JP2010111846A - 接着剤組成物、回路接続用接着剤及び回路接続体 - Google Patents
接着剤組成物、回路接続用接着剤及び回路接続体 Download PDFInfo
- Publication number
- JP2010111846A JP2010111846A JP2009157712A JP2009157712A JP2010111846A JP 2010111846 A JP2010111846 A JP 2010111846A JP 2009157712 A JP2009157712 A JP 2009157712A JP 2009157712 A JP2009157712 A JP 2009157712A JP 2010111846 A JP2010111846 A JP 2010111846A
- Authority
- JP
- Japan
- Prior art keywords
- circuit
- adhesive
- adhesive composition
- group
- meth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 159
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 159
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 150000001875 compounds Chemical class 0.000 claims abstract description 32
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 28
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims abstract description 12
- 239000004202 carbamide Substances 0.000 claims abstract description 11
- 125000005370 alkoxysilyl group Chemical group 0.000 claims abstract description 8
- 239000007870 radical polymerization initiator Substances 0.000 claims abstract description 8
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 7
- -1 vinyl compound Chemical class 0.000 claims description 45
- 239000002245 particle Substances 0.000 claims description 42
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 11
- 239000004065 semiconductor Substances 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical class [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 39
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 33
- 239000010408 film Substances 0.000 description 30
- 239000000047 product Substances 0.000 description 24
- 238000001723 curing Methods 0.000 description 23
- 238000010438 heat treatment Methods 0.000 description 21
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 16
- 239000000758 substrate Substances 0.000 description 14
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000011347 resin Substances 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 239000011521 glass Substances 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 238000013329 compounding Methods 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000005060 rubber Substances 0.000 description 8
- 229910052581 Si3N4 Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 7
- 229920000459 Nitrile rubber Polymers 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 239000004642 Polyimide Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- 239000004973 liquid crystal related substance Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002923 metal particle Substances 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 229920001721 polyimide Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- LVNLBBGBASVLLI-UHFFFAOYSA-N 3-triethoxysilylpropylurea Chemical compound CCO[Si](OCC)(OCC)CCCNC(N)=O LVNLBBGBASVLLI-UHFFFAOYSA-N 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229920006287 phenoxy resin Polymers 0.000 description 3
