JP5331484B2 - Itq−26、新規結晶性微孔質物質 - Google Patents
Itq−26、新規結晶性微孔質物質 Download PDFInfo
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- JP5331484B2 JP5331484B2 JP2008547341A JP2008547341A JP5331484B2 JP 5331484 B2 JP5331484 B2 JP 5331484B2 JP 2008547341 A JP2008547341 A JP 2008547341A JP 2008547341 A JP2008547341 A JP 2008547341A JP 5331484 B2 JP5331484 B2 JP 5331484B2
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- 239000012229 microporous material Substances 0.000 title description 6
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
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- CTCOPPBXAFHGRB-UHFFFAOYSA-N ethanolate;germanium(4+) Chemical compound [Ge+4].CC[O-].CC[O-].CC[O-].CC[O-] CTCOPPBXAFHGRB-UHFFFAOYSA-N 0.000 description 1
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- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
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- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- XDNIBIHCBXESNN-UHFFFAOYSA-N phosphane;toluene Chemical compound P.CC1=CC=CC=C1 XDNIBIHCBXESNN-UHFFFAOYSA-N 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical class Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 125000003748 selenium group Chemical group *[Se]* 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000005469 synchrotron radiation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Images
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- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
- C01B39/082—Gallosilicates
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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- C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
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- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
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- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
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- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
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- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
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- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
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- Oil, Petroleum & Natural Gas (AREA)
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- General Chemical & Material Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Description
N0=1 N1≦4 N2≦12 N3≦36 Nk≦4×3k−1
R/YO2 0.01〜1
H2O/YO2 2〜50
X/YO2 0〜0.2
そして好ましくは次の範囲内:
R/YO2 0.1〜0.5
H2O/YO2 5〜20
X/YO2 0〜0.1
の組成の、そして、XがB、Ga、Al、Fe、Li、Be、P、Zn、Cr、Mg、Co、Ni、Mn、As、In、Sn、Sb、Ti、およびZrの1種以上などの四面体配位できる任意の金属、より好ましくは四面体配位できる1種以上の3価金属、更により好ましくは元素B、Ga、Al、およびFeの1種以上であり、そしてYは、単独でのまたはGeおよびTiなどの四面体配位できる任意の他の4価金層と組み合わせたSiである、表2と類似した回折パターンを有するITQ−26の結晶性シリケート組成物の合成方法を含む。
ゲルマニウム含有ゲルを次の記載に従って調製した:0.62gの酸化ゲルマニウムを、1000gの溶液中0.62モルのOH濃度の水酸化1,3−ビス−(トリエチルホスホニウムメチル)−ベンゼン(図1)の24.19gの溶液に溶解させた。次に、5.02gのオルトケイ酸テトラエチルを当該溶液中で加水分解し、混合物を、形成したエタノールの完全な蒸発が達成されるまで撹拌下に蒸発させた。重量が8.62gのゲルに達したとき、0.62gのHF(48.1%重量)を加え、混合物を均質にした。ゲルの最終組成は次の通りであった:
0.80 SiO2:0.20 GeO2:0.25 m−B(Et3P)2(OH)2:0.50 HF:7.50 H2O
・BET表面積:257m2/g
・微孔面積:243m2/g
・微孔体積:0.12cm3/g
・孔直径:7.1Å
ゲルマニウム含有ゲルを次の記載に従って調製した:0.75gの酸化ゲルマニウムを、15重量%の水酸化1,3−ビス−(トリエチルホスホニウムメチル)−ベンゼンの22.5gの溶液に溶解させた。次に、6.01gのオルトケイ酸テトラエチルを当該溶液中で加水分解し、混合物を、形成したエタノールの完全な蒸発が達成されるまで撹拌下に蒸発させた。重量が10.3gのゲルに達したとき、0.74gのHF(49%重量)を加え、混合物を均質にした。ゲルの最終組成は次の通りであった:
0.80 SiO2:0.20 GeO2:0.25 m−B(Et3P)2(OH)2:0.50 HF:7.50 H2O
Claims (17)
- 前記四面体原子は、Li、Be、Al、P、Si、Ga、Ge、Zn、Cr、Mg、Fe、Co、Ni、Mn、As、In、Sn、Sb、TiおよびZrからなる群から選択された1種以上の元素を含むことを特徴とする請求項1に記載の結晶性物質。
- 前記橋架け原子は、O、N、F、S、SeおよびCからなる群から選択された1種以上の元素を含むことを特徴とする請求項1または2に記載の結晶性物質。
- 式 mR:aX2O3:YO2・nH2O
(式中、Rは有機化合物であり;XはB、Ga、AlおよびFeからなる群から選択された1種以上の金属であり;YはSi、GeおよびTiからなる群から選択された1種以上の金属であり;mは1以下の実数であり、aは0.2以下の実数であり;nは10以下の実数である)で表される組成を有することを特徴とする請求項4に記載の結晶性物質。 - 式 aX2O3:YO2・nH2O
(式中、XはB、Ga、AlおよびFeからなる群から選択された1種以上の金属であり;YはSi、GeおよびTiからなる群から選択された1種以上の金属であり;aは0.2以下の実数であり;nは10以下の実数である)で表される組成を有することを特徴とする請求項6に記載の焼成脱水物質。 - 請求項6に記載の物質を使用することを特徴とする炭化水素含有流れからの炭化水素の分離方法。
- 有機化合物を含む供給原料を少なくとも1種の転化生成物に転化する方法であって、
前記供給原料を、活性形態にある請求項6に記載の物質を含む触媒と有機化合物転化条件で接触させる工程を含むことを特徴とする方法。 - 前記触媒は、水素化金属と組み合わせられることを特徴とする請求項9に記載の方法。
- 前記水素化金属は、タングステン、バナジウム、モリブデン、レニウム、ニッケル、コバルト、クロム、マンガンおよび貴金属からなる群から選択された1種以上の金属であることを特徴とする請求項10に記載の方法。
- Xは、B、Ga、AlおよびFeからなる群から選択された1種以上の金属であり、
Yは、ケイ素であり、かつGeおよびTiからなる群から選択された1種以上の金属を含むことができる
ことを特徴とする請求項12に記載の方法。 - 前記モル比範囲は、
R/YO2 0.1〜0.5
H2O/YO2 5〜20
X/YO2 0〜0.1
であることを特徴とする請求項12に記載の方法。 - 前記有機構造指向剤(SDA)は、1,3−ビス−(トリエチルホスホニウムメチル)ベンゼンであることを特徴とする請求項12に記載の結晶性シリケート組成物の合成方法。
- 請求項12に記載の方法を用いて製造されることを特徴とする結晶性シリケート組成物。
- 下記の表5と同様の回折パターンを有する結晶性シリケート組成物ITQ−26の合成方法であって、
シリカ源、有機構造指向剤(R)、水および場合により金属源(X)を混ぜ合わせて、モル比換算で下記の範囲の組成を有する混合物を形成することによることを特徴とする方法。
R/YO2 0.01〜1
H2O/YO2 2〜50
X/YO2 0〜0.2
(式中、Xは、B、Ga、Al、Fe、Li、Be、P、Zn、Cr、Mg、Co、Ni、Mn、As、In、Sn、Sb、TiおよびZrからなる群から選択された1種以上の金属であり;Yは、ケイ素であり、かつGeおよびTiからなる群から選択された1種以上の金属を含むことができる。)
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US75187505P | 2005-12-20 | 2005-12-20 | |
US60/751,875 | 2005-12-20 | ||
PCT/US2006/047849 WO2007075382A1 (en) | 2005-12-20 | 2006-12-15 | Itq-26, new crystalline microporous material |
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EP (1) | EP1973847A1 (ja) |
JP (1) | JP5331484B2 (ja) |
CN (1) | CN101341093B (ja) |
CA (1) | CA2631560C (ja) |
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US8025864B2 (en) | 2006-12-07 | 2011-09-27 | Exxonmobil Research And Engineering Company | ITQ-34, new crystalline microporous material |
US8529868B2 (en) * | 2009-12-31 | 2013-09-10 | Exxonmobil Research And Engineering Company | ITQ-40, new crystalline microporous material |
