JP2010285694A5 - - Google Patents
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- Publication number
- JP2010285694A5 JP2010285694A5 JP2010167345A JP2010167345A JP2010285694A5 JP 2010285694 A5 JP2010285694 A5 JP 2010285694A5 JP 2010167345 A JP2010167345 A JP 2010167345A JP 2010167345 A JP2010167345 A JP 2010167345A JP 2010285694 A5 JP2010285694 A5 JP 2010285694A5
- Authority
- JP
- Japan
- Prior art keywords
- potential
- molten electrolyte
- cathode
- reference electrode
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003792 electrolyte Substances 0.000 claims 22
- 229910052751 metal Inorganic materials 0.000 claims 15
- 239000002184 metal Substances 0.000 claims 15
- 239000012528 membrane Substances 0.000 claims 13
- 238000000034 method Methods 0.000 claims 11
- 150000001768 cations Chemical class 0.000 claims 9
- 150000002500 ions Chemical class 0.000 claims 6
- 150000002739 metals Chemical class 0.000 claims 5
- 239000007784 solid electrolyte Substances 0.000 claims 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 3
- 229910044991 metal oxide Inorganic materials 0.000 claims 3
- 150000004706 metal oxides Chemical class 0.000 claims 3
- 239000011651 chromium Substances 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- 239000010931 gold Substances 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- 239000011572 manganese Substances 0.000 claims 2
- 238000005259 measurement Methods 0.000 claims 2
- 229910001507 metal halide Inorganic materials 0.000 claims 2
- 150000005309 metal halides Chemical class 0.000 claims 2
- 229910052976 metal sulfide Inorganic materials 0.000 claims 2
- 229910002076 stabilized zirconia Inorganic materials 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims 1
- 229910001634 calcium fluoride Inorganic materials 0.000 claims 1
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 238000000691 measurement method Methods 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 229910052761 rare earth metal Inorganic materials 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000002893 slag Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3468797P | 1997-01-06 | 1997-01-06 | |
| US60/034,687 | 1997-01-06 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP53115398A Division JP4689773B2 (ja) | 1997-01-06 | 1998-01-06 | 金属抽出法及び金属抽出装置 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010285694A JP2010285694A (ja) | 2010-12-24 |
| JP2010285694A5 true JP2010285694A5 (cg-RX-API-DMAC7.html) | 2011-02-10 |
| JP5203426B2 JP5203426B2 (ja) | 2013-06-05 |
Family
ID=21877977
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP53115398A Expired - Lifetime JP4689773B2 (ja) | 1997-01-06 | 1998-01-06 | 金属抽出法及び金属抽出装置 |
| JP2010167345A Expired - Lifetime JP5203426B2 (ja) | 1997-01-06 | 2010-07-26 | 金属種の組成及び輸送特性の測定方法及び装置 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP53115398A Expired - Lifetime JP4689773B2 (ja) | 1997-01-06 | 1998-01-06 | 金属抽出法及び金属抽出装置 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5976345A (cg-RX-API-DMAC7.html) |
| EP (1) | EP0951586A2 (cg-RX-API-DMAC7.html) |
| JP (2) | JP4689773B2 (cg-RX-API-DMAC7.html) |
| AU (1) | AU5734898A (cg-RX-API-DMAC7.html) |
| CA (1) | CA2277847C (cg-RX-API-DMAC7.html) |
| NO (1) | NO993345L (cg-RX-API-DMAC7.html) |
| WO (1) | WO1998030738A2 (cg-RX-API-DMAC7.html) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5976345A (en) * | 1997-01-06 | 1999-11-02 | Boston University | Method and apparatus for metal extraction and sensor device related thereto |
| GB9810305D0 (en) * | 1998-05-15 | 1998-07-15 | Foseco Int | Method and apparatus for the treatment of a melt |
| AUPR602901A0 (en) * | 2001-06-29 | 2001-07-26 | Bhp Innovation Pty Ltd | Removal of oxygen from metals oxides and solid metal solutions |
| AUPR737401A0 (en) * | 2001-08-30 | 2001-09-20 | Technological Resources Pty Limited | Method and apparatus for generating hydrogen gas |
| US6540902B1 (en) * | 2001-09-05 | 2003-04-01 | The United States Of America As Represented By The United States Department Of Energy | Direct electrochemical reduction of metal-oxides |
| JP2005510630A (ja) * | 2001-11-22 | 2005-04-21 | キューアイティー−フェル エ チタン インク． | 液体状態の化合物を含む酸化チタンからチタン金属又は合金を電解採取する方法 |
| AUPS107102A0 (en) * | 2002-03-13 | 2002-04-11 | Bhp Billiton Innovation Pty Ltd | Electrolytic reduction of metal oxides |
| AU2002952083A0 (en) * | 2002-10-16 | 2002-10-31 | Bhp Billiton Innovation Pty Ltd | Minimising carbon transfer in an electrolytic cell |
| RU2334024C2 (ru) * | 2002-12-12 | 2008-09-20 | Би Эйч Пи БИЛЛИТОН ИННОВЕЙШН ПТИ ЛТД | Электрохимическое восстановление оксидов металлов |
| FI119400B (fi) * | 2003-03-14 | 2008-10-31 | Outotec Oyj | Menetelmä prosessin säätämiseksi |
| EP1814646A2 (en) * | 2004-11-23 | 2007-08-08 | Trustees Of Boston University | Composite mixed oxide ionic and electronic conductors for hydrogen separation |
| JP4252531B2 (ja) * | 2004-12-15 | 2009-04-08 | 株式会社大阪チタニウムテクノロジーズ | 金属製造方法 |
| WO2006138611A2 (en) | 2005-06-16 | 2006-12-28 | Trustees Of Boston University | Waste to hydrogen conversion process and related apparatus |
| US8658007B2 (en) * | 2005-07-15 | 2014-02-25 | The Trustees Of Boston University | Oxygen-producing inert anodes for SOM process |
| EP1954379A2 (en) * | 2005-09-29 | 2008-08-13 | Trustees Of Boston University | Mixed ionic and electronic conducting membrane |
| EP1999286B1 (en) * | 2006-03-10 | 2017-04-19 | Elkem AS | Method for electrolytic production and refining of silicon |
| NO20063072L (no) * | 2006-03-10 | 2007-09-11 | Elkem As | Fremgangsmate for elektrolytisk raffinering av metaller |
| US7901561B2 (en) * | 2006-03-10 | 2011-03-08 | Elkem As | Method for electrolytic production and refining of metals |
| US20080023321A1 (en) * | 2006-07-31 | 2008-01-31 | Donald Sadoway | Apparatus for electrolysis of molten oxides |
| US20100288649A1 (en) * | 2006-10-11 | 2010-11-18 | Pal Uday B | Magnesiothermic som process for production of metals |
| RU2383014C1 (ru) * | 2008-09-29 | 2010-02-27 | Государственное образовательное учреждение высшего профессионального образования "Алтайский государственный университет" | Экстракционно-вольтамперометрический способ определения цинка, кадмия, свинца и меди в природных водах |
| RU2382355C1 (ru) * | 2008-10-07 | 2010-02-20 | Государственное образовательное учреждение высшего профессионального образования "Алтайский государственный университет" | Экстракционно-вольтамперометрический способ определения цинка, кадмия, свинца, меди и железа в твердых образцах природных объектов |
| US8460535B2 (en) * | 2009-04-30 | 2013-06-11 | Infinium, Inc. | Primary production of elements |
| US8852419B2 (en) | 2009-10-02 | 2014-10-07 | Infinium, Inc. | Method and apparatus for recycling high-vapor pressure, low-electronegativity metals |
| US8377408B2 (en) | 2010-04-20 | 2013-02-19 | High Temperature Physics, Llc | Process for the production of carbon nanoparticles and sequestration of carbon |
| DE102010041019A1 (de) * | 2010-09-20 | 2012-03-22 | Siemens Aktiengesellschaft | Wiederaufladbare Energiespeichereinheit |
| US8420042B2 (en) | 2010-09-21 | 2013-04-16 | High Temperature Physics, Llc | Process for the production of carbon graphenes and other nanomaterials |
| US9562296B2 (en) | 2010-11-02 | 2017-02-07 | I'msep Co., Ltd. | Production method for silicon nanoparticles |
| US9255337B2 (en) * | 2010-12-05 | 2016-02-09 | Infinium, Inc. | Methods and apparatus for processing of rare earth metal ore |
| CN102043009B (zh) * | 2010-12-14 | 2013-10-30 | 沈阳工业大学 | 电解法采集不锈钢样品并测定铬镍锰硅含量的装置和方法 |
| US9260308B2 (en) | 2011-04-19 | 2016-02-16 | Graphene Technologies, Inc. | Nanomaterials and process for making the same |
| JP5829843B2 (ja) * | 2011-06-24 | 2015-12-09 | 株式会社エプシロン | 多結晶シリコンの製造方法及び多結晶シリコンの製造方法に用いられる還元・電解炉 |
| US8617457B2 (en) | 2011-07-08 | 2013-12-31 | Infinium, Inc. | Apparatus and method for condensing metal vapor |
| WO2013028798A1 (en) | 2011-08-22 | 2013-02-28 | Metal Oxygen Separtation Technologies, Inc. | Liquid anodes and fuels for production of metals from their oxides by molten salt electrolysis with a solid electrolyte |
| CA2883430C (en) | 2011-09-01 | 2019-10-29 | Infinium, Inc. | Conductor of high electrical current at high temperature in oxygen and liquid metal environment |
| WO2013052753A1 (en) | 2011-10-07 | 2013-04-11 | Metal Oxygen Separation Technologies, Inc. | Methods and apparatuses for efficient metals production and distillation with oxide electrolysis |
| WO2014004610A1 (en) | 2012-06-27 | 2014-01-03 | Arizona Board Of Regents, A Body Corporate Of The State Of Arizona, Acting For And On Behalf Of Arizona State University | System and method for electrorefining of silicon |
| GB201223375D0 (en) * | 2012-12-24 | 2013-02-06 | Metalysis Ltd | Method and apparatus for producing metal by electrolytic reduction |
| US10087539B2 (en) | 2013-06-12 | 2018-10-02 | Infinium, Inc. | Liquid metal electrodes for gas separation |
| WO2014201207A2 (en) * | 2013-06-14 | 2014-12-18 | Arizona Board Of Regents, A Body Corporate Of The State Of Arizona, Acting For And On Behalf Of Arizona State University | System and method for purification of electrolytic salt |
| DE102013211922A1 (de) * | 2013-06-24 | 2014-12-24 | Siemens Aktiengesellschaft | Vorrichtung zur Reduktion eines Metallions aus einer Salzschmelze |
| KR101556774B1 (ko) | 2014-08-20 | 2015-10-05 | 서울대학교산학협력단 | 전해채취법을 이용한 티타늄의 제조방법 |
| US20160108532A1 (en) * | 2014-10-17 | 2016-04-21 | Infinium, Inc. | Method and apparatus for liquid metal electrode connection in production or refining of metals |
| AU2016343928B2 (en) * | 2015-10-30 | 2021-01-28 | Biosense Webster (Israel) Ltd. | Foldable 2-D CMUT-on-CMOS arrays |
| RU2684091C1 (ru) * | 2018-06-06 | 2019-04-03 | федеральное государственное бюджетное образовательное учреждение высшего образования "Алтайский государственный университет" | Способ экстрагирования неорганических форм цинка, кадмия, свинца и меди из твердых образцов природных объектов |
| CN109763147B (zh) * | 2019-03-28 | 2020-11-06 | 乌海三美国际矿业有限公司 | 一种锰合金生产设备 |
| JP7377633B2 (ja) * | 2019-06-21 | 2023-11-10 | 三菱重工業株式会社 | 電解製錬炉 |
| JP7303037B2 (ja) * | 2019-06-21 | 2023-07-04 | 三菱重工業株式会社 | 電解製錬システム |
| US11549882B2 (en) * | 2020-02-21 | 2023-01-10 | The Regents Of The University Of Michigan | Reference electrode and electrochemical monitoring system |
| JP7334710B2 (ja) * | 2020-11-02 | 2023-08-29 | 株式会社豊田中央研究所 | 発電装置および発電方法 |
| KR102306152B1 (ko) * | 2021-03-19 | 2021-09-28 | 한국지질자원연구원 | 산소센서를 이용한 금속산화물의 용해도 분석방법, 산소센서를 이용한 금속산화물의 용해도 분석장치, 산소센서를 이용한 금속제련장치 및 산소센서를 이용한 금속제련방법 |
