FR3063994B1 - Procede de synthese a ensemencement multiple de cristaux de zeolithe a granulometrie controlee - Google Patents

Procede de synthese a ensemencement multiple de cristaux de zeolithe a granulometrie controlee Download PDF

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Publication number
FR3063994B1
FR3063994B1 FR1752198A FR1752198A FR3063994B1 FR 3063994 B1 FR3063994 B1 FR 3063994B1 FR 1752198 A FR1752198 A FR 1752198A FR 1752198 A FR1752198 A FR 1752198A FR 3063994 B1 FR3063994 B1 FR 3063994B1
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France
Prior art keywords
particle size
crystals
zeolith
synthesis
controlled particle
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FR1752198A
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FR3063994A1 (fr
Inventor
Serge Nicolas
Cecile Lutz
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Arkema France SA
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Arkema France SA
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Priority to FR1752198A priority Critical patent/FR3063994B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to PCT/FR2018/050570 priority patent/WO2018167416A1/fr
Priority to MX2019010518A priority patent/MX2019010518A/es
Priority to EA201992197A priority patent/EA039625B1/ru
Priority to EP18713329.3A priority patent/EP3596011A1/fr
Priority to CN201880018811.0A priority patent/CN110431107B/zh
Priority to US16/493,593 priority patent/US11124421B2/en
Priority to KR1020197028495A priority patent/KR102304762B1/ko
Priority to JP2019550845A priority patent/JP7082985B2/ja
Priority to TW107109169A priority patent/TWI672269B/zh
Publication of FR3063994A1 publication Critical patent/FR3063994A1/fr
Priority to ZA2019/05757A priority patent/ZA201905757B/en
Application granted granted Critical
Publication of FR3063994B1 publication Critical patent/FR3063994B1/fr
Priority to JP2022028397A priority patent/JP2022081537A/ja
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Anticipated expiration legal-status Critical

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7003—A-type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7011—MAZ-type, e.g. Mazzite, Omega, ZSM-4 or LZ-202
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7019—EMT-type, e.g. EMC-2, ECR-30, CSZ-1, ZSM-3 or ZSM-20
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/14—Type A
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/14—Type A
    • C01B39/16—Type A from aqueous solutions of an alkali metal aluminate and an alkali metal silicate excluding any other source of alumina or silica but seeds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/26—Mordenite type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/30—Erionite or offretite type, e.g. zeolite T
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/34—Type ZSM-4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C01P2004/53—Particles with a specific particle size distribution bimodal size distribution

Abstract

La présente invention concerne un procédé de préparation de cristaux de zéolithe présentant une distribution granulométrique multimodale, et dont les tailles sont comprises entre 0,02 µm et 20 µm, ledit procédé comprenant une première introduction d'un ou plusieurs agent(s) d'ensemencement dans le réacteur tubulaire ou en amont du réacteur tubulaire, et au moins une seconde introduction d'un ou plusieurs agent(s) d'ensemencement, identique(s) ou différent(s) dans le réacteur tubulaire.
FR1752198A 2017-03-17 2017-03-17 Procede de synthese a ensemencement multiple de cristaux de zeolithe a granulometrie controlee Active FR3063994B1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
FR1752198A FR3063994B1 (fr) 2017-03-17 2017-03-17 Procede de synthese a ensemencement multiple de cristaux de zeolithe a granulometrie controlee
JP2019550845A JP7082985B2 (ja) 2017-03-17 2018-03-12 制御された粒径を有するゼオライト結晶のマルチシーディングを伴う合成方法
EA201992197A EA039625B1 (ru) 2017-03-17 2018-03-12 Способ для мультизатравочного синтеза кристаллов цеолита с управляемым размером зерна
EP18713329.3A EP3596011A1 (fr) 2017-03-17 2018-03-12 Procédé de synthèse à ensemencement multiple de cristaux de zéolithe à granulométrie contrôlée
CN201880018811.0A CN110431107B (zh) 2017-03-17 2018-03-12 多次种晶合成具有受控粒度的沸石晶体的方法
US16/493,593 US11124421B2 (en) 2017-03-17 2018-03-12 Process for the synthesis, with multiple seeding, of zeolite crystals having a controlled particle size
PCT/FR2018/050570 WO2018167416A1 (fr) 2017-03-17 2018-03-12 Procédé de synthèse à ensemencement multiple de cristaux de zéolithe à granulométrie contrôlée
MX2019010518A MX2019010518A (es) 2017-03-17 2018-03-12 Metodo de sintesis con siembra multiple de cristales de zeolita de granulometria controlada.
KR1020197028495A KR102304762B1 (ko) 2017-03-17 2018-03-12 제어된 입자 크기를 가진 제올라이트 결정들의 다중 시딩 합성을 위한 방법
TW107109169A TWI672269B (zh) 2017-03-17 2018-03-16 利用多引晶合成具有受控粒子尺寸之沸石晶體之方法
ZA2019/05757A ZA201905757B (en) 2017-03-17 2019-08-30 Method for the multi-seeding synthesis of zeolite crystals with controlled grain size
JP2022028397A JP2022081537A (ja) 2017-03-17 2022-02-25 制御された粒径を有するゼオライト結晶のマルチシーディングを伴う合成方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1752198 2017-03-17
FR1752198A FR3063994B1 (fr) 2017-03-17 2017-03-17 Procede de synthese a ensemencement multiple de cristaux de zeolithe a granulometrie controlee

Publications (2)

Publication Number Publication Date
FR3063994A1 FR3063994A1 (fr) 2018-09-21
FR3063994B1 true FR3063994B1 (fr) 2022-01-21

Family

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Family Applications (1)

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FR1752198A Active FR3063994B1 (fr) 2017-03-17 2017-03-17 Procede de synthese a ensemencement multiple de cristaux de zeolithe a granulometrie controlee

Country Status (11)

Country Link
US (1) US11124421B2 (fr)
EP (1) EP3596011A1 (fr)
JP (2) JP7082985B2 (fr)
KR (1) KR102304762B1 (fr)
CN (1) CN110431107B (fr)
EA (1) EA039625B1 (fr)
FR (1) FR3063994B1 (fr)
MX (1) MX2019010518A (fr)
TW (1) TWI672269B (fr)
WO (1) WO2018167416A1 (fr)
ZA (1) ZA201905757B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020214472A1 (fr) * 2019-04-15 2020-10-22 Pacific Industrial Development Corporation Méthode de production continue de zéolites de type aei de taille nanométrique
FR3141080A1 (fr) * 2022-10-19 2024-04-26 Arkema France Procédé de synthèse de zéolithe zsm-5 en continu

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1357762A (fr) 1963-02-27 1964-04-10 Pernod & Ricard Perfectionnements aux procédés de préparation de jus de fruits et de légumes et notamment de jus de raisin
US4818509A (en) * 1984-03-23 1989-04-04 Mobil Oil Corporation Continuous process for manufacturing crystalline zeolites in continuously stirred backmixed crystallizers
ZA851734B (en) * 1984-03-23 1986-10-29 Mobil Oil Corp A continuous process for manufacturing crystalline zeolites
GB9422401D0 (en) * 1994-11-07 1995-01-04 Unilever Plc Aluminosilicates
JP3257509B2 (ja) * 1997-11-27 2002-02-18 東ソー株式会社 低シリカフォージャサイト型ゼオライトおよびその製造方法
US5989518A (en) * 1998-12-29 1999-11-23 Uop Llc Process for synthesizing and controlling the particle size and particle size distribution of a molecular sieve
US6773694B1 (en) * 1999-12-22 2004-08-10 Uop Llc Process for synthesizing molecular sieves
ES2217962B1 (es) * 2003-02-14 2006-02-16 Universidad Politecnica De Valencia Material cristalino poroso (zeolita itq-24),su procedimiento de preparacion y su uso en la conversion catalitica de componentes organicos.
US7112316B1 (en) 2005-08-08 2006-09-26 Uop Llc Process for preparing molecular sieves via continuous addition of nutrients
GB0523707D0 (en) 2005-11-22 2005-12-28 Nitech Solutions Ltd Improved apparatus and method for temperature controlled processes
FR2925478B1 (fr) * 2007-12-20 2009-12-18 Ceca Sa Zeolite de type lsx a granulometrie controlee
WO2015005407A1 (fr) 2013-07-09 2015-01-15 三菱化学株式会社 Procédé de production de zéolite
US20160159648A1 (en) 2013-07-11 2016-06-09 Ube Industries, Ltd. Silicon nitride powder for mold release agent of casting mold for casting polycrystalline silicon ingot and method for manufacturing said silicon nitride powder, slurry containing said silicon nitride powder, casting mold for casting polycrystalline silicon ingot and method for manufacturing same, and method for manufacturing polycrystalline silicon ingot using said casting mold
FR3063996B1 (fr) * 2017-03-17 2022-01-14 Arkema France Procede de synthese de cristaux de zeolithe avec agent d'ensemencement

Also Published As

Publication number Publication date
US20210139337A1 (en) 2021-05-13
MX2019010518A (es) 2019-10-17
FR3063994A1 (fr) 2018-09-21
CN110431107A (zh) 2019-11-08
US11124421B2 (en) 2021-09-21
CN110431107B (zh) 2022-11-15
KR102304762B1 (ko) 2021-09-23
ZA201905757B (en) 2021-01-27
TW201836980A (zh) 2018-10-16
JP2020510603A (ja) 2020-04-09
TWI672269B (zh) 2019-09-21
JP7082985B2 (ja) 2022-06-09
WO2018167416A1 (fr) 2018-09-20
KR20190125379A (ko) 2019-11-06
EA201992197A1 (ru) 2020-02-07
EA039625B1 (ru) 2022-02-17
EP3596011A1 (fr) 2020-01-22
JP2022081537A (ja) 2022-05-31

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