MX169590B - Material sintetico, cristalino y poroso que contiene oxidos de silicio, titanio y galio - Google Patents

Material sintetico, cristalino y poroso que contiene oxidos de silicio, titanio y galio

Info

Publication number
MX169590B
MX169590B MX008944A MX894487A MX169590B MX 169590 B MX169590 B MX 169590B MX 008944 A MX008944 A MX 008944A MX 894487 A MX894487 A MX 894487A MX 169590 B MX169590 B MX 169590B
Authority
MX
Mexico
Prior art keywords
crystalline
titanium
synthetic
silicon
galium
Prior art date
Application number
MX008944A
Other languages
English (en)
Inventor
Antonio Esposito
Giuseppe Bellussi
Mario Gabriele Clerici
Angela Carati
Original Assignee
Eniricerche Spa
Enichem Sintesi
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche Spa, Enichem Sintesi, Snam Progetti filed Critical Eniricerche Spa
Publication of MX169590B publication Critical patent/MX169590B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/22—MFI, e.g. ZSM-5. silicalite, LZ-241

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Silicon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La presente invención se refiere a material sintetico de forma cristalino y poroso de naturaleza reolítica, conteniendo óxidos de silicio, titanio y galio, caracterizado por el hecho de que en el estado anhidro y calcinado responde a la siguiente fórmula empírica: pHGaO2 . qTiO2 . SiO2 donde p tiene un valor mayor de cero y menor o igual a 0.05 y q tiene un valor mayor de cero y menor o igual de 0.025, un H+ de HGaO2 puede ser al menos parcialmente sustituible o sustituido con cationes, al presentar el espectro de difracción a los rayos X de polvos.
MX008944A 1986-10-22 1987-10-22 Material sintetico, cristalino y poroso que contiene oxidos de silicio, titanio y galio MX169590B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT8622070A IT1213363B (it) 1986-10-22 1986-10-22 Materiale sintetico cristallino poroso contenente ossidi di silicio titanio e gallio.

Publications (1)

Publication Number Publication Date
MX169590B true MX169590B (es) 1993-07-14

Family

ID=11191020

Family Applications (1)

Application Number Title Priority Date Filing Date
MX008944A MX169590B (es) 1986-10-22 1987-10-22 Material sintetico, cristalino y poroso que contiene oxidos de silicio, titanio y galio

Country Status (14)

Country Link
US (2) US5888471A (es)
EP (1) EP0266825B1 (es)
JP (1) JP2529117B2 (es)
KR (1) KR900009148B1 (es)
AT (1) ATE58891T1 (es)
BR (1) BR8705830A (es)
CA (1) CA1303592C (es)
DE (1) DE3766599D1 (es)
DK (1) DK166771B1 (es)
ES (1) ES2020553B3 (es)
GR (1) GR3001399T3 (es)
IT (1) IT1213363B (es)
MX (1) MX169590B (es)
RU (1) RU2012396C1 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1213363B (it) * 1986-10-22 1989-12-20 Eniricerche Spa Materiale sintetico cristallino poroso contenente ossidi di silicio titanio e gallio.
IT1248644B (it) * 1990-05-25 1995-01-26 Enichem Sintesi Procedimento per l'oissidazione di eteri
IT1243772B (it) * 1990-08-01 1994-06-28 Eniricerche Spa Procedimento per l'ossidazione di composti paraffinici con ossigeno
DE69225311T2 (de) * 1991-01-11 1998-08-20 Mobil Oil Corp Schichtenförmige oxide sowie geschwollene und saeulenartige formen dieser materialien
GB2252556A (en) * 1991-02-08 1992-08-12 Bp Chem Int Ltd Alkoxy-alcohols from olefins
IT1250756B (it) * 1991-08-02 1995-04-21 Eniricerche Spa Procedimento per la produzione di ossidi olefinici
DE4138155A1 (de) * 1991-11-21 1993-05-27 Basf Ag Verfahren zur herstellung von im wesentlichen alkalifreien titansilikat-kristallen mit zeolithstruktur
ES2089378T3 (es) * 1991-11-26 1996-10-01 Eniricerche Spa Procedimiento para oxidar compuestos organicos con peroxido de hidrogeno producido en un procedimiento redox con antraquinona.
US5856575A (en) * 1997-01-22 1999-01-05 Council Of Scientific Industrial Research Process for the preparation of N-acetyl aminophenols
US6042807A (en) * 1997-04-02 2000-03-28 Arco Chemical Technology, L.P. Tellurium-containing molecular sieves
DE19717320A1 (de) * 1997-04-24 1998-10-29 Basf Ag Einstufiges Verfahren zur Herstellung von Glykolmonoethern aus Olefinen
IT1295267B1 (it) 1997-10-03 1999-05-04 Enichem Spa Processo per preparare zeoliti legate
DE19939416A1 (de) 1999-08-20 2001-02-22 Basf Ag Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs
IT1318680B1 (it) 2000-08-11 2003-08-27 Enichem Spa Processo per la produzione in continuo di ossidi olefinici.
JP4790359B2 (ja) * 2005-09-30 2011-10-12 日本乳化剤株式会社 水素イオン形態のメタロシリケート触媒を用いるグリコールエーテルの製造法
TWI508935B (zh) 2011-08-11 2015-11-21 China Petrochemical Dev Corp Taipei Taiwan Titanium-silicon molecular sieve and its preparation method and method for producing cyclohexanone oxime using the molecular sieve
TWI432262B (zh) 2012-08-10 2014-04-01 China Petrochemical Dev Corp Taipei Taiwan Method for making epoxides
TWI471299B (zh) 2012-10-04 2015-02-01 China Petrochemical Dev Corp Taipei Taiwan Hydroxylation of phenol
TWI589567B (zh) 2012-12-24 2017-07-01 China Petrochemical Development Corporation Taipei (Taiwan) Method of making epoxides
TW201425288A (zh) * 2012-12-25 2014-07-01 China Petrochemical Dev Corp Taipei Taiwan 苯二酚之製備方法
RU2523547C1 (ru) * 2013-05-15 2014-07-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Нижегородский государственный технический университет им. Р.Е. Алексеева" НГТУ Способ капсулирования силикалита титана в полимерной матрице

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
SE7610788L (sv) * 1975-10-03 1977-03-31 Ici Ltd Zeolit nu-1 och sett att framstella densamma
IT1127311B (it) * 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
DE3237389A1 (de) * 1981-10-08 1983-04-28 The Agency of Industrial Science and Technology, Tokyo Kristalline aluminium- und galliumsilikate, verfahren zu deren herstellung und verwendung zur dadurch katalysierten herstellung von niederen olefinen
CA1209981A (en) * 1982-09-04 1986-08-19 Dennis Young Crystalline gallosilicates, a process for producing them and their use as catalysts
EP0107876B1 (en) * 1982-10-28 1990-03-21 Shell Internationale Researchmaatschappij B.V. Process for the preparation of an aromatic hydrocarbon mixture
US4639358A (en) * 1983-12-19 1987-01-27 Mobil Oil Corporation Crystalline silicophosphoaluminate MCM-1
US4640829A (en) * 1984-04-16 1987-02-03 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-50 using dibenzyldimethylammonium ions and the product produced
US4623530A (en) * 1985-02-20 1986-11-18 United States Steel Corporation Crystalline magnesia-silica composites and process for producing same
US4729979A (en) * 1985-03-11 1988-03-08 Amoco Corporation Copper aluminum borate
US5246690A (en) * 1985-12-19 1993-09-21 Eniricerche S.P.A. Synthetic, crystalline, porous material containing silicon oxide, titanium oxide and aluminum oxide
IT1213363B (it) * 1986-10-22 1989-12-20 Eniricerche Spa Materiale sintetico cristallino poroso contenente ossidi di silicio titanio e gallio.
IT1213433B (it) * 1986-12-23 1989-12-20 Eniricerche S P A Agip S P A Procedimento per oligomerizzare olefine leggere
FR2629444B1 (fr) * 1988-04-01 1990-12-07 Rhone Poulenc Chimie Zeolites a base de silice et d'oxyde de germanium et procede de synthese de celles-ci
DE4120847A1 (de) * 1991-06-25 1993-01-14 Vaw Ver Aluminium Werke Ag Kristallines, zeolithanaloges gallosilicat und verfahren zu dessen herstellung

Also Published As

Publication number Publication date
GR3001399T3 (en) 1992-09-11
ATE58891T1 (de) 1990-12-15
KR900009148B1 (ko) 1990-12-22
US6083864A (en) 2000-07-04
IT8622070A0 (it) 1986-10-22
DK166771B1 (da) 1993-07-12
ES2020553B3 (es) 1991-08-16
JP2529117B2 (ja) 1996-08-28
IT1213363B (it) 1989-12-20
CA1303592C (en) 1992-06-16
EP0266825A1 (en) 1988-05-11
DK548087D0 (da) 1987-10-20
DE3766599D1 (de) 1991-01-17
JPS63112412A (ja) 1988-05-17
RU2012396C1 (ru) 1994-05-15
KR890006517A (ko) 1989-06-14
DK548087A (da) 1988-04-23
US5888471A (en) 1999-03-30
BR8705830A (pt) 1988-05-31
EP0266825B1 (en) 1990-12-05

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