- 239000013034 phenoxy resin Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- NLBJAOHLJABDAU-UHFFFAOYSA-N (3-methylbenzoyl) 3-methylbenzenecarboperoxoate Chemical compound CC1=CC=CC(C(=O)OOC(=O)C=2C=C(C)C=CC=2)=C1 NLBJAOHLJABDAU-UHFFFAOYSA-N 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- CRJIYMRJTJWVLU-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-yl 3-(5,5-dimethylhexyl)dioxirane-3-carboxylate Chemical compound CC(C)(C)CCCCC1(C(=O)OC(C)(C)CC(C)(C)C)OO1 CRJIYMRJTJWVLU-UHFFFAOYSA-N 0.000 description 2
- DPGYCJUCJYUHTM-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-yloxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)CC(C)(C)C DPGYCJUCJYUHTM-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- IFXDUNDBQDXPQZ-UHFFFAOYSA-N 2-methylbutan-2-yl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CC IFXDUNDBQDXPQZ-UHFFFAOYSA-N 0.000 description 2
- UDXXYUDJOHIIDZ-UHFFFAOYSA-N 2-phosphonooxyethyl prop-2-enoate Chemical compound OP(O)(=O)OCCOC(=O)C=C UDXXYUDJOHIIDZ-UHFFFAOYSA-N 0.000 description 2
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 2
- LVACOMKKELLCHJ-UHFFFAOYSA-N 3-trimethoxysilylpropylurea Chemical compound CO[Si](OC)(OC)CCCNC(N)=O LVACOMKKELLCHJ-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 230000003685 thermal hair damage Effects 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- RPNDKNJEUSJAMT-UHFFFAOYSA-N (2,2,3,3-tetramethylpiperidin-1-yl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)ON1CCCC(C)(C)C1(C)C RPNDKNJEUSJAMT-UHFFFAOYSA-N 0.000 description 1
- FVQMJJQUGGVLEP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)C FVQMJJQUGGVLEP-UHFFFAOYSA-N 0.000 description 1
- HCXVPNKIBYLBIT-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOOC(C)(C)C HCXVPNKIBYLBIT-UHFFFAOYSA-N 0.000 description 1
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- MVELOSYXCOVILT-UHFFFAOYSA-N (4-hydroxy-2-methylpentan-2-yl) 7,7-dimethyloctaneperoxoate Chemical compound CC(O)CC(C)(C)OOC(=O)CCCCCC(C)(C)C MVELOSYXCOVILT-UHFFFAOYSA-N 0.000 description 1
- NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- BLKRGXCGFRXRNQ-SNAWJCMRSA-N (z)-3-carbonoperoxoyl-4,4-dimethylpent-2-enoic acid Chemical compound OC(=O)/C=C(C(C)(C)C)\C(=O)OO BLKRGXCGFRXRNQ-SNAWJCMRSA-N 0.000 description 1
- ONILJRYQYWLXQU-UHFFFAOYSA-N 1,1-dioctyl-3-(3-triethoxysilylpropyl)urea Chemical compound CCCCCCCCN(CCCCCCCC)C(=O)NCCC[Si](OCC)(OCC)OCC ONILJRYQYWLXQU-UHFFFAOYSA-N 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- HTHSRWGCXUDZTR-UHFFFAOYSA-N 1-(1-phenylethyl)-3-(3-triethoxysilylpropyl)urea Chemical compound CCO[Si](OCC)(OCC)CCCNC(=O)NC(C)C1=CC=CC=C1 HTHSRWGCXUDZTR-UHFFFAOYSA-N 0.000 description 1
- FQOYZQDJLOORSU-UHFFFAOYSA-N 1-(1-phenylethyl)-3-(3-trimethoxysilylpropyl)urea Chemical compound C1(=CC=CC=C1)C(C)NC(=O)NCCC[Si](OC)(OC)OC FQOYZQDJLOORSU-UHFFFAOYSA-N 0.000 description 1
