JP2008520537A - Itq−27、新規結晶性微孔性材料 - Google Patents
Itq−27、新規結晶性微孔性材料 Download PDFInfo
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- JP2008520537A JP2008520537A JP2007543104A JP2007543104A JP2008520537A JP 2008520537 A JP2008520537 A JP 2008520537A JP 2007543104 A JP2007543104 A JP 2007543104A JP 2007543104 A JP2007543104 A JP 2007543104A JP 2008520537 A JP2008520537 A JP 2008520537A
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- tetrahedral
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- itq
- metal
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- 239000012229 microporous material Substances 0.000 title abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 37
- 239000000463 material Substances 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 14
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 238000002441 X-ray diffraction Methods 0.000 claims abstract description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 7
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims description 33
- 239000002184 metal Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000003054 catalyst Substances 0.000 claims description 22
- 229910052782 aluminium Inorganic materials 0.000 claims description 20
- 229910052719 titanium Inorganic materials 0.000 claims description 18
- 239000010936 titanium Substances 0.000 claims description 18
- 229910052790 beryllium Inorganic materials 0.000 claims description 17
- 229910052796 boron Inorganic materials 0.000 claims description 17
- 229910052733 gallium Inorganic materials 0.000 claims description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- 239000002178 crystalline material Substances 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 150000002739 metals Chemical class 0.000 claims description 14
- 229910052732 germanium Inorganic materials 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 229910052804 chromium Inorganic materials 0.000 claims description 11
- 239000011651 chromium Substances 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 229910052787 antimony Inorganic materials 0.000 claims description 9
- 229910052785 arsenic Inorganic materials 0.000 claims description 9
- 229910052738 indium Inorganic materials 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 229910052718 tin Inorganic materials 0.000 claims description 9
- 229910052726 zirconium Inorganic materials 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 239000011572 manganese Substances 0.000 claims description 7
- 150000002894 organic compounds Chemical group 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 238000001308 synthesis method Methods 0.000 claims description 6
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- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- BYGXNRZZNBOSBD-UHFFFAOYSA-N dimethyl(diphenyl)phosphanium Chemical compound C=1C=CC=CC=1[P+](C)(C)C1=CC=CC=C1 BYGXNRZZNBOSBD-UHFFFAOYSA-N 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
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- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 230000002194 synthesizing effect Effects 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
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- 229910000510 noble metal Inorganic materials 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052711 selenium Inorganic materials 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
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- 239000010937 tungsten Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910052987 metal hydride Inorganic materials 0.000 claims 2
- 150000004681 metal hydrides Chemical class 0.000 claims 2
- 229910019655 synthetic inorganic crystalline material Inorganic materials 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 238000001354 calcination Methods 0.000 abstract description 4
- 125000004429 atom Chemical group 0.000 description 59
