IT1250756B - Procedimento per la produzione di ossidi olefinici - Google Patents

Procedimento per la produzione di ossidi olefinici

Info

Publication number
IT1250756B
IT1250756B ITMI912196A ITMI912196A IT1250756B IT 1250756 B IT1250756 B IT 1250756B IT MI912196 A ITMI912196 A IT MI912196A IT MI912196 A ITMI912196 A IT MI912196A IT 1250756 B IT1250756 B IT 1250756B
Authority
IT
Italy
Prior art keywords
production
diisobutyl
reaction
procedure
olefinic oxides
Prior art date
Application number
ITMI912196A
Other languages
English (en)
Inventor
Mario Gabriele Clerici
Patrizia Ingallina
Original Assignee
Eniricerche Spa
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche Spa, Snam Progetti filed Critical Eniricerche Spa
Priority to ITMI912196A priority Critical patent/IT1250756B/it
Publication of ITMI912196A0 publication Critical patent/ITMI912196A0/it
Priority to US07/923,326 priority patent/US5221795A/en
Priority to DE69202532T priority patent/DE69202532T2/de
Priority to EP92202362A priority patent/EP0526945B1/en
Priority to DK92202362.7T priority patent/DK0526945T3/da
Priority to ES92202362T priority patent/ES2072089T3/es
Priority to AT92202362T priority patent/ATE122667T1/de
Publication of ITMI912196A1 publication Critical patent/ITMI912196A1/it
Application granted granted Critical
Publication of IT1250756B publication Critical patent/IT1250756B/it

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procedimento per la produzione di ossidi olefinici per reazione fra una olefina, ossigeno o aria in presenza di catalizzatore costituito da titanio silicalite e di un sistema redox comprendente alchilantraidrochinone e alchilantrachinone, la reazione essendo eseguita in una miscela di solventi costituita da:a) uno o più idrocarburi aromatici o alchil aromatici mono o polinucleari scelti tra benzene, toluene, xilene, alfa-metilnaftalina o derivati alogenati di questi quale il diclorobenzene b) uno o più composti organici polari a punto di ebollizione compreso tra 150 350°C e scelti tra diisobutil-carbinolo, diisobutil-chetone, metilcicloesil acetato, dimetilftalato, dibutilftalato, dietilesilftalato e tributilftalato c) un alcool a basso peso molecolare preferibilmente metanolo.
ITMI912196A 1991-08-02 1991-08-02 Procedimento per la produzione di ossidi olefinici IT1250756B (it)

Priority Applications (7)

Application Number Priority Date Filing Date Title
ITMI912196A IT1250756B (it) 1991-08-02 1991-08-02 Procedimento per la produzione di ossidi olefinici
US07/923,326 US5221795A (en) 1991-08-02 1992-07-31 Process for producing olefin oxides
DE69202532T DE69202532T2 (de) 1991-08-02 1992-08-01 Verfahren zur Produktion von Olefinoxiden.
EP92202362A EP0526945B1 (en) 1991-08-02 1992-08-01 Process for producing olefin oxides
DK92202362.7T DK0526945T3 (da) 1991-08-02 1992-08-01 Fremgangsmåde til fremstilling af olefinoxider
ES92202362T ES2072089T3 (es) 1991-08-02 1992-08-01 Procedimiento para producir oxidos de olefinas.
AT92202362T ATE122667T1 (de) 1991-08-02 1992-08-01 Verfahren zur produktion von olefinoxiden.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI912196A IT1250756B (it) 1991-08-02 1991-08-02 Procedimento per la produzione di ossidi olefinici

Publications (3)

Publication Number Publication Date
ITMI912196A0 ITMI912196A0 (it) 1991-08-02
ITMI912196A1 ITMI912196A1 (it) 1993-02-02
IT1250756B true IT1250756B (it) 1995-04-21

Family

ID=11360527

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI912196A IT1250756B (it) 1991-08-02 1991-08-02 Procedimento per la produzione di ossidi olefinici

Country Status (7)

Country Link
US (1) US5221795A (it)
EP (1) EP0526945B1 (it)
AT (1) ATE122667T1 (it)
DE (1) DE69202532T2 (it)
DK (1) DK0526945T3 (it)
ES (1) ES2072089T3 (it)
IT (1) IT1250756B (it)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5214168A (en) * 1992-04-30 1993-05-25 Arco Chemical Technology, L.P. Integrated process for epoxide production
US5412122A (en) * 1993-12-23 1995-05-02 Arco Chemical Technology, L.P. Epoxidation process
US5354875A (en) * 1993-12-23 1994-10-11 Uop Epoxidation of olefins using a titania-supported titanosilicate
US5384418A (en) * 1994-01-25 1995-01-24 Arco Chemical Technology, L.P. Integrated process for epoxide production
US5463090A (en) * 1994-10-27 1995-10-31 Arco Chemical Technology, L.P. Integrated process for epoxide production
ES2130540T3 (es) * 1994-09-28 1999-07-01 Arco Chem Tech Procedimiento de preparacion de peroxido de hidrogeno, procedimiento integral de epoxidacion y nuevas sales de alquilamonio de antrahidroquinona y antraquinona sustituidas con acido sulfonico.
US5523426A (en) * 1995-01-04 1996-06-04 Arco Chemical Technology, L.P. Integrated process for epoxidation
US5693834A (en) * 1995-03-15 1997-12-02 Arco Chemical Technology, L.P. Integrated process for epoxidation
US5591875A (en) * 1995-08-02 1997-01-07 Chang; Te Epoxidation Process
US5599956A (en) * 1996-02-22 1997-02-04 Uop Integrated process for the production of propylene oxide
IT1283455B1 (it) * 1996-07-19 1998-04-21 Enichem Spa Procedimento per la preparazione di epossidi da olefine
US5744619A (en) * 1997-03-17 1998-04-28 Uop Llc Titanovanadosilicalites as epoxidation catalysts for olefins
DE19716412A1 (de) * 1997-04-18 1998-10-22 Linde Ag Verfahren zur Herstellung von Epoxiden aus Olefinen
DE19835481A1 (de) * 1998-08-07 2000-02-17 Bayer Ag Verfahren zur Oxidation von Kohlenwasserstoffen
DE19857137A1 (de) 1998-12-11 2000-06-15 Bayer Ag Integriertes Verfahren zur Herstellung von Epoxiden aus Olefinen
EP1122249A1 (fr) 2000-02-02 2001-08-08 SOLVAY (Société Anonyme) Procédé de fabrication d'un oxiranne
RU2180661C1 (ru) * 2000-06-19 2002-03-20 Институт химии нефти СО РАН Способ получения эпоксидных соединений
US7141683B2 (en) 2002-05-02 2006-11-28 Degussa Ag Process for the epoxidation of olefins
EP1359148A1 (en) * 2002-05-02 2003-11-05 Degussa AG Process for the epoxidation of olefins
WO2007080995A1 (en) * 2006-01-11 2007-07-19 Sumitomo Chemical Company, Limited Process for producing of epoxy compound
US8207359B2 (en) * 2006-04-27 2012-06-26 Sumitomo Chemical Company, Limited Method for producing epoxy compound
KR101810328B1 (ko) 2016-08-22 2017-12-19 롯데케미칼 주식회사 프로필렌 직접산화 반응용 촉매, 이의 제조방법 및 이를 이용한 프로필렌 직접산화 반응에 의한 프로필렌 옥사이드 제조방법

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1549184A (it) * 1967-02-07 1968-12-13
GB1209321A (en) * 1967-06-29 1970-10-21 Ici Ltd Process for the production of epoxides
DE1817717A1 (de) * 1968-01-02 1970-02-26 Inst Francais Du Petrol Verfahren zur Herstellung eines Epoxyds
CA1128540A (en) * 1978-09-25 1982-07-27 Union Carbide Corporation Epoxidation of olefins using in situ generated hydrogen peroxide
IT1127311B (it) * 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
DE3205648A1 (de) * 1982-02-17 1983-08-25 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von c(pfeil abwaerts)3(pfeil abwaerts)-c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-epoxiden
IT1152299B (it) * 1982-07-28 1986-12-31 Anic Spa Procedimento per l'espossidazione di composti olefinici
IT1207519B (it) * 1985-12-19 1989-05-25 Eniricerche Spa Materiale sintetico cristallino poroso contenetne ossidi di silicio titanio e alluminio.
IT1207520B (it) * 1985-12-19 1989-05-25 Eniricerche S P A Snamprogetti Materiale sintetico cristallino poroso contenente ossidi di silicio titanio e ferro.
ES2033693T3 (es) * 1986-01-28 1993-04-01 Eniricerche S.P.A. Un procedimiento para la exposidacion de compuestos olefinicos.
IT1213363B (it) * 1986-10-22 1989-12-20 Eniricerche Spa Materiale sintetico cristallino poroso contenente ossidi di silicio titanio e gallio.
IT1223338B (it) * 1987-11-02 1990-09-19 Eniricerche Spa Preparazione di composti epossidici a configurazione cis e trans a partire da miscele degli stereoisomeri olefinici corrispondenti

Also Published As

Publication number Publication date
ITMI912196A0 (it) 1991-08-02
ITMI912196A1 (it) 1993-02-02
US5221795A (en) 1993-06-22
EP0526945B1 (en) 1995-05-17
DK0526945T3 (da) 1995-07-17
ATE122667T1 (de) 1995-06-15
ES2072089T3 (es) 1995-07-01
EP0526945A1 (en) 1993-02-10
DE69202532T2 (de) 1995-09-14
DE69202532D1 (de) 1995-06-22

Similar Documents

Publication Publication Date Title
IT1250756B (it) Procedimento per la produzione di ossidi olefinici
Stout et al. Pyrrole aminoimidazole alkaloid metabiosynthesis with marine sponges Agelas conifera and Stylissa caribica
BR0008430A (pt) Sistema catalisador de polimerização de alfa-olfelina que contém um composto silano aromático
Wojtas et al. Total synthesis of nosiheptide
de Vries et al. Selective Modification of Ribosomally Synthesized and Post‐Translationally Modified Peptides (RiPPs) through Diels–Alder Cycloadditions on Dehydroalanine Residues
NO180538C (no) N-sulfonyl-2-oksoindol-derivater som har affinitet for vasopressin- og/eller ocytocin-reseptorer, farmasöytiske blandinger som inneholder dem og mellomprodukter ved fremstilling av derivatene
RU94042914A (ru) Способ извлечения бензола из смешанных углеводородов
Bourboula et al. A Photochemical Protocol for the Synthesis of Weinreb and Morpholine Amides from Carboxylic Acids
NO308006B1 (no) Polymerisasjonsprosess for olefiner
SE7710840L (sv) Enzymstabilisering
Hoffknecht et al. Influence of the Multivalency of Ultrashort Arg‐Trp‐Based Antimicrobial Peptides (AMP) on Their Antibacterial Activity
Verlinden et al. Synthesis of heterocycle‐bridged peptidic macrocycles through 1, 3‐diyne transformations
Ng‐Choi et al. Solid‐phase synthesis of 5‐arylhistidine‐containing peptides with antimicrobial activity through a microwave‐assisted Suzuki–Miyaura cross‐coupling
Plodek et al. Synthesis of the Azaoxoaporphine Alkaloid Sampangine and Ascididemin‐Type Pyridoacridines through TMPMgCl· LiCl‐Mediated Ring Closure
May et al. Intraannular Savige–Fontana Reaction: One‐Step Conversion of One Class of Monocyclic Peptides into Another Class of Bicyclic Peptides
Zhu et al. Ligand‐Free Copper‐Catalyzed One‐Pot Synthesis of Indole‐2‐carboxylic Esters
Inagaki et al. THE SELECTION OF O2 (1Δg)-OLEFIN REACTION COURSES. INTERMOLECULAR NONBONDED ATTRACTION AND π BOND POLARITY OF OLEFINS
Coutts et al. Organic Sulfur Compounds: II. Catalyzed Sodium Borohydride Reductions of Selected α-(o-Nitrophenylthio) Acids
Vilà et al. Solid‐Phase Synthesis of Peptide Conjugates Derived from the Antimicrobial Cyclic Decapeptide BPC194
Schubert et al. Molybdenum Pentachloride Mediated Synthesis of Spirocyclic Compounds by Intramolecular Oxidative Coupling
Liu et al. Arylboronate Ester Protected Amino Acids as Orthogonal Building Blocks for Fmoc Solid‐Phase Peptide Synthesis
Zhao et al. Vicinal Dichlorination of o-Vinylbiphenyls and the Synthesis of 9-(Arylmethyl) fluorenes via Tandem Friedel–Crafts Alkylations
Yadav et al. Regioselective Synthesis of Arylsulfonyl Benzophenones via Aerobic Oxidative [3+ 3] Benzannulation Reactions
Hutchinson et al. Formation of a novel thiopyranoindole ring system
ES8603802A1 (es) Procedimiento de preparacion de nuevos derivados 1-hidroxi- propilresorcinos provistos de un grupo fenilo sustituido

Legal Events

Date Code Title Description
0001 Granted
TA Fee payment date (situation as of event date), data collected since 19931001

Effective date: 19970814