- ZVEMLYIXBCTVOF-UHFFFAOYSA-N 1-(2-isocyanatopropan-2-yl)-3-prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC(C(C)(C)N=C=O)=C1 ZVEMLYIXBCTVOF-UHFFFAOYSA-N 0.000 description 1
- QUMXDOLUJCHOAY-UHFFFAOYSA-N 1-Phenylethyl acetate Chemical compound CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 description 1
- JYNPNMTWKNWIDI-UHFFFAOYSA-N 1-benzyl-3-(3-trimethoxysilylpropyl)urea Chemical compound CO[Si](CCCNC(=O)NCc1ccccc1)(OC)OC JYNPNMTWKNWIDI-UHFFFAOYSA-N 0.000 description 1
- PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical group CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 1
- OZFIGURLAJSLIR-UHFFFAOYSA-N 1-ethenyl-2h-pyridine Chemical compound C=CN1CC=CC=C1 OZFIGURLAJSLIR-UHFFFAOYSA-N 0.000 description 1
- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 1
- VLQQNGTYOSEZQL-UHFFFAOYSA-N 1-tert-butylperoxyethyl hexyl carbonate Chemical compound CCCCCCOC(=O)OC(C)OOC(C)(C)C VLQQNGTYOSEZQL-UHFFFAOYSA-N 0.000 description 1
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 1
- JVNHNXXTIIQWBZ-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2,3-dimethylbutanenitrile Chemical compound CC(C)C(C)(C#N)N=NC(C)(C)C#N JVNHNXXTIIQWBZ-UHFFFAOYSA-N 0.000 description 1
- IEMBFTKNPXENSE-UHFFFAOYSA-N 2-(2-methylpentan-2-ylperoxy)propan-2-yl hydrogen carbonate Chemical compound CCCC(C)(C)OOC(C)(C)OC(O)=O IEMBFTKNPXENSE-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- XKBHBVFIWWDGQX-UHFFFAOYSA-N 2-bromo-3,3,4,4,5,5,5-heptafluoropent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(Br)=C XKBHBVFIWWDGQX-UHFFFAOYSA-N 0.000 description 1
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- DPNXHTDWGGVXID-UHFFFAOYSA-N 2-isocyanatoethyl prop-2-enoate Chemical compound C=CC(=O)OCCN=C=O DPNXHTDWGGVXID-UHFFFAOYSA-N 0.000 description 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- ZIDNXYVJSYJXPE-UHFFFAOYSA-N 2-methylbutan-2-yl 7,7-dimethyloctaneperoxoate Chemical compound CCC(C)(C)OOC(=O)CCCCCC(C)(C)C ZIDNXYVJSYJXPE-UHFFFAOYSA-N 0.000 description 1
- HDCMRFUDMYGBFU-UHFFFAOYSA-N 2-methylbutan-2-yl 7-methyloctaneperoxoate Chemical compound CCC(C)(C)OOC(=O)CCCCCC(C)C HDCMRFUDMYGBFU-UHFFFAOYSA-N 0.000 description 1
- RFSCGDQQLKVJEJ-UHFFFAOYSA-N 2-methylbutan-2-yl benzenecarboperoxoate Chemical compound CCC(C)(C)OOC(=O)C1=CC=CC=C1 RFSCGDQQLKVJEJ-UHFFFAOYSA-N 0.000 description 1
- YMMLZUQDXYPNOG-UHFFFAOYSA-N 2-methylpentan-2-yl 7,7-dimethyloctaneperoxoate Chemical compound CCCC(C)(C)OOC(=O)CCCCCC(C)(C)C YMMLZUQDXYPNOG-UHFFFAOYSA-N 0.000 description 1
- WXDJDZIIPSOZAH-UHFFFAOYSA-N 2-methylpentan-2-yl benzenecarboperoxoate Chemical compound CCCC(C)(C)OOC(=O)C1=CC=CC=C1 WXDJDZIIPSOZAH-UHFFFAOYSA-N 0.000 description 1
- KPKMKACZPZUNDP-UHFFFAOYSA-N 2-methylprop-2-enoic acid;phosphoric acid Chemical class OP(O)(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O KPKMKACZPZUNDP-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- VKERWIBXKLNXCY-UHFFFAOYSA-N 3,5,5-trimethyl-2-(2-methylbutan-2-ylperoxy)hexanoic acid Chemical compound CCC(C)(C)OOC(C(O)=O)C(C)CC(C)(C)C VKERWIBXKLNXCY-UHFFFAOYSA-N 0.000 description 1
