KR20140058697A - 프로필렌의 불균질 촉매화 부분 기상 산화에 의한 아크릴산의 형성 방법 - Google Patents
프로필렌의 불균질 촉매화 부분 기상 산화에 의한 아크릴산의 형성 방법 Download PDFInfo
- Publication number
- KR20140058697A KR20140058697A KR1020147011903A KR20147011903A KR20140058697A KR 20140058697 A KR20140058697 A KR 20140058697A KR 1020147011903 A KR1020147011903 A KR 1020147011903A KR 20147011903 A KR20147011903 A KR 20147011903A KR 20140058697 A KR20140058697 A KR 20140058697A
- Authority
- KR
- South Korea
- Prior art keywords
- reaction
- gas mixture
- catalyst
- propylene
- mol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/55—Cylinders or rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75236905P | 2005-12-22 | 2005-12-22 | |
| DE102005062026A DE102005062026A1 (de) | 2005-12-22 | 2005-12-22 | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure |
| US60/752,369 | 2005-12-22 | ||
| DE102005062026.4 | 2005-12-22 | ||
| PCT/EP2006/069527 WO2007074045A1 (de) | 2005-12-22 | 2006-12-11 | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propylen zu acrylsäure |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020087017752A Division KR101507616B1 (ko) | 2005-12-22 | 2006-12-11 | 프로필렌의 불균질 촉매화 부분 기상 산화에 의한아크릴산의 형성 방법 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20140058697A true KR20140058697A (ko) | 2014-05-14 |
Family
ID=38108833
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147011903A Ceased KR20140058697A (ko) | 2005-12-22 | 2006-12-11 | 프로필렌의 불균질 촉매화 부분 기상 산화에 의한 아크릴산의 형성 방법 |
| KR1020087017752A Expired - Fee Related KR101507616B1 (ko) | 2005-12-22 | 2006-12-11 | 프로필렌의 불균질 촉매화 부분 기상 산화에 의한아크릴산의 형성 방법 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020087017752A Expired - Fee Related KR101507616B1 (ko) | 2005-12-22 | 2006-12-11 | 프로필렌의 불균질 촉매화 부분 기상 산화에 의한아크릴산의 형성 방법 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7807853B2 (OSRAM) |
| EP (1) | EP1963248B1 (OSRAM) |
| JP (2) | JP2009520748A (OSRAM) |
| KR (2) | KR20140058697A (OSRAM) |
| CN (1) | CN101379018B (OSRAM) |
| DE (1) | DE102005062026A1 (OSRAM) |
| MY (1) | MY145843A (OSRAM) |
| RU (1) | RU2464256C2 (OSRAM) |
| TW (1) | TWI377193B (OSRAM) |
| WO (1) | WO2007074045A1 (OSRAM) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005062026A1 (de) * | 2005-12-22 | 2007-06-28 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure |
| DE102007055086A1 (de) | 2007-11-16 | 2009-05-20 | Basf Se | Verfahren zur Herstellung von Acrylsäure |
| DE102007004960A1 (de) | 2007-01-26 | 2008-07-31 | Basf Se | Verfahren zur Herstellung von Acrylsäure |
| DE102007029053A1 (de) * | 2007-06-21 | 2008-01-03 | Basf Ag | Verfahren der heterogen katalysierten partiellen Direktoxidation von n-Propan zu Acrylsäure |
| US9149799B2 (en) * | 2010-04-28 | 2015-10-06 | Basf Se | Eggshell catalyst consisting of a hollow cylindrical support body and a catalytically active oxide material applied to the outer surface of the support body |
| DE102010042216A1 (de) | 2010-10-08 | 2011-06-09 | Basf Se | Verfahren zur Hemmung der unerwünschten radikalischen Polymerisation von in einer flüssigen Phase P befindlicher Acrylsäure |
| JP5852134B2 (ja) | 2010-12-29 | 2016-02-03 | ローム アンド ハース カンパニーRohm And Haas Company | プロパン酸化のための反応器及び方法 |
| DE102011076931A1 (de) | 2011-06-03 | 2012-12-06 | Basf Se | Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base |
| SG11201401606WA (en) | 2011-10-18 | 2014-05-29 | Rohm & Haas | Method for preparing acrylic acid from propane and propylene |
| EP2983818A1 (en) | 2013-04-08 | 2016-02-17 | Saudi Basic Industries Corporation | Catalyst for conversion of propylene to product comprising a carboxylic acid moiety |
| DE102013006251A1 (de) * | 2013-04-11 | 2014-10-16 | Clariant International Ltd. | Verfahren zur Herstellung eines Katalysators zur partiellen Oxidation von Olefinen |
| CN105622822B (zh) * | 2016-03-02 | 2018-11-27 | 中国石油集团东北炼化工程有限公司吉林设计院 | 一种用于乙丙橡胶生产的催化剂的使用工艺 |
| WO2019116483A1 (ja) * | 2017-12-14 | 2019-06-20 | 三菱重工エンジニアリング株式会社 | アクリル酸の製造プラント及びアクリル酸の製造方法 |
| DE102018200841A1 (de) | 2018-01-19 | 2019-07-25 | Basf Se | Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen |
| WO2020020697A1 (de) | 2018-07-26 | 2020-01-30 | Basf Se | Verfahren zur hemmung der unerwünschten radikalischen polymerisation von in einer flüssigen phase p befindlicher acrylsäure |
| EP3770145A1 (en) | 2019-07-24 | 2021-01-27 | Basf Se | A process for the continuous production of either acrolein or acrylic acid as the target product from propene |
| JP7651589B2 (ja) | 2020-03-26 | 2025-03-26 | ベーアーエスエフ・エスエー | 液相pに存在するアクリル酸の望ましくないフリーラジカル重合を抑制する方法 |
| WO2025172146A1 (de) | 2024-02-15 | 2025-08-21 | Basf Se | Verfahren zur herstellung von acrylsäure |
| WO2025219137A1 (en) | 2024-04-17 | 2025-10-23 | Basf Se | Process for utilizing acrylic acid production waste streams by gasification and fermentation |
| WO2025219136A1 (en) | 2024-04-17 | 2025-10-23 | Basf Se | Process for utilizing acrylic acid production waste streams |
| WO2025219135A1 (en) | 2024-04-17 | 2025-10-23 | Basf Se | Process for utilizing high calorific acrylic acid production waste streams |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2626887B2 (de) * | 1976-06-16 | 1978-06-29 | Basf Ag, 6700 Ludwigshafen | Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure |
| DE2909597A1 (de) * | 1979-03-12 | 1980-09-25 | Basf Ag | Verfahren zur herstellung von 3 bis 4 c-atome enthaltenden alpha , beta -olefinisch ungesaettigten aldehyden |
| DE3213681A1 (de) * | 1982-04-14 | 1983-10-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von (alpha)-alkylacroleinen |
| US4413147A (en) | 1982-04-14 | 1983-11-01 | The Halcon Sd Group, Inc. | Conversion of isobutane to methacrolein |
| CA1217502A (en) | 1982-04-14 | 1987-02-03 | Sargis Khoobiar | Conversion of alkanes to unsaturated aldehydes |
| USRE32082E (en) | 1982-04-14 | 1986-02-11 | The Halcon Sd Group, Inc. | Conversion of isobutane to methacrolein |
| US4532365A (en) | 1982-09-20 | 1985-07-30 | The Halcon Sd Group, Inc. | Conversion of alkanes to unsaturated aldehydes |
| US4535188A (en) | 1982-04-14 | 1985-08-13 | The Halcon Sd Group, Inc. | Conversion of isobutane to methacrolein |
| NO163690C (no) | 1984-06-18 | 1990-07-04 | Air Prod & Chem | Fremgangsmaate for fremstilling av to kvaliteter av propylen. |
| CA1299193C (en) * | 1986-07-17 | 1992-04-21 | Gordon Gene Harkreader | Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid |
| DE19902562A1 (de) * | 1999-01-22 | 2000-07-27 | Basf Ag | Verfahren zur Herstellung von Acrolein durch heterogen katalysierte Gasphasen-Partialoxidation von Propen |
| CA2318720C (en) * | 1999-09-20 | 2008-10-14 | Kuraray Co., Ltd. | Process for polymerizing a methacrylic ester or an acrylic ester |
| DE19955168A1 (de) * | 1999-11-16 | 2001-05-17 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
| DE10028582A1 (de) | 2000-06-14 | 2001-12-20 | Basf Ag | Verfahren zur Herstellung von Acrolein oder Acrylsäure oder deren Gemischen aus Propan |
| DE10031518A1 (de) * | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Herstellung von Hydroformylierungsprodukten des Propylens und von Acrylsäure und/oder Acrolein |
| BR0206396A (pt) | 2001-01-12 | 2004-02-10 | Degussa | Processo contìnuo para preparação e purificação de ácido (met)acrìlico |
| DE10131297A1 (de) | 2001-06-29 | 2003-01-09 | Basf Ag | Verfahren zur Herstellung von partiellen Oxidationsprodukten und/oder partiellen Ammoxidationsprodukten wenigstens eines olefinischen Kohlenwasserstoffs |
| DE10211686A1 (de) | 2002-03-15 | 2003-10-02 | Stockhausen Chem Fab Gmbh | (Meth)Acrylsäurekristall und Verfahren zur Herstellung und Aufreinigung von wässriger (Meth)Acrylsäure |
| JP4302943B2 (ja) * | 2002-07-02 | 2009-07-29 | Necエレクトロニクス株式会社 | 半導体集積回路 |
| US7238827B2 (en) | 2002-09-27 | 2007-07-03 | Basf Aktiengesellschaft | Preparation of at least one partial oxidation and/or ammoxidation product of propylene |
| DE10245585A1 (de) | 2002-09-27 | 2004-04-08 | Basf Ag | Verfahren zur Herstellung von wenigstens einem partiellen Oxidations- und/oder Ammoxidationsprodukt des Propylens |
| DE10313208A1 (de) * | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
| DE10313209A1 (de) | 2003-03-25 | 2004-03-04 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
| DE10316039A1 (de) | 2003-04-07 | 2004-10-21 | Basf Ag | Verfahren zur Herstellung von wenigstens einem partiellen Oxidations-und/oder Ammoxidationsprodukt eines Kohlenwasserstoffs |
| DE102005013039A1 (de) | 2005-03-18 | 2006-09-21 | Basf Ag | Verfahren zur Herstellung von Acrolein, oder Acrylsäure oder deren Gemisch aus Propan |
| US7592483B2 (en) | 2004-07-01 | 2009-09-22 | Basf Aktiengesellschaft | Preparation of acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas phase oxidation of propylene |
| DE102005010111A1 (de) | 2005-03-02 | 2006-09-07 | Basf Ag | Verfahren zur Herstellung von Acrylsäure durch heterogen katalysierte partielle Gasphasenoxidation von Propylen |
| DE102005009885A1 (de) | 2005-03-01 | 2006-09-14 | Basf Ag | Verfahren zur Herstellung von Acrolein oder Acrylsäure oder deren Gemisch durch heterogen katalysierte partielle Gasphasenoxidation von Propylen |
| DE102005022798A1 (de) | 2005-05-12 | 2006-11-16 | Basf Ag | Verfahren zur Herstellung wenigstens eines Zielproduktes durch partielle Oxidation und/oder Ammoxidation von Propylen |
| DE102005062026A1 (de) * | 2005-12-22 | 2007-06-28 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure |
-
2005
- 2005-12-22 DE DE102005062026A patent/DE102005062026A1/de not_active Withdrawn
-
2006
- 2006-12-04 US US11/566,284 patent/US7807853B2/en not_active Expired - Fee Related
- 2006-12-11 EP EP06830501.0A patent/EP1963248B1/de not_active Not-in-force
- 2006-12-11 JP JP2008546370A patent/JP2009520748A/ja active Pending
- 2006-12-11 RU RU2008129548/04A patent/RU2464256C2/ru active
- 2006-12-11 KR KR1020147011903A patent/KR20140058697A/ko not_active Ceased
- 2006-12-11 MY MYPI20082240A patent/MY145843A/en unknown
- 2006-12-11 CN CN2006800531606A patent/CN101379018B/zh active Active
- 2006-12-11 KR KR1020087017752A patent/KR101507616B1/ko not_active Expired - Fee Related
- 2006-12-11 WO PCT/EP2006/069527 patent/WO2007074045A1/de not_active Ceased
- 2006-12-22 TW TW095148520A patent/TWI377193B/zh not_active IP Right Cessation
-
2013
- 2013-12-05 JP JP2013251949A patent/JP5940045B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1963248B1 (de) | 2016-06-08 |
| TW200732301A (en) | 2007-09-01 |
| US20070149808A1 (en) | 2007-06-28 |
| CN101379018B (zh) | 2012-07-04 |
| TWI377193B (en) | 2012-11-21 |
| KR101507616B1 (ko) | 2015-03-31 |
| JP2009520748A (ja) | 2009-05-28 |
| RU2008129548A (ru) | 2010-01-27 |
| DE102005062026A1 (de) | 2007-06-28 |
| KR20080081328A (ko) | 2008-09-09 |
| WO2007074045A1 (de) | 2007-07-05 |
| US7807853B2 (en) | 2010-10-05 |
| JP2014148500A (ja) | 2014-08-21 |
| RU2464256C2 (ru) | 2012-10-20 |
| CN101379018A (zh) | 2009-03-04 |
| MY145843A (en) | 2012-04-30 |
| EP1963248A1 (de) | 2008-09-03 |
| JP5940045B2 (ja) | 2016-06-29 |
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