| US20230131891A1 (en) | 2021-10-25 | 2023-04-27 | Airbus Defence and Space GmbH | Method And System For Extracting Metal And Oxygen From Powdered Metal Oxides |
| US11987893B2 (en) | 2021-10-25 | 2024-05-21 | Airbus Defence and Space GmbH | System and method for extracting oxygen from powdered metal oxides |
| CA3266621A1 (en) * | 2022-09-09 | 2024-03-14 | Phoenix Tailings, Inc. | Molten salt electrolytic cell and associated systems and processes |
| US20250135430A1 (en) | 2023-11-01 | 2025-05-01 | Airbus Defence and Space GmbH | Reactor Device for Converting Powdered Metal Oxides and Conversion System Comprising Same |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH441776A (de) | 1966-05-17 | 1967-08-15 | Marincek Borut | Verfahren zur Herstellung von Metallen durch Schmelzflusselektrolyse von Oxiden |
| US3692645A (en) | 1967-05-15 | 1972-09-19 | Alusuisse | Electrolytic process |
| US4108743A (en) * | 1977-05-02 | 1978-08-22 | Ford Motor Company | Method and apparatus for separating a metal from a salt thereof |
| JPS57116798A (en) * | 1981-01-13 | 1982-07-20 | Nippon Steel Corp | Control method for continuous electroplating |
| CA1203950A (en) * | 1982-12-23 | 1986-04-29 | Harold S. Cox | Anti-static articles |
| JPS60187693A (ja) * | 1984-03-07 | 1985-09-25 | Mitsubishi Chem Ind Ltd | チタン電解槽 |
| US4804448A (en) * | 1987-06-24 | 1989-02-14 | Eltron Research, Inc. | Apparatus for simultaneous generation of alkali metal species and oxygen gas |
| US4908113A (en) * | 1987-09-01 | 1990-03-13 | Institute Of Gas Technology | Apparatus for the electrochemical separation of oxygen |
| US4865925A (en) * | 1987-12-14 | 1989-09-12 | Hughes Aircraft Company | Gas permeable electrode for electrochemical system |
| CA2012009C (en) * | 1989-03-16 | 1999-01-19 | Tadashi Ogasawara | Process for the electrolytic production of magnesium |
| US4995948A (en) * | 1989-07-24 | 1991-02-26 | The United States Of America As Represented By The United States Department Of Energy | Apparatus and process for the electrolytic reduction of uranium and plutonium oxides |
| JPH03115592A (ja) * | 1989-09-28 | 1991-05-16 | Osaka Titanium Co Ltd | 溶融塩電解槽 |
| US5380467A (en) * | 1992-03-19 | 1995-01-10 | Westinghouse Electric Company | Composition for extracting oxygen from fluid streams |
| DE4241150C1 (de) * | 1992-12-07 | 1994-06-01 | Fraunhofer Ges Forschung | Elektrodenmembran-Verbund, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| US5312525A (en) * | 1993-01-06 | 1994-05-17 | Massachusetts Institute Of Technology | Method for refining molten metals and recovering metals from slags |
| US5547494A (en) * | 1995-03-22 | 1996-08-20 | Praxair Technology, Inc. | Staged electrolyte membrane |
| US5976345A (en) * | 1997-01-06 | 1999-11-02 | Boston University | Method and apparatus for metal extraction and sensor device related thereto |
-
1998
- 1998-01-05 US US09/002,581 patent/US5976345A/en not_active Expired - Lifetime
- 1998-01-06 JP JP53115398A patent/JP4689773B2/ja not_active Expired - Lifetime
- 1998-01-06 WO PCT/US1998/000456 patent/WO1998030738A2/en not_active Ceased
- 1998-01-06 CA CA002277847A patent/CA2277847C/en not_active Expired - Lifetime
- 1998-01-06 EP EP98901219A patent/EP0951586A2/en not_active Withdrawn
- 1998-01-06 AU AU57348/98A patent/AU5734898A/en not_active Abandoned
-
1999
- 1999-07-06 NO NO993345A patent/NO993345L/no unknown
- 1999-08-03 US US09/368,308 patent/US6299742B1/en not_active Expired - Lifetime
-
2010
- 2010-07-26 JP JP2010167345A patent/JP5203426B2/ja not_active Expired - Lifetime
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