- WTBPWOVBWKJVPF-UHFFFAOYSA-N 3-(2-ethylhexylperoxymethyl)heptane Chemical group CCCCC(CC)COOCC(CC)CCCC WTBPWOVBWKJVPF-UHFFFAOYSA-N 0.000 description 1
- VKRWVLAGVUOYLB-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propylurea Chemical compound CCO[Si](C)(OCC)CCCNC(N)=O VKRWVLAGVUOYLB-UHFFFAOYSA-N 0.000 description 1
- MXDWUGFTSGOHRF-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propylurea Chemical compound CO[Si](C)(OC)CCCNC(N)=O MXDWUGFTSGOHRF-UHFFFAOYSA-N 0.000 description 1
- VFXXTYGQYWRHJP-UHFFFAOYSA-N 4,4'-azobis(4-cyanopentanoic acid) Chemical compound OC(=O)CCC(C)(C#N)N=NC(C)(CCC(O)=O)C#N VFXXTYGQYWRHJP-UHFFFAOYSA-N 0.000 description 1
- HBWITNNIJDLPLS-UHFFFAOYSA-N 4-[1-[4-(dimethylamino)phenyl]ethenyl]-n,n-dimethylaniline Chemical compound C1=CC(N(C)C)=CC=C1C(=C)C1=CC=C(N(C)C)C=C1 HBWITNNIJDLPLS-UHFFFAOYSA-N 0.000 description 1
- UWDMKTDPDJCJOP-UHFFFAOYSA-N 4-hydroxy-2,2,6,6-tetramethylpiperidin-1-ium-4-carboxylate Chemical compound CC1(C)CC(O)(C(O)=O)CC(C)(C)N1 UWDMKTDPDJCJOP-UHFFFAOYSA-N 0.000 description 1
- NFWPZNNZUCPLAX-UHFFFAOYSA-N 4-methoxy-3-methylaniline Chemical compound COC1=CC=C(N)C=C1C NFWPZNNZUCPLAX-UHFFFAOYSA-N 0.000 description 1
- XESZUVZBAMCAEJ-UHFFFAOYSA-N 4-tert-butylcatechol Chemical compound CC(C)(C)C1=CC=C(O)C(O)=C1 XESZUVZBAMCAEJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- ARUISAIHTWRLDU-UHFFFAOYSA-N C(C1=CC=CC=C1)NC(=O)NCCC[Si](OCC)(OCC)OCC Chemical compound C(C1=CC=CC=C1)NC(=O)NCCC[Si](OCC)(OCC)OCC ARUISAIHTWRLDU-UHFFFAOYSA-N 0.000 description 1
- ZMVWAGRWCPMCMY-UHFFFAOYSA-N C=CC(=O)OCCOP(=O)=O Chemical compound C=CC(=O)OCCOP(=O)=O ZMVWAGRWCPMCMY-UHFFFAOYSA-N 0.000 description 1
- RHSCFNJCBGIZAS-UHFFFAOYSA-N CC(=C)C(=O)OCCCOP(=O)=O Chemical compound CC(=C)C(=O)OCCCOP(=O)=O RHSCFNJCBGIZAS-UHFFFAOYSA-N 0.000 description 1
- SQLBGYCQJROTJH-UHFFFAOYSA-N CCP(CC)OC(=O)C=C Chemical compound CCP(CC)OC(=O)C=C SQLBGYCQJROTJH-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920002121 Hydroxyl-terminated polybutadiene Polymers 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- QYTDEUPAUMOIOP-UHFFFAOYSA-N TEMPO Chemical group CC1(C)CCCC(C)(C)N1[O] QYTDEUPAUMOIOP-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- UNKQAWPNGDCPTE-UHFFFAOYSA-N [2,5-dimethyl-5-(3-methylbenzoyl)peroxyhexan-2-yl] 3-methylbenzenecarboperoxoate Chemical compound CC1=CC=CC(C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C=2C=C(C)C=CC=2)=C1 UNKQAWPNGDCPTE-UHFFFAOYSA-N 0.000 description 1
- JUIBLDFFVYKUAC-UHFFFAOYSA-N [5-(2-ethylhexanoylperoxy)-2,5-dimethylhexan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C(CC)CCCC JUIBLDFFVYKUAC-UHFFFAOYSA-N 0.000 description 1
