WO2004071956A3 - Un material cristalino poroso (zeolita itq-24), su procedimiento de preparación y su uso en la conversión catalítica de compuestos orgánicos - Google Patents

Un material cristalino poroso (zeolita itq-24), su procedimiento de preparación y su uso en la conversión catalítica de compuestos orgánicos Download PDF

Info

Publication number
WO2004071956A3
WO2004071956A3 PCT/ES2004/070006 ES2004070006W WO2004071956A3 WO 2004071956 A3 WO2004071956 A3 WO 2004071956A3 ES 2004070006 W ES2004070006 W ES 2004070006W WO 2004071956 A3 WO2004071956 A3 WO 2004071956A3
Authority
WO
WIPO (PCT)
Prior art keywords
crystalline material
porous crystalline
preparation
organic compounds
same
Prior art date
Application number
PCT/ES2004/070006
Other languages
English (en)
French (fr)
Other versions
WO2004071956A2 (es
Inventor
Canos Avelino Corma
Sanchez Rafael Castaneda
Segui Vicente Fornes
Garcia Fernando Rey
Original Assignee
Consejo Superior Investigacion
Univ Valencia Politecnica
Canos Avelino Corma
Sanchez Rafael Castaneda
Segui Vicente Fornes
Garcia Fernando Rey
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior Investigacion, Univ Valencia Politecnica, Canos Avelino Corma, Sanchez Rafael Castaneda, Segui Vicente Fornes, Garcia Fernando Rey filed Critical Consejo Superior Investigacion
Priority to EP04709639A priority Critical patent/EP1609758B1/en
Priority to JP2006502054A priority patent/JP4791953B2/ja
Priority to ES04709639T priority patent/ES2392048T3/es
Priority to CA2516046A priority patent/CA2516046C/en
Publication of WO2004071956A2 publication Critical patent/WO2004071956A2/es
Publication of WO2004071956A3 publication Critical patent/WO2004071956A3/es
Priority to US11/200,534 priority patent/US7344696B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención se refiere a un material sintético, poroso y cristalino caracterizado porque està formado por átomos en coordinación tetraédrica unidos entre sí a través de oxígenos, que presenta un celda unidad que contiene 56 átomos en coordinación tetraédrica, que se denomina ITQ-24, cuya fórmula química en estado calcinado y anhidro viene dada por nM1/pXO2: YO2 en la que X es al menos un elemento trivalente, Y es al menos un elemento tetravalente, el valor de n està comprendido entre 0 y 0.2 y M es al menos un catión de compensación de carga en estado de oxidación p.
PCT/ES2004/070006 2003-02-14 2004-02-10 Un material cristalino poroso (zeolita itq-24), su procedimiento de preparación y su uso en la conversión catalítica de compuestos orgánicos WO2004071956A2 (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP04709639A EP1609758B1 (en) 2003-02-14 2004-02-10 Porous crystalline material (zeolite itq-24), preparation method thereof and use of same in the catalytic conversion of organic compounds
JP2006502054A JP4791953B2 (ja) 2003-02-14 2004-02-10 多孔質結晶性物質（ゼオライトｉｔｑ−２４）、該結晶性物質の製造方法及び該結晶性物質の有機化合物の接触変換における使用
ES04709639T ES2392048T3 (es) 2003-02-14 2004-02-10 Material cristalino poroso (zeolita ITQ-24), su procedimiento de preparación y su uso en la conversión catalítica de compuestos orgánicos
CA2516046A CA2516046C (en) 2003-02-14 2004-02-10 Porous crystalline material (zeolite itq-24), preparation method thereof and use of same in the catalytic conversion of organic compounds
US11/200,534 US7344696B2 (en) 2003-02-14 2005-08-09 Porous crystalline material (zeolite ITQ-24), preparation method thereof and use of same in the catalytic conversion of organic compounds

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES200300445A ES2217962B1 (es) 2003-02-14 2003-02-14 Material cristalino poroso (zeolita itq-24),su procedimiento de preparacion y su uso en la conversion catalitica de componentes organicos.
ESP200300445 2003-02-14

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/200,534 Continuation US7344696B2 (en) 2003-02-14 2005-08-09 Porous crystalline material (zeolite ITQ-24), preparation method thereof and use of same in the catalytic conversion of organic compounds

Publications (2)

Publication Number Publication Date
WO2004071956A2 WO2004071956A2 (es) 2004-08-26
WO2004071956A3 true WO2004071956A3 (es) 2004-09-16

Family

ID=32865140

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/ES2004/070006 WO2004071956A2 (es) 2003-02-14 2004-02-10 Un material cristalino poroso (zeolita itq-24), su procedimiento de preparación y su uso en la conversión catalítica de compuestos orgánicos

Country Status (9)

Country Link
US (1) US7344696B2 (es)
EP (1) EP1609758B1 (es)
JP (1) JP4791953B2 (es)
KR (1) KR20060002765A (es)
CN (1) CN100422082C (es)
CA (1) CA2516046C (es)
ES (2) ES2217962B1 (es)
WO (1) WO2004071956A2 (es)
ZA (1) ZA200507353B (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2228278B1 (es) * 2003-09-29 2006-06-01 Universidad Politecnica De Valencia. Material cristalino microporoso de naturaleza zeolitica (zeolita itq-28).
ES2259537B1 (es) * 2005-01-17 2007-11-01 Universidad Politecnica De Valencia Sintesis de la zeolita itq-33.
FR2901550B1 (fr) * 2006-05-24 2008-09-12 Inst Francais Du Petrole Solide cristallise im-13 et son procede de preparation
US20090132093A1 (en) * 2007-08-21 2009-05-21 Motorola, Inc. Tactile Conforming Apparatus and Method for a Device
FR2923476B1 (fr) * 2007-11-12 2010-12-31 Inst Francais Du Petrole Solide cristalise im-17 et son procede de preparation
AU2010259935B2 (en) 2009-06-13 2016-05-26 Archer-Daniels-Midland Company Production of glutaric acid and derivatives from carbohydrate-containing materials
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
NZ596975A (en) 2009-06-13 2014-04-30 Rennovia Inc Production of adipic acid and derivatives from carbohydrate-containing materials
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
JP2012208325A (ja) * 2011-03-30 2012-10-25 Tosoh Corp 第四級アンモニウム化合物、その製造法及びそれを含む現像液組成物
US8763364B2 (en) 2011-04-18 2014-07-01 Chevron U.S.A. Inc. Treatment of cold start engine exhaust
US8772192B2 (en) * 2012-06-29 2014-07-08 Saudi Basic Industries Corporation Germanium silicalite catalyst and method of preparation and use
FR3063994B1 (fr) * 2017-03-17 2022-01-21 Arkema France Procede de synthese a ensemencement multiple de cristaux de zeolithe a granulometrie controlee
CN113966251A (zh) * 2019-06-06 2022-01-21 巴斯夫欧洲公司 Iwr骨架结构类型的硅铝酸盐沸石材料的直接合成及其在催化中的用途
JP2023510001A (ja) * 2020-01-16 2023-03-10 シェブロン ユー．エス．エー． インコーポレイテッド 分子篩ｓｓｚ－１１７、その合成及び使用
US11865524B2 (en) 2020-01-16 2024-01-09 Chevron U.S.A. Inc. Molecular sieve SSZ-117x, its synthesis and use
CN111847474B (zh) * 2020-07-17 2021-09-28 浙江恒澜科技有限公司 一种Ti-ITQ-24沸石分子筛及其原位合成方法和应用
CN113004149A (zh) * 2021-02-26 2021-06-22 大连理工大学 一种双季铵盐类化合物的制备方法
WO2023213936A1 (en) 2022-05-05 2023-11-09 Basf Se Synthesis of zeolitic materials of the iwr framework structure type from zeolitic precursor materials

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4676958A (en) * 1985-03-06 1987-06-30 Chevron Research Company Preparation of crystalline zeolites using magadiite
US5219813A (en) * 1992-01-03 1993-06-15 Council Of Scientific & Industrial Research Process for the preparation of novel molecular sieves
EP0551688A1 (en) * 1992-01-08 1993-07-21 Council of Scientific and Industrial Research A process for the preparation of crystalline molecular sieves
US6471940B1 (en) * 1999-09-28 2002-10-29 Japan Chemical Innovation Institute Preparation of zeolite

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4241068B2 (ja) 2002-03-07 2009-03-18 昭和電工株式会社 Ｍｗｗ型ゼオライト物質の製造方法
US7390763B2 (en) * 2003-10-31 2008-06-24 Chevron U.S.A. Inc. Preparing small crystal SSZ-32 and its use in a hydrocarbon conversion process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4676958A (en) * 1985-03-06 1987-06-30 Chevron Research Company Preparation of crystalline zeolites using magadiite
US5219813A (en) * 1992-01-03 1993-06-15 Council Of Scientific & Industrial Research Process for the preparation of novel molecular sieves
EP0551688A1 (en) * 1992-01-08 1993-07-21 Council of Scientific and Industrial Research A process for the preparation of crystalline molecular sieves
US6471940B1 (en) * 1999-09-28 2002-10-29 Japan Chemical Innovation Institute Preparation of zeolite

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
BHAUMIK A. ET AL.: "Synthesis of MTW-type material and its vanadium-silicate analogue using diquaternary ammonium cation as a template", MICROPOROUS MATERIALS, vol. 5, no. 3, 1995, pages 173 - 178, XP008040725 *
CASTANEDA R. ET AL.: "Synthesis of a new zeolite structure ITQ-24, with intersecting 10- and 12- membered ring pores", J. AM. CHEM. SOC., vol. 125, no. 26, 2003, pages 7820 - 7821, XP002904857 *
MAL, N.K. ET AL.: "Sn-ZSM-12, a new large pore MTW type tin-silicate molecular sieve: synthesis, characterization and catalytic properties in oxidation reactions", CATALYSIS LETTERS, vol. 33, no. 3,4, 1995, pages 387 - 394, XP008040789 *
TUEL, A.: "Synthesis, characterization and catalytic properties of the new TiZSM-12 zeolite", ZEOLITES, vol. 15, no. 3, 1995, pages 236 - 242, XP004033631 *

Also Published As

Publication number Publication date
ES2392048T3 (es) 2012-12-04
CA2516046A1 (en) 2004-08-26
CN100422082C (zh) 2008-10-01
WO2004071956A2 (es) 2004-08-26
EP1609758A2 (en) 2005-12-28
JP2006517508A (ja) 2006-07-27
US7344696B2 (en) 2008-03-18
CA2516046C (en) 2011-08-23
ZA200507353B (en) 2006-12-27
CN1829661A (zh) 2006-09-06
ES2217962A1 (es) 2004-11-01
KR20060002765A (ko) 2006-01-09
JP4791953B2 (ja) 2011-10-12
ES2217962B1 (es) 2006-02-16
EP1609758B1 (en) 2012-08-22
US20060036120A1 (en) 2006-02-16

Similar Documents

Publication Publication Date Title
WO2004071956A3 (es) Un material cristalino poroso (zeolita itq-24), su procedimiento de preparación y su uso en la conversión catalítica de compuestos orgánicos
ATE464272T1 (de) Zeolith itq-30
ATE206689T1 (de) Zeolith iiq-3
WO2005061443A3 (de) Benzoylsubstituierte phenylalanin-amide
DE60332834D1 (de) Mikroporöses kristallines zeolithmaterial (zeolith itq-22), syntheseverfahren dafür und verwendung davon als katalysator
FR2918050B1 (fr) Solide cristallise izm-2 et son procede de preparation
RU2018121988A (ru) EMM-28-новый синтетический кристаллический материал, его получение и применение
WO2006055305A3 (en) Itq-27, new crystalline microporous material
WO2004106296A3 (en) Trisubstituted heteroaromatic compounds as calcium sensing receptor modulators
DK0818417T3 (da) Zeolit
ES2186487A1 (es) Zeolita itq-15.
WO2006059103A3 (en) Pyridine based compounds useful as intermediates for pharmaceutical or agricultural end-products
DE69700457D1 (de) Zeolith ERS-10 und Verfahren zu seiner Herstellung
CA2356923A1 (en) Itq-7 zeolite
ZA201002540B (en) Crystallised solid izm-3 and method for preparing same
WO2007002722A3 (en) Synthesis of anastrozole and purification of one of its intermediate
IN2006CH00378A (en) Asymmetric urea compound and process for producing asymmetric compound by asymmetric conjugate addition reaction with the same as catalyst
EP0159845A3 (en) Synthesis of crystalline zeolite
CA2534324A1 (en) Ruthenium metathesis catalysts
AU2001293883A1 (en) Microporous crystalline material (itq-17), method for the preparation thereof and its use in processes for separating and transforming organic compounds
WO2008103367A3 (en) Method for assembling high-purity chemical libraries, proapoptotic compounds discovered by same
WO2008033230A3 (en) A method of making porous crystalline materials
WO2005108526A3 (en) Itq-25, new crystalline microporous material
EP1136121A3 (en) CFI-type zeolite, its preparation, catalyst containing it, use thereof for conversion of organic compounds
WO2010012797A3 (en) Synthesis of 3,4-diaryl-4,5-dihydro-(1h)-pyrazole-1- carboxamidine derivatives

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 11200534

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 2516046

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2006502054

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 1020057015004

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 2004709639

Country of ref document: EP

Ref document number: 2005/07353

Country of ref document: ZA

Ref document number: 1818/KOLNP/2005

Country of ref document: IN

Ref document number: 200507353

Country of ref document: ZA

WWE Wipo information: entry into national phase

Ref document number: 20048099914

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2004709639

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1020057015004

Country of ref document: KR

WWP Wipo information: published in national office

Ref document number: 11200534

Country of ref document: US