ES2072089T3 - Procedimiento para producir oxidos de olefinas. - Google Patents
Procedimiento para producir oxidos de olefinas.Info
- Publication number
- ES2072089T3 ES2072089T3 ES92202362T ES92202362T ES2072089T3 ES 2072089 T3 ES2072089 T3 ES 2072089T3 ES 92202362 T ES92202362 T ES 92202362T ES 92202362 T ES92202362 T ES 92202362T ES 2072089 T3 ES2072089 T3 ES 2072089T3
- Authority
- ES
- Spain
- Prior art keywords
- olephine
- phthalate
- oxides
- procedure
- produce
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract 2
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 abstract 1
- -1 DIETHYLHEXYL Chemical class 0.000 abstract 1
- HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000011877 solvent mixture Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- YXFVVABEGXRONW-CNRUNOGKSA-N tritiomethylbenzene Chemical compound [3H]CC1=CC=CC=C1 YXFVVABEGXRONW-CNRUNOGKSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PROCESOS PARA LA PRODUCCION DE OXIDOS DE OLEFINAS MEDIANTE LA REACCION DE UNA OLEFINA CON OXIGENO O AIRE, ANTE LA PRESENCIA DE UN CATALIZADOR CONSTITUIDO POR SILICALITA DE TITANIO Y UNA SISTEMA DE OXIDACION-REDUCCION QUE COMPRENDE ALQUILANTRAHIDROQUINONA Y ALQUIL-ANTRAQUINONA, LLEVANDOSE A CABO DICHA REACCION UN UNA MEZCLA SOLVENTE QUE CONTIENE: (A) UNO O MAS HIDROCARBUROS AROMATICOS O ALQUIL-AROMATICOS, MONO O POLINUCLEARES SELECCIONADOS DEL BENCENO, TOLUENO, XILENO, ALFAMETIL-NAFTALENO O DERIVADOS HALOGENADOS DE LOS MISMOS, TALES COMO EL DICLOROBENCENO; (B) UNO O MAS COMPUESTOS ORGANICOS POLARES CON UN PUNTO DE EBULLICION ENTRE LOS 150 Y LOS 350 (GRADOS) C Y SELECCIONADOS ENTRE DIISOBUTIL-CARBINOL, DI-ISOBUTIL-CETONA, ACETATO DE METILCICLOHEXILO, FTALATO DE DIMETILO, FTALATO DE DIBUTILO, FTALATO DE DIETILHEXILO Y FTALATO DE TRIBUTILO; (C) UN ALCOHOL DE POCO PESO MOLECULAR, PREFERENTEMENTE METANOL.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI912196A IT1250756B (it) | 1991-08-02 | 1991-08-02 | Procedimento per la produzione di ossidi olefinici |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2072089T3 true ES2072089T3 (es) | 1995-07-01 |
Family
ID=11360527
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES92202362T Expired - Lifetime ES2072089T3 (es) | 1991-08-02 | 1992-08-01 | Procedimiento para producir oxidos de olefinas. |
Country Status (7)
Country | Link |
---|---|
US (1) | US5221795A (es) |
EP (1) | EP0526945B1 (es) |
AT (1) | ATE122667T1 (es) |
DE (1) | DE69202532T2 (es) |
DK (1) | DK0526945T3 (es) |
ES (1) | ES2072089T3 (es) |
IT (1) | IT1250756B (es) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5214168A (en) * | 1992-04-30 | 1993-05-25 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
US5354875A (en) * | 1993-12-23 | 1994-10-11 | Uop | Epoxidation of olefins using a titania-supported titanosilicate |
US5412122A (en) * | 1993-12-23 | 1995-05-02 | Arco Chemical Technology, L.P. | Epoxidation process |
US5384418A (en) * | 1994-01-25 | 1995-01-24 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
EP0709339B1 (en) * | 1994-09-28 | 1999-04-28 | ARCO Chemical Technology, L.P. | Hydrogen peroxide process, integrated process for epoxidation and novel alkylammonium salts of sulfonic acid-substituted anthrahydroquinone and anthraquinone |
US5463090A (en) * | 1994-10-27 | 1995-10-31 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
US5523426A (en) * | 1995-01-04 | 1996-06-04 | Arco Chemical Technology, L.P. | Integrated process for epoxidation |
US5693834A (en) * | 1995-03-15 | 1997-12-02 | Arco Chemical Technology, L.P. | Integrated process for epoxidation |
US5591875A (en) * | 1995-08-02 | 1997-01-07 | Chang; Te | Epoxidation Process |
US5599956A (en) * | 1996-02-22 | 1997-02-04 | Uop | Integrated process for the production of propylene oxide |
IT1283455B1 (it) * | 1996-07-19 | 1998-04-21 | Enichem Spa | Procedimento per la preparazione di epossidi da olefine |