- KYIKRXIYLAGAKQ-UHFFFAOYSA-N abcn Chemical compound C1CCCCC1(C#N)N=NC1(C#N)CCCCC1 KYIKRXIYLAGAKQ-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000004849 alkoxymethyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- YLFIGGHWWPSIEG-UHFFFAOYSA-N aminoxyl Chemical group [O]N YLFIGGHWWPSIEG-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- RJNQAWYDOFQOFG-UHFFFAOYSA-N benzoyl 3-methylbenzenecarboperoxoate Chemical compound CC1=CC=CC(C(=O)OOC(=O)C=2C=CC=CC=2)=C1 RJNQAWYDOFQOFG-UHFFFAOYSA-N 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- YOQPKXIRWPWFIE-UHFFFAOYSA-N ctk4c8335 Chemical compound CC(=C)C(=O)OCCOP(=O)=O YOQPKXIRWPWFIE-UHFFFAOYSA-N 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
- CIKJANOSDPPCAU-UHFFFAOYSA-N ditert-butyl cyclohexane-1,4-dicarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1CCC(C(=O)OOC(C)(C)C)CC1 CIKJANOSDPPCAU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- BNKAXGCRDYRABM-UHFFFAOYSA-N ethenyl dihydrogen phosphate Chemical compound OP(O)(=O)OC=C BNKAXGCRDYRABM-UHFFFAOYSA-N 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 125000005439 maleimidyl group Chemical group C1(C=CC(N1*)=O)=O 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
- VXVLTXUYMPQNAF-UHFFFAOYSA-N methyl n-[1-[[1-(methoxycarbonylamino)cyclohexyl]diazenyl]cyclohexyl]carbamate Chemical compound C1CCCCC1(NC(=O)OC)N=NC1(NC(=O)OC)CCCCC1 VXVLTXUYMPQNAF-UHFFFAOYSA-N 0.000 description 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 description 1
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical class C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 150000004059 quinone derivatives Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Abstract
【解決手段】熱可塑性樹脂、分子内に(メタ)アクリロイル基を2個以上有するラジカル重合性化合物、ラジカル重合開始剤、及び分子内に尿素結合とアルコキシシリル基を有するシランカップリング剤、を含む接着剤組成物である。
【選択図】なし
Description
使用機器:日立L−6000型[(株)日立製作所]
カラム:ゲルパックGL−R420+ゲルパックGL−R430+ゲルパックGL−R440(計3本)[日立化成工業(株)製、商品名]
溶離液:テトラヒドロフラン
測定温度:40℃
流量:1.75ml/min
検出器:L−3300RI[(株)日立製作所]
50mlのフラスコ中で、トルエン5.00g及びビニル基を有するイソシアネート化合物であるイソシアン酸3−イソプロペニル−α、α−ジメチルベンジル(東京化成株式会社製)2.01gを混合した。続いて、2級アミノシラン化合物であるN−フェニル−γ−アミノプロピルトリメトキシシラン(信越化学工業株式会社製、製品名:KBM573、)2.55gをトルエン5.60gに溶解して調製した溶液を、室温下で10分間かけて上記フラスコ中に滴下した。
50mlのフラスコ中で、トルエン5.00g及びビニル基を有するイソシアネート化合物であるイソシアン酸3−イソプロペニル−α,α−ジメチルベンジル(東京化成株式会社製)2.01gを混合した。続いて、1級アミノシラン化合物であるγ−アミノプロピルトリメトキシシラン(信越化学工業株式会社製、製品名:KBM903)1.79gをトルエン3.37gに溶解して調製した溶液を、室温下で10分間かけて上記フラスコ中に滴下した。
50mlのフラスコ中で、トルエン4.00g及びアクリロイル基を有するイソシアネート化合物である2−イソシアナトエチルアクリレート(昭和電工株式会社製、製品名:カレンズAOI)1.41gを混合し、得られた溶液を氷浴にて冷却した。
(回路接続用接着剤の作製)
(a)成分として、フェノキシ樹脂(InChem社製、製品名:PKHM−30)を準備した。このフェノキシ樹脂40gを、ガラス製の容器に入れたメチルエチルケトン(和光純薬工業(株)社製、製品名:2−ブタノン、純度99%)60gに溶解して、固形分40質量%の分散液を調製した。
・1,4−ブチレングリコール(Aldrich社製、製品名:1,4−ブチレングリコール):100質量部
・重量平均分子量2000のポリブチレンアジペートジオール(Aldrich社製、製品名:ポリブチレンアジペートジオール):450質量部
・平均分子量2000のポリオキシテトラメチレングリコール(Aldrich社製、製品名:ポリオキシテトラメチレングリコール):450質量部
調製した各実施例及び各比較例の回路接続用接着剤を用い、以下の通りにして回路接続体を作製した。まず、ライン幅25μm、ピッチ50μm、厚み18μmの銅回路を500本有するフレキシブル回路板(FPC)、0.2μmの酸化インジウム(ITO)薄層を全面に形成したガラス基板(厚み1.1mm、表面抵抗20Ω/□)、及び0.5μmの窒化ケイ素(SiN)及び0.2μmの酸化インジウム(ITO)薄層を全面に形成したガラス基板(厚み1.1mm、表面抵抗20Ω/□)を準備した。
Claims (8)
- 熱可塑性樹脂、
分子内に(メタ)アクリロイル基を2個以上有するラジカル重合性化合物、
ラジカル重合開始剤、及び
分子内に尿素結合とアルコキシシリル基を有するシランカップリング剤、
を含む接着剤組成物。 - 前記シランカップリング剤が、前記分子内にビニル基を有する、請求項1記載の接着剤組成物。
- 分子内に少なくとも一つのリン酸基を有するビニル化合物を含む、請求項1又は2記載の接着剤組成物。
- 前記熱可塑性樹脂100質量部に対して、
前記ラジカル重合性化合物を50〜250質量部、
前記ラジカル重合開始剤を0.05〜30質量部、及び
前記シランカップリング剤を0.1〜30質量部、含む請求項1〜3のいずれか一項に記載の接着剤組成物。 - 導電性粒子を含んでおり、
前記導電性粒子の含有量が0.1〜30体積%である、請求項1〜4のいずれか一項に記載の接着剤組成物。 - 第1の回路電極と第2の回路電極とをそれぞれ有し、対向配置された第1の回路部材と第2の回路部材との間に介在させて、前記第1の回路部材と第2の回路部材とを対向する方向に加圧することによって、前記第1の回路電極と前記第2の回路電極とを電気的に接続する回路接続用接着剤であって、
請求項1〜5のいずれか一項に記載の接着剤組成物からなる回路接続用接着剤。 - 第1の回路電極と第2の回路電極とをそれぞれ有する第1の回路部材と第2の回路部材とを備え、
前記第1の回路電極と前記第2の回路電極とが相対向するように、前記第1の回路部材と第2の回路部材との間に請求項6に記載の回路接続用接着剤を介在させ、相対向する方向に加圧して接続された回路接続体。 - 前記第一の回路部材又は前記第二の回路部材が半導体素子である、請求項7記載の回路接続体。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009157712A JP5577635B2 (ja) | 2008-10-09 | 2009-07-02 | 接着剤組成物、回路接続用接着剤及び回路接続体 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008262718 | 2008-10-09 | ||
JP2008262718 | 2008-10-09 | ||
JP2009157712A JP5577635B2 (ja) | 2008-10-09 | 2009-07-02 | 接着剤組成物、回路接続用接着剤及び回路接続体 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010111846A true JP2010111846A (ja) | 2010-05-20 |
JP5577635B2 JP5577635B2 (ja) | 2014-08-27 |
Family
ID=42300649
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009157712A Active JP5577635B2 (ja) | 2008-10-09 | 2009-07-02 | 接着剤組成物、回路接続用接着剤及び回路接続体 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5577635B2 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013161713A1 (ja) * | 2012-04-25 | 2013-10-31 | 日立化成株式会社 | 回路接続材料、回路接続構造体、接着フィルム及び巻重体 |
CN103764776A (zh) * | 2011-09-06 | 2014-04-30 | 日立化成株式会社 | 粘接剂组合物和连接体 |
WO2014156373A1 (ja) * | 2013-03-28 | 2014-10-02 | 日東電工株式会社 | 活性エネルギー線硬化型接着剤組成物、偏光フィルムおよびその製造方法、光学フィルムならびに画像表示装置 |
JP2015525823A (ja) * | 2012-08-08 | 2015-09-07 | スリーエム イノベイティブ プロパティズ カンパニー | 尿素(マルチ)−(メタ)アクリレート(マルチ)−シラン化合物及びそれを含む物品 |
JP2015531999A (ja) * | 2012-08-08 | 2015-11-05 | スリーエム イノベイティブ プロパティズ カンパニー | 封入バリアフィルムを備える光起電装置 |
WO2017090693A1 (ja) * | 2015-11-25 | 2017-06-01 | 日立化成株式会社 | 接着剤組成物及び構造体 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002102812A1 (en) * | 2001-06-13 | 2002-12-27 | Konishi Co., Ltd. | Unsaturated organic compounds having hydrolyzable silicon-containing groups, process for producing the same, silicon-containing polymers and emulsions thereof |
JP2003277694A (ja) * | 2002-03-27 | 2003-10-02 | Hitachi Chem Co Ltd | 回路接続用接着剤組成物及びそれを用いた回路接続構造体 |
JP2006190644A (ja) * | 2004-12-30 | 2006-07-20 | Cheil Industries Inc | 異方性導電フィルム用組成物 |
JP2006257208A (ja) * | 2005-03-16 | 2006-09-28 | Hitachi Chem Co Ltd | 接着剤、回路接続用接着剤、接続体及び半導体装置 |
JP2007297579A (ja) * | 2006-04-05 | 2007-11-15 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続材料、接続体及び半導体装置 |
WO2008065997A1 (fr) * | 2006-12-01 | 2008-06-05 | Hitachi Chemical Company, Ltd. | Adhésif et structure de liaison utilisant celui-ci |
JP2008202020A (ja) * | 2007-01-23 | 2008-09-04 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続構造体及び半導体装置 |
JP2009256581A (ja) * | 2008-03-28 | 2009-11-05 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続用接着剤及びそれを用いた接続体 |
JP2009256619A (ja) * | 2008-03-28 | 2009-11-05 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続用接着剤、接続体及び半導体装置 |
JP2009256582A (ja) * | 2008-03-28 | 2009-11-05 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続用接着剤及びそれを用いた接続体 |
-
2009
- 2009-07-02 JP JP2009157712A patent/JP5577635B2/ja active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002102812A1 (en) * | 2001-06-13 | 2002-12-27 | Konishi Co., Ltd. | Unsaturated organic compounds having hydrolyzable silicon-containing groups, process for producing the same, silicon-containing polymers and emulsions thereof |
JP2003277694A (ja) * | 2002-03-27 | 2003-10-02 | Hitachi Chem Co Ltd | 回路接続用接着剤組成物及びそれを用いた回路接続構造体 |
JP2006190644A (ja) * | 2004-12-30 | 2006-07-20 | Cheil Industries Inc | 異方性導電フィルム用組成物 |
JP2006257208A (ja) * | 2005-03-16 | 2006-09-28 | Hitachi Chem Co Ltd | 接着剤、回路接続用接着剤、接続体及び半導体装置 |
JP2007297579A (ja) * | 2006-04-05 | 2007-11-15 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続材料、接続体及び半導体装置 |
WO2008065997A1 (fr) * | 2006-12-01 | 2008-06-05 | Hitachi Chemical Company, Ltd. | Adhésif et structure de liaison utilisant celui-ci |
JP2008202020A (ja) * | 2007-01-23 | 2008-09-04 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続構造体及び半導体装置 |
JP2009256581A (ja) * | 2008-03-28 | 2009-11-05 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続用接着剤及びそれを用いた接続体 |
JP2009256619A (ja) * | 2008-03-28 | 2009-11-05 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続用接着剤、接続体及び半導体装置 |
JP2009256582A (ja) * | 2008-03-28 | 2009-11-05 | Hitachi Chem Co Ltd | 接着剤組成物、回路接続用接着剤及びそれを用いた接続体 |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103764776A (zh) * | 2011-09-06 | 2014-04-30 | 日立化成株式会社 | 粘接剂组合物和连接体 |
JPWO2013161713A1 (ja) * | 2012-04-25 | 2015-12-24 | 日立化成株式会社 | 回路接続材料、回路接続構造体、接着フィルム及び巻重体 |
WO2013161713A1 (ja) * | 2012-04-25 | 2013-10-31 | 日立化成株式会社 | 回路接続材料、回路接続構造体、接着フィルム及び巻重体 |
US10011735B2 (en) | 2012-08-08 | 2018-07-03 | 3M Innovative Properties Companies | Diurethane (meth)acrylate-silane compositions and articles including the same |
US11174361B2 (en) | 2012-08-08 | 2021-11-16 | 3M Innovative Properties Company | Urea (multi)-urethane (meth)acrylate-silane compositions and articles including the same |
JP2015531999A (ja) * | 2012-08-08 | 2015-11-05 | スリーエム イノベイティブ プロパティズ カンパニー | 封入バリアフィルムを備える光起電装置 |
US11492453B2 (en) | 2012-08-08 | 2022-11-08 | 3M Innovative Properties Company | Urea (multi)-(meth)acrylate (multi)-silane compositions and articles including the same |
US11192989B2 (en) | 2012-08-08 | 2021-12-07 | 3M Innovative Properties Company | Urea (multi)-urethane (meth)acrylate-silane compositions and articles including the same |
US9790396B2 (en) | 2012-08-08 | 2017-10-17 | 3M Innovation Properties Company | Articles including a (co)polymer reaction product of a urethane (multi)-(meth)acrylate (multi)-silane |
US9982160B2 (en) | 2012-08-08 | 2018-05-29 | 3M Innovative Properties Company | Urea (multi)-(meth)acrylate (multi)-silane compositions and articles including the same |
JP2015525823A (ja) * | 2012-08-08 | 2015-09-07 | スリーエム イノベイティブ プロパティズ カンパニー | 尿素(マルチ)−(メタ)アクリレート(マルチ)−シラン化合物及びそれを含む物品 |
US10804419B2 (en) | 2012-08-08 | 2020-10-13 | 3M Innovative Properties Company | Photovoltaic devices with encapsulating barrier film |
US10774236B2 (en) | 2012-08-08 | 2020-09-15 | 3M Innovative Properties, Company | Urea (multi)-(meth)acrylate (multi)-silane compositions and articles including the same |
US10533111B2 (en) | 2012-08-08 | 2020-01-14 | 3M Innovative Properties Company | Urea (multi)-urethane (meth)acrylate-silane compositions and articles including the same |
WO2014156373A1 (ja) * | 2013-03-28 | 2014-10-02 | 日東電工株式会社 | 活性エネルギー線硬化型接着剤組成物、偏光フィルムおよびその製造方法、光学フィルムならびに画像表示装置 |
JP2014189788A (ja) * | 2013-03-28 | 2014-10-06 | Nitto Denko Corp | 活性エネルギー線硬化型接着剤組成物、偏光フィルムおよびその製造方法、光学フィルムならびに画像表示装置 |
JPWO2017090693A1 (ja) * | 2015-11-25 | 2018-09-13 | 日立化成株式会社 | 接着剤組成物及び構造体 |
KR20180084930A (ko) | 2015-11-25 | 2018-07-25 | 히타치가세이가부시끼가이샤 | 접착제 조성물 및 구조체 |
WO2017090693A1 (ja) * | 2015-11-25 | 2017-06-01 | 日立化成株式会社 | 接着剤組成物及び構造体 |
JP2022000530A (ja) * | 2015-11-25 | 2022-01-04 | 昭和電工マテリアルズ株式会社 | 接着剤組成物及び構造体 |
JP7173258B2 (ja) | 2015-11-25 | 2022-11-16 | 昭和電工マテリアルズ株式会社 | 接着剤組成物及び構造体 |
Also Published As
Publication number | Publication date |
---|---|
JP5577635B2 (ja) | 2014-08-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4760070B2 (ja) | 接着剤、回路接続用接着剤、接続体及び半導体装置 | |
JP4998468B2 (ja) | 接着剤組成物及び回路部材の接続構造 | |
JP6090311B2 (ja) | 回路接続材料、回路接続構造体及び接着フィルム | |
JP5223679B2 (ja) | 接着剤及びこれを用いた接続構造体 | |
JP5251393B2 (ja) | 接着剤組成物、回路接続用接着剤及びそれを用いた接続体 | |
JP6173928B2 (ja) | 接着剤組成物、回路接続用接着剤及び接続体 | |
JPWO2009031472A1 (ja) | 接着剤及びそれを用いた接続構造体 | |
JP5577635B2 (ja) | 接着剤組成物、回路接続用接着剤及び回路接続体 | |
JP6045918B2 (ja) | 回路接続材料、回路接続部材の接続構造及び半導体装置 | |
JP5292838B2 (ja) | 接着剤、及び回路部材の接続構造体 | |
JP2020109173A (ja) | 接着剤組成物及び接続体 | |
JP5293779B2 (ja) | 接着剤組成物、回路接続構造体、半導体装置及び太陽電池モジュール | |
JP5070748B2 (ja) | 接着剤組成物、回路接続材料、接続体及び半導体装置 | |
JP2009256581A (ja) | 接着剤組成物、回路接続用接着剤及びそれを用いた接続体 | |
JP5298977B2 (ja) | 接着剤組成物、回路接続用接着剤、接続体及び半導体装置 | |
JP2013227420A (ja) | 回路接続材料、回路接続構造体、接着フィルム及び巻重体。 | |
JP2003277694A (ja) | 回路接続用接着剤組成物及びそれを用いた回路接続構造体 | |
CN109804508B (zh) | 连接结构体、电路连接构件和粘接剂组合物 | |
WO2017090693A1 (ja) | 接着剤組成物及び構造体 | |
JP2012204059A (ja) | 回路接続材料及びそれを用いた回路接続構造体 | |
JP2010111847A (ja) | 接着剤組成物及び接続体 | |
WO2017037951A1 (ja) | 接着剤組成物、異方導電性接着剤組成物、回路接続材料及び接続体 | |
JP2011157557A (ja) | 接着剤、回路接続用接着剤、接続体及び半導体装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20120625 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130812 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130827 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131018 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140610 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140623 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 5577635 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |