JP2008045008A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2008045008A5 JP2008045008A5 JP2006220679A JP2006220679A JP2008045008A5 JP 2008045008 A5 JP2008045008 A5 JP 2008045008A5 JP 2006220679 A JP2006220679 A JP 2006220679A JP 2006220679 A JP2006220679 A JP 2006220679A JP 2008045008 A5 JP2008045008 A5 JP 2008045008A5
- Authority
- JP
- Japan
- Prior art keywords
- propylene
- ethylene
- resin composition
- weight
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 169
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 168
- 239000011342 resin composition Substances 0.000 claims description 93
- 239000005022 packaging material Substances 0.000 claims description 90
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 64
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 63
- 239000005977 Ethylene Substances 0.000 claims description 63
- 229920001155 polypropylene Polymers 0.000 claims description 36
- 229920001577 copolymer Polymers 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 29
- 229920005653 propylene-ethylene copolymer Polymers 0.000 claims description 29
- 239000004711 α-olefin Substances 0.000 claims description 24
- 239000012968 metallocene catalyst Substances 0.000 claims description 23
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 20
- 238000009826 distribution Methods 0.000 claims description 15
- 238000002844 melting Methods 0.000 claims description 14
- 230000008018 melting Effects 0.000 claims description 14
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 10
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 10
- 238000000465 moulding Methods 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 5
- 239000012785 packaging film Substances 0.000 claims description 5
- 229920006280 packaging film Polymers 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 239000010408 film Substances 0.000 description 130
- 238000006116 polymerization reaction Methods 0.000 description 114
- -1 polypropylene Polymers 0.000 description 73
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 58
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical group CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 56
- 238000004519 manufacturing process Methods 0.000 description 56
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 51
- 239000001257 hydrogen Substances 0.000 description 47
- 229910052739 hydrogen Inorganic materials 0.000 description 47
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 45
- 239000002002 slurry Substances 0.000 description 42
- 239000003054 catalyst Substances 0.000 description 40
- 150000002430 hydrocarbons Chemical group 0.000 description 40
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 31
- 239000007789 gas Substances 0.000 description 31
- 150000001875 compounds Chemical class 0.000 description 27
- 239000011949 solid catalyst Substances 0.000 description 25
- 238000000034 method Methods 0.000 description 19
- 239000007787 solid Substances 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- 230000001681 protective effect Effects 0.000 description 15
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 15
- 239000004743 Polypropylene Substances 0.000 description 14
- MWHBZZADOGTHOW-UHFFFAOYSA-N 5-tert-butyl-1,3,3-trimethyl-2,6a-dihydro-1H-pentalene Chemical compound CC1CC(C)(C)C2=CC(=CC12)C(C)(C)C MWHBZZADOGTHOW-UHFFFAOYSA-N 0.000 description 13
- 230000000903 blocking effect Effects 0.000 description 13
- 229920001971 elastomer Polymers 0.000 description 13
- 238000003780 insertion Methods 0.000 description 12
- 230000000704 physical effect Effects 0.000 description 12
- 238000004898 kneading Methods 0.000 description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 229910004298 SiO 2 Inorganic materials 0.000 description 9
- 229920001400 block copolymer Polymers 0.000 description 9
- 125000004122 cyclic group Chemical group 0.000 description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 9
- 239000004033 plastic Substances 0.000 description 9
- 229920003023 plastic Polymers 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 8
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
- 239000003446 ligand Substances 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 7
- 238000012685 gas phase polymerization Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000006467 substitution reaction Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 238000012661 block copolymerization Methods 0.000 description 6
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 6
- 235000013305 food Nutrition 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 229920005629 polypropylene homopolymer Polymers 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- 239000006228 supernatant Substances 0.000 description 6
- 239000003017 thermal stabilizer Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000002981 blocking agent Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 230000037431 insertion Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 229930195734 saturated hydrocarbon Natural products 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229910052723 transition metal Inorganic materials 0.000 description 5
- 150000003624 transition metals Chemical class 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 235000010724 Wisteria floribunda Nutrition 0.000 description 4
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 4
- 239000008116 calcium stearate Substances 0.000 description 4
- 235000013539 calcium stearate Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 150000002902 organometallic compounds Chemical class 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 4
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- ABIPLJQFLRXYES-UHFFFAOYSA-N 1,2,3,3a-tetrahydropentalene Chemical compound C1=CC=C2CCCC21 ABIPLJQFLRXYES-UHFFFAOYSA-N 0.000 description 3
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- XNNZEUNRCXKWIQ-UHFFFAOYSA-N 1,3,3,5-tetramethyl-2,6a-dihydro-1H-pentalene Chemical compound CC1(CC(C2C=C(C=C12)C)C)C XNNZEUNRCXKWIQ-UHFFFAOYSA-N 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 3
- NJAFJHNZERDADB-UHFFFAOYSA-N 5-ethyl-1,3,3-trimethyl-2,6a-dihydro-1H-pentalene Chemical compound CC1(CC(C2C=C(C=C12)CC)C)C NJAFJHNZERDADB-UHFFFAOYSA-N 0.000 description 3
- WOEGXONSDLQQML-UHFFFAOYSA-N 5-tert-butyl-1,3,3-triethyl-2-methyl-2,6a-dihydro-1H-pentalene Chemical compound CCC1C(C)C(CC)(CC)C2=CC(=CC12)C(C)(C)C WOEGXONSDLQQML-UHFFFAOYSA-N 0.000 description 3
- IQCQSLHNXPMLNH-UHFFFAOYSA-N 5-tert-butyl-1,3-diphenyl-1,2,3,3a-tetrahydropentalene Chemical compound C1(=CC=CC=C1)C1CC(C2C=C(C=C12)C(C)(C)C)C1=CC=CC=C1 IQCQSLHNXPMLNH-UHFFFAOYSA-N 0.000 description 3
- LVSLBYMNQQGTTG-UHFFFAOYSA-N 5-tert-butyl-1-methyl-3-phenyl-1,2,3,3a-tetrahydropentalene Chemical compound CC1CC(C2C=C(C=C12)C(C)(C)C)C1=CC=CC=C1 LVSLBYMNQQGTTG-UHFFFAOYSA-N 0.000 description 3
- PXGSJNDESQUKFH-UHFFFAOYSA-N 5-tert-butyl-3,3-dimethyl-1-phenyl-2,6a-dihydro-1H-pentalene Chemical compound CC1(CC(C2C=C(C=C12)C(C)(C)C)C1=CC=CC=C1)C PXGSJNDESQUKFH-UHFFFAOYSA-N 0.000 description 3
- MJYVQZBLTLRRGK-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1,2,3,3a-tetrahydropentalene Chemical compound CC1CCC2=CC(=CC12)C(C)(C)C MJYVQZBLTLRRGK-UHFFFAOYSA-N 0.000 description 3
- TUNPFRVURLQXEC-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1,3-bis(4-methylphenyl)-2,6a-dihydro-1H-pentalene Chemical compound C1(=CC=C(C=C1)C1(CC(C2C=C(C=C12)C(C)(C)C)C1=CC=C(C=C1)C)C)C TUNPFRVURLQXEC-UHFFFAOYSA-N 0.000 description 3
- QFQHDNUJRSACMB-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1,3-diphenyl-2,6a-dihydro-1H-pentalene Chemical compound C1(=CC=CC=C1)C1(CC(C2C=C(C=C12)C(C)(C)C)C1=CC=CC=C1)C QFQHDNUJRSACMB-UHFFFAOYSA-N 0.000 description 3
- LJWOIODETWAUER-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1-(4-methylphenyl)-1,2,3,3a-tetrahydropentalene Chemical compound C1(=CC=C(C=C1)C1CC(C2C=C(C=C12)C(C)(C)C)C)C LJWOIODETWAUER-UHFFFAOYSA-N 0.000 description 3
- DZKZYBUGCVZKLY-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1-phenyl-1,2,3,3a-tetrahydropentalene Chemical compound C1(=CC=CC=C1)C1CC(C2C=C(C=C12)C(C)(C)C)C DZKZYBUGCVZKLY-UHFFFAOYSA-N 0.000 description 3