US9782759B2 (en) | 2014-01-22 | 2017-10-10 | California Institute Of Technology | Methods for producing crystalline microporous solids with IWV topology and compositions derived from the same |
WO2018227850A1 (zh) * | 2017-06-13 | 2018-12-20 | 中国石油化工股份有限公司 | 分子筛scm-15、其合成方法及其用途 |
CN111491891B (zh) * | 2017-12-21 | 2023-07-04 | 埃克森美孚科技工程公司 | Emm-31材料及其方法和用途 |
CN114180595B (zh) * | 2020-09-14 | 2023-09-29 | 中国石油化工股份有限公司 | Itq-26分子筛及其制备方法 |
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US3354078A (en) | 1965-02-04 | 1967-11-21 | Mobil Oil Corp | Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide |
US4310440A (en) | 1980-07-07 | 1982-01-12 | Union Carbide Corporation | Crystalline metallophosphate compositions |
US4440871A (en) | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
US4707345A (en) * | 1984-04-26 | 1987-11-17 | Union Carbide Corporation | Titanium-aluminum-silicon-oxide molecular sieve compositions and process for preparing the same |
US4582693A (en) * | 1984-11-16 | 1986-04-15 | The Standard Oil Company | Synthesis of silica molecular sieves using synthesis directing organic dyes |
US4913799A (en) * | 1984-12-18 | 1990-04-03 | Uop | Hydrocracking catalysts and processes employing non-zeolitic molecular sieves |
JPS63129014A (ja) * | 1986-09-04 | 1988-06-01 | ユニオン・オイル・コンパニー・オブ・カリフォルニア | オフレタイト構造を有する結晶質ガリオシリケート分子篩およびその製造方法 |
ES2186487B1 (es) * | 2000-10-11 | 2004-01-16 | Univ Valencia Politecnica | Zeolita itq-15. |
ES2186489B1 (es) * | 2000-10-11 | 2004-01-16 | Univ Valencia Politecnica | Zeolita itq-16. |
ES2200624B1 (es) * | 2001-02-09 | 2005-05-01 | Universidad Politecnica De Valencia | Sintesis en medio alcalino de la zeolita itq.-16. |
US6471941B1 (en) * | 2001-05-29 | 2002-10-29 | Exxonmobil Research And Engineering Company | Synthetic porous crystalline material ITQ-13, its synthesis and use |
US6471939B1 (en) * | 2001-05-29 | 2002-10-29 | Exxonmobil Research And Engineering Company | Synthetic porous crystalline material ITQ-12, its synthesis and use |
ES2196963B1 (es) * | 2001-07-03 | 2005-02-16 | Universidad Politecnica De Valencia | Sintesis de itq-17 en ausencia de iones fluoruro. |
ES2204257B1 (es) * | 2001-11-30 | 2005-05-01 | Universidad Politecnica De Valencia | Sintesis de itq-21 en ausencia de iones fluoruro. |
US7449169B2 (en) * | 2002-05-23 | 2008-11-11 | Consejo Superior De Investigaciones Cientificas | Microporous crystalline zeolite material (zeolite ITQ-22), synthesis method thereof and use of same as a catalyst |
US20050238575A1 (en) * | 2004-04-23 | 2005-10-27 | Avelino Corma | ITQ-25, new crystalline microporous material |
US8025864B2 (en) * | 2006-12-07 | 2011-09-27 | Exxonmobil Research And Engineering Company | ITQ-34, new crystalline microporous material |
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