JP2008513337A - 膜増強反応器 - Google Patents

膜増強反応器 Download PDF

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Publication number
JP2008513337A
JP2008513337A JP2007532531A JP2007532531A JP2008513337A JP 2008513337 A JP2008513337 A JP 2008513337A JP 2007532531 A JP2007532531 A JP 2007532531A JP 2007532531 A JP2007532531 A JP 2007532531A JP 2008513337 A JP2008513337 A JP 2008513337A
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Prior art keywords
hydrogen
reactor
intermediate layer
membrane
particles
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JP2007532531A
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Japanese (ja)
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JP2008513337A5 (https=
Inventor
ウェリントン，スコット，リー
マツァコス，アンドレアス，ニコラス
マルディロビッチ，アイバン，ペトロビッチ
マー，イー，フア
エングウォール，エリック，エドウィン
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ウスター ポリテクニック インスティチュート
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Publication of JP2008513337A publication Critical patent/JP2008513337A/ja
Publication of JP2008513337A5 publication Critical patent/JP2008513337A5/ja
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B01D71/025—Aluminium oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06—Tubular membrane modules
    • B01D63/062—Tubular membrane modules with membranes on a surface of a support tube
    • B01D63/065—Tubular membrane modules with membranes on a surface of a support tube on the outer surface thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06—Tubular membrane modules
    • B01D63/069—Tubular membrane modules comprising a bundle of tubular membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02231—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02232—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion characterised by membranes
    • C01B3/505—Membranes containing palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/42—Catalysts within the flow path
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/22—Thermal or heat-resistance properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86—Carbon dioxide sequestration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Combustion & Propulsion (AREA)
  • Electrochemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
JP2007532531A 2004-09-21 2005-09-19 膜増強反応器 Pending JP2008513337A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US61160804P 2004-09-21 2004-09-21
PCT/US2005/033267 WO2006034086A1 (en) 2004-09-21 2005-09-19 Membrane enhanced reactor

Publications (2)

Publication Number Publication Date
JP2008513337A true JP2008513337A (ja) 2008-05-01
JP2008513337A5 JP2008513337A5 (https=) 2008-10-30

Family

ID=35708904

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007532531A Pending JP2008513337A (ja) 2004-09-21 2005-09-19 膜増強反応器

Country Status (7)

Country Link
EP (1) EP1789172A1 (https=)
JP (1) JP2008513337A (https=)
AU (1) AU2005287034B2 (https=)
CA (1) CA2580580A1 (https=)
NO (1) NO20071532L (https=)
TW (1) TW200630158A (https=)
WO (1) WO2006034086A1 (https=)

Cited By (20)

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Publication number Priority date Publication date Assignee Title
JP2010042370A (ja) * 2008-08-15 2010-02-25 Ngk Insulators Ltd 水素分離体
JP2013139382A (ja) * 2011-12-30 2013-07-18 Industrial Technology Research Inst 多孔質基材の修飾方法および修飾された多孔質基材
JP2013184139A (ja) * 2012-03-09 2013-09-19 Asahi Kasei Chemicals Corp 水蒸気分離膜及びその製造方法
TWI449808B (zh) * 2011-12-30 2014-08-21 Ind Tech Res Inst 多孔基材的修飾方法及經修飾的多孔基材
JP2015507533A (ja) * 2011-12-19 2015-03-12 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 水素分離複合膜の作製方法
US9683182B2 (en) 2013-05-20 2017-06-20 Shell Oil Company Two-stage diesel aromatics saturation process utilizing intermediate stripping and base metal catalyst
CN111424306A (zh) * 2020-04-13 2020-07-17 厦门通富微电子有限公司 一种气泡剥离装置及电镀液电镀系统
US11322766B2 (en) 2020-05-28 2022-05-03 Saudi Arabian Oil Company Direct hydrocarbon metal supported solid oxide fuel cell
US11492254B2 (en) 2020-06-18 2022-11-08 Saudi Arabian Oil Company Hydrogen production with membrane reformer
US11492255B2 (en) 2020-04-03 2022-11-08 Saudi Arabian Oil Company Steam methane reforming with steam regeneration
US11578016B1 (en) 2021-08-12 2023-02-14 Saudi Arabian Oil Company Olefin production via dry reforming and olefin synthesis in a vessel
US11583824B2 (en) 2020-06-18 2023-02-21 Saudi Arabian Oil Company Hydrogen production with membrane reformer
US11617981B1 (en) 2022-01-03 2023-04-04 Saudi Arabian Oil Company Method for capturing CO2 with assisted vapor compression
US11639290B2 (en) 2020-06-04 2023-05-02 Saudi Arabian Oil Company Dry reforming of methane with carbon dioxide at elevated pressure
US11718575B2 (en) 2021-08-12 2023-08-08 Saudi Arabian Oil Company Methanol production via dry reforming and methanol synthesis in a vessel
US11787759B2 (en) 2021-08-12 2023-10-17 Saudi Arabian Oil Company Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel
US11999619B2 (en) 2020-06-18 2024-06-04 Saudi Arabian Oil Company Hydrogen production with membrane reactor
JP7516174B2 (ja) 2020-09-09 2024-07-16 日産自動車株式会社 ガス分離膜及びその製造方法
US12220666B2 (en) 2021-01-12 2025-02-11 Saudi Arabian Oil Company Ultrathin membrane fabrication
US12258272B2 (en) 2021-08-12 2025-03-25 Saudi Arabian Oil Company Dry reforming of methane using a nickel-based bi-metallic catalyst

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Publication number Priority date Publication date Assignee Title
US7727596B2 (en) * 2004-07-21 2010-06-01 Worcester Polytechnic Institute Method for fabricating a composite gas separation module
US8048199B2 (en) 2007-02-20 2011-11-01 Shell Oil Company Method of making a leak stable gas separation membrane system
AU2008236737A1 (en) 2007-04-05 2008-10-16 Worcester Polytechnic Institute Composite structures with porous anodic oxide layers and methods of fabrication
JP5147375B2 (ja) * 2007-12-11 2013-02-20 大日本印刷株式会社 反応膜、水素製造装置および燃料電池
WO2010104421A1 (en) * 2009-03-10 2010-09-16 Powercell Sweden Ab Arrangement and method for generating hydrogen from hydrocarbon fuel
CN101920332B (zh) * 2010-04-29 2012-05-02 西安西工大超晶科技发展有限责任公司 一种不锈钢/铜复合梯度材料热交换过渡区部件的制造方法
US8652239B2 (en) 2010-05-03 2014-02-18 Worcester Polytechnic Institute High permeance sulfur tolerant Pd/Cu alloy membranes
CA2817490C (en) 2010-11-16 2019-02-12 Stichting Energieonderzoek Centrum Nederland Catalyst for hydrogen production
CN105013297B (zh) * 2014-04-23 2017-12-26 中国科学院大连化学物理研究所 一种用分子筛修饰钯基复合膜的方法
EP3686318A1 (en) 2019-01-23 2020-07-29 Paul Scherrer Institut Porous transport layer based on plurality of sintered porous layers
CN111905504A (zh) * 2020-07-03 2020-11-10 王保林 一种工业废气及废气中金属颗粒物处理装置
CN113041970B (zh) * 2021-03-17 2021-11-26 南京理工大学 一种内置扰流结构催化膜式反应器
AU2023220484B2 (en) * 2022-02-21 2025-10-23 Ngk Insulators, Ltd. Reactor
DE102022203604A1 (de) 2022-04-11 2023-10-12 Siemens Energy Global GmbH & Co. KG Pulver, keramische Wand, Reaktionskammer sowie Verfahren

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JPH04227035A (ja) * 1990-08-10 1992-08-17 Bend Res Inc 水素透過性複合金属膜
JPH04346824A (ja) * 1991-05-21 1992-12-02 Mitsubishi Heavy Ind Ltd 水素分離膜
JPH0585702A (ja) * 1991-09-30 1993-04-06 Mitsubishi Heavy Ind Ltd 水素分離膜の製造方法
JPH05285357A (ja) * 1992-04-09 1993-11-02 Mitsubishi Heavy Ind Ltd 水素分離膜
JPH1028850A (ja) * 1996-07-12 1998-02-03 Toyota Motor Corp 水素分離構造体
WO1999030806A1 (en) * 1997-12-15 1999-06-24 Worcester Polytechnic Institute Hydrogen gas-extraction module
JP2001286742A (ja) * 2000-04-10 2001-10-16 Mitsubishi Heavy Ind Ltd 水素分離膜
JP2002219341A (ja) * 2001-01-30 2002-08-06 Kobe Steel Ltd 水素選択透過膜支持用基材および水素選択透過部材
WO2003011433A1 (de) * 2001-07-25 2003-02-13 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Metallische lösungs-diffusions-membran sowie verfahren zur herstellung
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JP2006520686A (ja) * 2003-03-21 2006-09-14 ウスター ポリテクニック インスティチュート 中間金属層を有する複合ガス分離モジュール
JP2006525119A (ja) * 2003-05-02 2006-11-09 ウスター ポリテクニック インスティチュート 高タンマン温度中間層を有する複合ガス分離モジュール

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US5498278A (en) * 1990-08-10 1996-03-12 Bend Research, Inc. Composite hydrogen separation element and module
FR2820988B1 (fr) * 2001-02-19 2003-04-25 Cie D Etudes Des Technologies Structures composites de membranes selectivement permeables a l'hydrogene et processeurs de gaz combustibles en faisant usage
US6916454B2 (en) * 2001-03-30 2005-07-12 Siemens Westinghouse Power Corporation Metal gas separation membrane
US7001446B2 (en) * 2002-03-05 2006-02-21 Eltron Research, Inc. Dense, layered membranes for hydrogen separation
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Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04227035A (ja) * 1990-08-10 1992-08-17 Bend Res Inc 水素透過性複合金属膜
JPH04346824A (ja) * 1991-05-21 1992-12-02 Mitsubishi Heavy Ind Ltd 水素分離膜
JPH0585702A (ja) * 1991-09-30 1993-04-06 Mitsubishi Heavy Ind Ltd 水素分離膜の製造方法
JPH05285357A (ja) * 1992-04-09 1993-11-02 Mitsubishi Heavy Ind Ltd 水素分離膜
JPH1028850A (ja) * 1996-07-12 1998-02-03 Toyota Motor Corp 水素分離構造体
WO1999030806A1 (en) * 1997-12-15 1999-06-24 Worcester Polytechnic Institute Hydrogen gas-extraction module
JP2001286742A (ja) * 2000-04-10 2001-10-16 Mitsubishi Heavy Ind Ltd 水素分離膜
JP2002219341A (ja) * 2001-01-30 2002-08-06 Kobe Steel Ltd 水素選択透過膜支持用基材および水素選択透過部材
WO2003011433A1 (de) * 2001-07-25 2003-02-13 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Metallische lösungs-diffusions-membran sowie verfahren zur herstellung
WO2003076050A1 (en) * 2002-03-05 2003-09-18 Eltron Research, Inc. Hydrogen transport membranes
JP2006520686A (ja) * 2003-03-21 2006-09-14 ウスター ポリテクニック インスティチュート 中間金属層を有する複合ガス分離モジュール
JP2006525119A (ja) * 2003-05-02 2006-11-09 ウスター ポリテクニック インスティチュート 高タンマン温度中間層を有する複合ガス分離モジュール

Cited By (22)

* Cited by examiner, † Cited by third party
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JP2010042370A (ja) * 2008-08-15 2010-02-25 Ngk Insulators Ltd 水素分離体
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