- 239000013078 crystal Substances 0.000 description 12
- -1 alkaline earth metal cations Chemical class 0.000 description 10
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- 150000001768 cations Chemical class 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 5
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000004305 biphenyl Substances 0.000 description 4
- 235000010290 biphenyl Nutrition 0.000 description 4
- 125000006267 biphenyl group Chemical group 0.000 description 4
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- 239000000499 gel Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
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- 238000003756 stirring Methods 0.000 description 4
- 229910017119 AlPO Inorganic materials 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- LTPBRCUWZOMYOC-UHFFFAOYSA-N Beryllium oxide Chemical compound O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
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- 230000003197 catalytic effect Effects 0.000 description 3
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- 230000000694 effects Effects 0.000 description 3
- 230000036571 hydration Effects 0.000 description 3
- 238000006703 hydration reaction Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 3
- 239000002808 molecular sieve Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000007669 thermal treatment Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000269350 Anura Species 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
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- 239000011149 active material Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000003957 anion exchange resin Substances 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 2
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- 229910052802 copper Inorganic materials 0.000 description 2
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- 238000005336 cracking Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- MGLUUYLPGOWCNW-UHFFFAOYSA-M dimethyl(diphenyl)phosphanium;iodide Chemical compound [I-].C=1C=CC=CC=1[P+](C)(C)C1=CC=CC=C1 MGLUUYLPGOWCNW-UHFFFAOYSA-M 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- GPAYUJZHTULNBE-UHFFFAOYSA-N diphenylphosphine Chemical compound C=1C=CC=CC=1PC1=CC=CC=C1 GPAYUJZHTULNBE-UHFFFAOYSA-N 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Chemical compound [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
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- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
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- 150000004706 metal oxides Chemical class 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
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- 239000002243 precursor Substances 0.000 description 2
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- 239000011593 sulfur Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
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- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- DLTRKOONGHEXQY-UHFFFAOYSA-N NN.[Li+] Chemical compound NN.[Li+] DLTRKOONGHEXQY-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- WNPMJIKMURUYFG-UHFFFAOYSA-N [N+](=O)([O-])[O-].[Ge+2].[N+](=O)([O-])[O-] Chemical compound [N+](=O)([O-])[O-].[Ge+2].[N+](=O)([O-])[O-] WNPMJIKMURUYFG-UHFFFAOYSA-N 0.000 description 1
- MIPBRUSCLWRYIR-UHFFFAOYSA-J [Zr+4].[O-]P(=O)OP([O-])=O.[O-]P(=O)OP([O-])=O Chemical compound [Zr+4].[O-]P(=O)OP([O-])=O.[O-]P(=O)OP([O-])=O MIPBRUSCLWRYIR-UHFFFAOYSA-J 0.000 description 1
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- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
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- 239000012298 atmosphere Substances 0.000 description 1
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- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000002288 cocrystallisation Methods 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
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- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229910001649 dickite Inorganic materials 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- ZIRGYXSHNNISGB-UHFFFAOYSA-M dimethyl(diphenyl)phosphanium;hydroxide Chemical compound [OH-].C=1C=CC=CC=1[P+](C)(C)C1=CC=CC=C1 ZIRGYXSHNNISGB-UHFFFAOYSA-M 0.000 description 1
- VCCPPDBHPDQSNT-UHFFFAOYSA-N dimethylphosphanium hydroxide Chemical compound [OH-].C[PH2+]C VCCPPDBHPDQSNT-UHFFFAOYSA-N 0.000 description 1
- MYTMXVHNEWBFAL-UHFFFAOYSA-L dipotassium;carbonate;hydrate Chemical compound O.[K+].[K+].[O-]C([O-])=O MYTMXVHNEWBFAL-UHFFFAOYSA-L 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- CTCOPPBXAFHGRB-UHFFFAOYSA-N ethanolate;germanium(4+) Chemical compound [Ge+4].CC[O-].CC[O-].CC[O-].CC[O-] CTCOPPBXAFHGRB-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
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- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229940044658 gallium nitrate Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011738 major mineral Substances 0.000 description 1
- 235000011963 major mineral Nutrition 0.000 description 1
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- 230000011987 methylation Effects 0.000 description 1
- 238000007069 methylation reaction Methods 0.000 description 1
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- 229910052680 mordenite Inorganic materials 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 125000003748 selenium group Chemical group *[Se]* 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
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Abstract
【選択図】図2
Description
R/YO2 0.01〜1
H2O/YO2 2〜50
X/YO2 0〜.2
そして好ましくは以下の範囲内:
R/YO2 0.1〜.5
H2O/YO2 5〜20
X/YO2 0〜.1
の組成で、シリカ供給源、有機構造指向剤(SDA)、水および任意の金属、Xを一緒に混合することによる、表2と同様の回折パターンを有するITQ−27の結晶性シリケート組成物の合成方法も含む。Xは1種以上のB、Ga、Al、Fe、Li、Be、P、Zn、Cr、Mg、Co、Ni、Be、Mn、As、In、Sn、Sb、TiおよびZrなどのいずれかの四面体配位可能な金属であり、より好ましくは1種以上の四面体配位可能な三価金属であり、そしてなおより好ましくは1種以上の元素B、Ga、AlおよびFeであり、そしてYは単独で、またはGeおよびTiなどのいずれかの他の四面体配位可能な四価金属との組み合わせでSiである。
K2CO3の存在下でクロロホルム中ヨウ化メチルによるジフェニルホスフィンのメチル化によって、図1に示されるジフェニル−ジメチル−ホスホニウムテンプレートを得た。次いでそれを一晩、アニオン交換樹脂によって相当する水酸化物にバッチ式で変換した。窒素雰囲気下(または水の不在下)で10.80g(0.058モル)のジフェニルホスフィンを50mlのイソプロパノールに溶解した。次いで9.55gの炭酸カリウムセスキ水和物を添加し、そして混合物を撹拌した。最後に24.60g(0.173モル)のヨウ化メチルを滴下した。48時間後、8gのヨウ化メチルを再び添加し、そして混合物を全5日間、放置した。
テフロン(登録商標)(Teflon)ライニングステンレス鋼オートクレーブにおいて熱水条件下および連続撹拌下で、以下の組成のゲルから合成を実行した。
SiO2:0.014 Al2O3:0.50 Me2Ph2POH:0.50 HF:4.2 H2O
0.29モル/1000gの溶液濃度を有する95.04gのジフェニル−ジメチル−ホスホニウム(Me2Ph2P)ヒドロキシド中で0.32gのアルミニウムイソプロポキシドおよび11.50gのオルトケイ酸テトラエチル(TEOS)を加水分解することによってITQ−27の合成を実行した。この混合物を撹拌下で濃縮し、そして加水分解において形成されたアルコールを完全に蒸発させた。1.14gのHF溶液(48.1重量%)を添加し、そして過剰量の水の完全蒸発まで混合物を撹拌下で放置した。少量の非晶質材料を有するITQ−27の種結晶を添加した(混合物中の全シリカに対して5重量%)。ゲルの組成は以下の通りである:
SiO2:0.014 Al2O3:0.50 Me2Ph2POH:0.50 HF:3 H2O
テフロン(登録商標)(Teflon)ライニングステンレス鋼オートクレーブ中、タンブリング下で混合物を48日間加熱した。生成物は純粋なITQ−27であった。空気中、580℃まで3時間、試料を焼成した。
・床表面積:450m2/g
・微孔面積:434m2/g
・微孔容積:0.21cm3/g
・孔直径:6.7Å
Claims (20)
- 架橋原子によって連結された四面体原子(T)のフレームワークを有し、明細書の表1に示される様式で最近位の四面体(T)原子を連結することによって四面体原子フレームワークが画定されることを特徴とする合成結晶性材料。
- 前記四面体原子がLi、Be、Al、P、Si、Ga、Ge、Zn、Cr、Mg、Fe、Co、Ni、Be、Mn、As、In、Sn、Sb、TiおよびZrよりなる群から選択される1種以上の元素を含むことを特徴とする請求項1に記載の結晶性材料。
- 前記架橋原子がO、N、F、S、SeおよびCよりなる群から選択される1種以上の元素を含むことを特徴とする請求項1に記載の結晶性材料。
- 実質的に明細書の表2に明示されるピークを含むX線回折パターンを特徴とする合成された状態の合成多孔性結晶性材料。
- mR:aX2O3:YO2・nH2O(式中、Rは有機化合物であり、XはB、Ga、AlおよびFeよりなる群から選択される1種以上の金属であり、YはSi、GeおよびTiよりなる群から選択される1種以上の金属であり、m、aおよびnは10以下の実数である)の組成を有することを特徴とする請求項4に記載の結晶性材料。
- 実質的に明細書の表3に明示される最も有意な線を含むX線回折パターンを有することを特徴とする焼成脱水材料。
- aX2O3:YO2・nH2O(式中、XはB、Ga、AlおよびFeよりなる群から選択される1種以上の金属であり、YはSi、GeおよびTiよりなる群から選択される1種以上の金属であり、aおよびnは10以下の実数である)の組成を有することを特徴とする請求項6に記載の焼成脱水材料。
- 請求項1〜7のいずれかに記載の材料を使用することを特徴とする炭化水素含有流から炭化水素を分離する方法。
- 有機化合物を含む供給原料を少なくとも一種の転化生成物へ転化する方法であって、請求項1〜7のいずれかに記載の材料の活性型を含む触媒と前記供給原料を、有機化合物転化条件下で接触させる工程を含むことを特徴とする転化方法。
- 前記触媒が水素化金属と組み合わされることを特徴とする請求項9に記載の転化方法。
- 前記水素化金属がタングステン、バナジウム、モリブデン、レニウム、ニッケル、コバルト、クロム、マンガンおよび貴金属よりなる群から選択される1種以上の金属であることを特徴とする請求項10に記載の転化方法。
- 表2と同様の回折パターンを有するITQ−27の結晶性シリケート組成物の合成方法であって、
シリカ供給源、有機構造指向剤(R)、水および任意の金属(X)を、モル比で以下の範囲内:
R/YO2 0.01〜1
H2O/YO2 2〜50
X/YO2 0〜.2
(式中、Xは四面体配位可能ないずれかの三価金属であり、Yはケイ素および四面体配位可能な任意のいずれかの他の四価金属である)
の組成で一緒に混合することによる合成方法。 - XがB、Ga、AlまたはFeよりなる群から選択される1種以上の金属であり、
Yがケイ素であり、かつGeおよびTiよりなる群から選択される1種以上の金属を含み得る
ことを特徴とする請求項12に記載の合成方法。 - 表2と同様の回折パターンを有するITQ−27の結晶性シリケート組成物の合成方法であって、
シリカ供給源、有機構造指向剤(R)、水および任意の金属(X)を、モル比で以下の範囲内:
R/YO2 0.01〜1
H2O/YO2 2〜50
X/YO2 0〜.2
(式中、XはB、Ga、Al、Fe、Li、Be、P、Zn、Cr、Mg、Co、Ni、Be、Mn、As、In、Sn、Sb、TiおよびZrよりなる群から選択される1種以上の金属であり、Yはケイ素であり、かつGeおよびTiよりなる群から選択される1種以上の金属を含み得る)
の組成で一緒に混合することによる合成方法。 - 前記モル比の範囲が
R/YO2 0.1〜.5
H2O/YO2 5〜20
X/YO2 0〜.1
であることを特徴とする請求項12〜14のいずれかに記載の合成方法。 - 前記有機構造指向剤(SDA)がジフェニル−ジメチル−ホスホニウムであることを特徴とする請求項12〜14のいずれかに記載の合成方法。
- 前記有機構造指向剤(SDA)がジフェニル−ジメチル−ホスホニウムであることを特徴とする請求項15に記載の合成方法。
- 請求項12、13、14および17のいずれかに記載の方法を使用して製造された生成物。
- 請求項15に記載の方法を使用して製造された生成物。
- 請求項16に記載の方法を使用して製造された生成物。
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JP2017128495A (ja) * | 2015-11-09 | 2017-07-27 | 中国石油化工股▲ふん▼有限公司 | Scm−11モレキュラーシーブ、その製造方法及びその使用 |
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ES2284379B1 (es) * | 2006-02-28 | 2008-11-01 | Universidad Politecnica De Valencia | Un material cristalino microporoso, zeolita itq-37, procedimiento de preparacion y uso. |
FR2901550B1 (fr) * | 2006-05-24 | 2008-09-12 | Inst Francais Du Petrole | Solide cristallise im-13 et son procede de preparation |
US7575737B1 (en) * | 2008-12-18 | 2009-08-18 | Uop Llc | UZM-27 family of crystalline aluminosilicate compositions and a method of preparing the compositions |
US8529868B2 (en) * | 2009-12-31 | 2013-09-10 | Exxonmobil Research And Engineering Company | ITQ-40, new crystalline microporous material |
US8672156B2 (en) * | 2011-01-25 | 2014-03-18 | Cap Craft Corp. | Bottle and cap |
ES2430404B1 (es) * | 2012-04-18 | 2014-09-29 | Consejo Superior De Investigaciones Científicas (Csic) | Material ITQ-49, su procedimiento de obtención y su uso |
US9861968B2 (en) | 2014-01-22 | 2018-01-09 | California Institute Of Technology | Methods for producing crystalline microporous solids with the HEU topology and compositions derived from the same |
CN107873015B (zh) | 2015-06-01 | 2021-12-24 | 加州理工学院 | 具有新的cit-13拓扑结构的晶体锗硅酸盐材料及其制备方法 |
US10828625B2 (en) | 2015-06-01 | 2020-11-10 | California Institute Of Technology | Crystalline germanosilicate materials of new CIT-13 topology and methods of preparing the same |
US9694353B2 (en) * | 2015-10-07 | 2017-07-04 | Chevron U.S.A. Inc. | Molecular sieve SSZ-90, its synthesis and use |
US10913053B2 (en) | 2016-03-04 | 2021-02-09 | California Institute Of Technology | Germanosilicate compositions and methods of preparing the same |
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JPS5988311A (ja) * | 1982-10-04 | 1984-05-22 | インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− | 結晶性ゼオライト物質およびその製造方法 |
JP2004501049A (ja) * | 2000-05-31 | 2004-01-15 | シェブロン ユー.エス.エー. インコーポレイテッド | ゼオライトssz−53 |
Cited By (2)
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JP2010511593A (ja) * | 2006-12-07 | 2010-04-15 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | Itq−34結晶性微細孔質物質 |
JP2017128495A (ja) * | 2015-11-09 | 2017-07-27 | 中国石油化工股▲ふん▼有限公司 | Scm−11モレキュラーシーブ、その製造方法及びその使用 |
Also Published As
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CA2586377C (en) | 2015-12-29 |
EP1824786B1 (en) | 2019-07-10 |
WO2006055305A3 (en) | 2007-01-18 |
US7527782B2 (en) | 2009-05-05 |
NO20073086L (no) | 2007-08-17 |
CA2586377A1 (en) | 2006-05-26 |
WO2006055305A2 (en) | 2006-05-26 |
BRPI0518354A2 (pt) | 2008-11-18 |
ES2745930T3 (es) | 2020-03-04 |
US20060110321A1 (en) | 2006-05-25 |
EP1824786A2 (en) | 2007-08-29 |
KR20070086328A (ko) | 2007-08-27 |
MX2007005445A (es) | 2007-09-27 |
JP5162249B2 (ja) | 2013-03-13 |
EP1824786A4 (en) | 2015-01-21 |
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