO2005026093A1 (en) * | 2003-09-17 | 2005-03-24 | Korea Institute Of Science And Technology | Method for the production of dimethyl ether |
Non-Patent Citations (1)
Title |
---|
JPN6013005955; Journal of Catalysis Vol.124, 1990, pp.73-85 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015044926A (ja) * | 2013-08-28 | 2015-03-12 | 独立行政法人産業技術総合研究所 | 炭化水素製造方法及び炭化水素製造装置 |
WO2019230854A1 (ja) * | 2018-05-29 | 2019-12-05 | 積水化学工業株式会社 | 触媒、二酸化炭素還元方法、及び二酸化炭素還元装置 |
US11305261B2 (en) | 2018-05-29 | 2022-04-19 | Sekisui Chemical Co., Ltd. | Catalyst, carbon dioxide reducing method, and apparatus for reducing carbon dioxide |
WO2021186663A1 (ja) * | 2020-03-19 | 2021-09-23 | 株式会社日立製作所 | 一酸化炭素製造装置及び一酸化炭素製造システム |
Also Published As
Publication number | Publication date |
---|---|
EA200901458A1 (ru) | 2010-04-30 |
EP2152409A1 (en) | 2010-02-17 |
US8961829B2 (en) | 2015-02-24 |
CN101678329B (zh) | 2013-09-18 |
JP5592250B2 (ja) | 2014-09-17 |
WO2008131898A1 (en) | 2008-11-06 |
CN101678329A (zh) | 2010-03-24 |
EP2152409B1 (en) | 2016-06-29 |
EA016492B9 (ru) | 2012-07-30 |
EA016492B1 (ru) | 2012-05-30 |
US20100190874A1 (en) | 2010-07-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5592250B2 (ja) | 二酸化炭素の合成ガスへの接触水素化 | |
JP5411133B2 (ja) | 二酸化炭素の合成ガスへの接触水素化 | |
Palma et al. | Enhancing Pt-Ni/CeO2 performances for ethanol reforming by catalyst supporting on high surface silica | |
US8962702B2 (en) | Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use | |
RU2516546C2 (ru) | Способ эксплуатации реактора для высокотемпературной конверсии | |
Seshan et al. | Carbon dioxide reforming of methane in the presence of nickel and platinum catalysts supported on ZrO2 | |
US20200269217A1 (en) | Perovskite metal oxide catalyst, in which metal ion is substituted, for reducing carbon deposition, preparation method therefor, and methane reforming reaction method using same | |
US20160332874A1 (en) | Method for carbon dioxide hydrogenation of syngas | |
EP3155070A1 (en) | Process for converting of methane stream reforming syngas with co2 | |
US9688593B2 (en) | Method for carbon dioxide hydrogenation of syngas and the integration of the process with syngas conversion processes | |
EP2607302B1 (en) | A method for producing hydrogen from ethanol | |
JP5531462B2 (ja) | 二酸化炭素改質用触媒、その製造方法、二酸化炭素改質用触媒の担体、改質器、および合成ガスの製造方法 | |
KR102092736B1 (ko) | 탄소 침적을 감소시킬 수 있는, 금속이온이 치환된 페로브스카이트 금속산화물 촉매의 제조 방법 및 이를 이용한 메탄 개질 반응 방법 | |
JPWO2005037962A1 (ja) | プロパンまたはブタンを主成分とする液化石油ガスの製造方法 | |
US20170157595A1 (en) | Novel catalyst for the water gas shift reaction | |
US20230242406A1 (en) | Method for producing carbon monoxide and apparatus used therefor | |
RU2677875C1 (ru) | Катализатор и способ получения обогащенной по водороду газовой смеси из диметилового эфира и воздуха | |
JP5242086B2 (ja) | 水素製造エタノール改質触媒及び水素製造方法 | |
JPH11300205A (ja) | 合成ガス製造用触媒及び合成ガスの製造方法 | |
REFORMING | CHAPTER THREE HYDROGEN PRODUCTION FROM ETHANOL STEAM REFORMING OVER SUPPORTED COBALT CATALYSTS | |
JP2009102209A (ja) | 水素製造方法、及びエタノール改質触媒 | |
JP2009101328A (ja) | エタノール改質触媒、及び水素製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20110323 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130204 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130212 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130502 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140304 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140604 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140701 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140731 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5592250 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |