JP2009520748A - アクリル酸を形成するためのプロピレンの不均一触媒部分気相酸化の方法 - Google Patents

アクリル酸を形成するためのプロピレンの不均一触媒部分気相酸化の方法 Download PDF

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JP2009520748A
JP2009520748A JP2008546370A JP2008546370A JP2009520748A JP 2009520748 A JP2009520748 A JP 2009520748A JP 2008546370 A JP2008546370 A JP 2008546370A JP 2008546370 A JP2008546370 A JP 2008546370A JP 2009520748 A JP2009520748 A JP 2009520748A
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gas mixture
reaction gas
mol
propylene
reaction
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JP2009520748A5 (OSRAM
Inventor
ディーテルレ マルティン
ディーフェンバッハー アルミン
ヨアヒム ミュラー−エンゲル クラウス
ペッツォルト ヨッヘン
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2008546370A 2005-12-22 2006-12-11 アクリル酸を形成するためのプロピレンの不均一触媒部分気相酸化の方法 Pending JP2009520748A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US75236905P 2005-12-22 2005-12-22
DE102005062026A DE102005062026A1 (de) 2005-12-22 2005-12-22 Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
PCT/EP2006/069527 WO2007074045A1 (de) 2005-12-22 2006-12-11 Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propylen zu acrylsäure

Related Child Applications (1)

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JP2013251949A Division JP5940045B2 (ja) 2005-12-22 2013-12-05 アクリル酸を形成するためのプロピレンの不均一触媒部分気相酸化の方法

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JP2009520748A true JP2009520748A (ja) 2009-05-28
JP2009520748A5 JP2009520748A5 (OSRAM) 2010-02-04

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JP2013251949A Expired - Fee Related JP5940045B2 (ja) 2005-12-22 2013-12-05 アクリル酸を形成するためのプロピレンの不均一触媒部分気相酸化の方法

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US (1) US7807853B2 (OSRAM)
EP (1) EP1963248B1 (OSRAM)
JP (2) JP2009520748A (OSRAM)
KR (2) KR20140058697A (OSRAM)
CN (1) CN101379018B (OSRAM)
DE (1) DE102005062026A1 (OSRAM)
MY (1) MY145843A (OSRAM)
RU (1) RU2464256C2 (OSRAM)
TW (1) TWI377193B (OSRAM)
WO (1) WO2007074045A1 (OSRAM)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014148500A (ja) * 2005-12-22 2014-08-21 Basf Se アクリル酸を形成するためのプロピレンの不均一触媒部分気相酸化の方法
WO2019116483A1 (ja) * 2017-12-14 2019-06-20 三菱重工エンジニアリング株式会社 アクリル酸の製造プラント及びアクリル酸の製造方法

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DE102007055086A1 (de) 2007-11-16 2009-05-20 Basf Se Verfahren zur Herstellung von Acrylsäure
DE102007004960A1 (de) 2007-01-26 2008-07-31 Basf Se Verfahren zur Herstellung von Acrylsäure
DE102007029053A1 (de) * 2007-06-21 2008-01-03 Basf Ag Verfahren der heterogen katalysierten partiellen Direktoxidation von n-Propan zu Acrylsäure
US9149799B2 (en) * 2010-04-28 2015-10-06 Basf Se Eggshell catalyst consisting of a hollow cylindrical support body and a catalytically active oxide material applied to the outer surface of the support body
DE102010042216A1 (de) 2010-10-08 2011-06-09 Basf Se Verfahren zur Hemmung der unerwünschten radikalischen Polymerisation von in einer flüssigen Phase P befindlicher Acrylsäure
JP5852134B2 (ja) 2010-12-29 2016-02-03 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ プロパン酸化のための反応器及び方法
DE102011076931A1 (de) 2011-06-03 2012-12-06 Basf Se Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base
SG11201401606WA (en) 2011-10-18 2014-05-29 Rohm & Haas Method for preparing acrylic acid from propane and propylene
EP2983818A1 (en) 2013-04-08 2016-02-17 Saudi Basic Industries Corporation Catalyst for conversion of propylene to product comprising a carboxylic acid moiety
DE102013006251A1 (de) * 2013-04-11 2014-10-16 Clariant International Ltd. Verfahren zur Herstellung eines Katalysators zur partiellen Oxidation von Olefinen
CN105622822B (zh) * 2016-03-02 2018-11-27 中国石油集团东北炼化工程有限公司吉林设计院 一种用于乙丙橡胶生产的催化剂的使用工艺
DE102018200841A1 (de) 2018-01-19 2019-07-25 Basf Se Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen
WO2020020697A1 (de) 2018-07-26 2020-01-30 Basf Se Verfahren zur hemmung der unerwünschten radikalischen polymerisation von in einer flüssigen phase p befindlicher acrylsäure
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
JP7651589B2 (ja) 2020-03-26 2025-03-26 ベーアーエスエフ・エスエー 液相ｐに存在するアクリル酸の望ましくないフリーラジカル重合を抑制する方法
WO2025172146A1 (de) 2024-02-15 2025-08-21 Basf Se Verfahren zur herstellung von acrylsäure
WO2025219137A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams by gasification and fermentation
WO2025219136A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams
WO2025219135A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing high calorific acrylic acid production waste streams

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WO2004031106A1 (de) * 2002-09-27 2004-04-15 Basf Aktiengesellschaft Verfahren zur herstellung von wenigstens einem partiellen oxidations- und/oder ammoxidationsprodukt des propylens

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014148500A (ja) * 2005-12-22 2014-08-21 Basf Se アクリル酸を形成するためのプロピレンの不均一触媒部分気相酸化の方法
WO2019116483A1 (ja) * 2017-12-14 2019-06-20 三菱重工エンジニアリング株式会社 アクリル酸の製造プラント及びアクリル酸の製造方法

Also Published As

Publication number Publication date
EP1963248B1 (de) 2016-06-08
TW200732301A (en) 2007-09-01
US20070149808A1 (en) 2007-06-28
CN101379018B (zh) 2012-07-04
TWI377193B (en) 2012-11-21
KR101507616B1 (ko) 2015-03-31
KR20140058697A (ko) 2014-05-14
RU2008129548A (ru) 2010-01-27
DE102005062026A1 (de) 2007-06-28
KR20080081328A (ko) 2008-09-09
WO2007074045A1 (de) 2007-07-05
US7807853B2 (en) 2010-10-05
JP2014148500A (ja) 2014-08-21
RU2464256C2 (ru) 2012-10-20
CN101379018A (zh) 2009-03-04
MY145843A (en) 2012-04-30
EP1963248A1 (de) 2008-09-03
JP5940045B2 (ja) 2016-06-29

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