US5744619A (en) * | 1997-03-17 | 1998-04-28 | Uop Llc | Titanovanadosilicalites as epoxidation catalysts for olefins |
DE19716412A1 (de) * | 1997-04-18 | 1998-10-22 | Linde Ag | Verfahren zur Herstellung von Epoxiden aus Olefinen |
DE19835481A1 (de) | 1998-08-07 | 2000-02-17 | Bayer Ag | Verfahren zur Oxidation von Kohlenwasserstoffen |
DE19857137A1 (de) | 1998-12-11 | 2000-06-15 | Bayer Ag | Integriertes Verfahren zur Herstellung von Epoxiden aus Olefinen |
EP1122249A1 (fr) | 2000-02-02 | 2001-08-08 | SOLVAY (Société Anonyme) | Procédé de fabrication d'un oxiranne |
US7141683B2 (en) | 2002-05-02 | 2006-11-28 | Degussa Ag | Process for the epoxidation of olefins |
EP1359148A1 (en) * | 2002-05-02 | 2003-11-05 | Degussa AG | Process for the epoxidation of olefins |
US7994349B2 (en) * | 2006-01-11 | 2011-08-09 | Sumitomo Chemical Company, Limited | Process for producing of epoxy compound |
US8207359B2 (en) * | 2006-04-27 | 2012-06-26 | Sumitomo Chemical Company, Limited | Method for producing epoxy compound |
KR101810328B1 (ko) | 2016-08-22 | 2017-12-19 | 롯데케미칼 주식회사 | 프로필렌 직접산화 반응용 촉매, 이의 제조방법 및 이를 이용한 프로필렌 직접산화 반응에 의한 프로필렌 옥사이드 제조방법 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1549184A (es) * | 1967-02-07 | 1968-12-13 | ||
GB1209321A (en) * | 1967-06-29 | 1970-10-21 | Ici Ltd | Process for the production of epoxides |
DE1817717A1 (de) * | 1968-01-02 | 1970-02-26 | Inst Francais Du Petrol | Verfahren zur Herstellung eines Epoxyds |
CA1128540A (en) * | 1978-09-25 | 1982-07-27 | Union Carbide Corporation | Epoxidation of olefins using in situ generated hydrogen peroxide |
IT1127311B (it) * | 1979-12-21 | 1986-05-21 | Anic Spa | Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi |
DE3205648A1 (de) * | 1982-02-17 | 1983-08-25 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von c(pfeil abwaerts)3(pfeil abwaerts)-c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-epoxiden |
IT1152299B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'espossidazione di composti olefinici |
IT1207520B (it) * | 1985-12-19 | 1989-05-25 | Eniricerche S P A Snamprogetti | Materiale sintetico cristallino poroso contenente ossidi di silicio titanio e ferro. |
IT1207519B (it) * | 1985-12-19 | 1989-05-25 | Eniricerche Spa | Materiale sintetico cristallino poroso contenetne ossidi di silicio titanio e alluminio. |
EP0230949B1 (en) * | 1986-01-28 | 1992-07-22 | ENIRICERCHE S.p.A. | A process for the epoxydation of olefinic compounds |
IT1213363B (it) * | 1986-10-22 | 1989-12-20 | Eniricerche Spa | Materiale sintetico cristallino poroso contenente ossidi di silicio titanio e gallio. |
IT1223338B (it) * | 1987-11-02 | 1990-09-19 | Eniricerche Spa | Preparazione di composti epossidici a configurazione cis e trans a partire da miscele degli stereoisomeri olefinici corrispondenti |
-
1991
- 1991-08-02 IT ITMI912196A patent/IT1250756B/it active IP Right Grant
-
1992
- 1992-07-31 US US07/923,326 patent/US5221795A/en not_active Expired - Fee Related
- 1992-08-01 DK DK92202362.7T patent/DK0526945T3/da active
- 1992-08-01 AT AT92202362T patent/ATE122667T1/de not_active IP Right Cessation
- 1992-08-01 ES ES92202362T patent/ES2072089T3/es not_active Expired - Lifetime
- 1992-08-01 DE DE69202532T patent/DE69202532T2/de not_active Expired - Fee Related
- 1992-08-01 EP EP92202362A patent/EP0526945B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
IT1250756B (it) | 1995-04-21 |
DK0526945T3 (da) | 1995-07-17 |
EP0526945A1 (en) | 1993-02-10 |
ATE122667T1 (de) | 1995-06-15 |
DE69202532T2 (de) | 1995-09-14 |
ITMI912196A0 (it) | 1991-08-02 |
US5221795A (en) | 1993-06-22 |
DE69202532D1 (de) | 1995-06-22 |
EP0526945B1 (en) | 1995-05-17 |
ITMI912196A1 (it) | 1993-02-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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