ES2196963B1 - Sintesis de itq-17 en ausencia de iones fluoruro. - Google Patents
Sintesis de itq-17 en ausencia de iones fluoruro.Info
- Publication number
- ES2196963B1 ES2196963B1 ES200101608A ES200101608A ES2196963B1 ES 2196963 B1 ES2196963 B1 ES 2196963B1 ES 200101608 A ES200101608 A ES 200101608A ES 200101608 A ES200101608 A ES 200101608A ES 2196963 B1 ES2196963 B1 ES 2196963B1
- Authority
- ES
- Spain
- Prior art keywords
- itq
- synthesis
- absence
- fluoride ions
- azoniabicyclo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- -1 FLUORIDE IONS Chemical class 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- SBYHFKPVCBCYGV-UHFFFAOYSA-N quinuclidine Chemical compound C1CC2CCN1CC2 SBYHFKPVCBCYGV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000002178 crystalline material Substances 0.000 abstract 1
- 150000002222 fluorine compounds Chemical class 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/27—Beta, e.g. NU-2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Síntesis de ITQ-17 en ausencia de iones fluoruro. En la presente invención, se presenta un material cristalino microporoso, que en estado calcinado tiene una composición equivalente a la ITQ-17, que no contiene fluoruros y que en su forma sintetizada sin calcinar tiene una composición molar en forma de óxidos y en su forma anhidra: xX2 03 : (1-z)Y02 : zGe02 : r/n Rn0 en la que X es un elemento trivalente tal como A1, B, Fe, In, Ga, Cr, o mezclas de estos, Y es uno o más elementos tetravalentes distinto/s de germanio, y preferentemente silicio, y R es un compuesto orgánico director de estructura y preferentemente el catión 1-metil-4- Aza,1-azoniabiciclo [2.2.2] octano (DABMe+) o el catión 1,4- bis[N-(4-aza,1-azoniabiciclo [2,2,2] octano) metil]benceno (d- DABBz)2+.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200101608A ES2196963B1 (es) | 2001-07-03 | 2001-07-03 | Sintesis de itq-17 en ausencia de iones fluoruro. |
CNB02817206XA CN1325379C (zh) | 2001-07-03 | 2002-07-03 | 在氟离子不存在下合成itq-17 |
CA002452840A CA2452840A1 (en) | 2001-07-03 | 2002-07-03 | Synthesis of itq-17 in the absence of fluoride ions |
PCT/ES2002/000330 WO2003004413A1 (es) | 2001-07-03 | 2002-07-03 | Sintesis de itq-17 en ausencia de iones fluoruro |
JP2003510391A JP2004533395A (ja) | 2001-07-03 | 2002-07-03 | フッ化物イオンの不存在下でのitq−17の合成 |
EP20020745443 EP1413553A1 (en) | 2001-07-03 | 2002-07-03 | Synthesis of itq-17 in the absence of fluoride ions |
US10/750,329 US7014836B2 (en) | 2001-07-03 | 2003-12-31 | Synthesis of ITQ-17 in the absence of fluoride ions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200101608A ES2196963B1 (es) | 2001-07-03 | 2001-07-03 | Sintesis de itq-17 en ausencia de iones fluoruro. |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2196963A1 ES2196963A1 (es) | 2003-12-16 |
ES2196963B1 true ES2196963B1 (es) | 2005-02-16 |
Family
ID=8498354
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES200101608A Expired - Fee Related ES2196963B1 (es) | 2001-07-03 | 2001-07-03 | Sintesis de itq-17 en ausencia de iones fluoruro. |
Country Status (7)
Country | Link |
---|---|
US (1) | US7014836B2 (es) |
EP (1) | EP1413553A1 (es) |
JP (1) | JP2004533395A (es) |
CN (1) | CN1325379C (es) |
CA (1) | CA2452840A1 (es) |
ES (1) | ES2196963B1 (es) |
WO (1) | WO2003004413A1 (es) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7449168B2 (en) * | 2004-12-27 | 2008-11-11 | Saudi Basic Industries Corporation | Process for making a germanium-zeolite |
US7029650B1 (en) * | 2004-12-27 | 2006-04-18 | Saudi Basic Industries Corporation | Process for making a germanium-zeolite |
ES2259537B1 (es) * | 2005-01-17 | 2007-11-01 | Universidad Politecnica De Valencia | Sintesis de la zeolita itq-33. |
WO2007075382A1 (en) * | 2005-12-20 | 2007-07-05 | Exxonmobil Research And Engineering Company | Itq-26, new crystalline microporous material |
US7791282B2 (en) | 2006-11-28 | 2010-09-07 | Hubbell Incorporated | Motion sensor switch for 3-way light circuit and method of lighting control using the same |
WO2009134534A2 (en) * | 2008-05-02 | 2009-11-05 | Exxonmobil Chemical Patents Inc. | Treatment of small pore molecular sieves and their use in the conversion of oxygenates to olefins |
US10913053B2 (en) | 2016-03-04 | 2021-02-09 | California Institute Of Technology | Germanosilicate compositions and methods of preparing the same |
CN108217671B (zh) * | 2016-12-09 | 2021-08-31 | 中国科学院大连化学物理研究所 | 一种含锡bec型分子筛及其制备方法 |
CN115697909A (zh) | 2020-05-22 | 2023-02-03 | 雪佛龙美国公司 | 分子筛ssz-120、其合成和用途 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3459676A (en) * | 1966-06-14 | 1969-08-05 | Mobil Oil Corp | Synthetic zeolite and method for preparing the same |
US3692470A (en) * | 1969-10-09 | 1972-09-19 | Mobil Oil Corp | Crystalline zeolite zsm-10 |
US4582693A (en) * | 1984-11-16 | 1986-04-15 | The Standard Oil Company | Synthesis of silica molecular sieves using synthesis directing organic dyes |
ES2155761B1 (es) * | 1998-12-22 | 2001-12-01 | Univ Valencia Politecnica | Zeolita itq-7. |
ES2186488B1 (es) * | 2000-10-11 | 2004-01-16 | Univ Valencia Politecnica | Zeolita itq-17. |
ES2200624B1 (es) * | 2001-02-09 | 2005-05-01 | Universidad Politecnica De Valencia | Sintesis en medio alcalino de la zeolita itq.-16. |
US6787124B2 (en) * | 2002-03-15 | 2004-09-07 | Exxonmobil Research And Engineering Company | Synthetic porous crystalline material, EMM-1, its synthesis and use |
-
2001
- 2001-07-03 ES ES200101608A patent/ES2196963B1/es not_active Expired - Fee Related
-
2002
- 2002-07-03 CN CNB02817206XA patent/CN1325379C/zh not_active Expired - Fee Related
- 2002-07-03 CA CA002452840A patent/CA2452840A1/en not_active Abandoned
- 2002-07-03 EP EP20020745443 patent/EP1413553A1/en not_active Withdrawn
- 2002-07-03 WO PCT/ES2002/000330 patent/WO2003004413A1/es active Application Filing
- 2002-07-03 JP JP2003510391A patent/JP2004533395A/ja not_active Ceased
-
2003
- 2003-12-31 US US10/750,329 patent/US7014836B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
TAKEWAKI, T. et al. Zeolite synthesis using 1,4-diazabiciclo[2.2.2]octane (DABCO) derivatives as structure-directing agents. Microporous and Mesoporous Materials, 1999, Volumen 33, páginas 197-207, 28.06.1999. * |
Also Published As
Publication number | Publication date |
---|---|
CN1714044A (zh) | 2005-12-28 |
US7014836B2 (en) | 2006-03-21 |
JP2004533395A (ja) | 2004-11-04 |
EP1413553A1 (en) | 2004-04-28 |
CA2452840A1 (en) | 2003-01-16 |
US20040171477A1 (en) | 2004-09-02 |
WO2003004413A1 (es) | 2003-01-16 |
CN1325379C (zh) | 2007-07-11 |
ES2196963A1 (es) | 2003-12-16 |
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Legal Events
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