ES2196963A1 - Sintesis de itq-17 en ausencia de iones fluoruro. - Google Patents

Sintesis de itq-17 en ausencia de iones fluoruro.

Info

Publication number
ES2196963A1
ES2196963A1 ES200101608A ES200101608A ES2196963A1 ES 2196963 A1 ES2196963 A1 ES 2196963A1 ES 200101608 A ES200101608 A ES 200101608A ES 200101608 A ES200101608 A ES 200101608A ES 2196963 A1 ES2196963 A1 ES 2196963A1
Authority
ES
Spain
Prior art keywords
strong
medium
calcined form
new
itq
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200101608A
Other languages
English (en)
Other versions
ES2196963B1 (es
Inventor
Canos Avelino Corma
Villalba M Teresa Navarro
Garcia Fernando Rey
Valencia Susana Valencia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES200101608A priority Critical patent/ES2196963B1/es
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to JP2003510391A priority patent/JP2004533395A/ja
Priority to CA002452840A priority patent/CA2452840A1/en
Priority to PCT/ES2002/000330 priority patent/WO2003004413A1/es
Priority to CNB02817206XA priority patent/CN1325379C/zh
Priority to EP20020745443 priority patent/EP1413553A1/en
Publication of ES2196963A1 publication Critical patent/ES2196963A1/es
Priority to US10/750,329 priority patent/US7014836B2/en
Application granted granted Critical
Publication of ES2196963B1 publication Critical patent/ES2196963B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/27—Beta, e.g. NU-2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

Síntesis de ITQ-17 en ausencia de iones fluoruro. En la presente invención, se presenta un material cristalino microporoso, que en estado calcinado tiene una composición equivalente a la ITQ-17, que no contiene fluoruros y que en su forma sintetizada sin calcinar tiene una composición molar en forma de óxidos y en su forma anhidra: xX2 03 : (1-z)Y02 : zGe02 : r/n Rn0 en la que X es un elemento trivalente tal como A1, B, Fe, In, Ga, Cr, o mezclas de estos, Y es uno o más elementos tetravalentes distinto/s de germanio, y preferentemente silicio, y R es un compuesto orgánico director de estructura y preferentemente el catión 1-metil-4- Aza,1-azoniabiciclo [2.2.2] octano (DABMe+) o el catión 1,4- bis[N-(4-aza,1-azoniabiciclo [2,2,2] octano) metil]benceno (d- DABBz)2+.
ES200101608A 2001-07-03 2001-07-03 Sintesis de itq-17 en ausencia de iones fluoruro. Expired - Fee Related ES2196963B1 (es)

Priority Applications (7)

Application Number Priority Date Filing Date Title
ES200101608A ES2196963B1 (es) 2001-07-03 2001-07-03 Sintesis de itq-17 en ausencia de iones fluoruro.
CA002452840A CA2452840A1 (en) 2001-07-03 2002-07-03 Synthesis of itq-17 in the absence of fluoride ions
PCT/ES2002/000330 WO2003004413A1 (es) 2001-07-03 2002-07-03 Sintesis de itq-17 en ausencia de iones fluoruro
CNB02817206XA CN1325379C (zh) 2001-07-03 2002-07-03 在氟离子不存在下合成itq－17
JP2003510391A JP2004533395A (ja) 2001-07-03 2002-07-03 フッ化物イオンの不存在下でのｉｔｑ−１７の合成
EP20020745443 EP1413553A1 (en) 2001-07-03 2002-07-03 Synthesis of itq-17 in the absence of fluoride ions
US10/750,329 US7014836B2 (en) 2001-07-03 2003-12-31 Synthesis of ITQ-17 in the absence of fluoride ions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200101608A ES2196963B1 (es) 2001-07-03 2001-07-03 Sintesis de itq-17 en ausencia de iones fluoruro.

Publications (2)

Publication Number Publication Date
ES2196963A1 true ES2196963A1 (es) 2003-12-16
ES2196963B1 ES2196963B1 (es) 2005-02-16

Family

ID=8498354

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200101608A Expired - Fee Related ES2196963B1 (es) 2001-07-03 2001-07-03 Sintesis de itq-17 en ausencia de iones fluoruro.

Country Status (7)

Country Link
US (1) US7014836B2 (es)
EP (1) EP1413553A1 (es)
JP (1) JP2004533395A (es)
CN (1) CN1325379C (es)
CA (1) CA2452840A1 (es)
ES (1) ES2196963B1 (es)
WO (1) WO2003004413A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7449168B2 (en) * 2004-12-27 2008-11-11 Saudi Basic Industries Corporation Process for making a germanium-zeolite
US7029650B1 (en) * 2004-12-27 2006-04-18 Saudi Basic Industries Corporation Process for making a germanium-zeolite
ES2259537B1 (es) * 2005-01-17 2007-11-01 Universidad Politecnica De Valencia Sintesis de la zeolita itq-33.
CA2631560C (en) * 2005-12-20 2014-08-12 Exxonmobil Research And Engineering Company Itq-26, new crystalline microporous material
US7791282B2 (en) 2006-11-28 2010-09-07 Hubbell Incorporated Motion sensor switch for 3-way light circuit and method of lighting control using the same
WO2009134534A2 (en) * 2008-05-02 2009-11-05 Exxonmobil Chemical Patents Inc. Treatment of small pore molecular sieves and their use in the conversion of oxygenates to olefins
EP3950591A1 (en) * 2016-03-04 2022-02-09 California Institute of Technology New germanosilicate compositions and methods of preparing the same
CN108217671B (zh) * 2016-12-09 2021-08-31 中国科学院大连化学物理研究所 一种含锡bec型分子筛及其制备方法
KR20230015379A (ko) 2020-05-22 2023-01-31 셰브런 유.에스.에이.인크. 분자체 ssz-120, 이의 합성 및 용도

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3459676A (en) * 1966-06-14 1969-08-05 Mobil Oil Corp Synthetic zeolite and method for preparing the same
US3692470A (en) * 1969-10-09 1972-09-19 Mobil Oil Corp Crystalline zeolite zsm-10

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4582693A (en) * 1984-11-16 1986-04-15 The Standard Oil Company Synthesis of silica molecular sieves using synthesis directing organic dyes
ES2155761B1 (es) * 1998-12-22 2001-12-01 Univ Valencia Politecnica Zeolita itq-7.
ES2186488B1 (es) * 2000-10-11 2004-01-16 Univ Valencia Politecnica Zeolita itq-17.
ES2200624B1 (es) * 2001-02-09 2005-05-01 Universidad Politecnica De Valencia Sintesis en medio alcalino de la zeolita itq.-16.
US6787124B2 (en) * 2002-03-15 2004-09-07 Exxonmobil Research And Engineering Company Synthetic porous crystalline material, EMM-1, its synthesis and use

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3459676A (en) * 1966-06-14 1969-08-05 Mobil Oil Corp Synthetic zeolite and method for preparing the same
US3692470A (en) * 1969-10-09 1972-09-19 Mobil Oil Corp Crystalline zeolite zsm-10

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
TAKEWAKI, T. et al. Zeolite synthesis using 1,4-diazabiciclo[2.2.2]octane (DABCO) derivatives as structure-directing agents. Microporous and Mesoporous Materials, 1999, Volumen 33, pßginas 197-207, 28.06.1999. *

Also Published As

Publication number Publication date
CN1325379C (zh) 2007-07-11
WO2003004413A1 (es) 2003-01-16
ES2196963B1 (es) 2005-02-16
CA2452840A1 (en) 2003-01-16
EP1413553A1 (en) 2004-04-28
CN1714044A (zh) 2005-12-28
US7014836B2 (en) 2006-03-21
JP2004533395A (ja) 2004-11-04
US20040171477A1 (en) 2004-09-02

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