JP2010510161A - 統合化学法 - Google Patents
統合化学法 Download PDFInfo
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Abstract
Description
Metz, B、Davidson, O、De Coninck H、Loos. M及びMeyer, L.(編集)、2006年、「Carbon Dioxide Capture and Storage - IPCC Special Report, UN Intergovernmental Panel on Climate Change」、ISBN92-9169-119-4、
Herzog, H.、2002年「Carbon Sequestration via Mineral Carbonation: Overview and Assessment」、2006年2月にアクセスされたhttp://sequestration.mit.edu/pdf/carbonates.pdf、
Huijgen, W.J.J及びComans, R.N.J.、2005年「Carbon dioxide sequestration by mineral carbonation-Literature Review Update 2003-2004」、ECN-C-05-022、
Lackner, K.S.、Grimes, P.及びZiock, H-J.、2001年「Capturing Carbon Dioxide From Air, 1st National Conference on Carbon Sequestration(2001年5月14〜17日、米国」、2006年1月にアクセスされたhttp://www.netl.doe.gov/publications/proceedings/01/carbon_seq/carbon_seq01.html、
O'Connor, W.K.、Dahlin, D.C.、Rush, G.E.、Gerdemann, S.J.、Penner, L.R.及びNilsen, D.N.、2005年「Aqueous Mineral Carbonation-Mineral Availability, Pre-treatment, Reaction Parametrics and Process Studies-Final Report」 DOE/ARC-TR-04-002、Albany Research Center、米国エネルギー省、
ZECA社、2006年「Overview - carbon dioxide」、2006年3月にアクセスされたhttp://www.zeca.org/overview/carbon dioxide.html.
Rau及びCaldeiraによる米国特許出願公開第2001/0022952号明細書「Method and Apparatus for Extracting and Sequestering Carbon Dioxide」、
Geerlings、Mesters及びOosterbeekの米国特許出願公開第2004/0131531号明細書「Process for Mineral Carbonation with Carbon Dioxide」、
Geerlings及びWeskerによる米国特許出願公開第2004/0126293号明細書「Process for Removal of Carbon Dioxide from Flue Gases」、
Blencoe、Palmer、Anovitz及びBeardによる米国特許出願公開第2004/0213705号明細書「Carbonation of Metal Silicates for long-term CO2 Sequestration」、
Dziedic、Gross、Gorski及びJohnsonによる米国特許出願公開第2004/0219090号明細書「Sequestration of Carbon Dioxide」、
Park及びFanによる米国特許出願公開第2005/0180910号明細書「Carbon Dioxide Sequestration using Alkaline Earth Metal-Bearing Minerals」。
Claims (28)
- 二酸化炭素とアルカリ金属又はアルカリ土類金属ケイ酸塩原料との反応により対応するアルカリ金属又はアルカリ土類金属炭酸塩を形成する、二酸化炭素を固化するための方法であって、燃料の燃焼によりアルカリ金属又はアルカリ土類金属ケイ酸塩原料を直接熱活性化して、活性化された原料を製造する工程、活性化された原料を溶媒スラリー中に懸濁する工程、及び活性化された原料を二酸化炭素と接触させて、二酸化炭素を転化してアルカリ金属又はアルカリ土類金属炭酸塩を形成する工程を含む方法。
- 燃料の燃焼によるアルカリ金属又はアルカリ土類金属ケイ酸塩原料の直接熱活性化が、炉、窯若しくは類似の燃焼チャンバ又は加熱容器で起こる、請求項1に記載の方法。
- 燃料の燃焼による直接熱活性化の前に、二酸化炭素と活性化された原料との反応から放出された熱及び/又は連結した炭素又は炭化水素燃料の燃焼、ガス化又は改質工程から生じた低級の若しくは廃熱を用いて、アルカリ金属又はアルカリ土類金属原料が予熱される、請求項1又は2に記載の方法。
- 原料の直接熱活性化が、前記原料の温度を約580〜800℃の温度に上げて維持することにより行なわれる、請求項1〜3のいずれか1項に記載の方法。
- 原料が、その加熱中に原料を回転及び/又は攪拌できるように構成された加熱容器内で加熱され、脱水酸化及び活性化を助長する、請求項1〜4のいずれか1項に記載の方法。
- 原料が、1個以上の実質的に垂直なチャンバを含む垂直軸構造の加熱容器内で加熱され、そして原料が、燃料の燃焼により生じたガスに対して向流で充填されて流れる、請求項1〜5のいずれか1項に記載の方法。
- 原料が、適切に構成された加熱容器内の燃料燃焼チャンバからの放射、伝導又は対流によって、燃料の燃焼ガスから隔離されて加熱される、請求項1〜6のいずれか1項に記載の方法。
- アルカリ又はアルカリ土類金属ケイ酸塩原料が、パイプ又は容器中を、加熱容器を通して流体媒体によって輸送され、流体媒体がガス又は液体のいずれかである、請求項2に記載の方法。
- 原料が微粉砕されて、原料平均粒径を約200μm未満に減らす、請求項1〜8のいずれか1項に記載の方法。
- 直接熱活性化の前及び/又は後に、活性化された原料を、弱酸性水溶液又は混合水溶液及び/又は食塩水又は二酸化炭素と混和できる他の溶媒内に懸濁させる、請求項1〜9のいずれか1項に記載の方法。
- 溶媒が、水、例えば酢酸、シュウ酸、アスコルビン酸、フタル酸、オルトリン酸、クエン酸、ギ酸のような弱酸又はそのような弱酸の塩溶液、食塩水、食塩及び重炭酸ナトリウム水溶液、重炭酸カリウム溶液、エタノール若しくはメタノール水溶液などの水及びアルコール混合溶液、水及びグリコール混合溶液、水及びグリセロール混合溶液の任意の1種以上から選択される、請求項10に記載の方法。
- 活性化された原料が、弱酸を含む水性溶媒流と混ぜられて、さらに直接熱活性化工程後に湿式粉砕工程で75μm未満の粒径に微粉砕される、請求項1〜11のいずれか1項に記載の方法。
- 活性化された原料を、超臨界の、液化された又は高圧の二酸化炭素ガスと接触させて、二酸化炭素をアルカリ金属又はアルカリ土類金属炭酸塩に実質的に転化する、請求項1〜12のいずれか1項に記載の方法。
- 二酸化炭素及び活性化された原料を、高乱流又は高速分散又は磨砕条件を作れるように構成された反応容器内で接触させて、二酸化炭素をアルカリ金属又はアルカリ土類金属炭酸塩に速く及び実質的に転化する、請求項1〜13のいずれか1項に記載の方法。
- 二酸化炭素が、炭素燃料燃焼工程、炭化水素燃料燃焼工程、又は炭化水素ガス化工程若しくは改質工程からの排出物から生じる、請求項1〜14のいずれか1項に記載の方法。
- 二酸化炭素が、石炭、石油又は天然ガスを燃料とする発電による燃焼排出物から生じる、請求項15に記載の方法。
- 二酸化炭素ガスが、アンモニア製造プラントから生じる、請求項1〜16のいずれか1項に記載の方法。
- 二酸化炭素ガスが、ポルトランド(Portland)セメント製造プラントから生じる、請求項1〜17のいずれか1項に記載の方法。
- 二酸化炭素が、再生可能バイオマス由来の少なくとも20%の燃料の酸化から生じる、請求項1〜18のいずれか1項に記載の方法。
- 燃料が、再生可能バイオマスから生じた少なくとも20%の燃料を含む、請求項1〜19のいずれか1項に記載の方法。
- アルカリ金属又はアルカリ土類金属原料が、蛇紋石若しくはその多形体、アンチゴライト、リザルダイト若しくはクリソタイル、かんらん石、苦土かんらん石、水滑石、ダナイト、かんらん岩、珪灰石、滑石、ハルツバージャイト、又はこれらの任意の2種以上の混合物を含む、請求項1〜20のいずれか1項に記載の方法。
- 次の炭酸塩中への固化を簡略化するために、酸素を多く含む流れを加えることにより燃料の燃焼を行なって、二酸化炭素及び水蒸気を発生させる、請求項1〜21のいずれか1項に記載の方法。
- アルカリ金属又はアルカリ土類金属原料を破砕器内で破砕し、そして連結した発電プラントによって作られた電気エネルギーを引き出す微粉砕回路のミル内で粉砕する、請求項1〜22のいずれか1項に記載の方法。
- 二酸化炭素が希釈流であるか、又は大気から直接引かれている、請求項1〜12のいずれか1項に記載の方法。
- 二酸化炭素が、活性化された原料を含む開放地、スラリーダム、ストックパイル若しくは類似の通気構造体又は堆積浸出配列の系内で、活性化された原料と接触させられる、請求項24に記載の方法。
- スプレー、アトマイザー又はチャネルが、活性化された原料を含む開放地、スラリーダム、ストックパイル若しくは類似の通気構造体又は堆積浸出配列の系を通して水流を分配するのに使用される、請求項25に記載の方法。
- 二酸化炭素と活性化された原料との反応により生成した炭酸塩が、系から定期的に除去される、請求項26に記載の方法。
- 酵素触媒を水流に加えて炭酸の形成を促進する、請求項26に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2006906519A AU2006906519A0 (en) | 2006-11-22 | Process for solidification of carbon dioxide | |
AU2006906519 | 2006-11-22 | ||
AU2007901812 | 2007-04-04 | ||
AU2007901812A AU2007901812A0 (en) | 2007-04-04 | Process for sequestration of carbon dioxide | |
PCT/AU2007/001790 WO2008061305A1 (en) | 2006-11-22 | 2007-11-21 | Integrated chemical process |
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JP2010510161A true JP2010510161A (ja) | 2010-04-02 |
JP5313911B2 JP5313911B2 (ja) | 2013-10-09 |
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JP2009537449A Active JP5313911B2 (ja) | 2006-11-22 | 2007-11-21 | 統合化学法 |
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US (2) | US9566550B2 (ja) |
EP (1) | EP2097164B1 (ja) |
JP (1) | JP5313911B2 (ja) |
KR (1) | KR101464010B1 (ja) |
AU (2) | AU2007324344B2 (ja) |
CA (1) | CA2670299C (ja) |
MX (1) | MX2009005386A (ja) |
RU (1) | RU2446871C2 (ja) |
TR (1) | TR201909630T4 (ja) |
WO (1) | WO2008061305A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2013505124A (ja) * | 2009-09-18 | 2013-02-14 | アリゾナ・ボード・オブ・リージェンツ・フォー・アンド・オン・ビハーフ・オブ・アリゾナ・ステイト・ユニバーシティー | 含水鉱物の高温処理 |
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TR201909630T4 (tr) | 2019-07-22 |
KR20090102760A (ko) | 2009-09-30 |
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EP2097164A1 (en) | 2009-09-09 |
US9855526B2 (en) | 2018-01-02 |
CA2670299A1 (en) | 2008-05-29 |
AU2010100761B4 (en) | 2010-09-30 |
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CA2670299C (en) | 2015-06-16 |
RU2009123510A (ru) | 2010-12-27 |
AU2010100761A4 (en) | 2010-08-12 |
MX2009005386A (es) | 2009-06-26 |
EP2097164A4 (en) | 2012-04-11 |
US9566550B2 (en) | 2017-02-14 |
US20090305378A1 (en) | 2009-12-10 |
RU2446871C2 (ru) | 2012-04-10 |
JP5313911B2 (ja) | 2013-10-09 |
US20170151530A1 (en) | 2017-06-01 |
EP2097164B1 (en) | 2019-04-17 |
WO2008061305A1 (en) | 2008-05-29 |
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