- UIMOYEAWIMSMRR-UHFFFAOYSA-N 5-tert-butyl-3-phenyl-1,2,3,3a-tetrahydropentalene Chemical compound C1(=CC=CC=C1)C1CCC2=CC(=CC12)C(C)(C)C UIMOYEAWIMSMRR-UHFFFAOYSA-N 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- KUNZSLJMPCDOGI-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2] Chemical compound [Cl-].[Cl-].[Hf+2] KUNZSLJMPCDOGI-UHFFFAOYSA-L 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 238000001802 infusion Methods 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 125000001624 naphthyl group Chemical group 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229920001384 propylene homopolymer Polymers 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 3
- 125000003944 tolyl group Chemical group 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 2
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- 125000005917 3-methylpentyl group Chemical group 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- SXJQRFQLVQBFJU-UHFFFAOYSA-N 5-tert-butyl-1,3-dimethyl-1,2,3,3a-tetrahydropentalene Chemical compound CC1CC(C2C=C(C=C12)C(C)(C)C)C SXJQRFQLVQBFJU-UHFFFAOYSA-N 0.000 description 2
- GJWJNDOIDSVRBF-UHFFFAOYSA-N 5-tert-butyl-3,3-dimethyl-2,6a-dihydro-1H-pentalene Chemical compound CC1(CCC2C=C(C=C12)C(C)(C)C)C GJWJNDOIDSVRBF-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- FLFNHHSXSLXYQB-UHFFFAOYSA-L CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 FLFNHHSXSLXYQB-UHFFFAOYSA-L 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical group CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- 229920011250 Polypropylene Block Copolymer Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- GBUUAQMMMLMUGS-UHFFFAOYSA-L [Cl-].[Cl-].CC(C)=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=C(C=C1C)C(C)(C)C Chemical compound [Cl-].[Cl-].CC(C)=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=C(C=C1C)C(C)(C)C GBUUAQMMMLMUGS-UHFFFAOYSA-L 0.000 description 2
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical group OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 125000005299 dibenzofluorenyl group Chemical group C1(=CC=CC2=C3C(=C4C=5C=CC=CC5CC4=C21)C=CC=C3)* 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 125000002541 furyl group Chemical group 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- UJNZOIKQAUQOCN-UHFFFAOYSA-N methyl(diphenyl)phosphane Chemical compound C=1C=CC=CC=1P(C)C1=CC=CC=C1 UJNZOIKQAUQOCN-UHFFFAOYSA-N 0.000 description 2
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 description 2
- 150000002903 organophosphorus compounds Chemical class 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 125000005561 phenanthryl group Chemical group 0.000 description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 2
- QIIPQYDSKRYMFG-UHFFFAOYSA-N phenyl hydrogen carbonate Chemical group OC(=O)OC1=CC=CC=C1 QIIPQYDSKRYMFG-UHFFFAOYSA-N 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 125000001725 pyrenyl group Chemical group 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 125000001544 thienyl group Chemical group 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical group CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 2
- WNANKUWCBFKJIK-UHFFFAOYSA-N trimethyl-(4,6,6-trimethyl-4,5-dihydro-3aH-pentalen-2-yl)silane Chemical compound CC1(CC(C2C=C(C=C12)[Si](C)(C)C)C)C WNANKUWCBFKJIK-UHFFFAOYSA-N 0.000 description 2
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OWWIWYDDISJUMY-UHFFFAOYSA-N 2,3-dimethylbut-1-ene Chemical compound CC(C)C(C)=C OWWIWYDDISJUMY-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 1
- BWEKDYGHDCHWEN-UHFFFAOYSA-N 2-methylhex-2-ene Chemical compound CCCC=C(C)C BWEKDYGHDCHWEN-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- PKXHXOTZMFCXSH-UHFFFAOYSA-N 3,3-dimethylbut-1-ene Chemical compound CC(C)(C)C=C PKXHXOTZMFCXSH-UHFFFAOYSA-N 0.000 description 1
- AUJLDZJNMXNESO-UHFFFAOYSA-N 3-ethylhex-3-ene Chemical compound CCC=C(CC)CC AUJLDZJNMXNESO-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- FHHSSXNRVNXTBG-UHFFFAOYSA-N 3-methylhex-3-ene Chemical compound CCC=C(C)CC FHHSSXNRVNXTBG-UHFFFAOYSA-N 0.000 description 1
- RYKZRKKEYSRDNF-UHFFFAOYSA-N 3-methylidenepentane Chemical compound CCC(=C)CC RYKZRKKEYSRDNF-UHFFFAOYSA-N 0.000 description 1
- RGTDIFHVRPXHFT-UHFFFAOYSA-N 3-methylnon-3-ene Chemical compound CCCCCC=C(C)CC RGTDIFHVRPXHFT-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- YCTDZYMMFQCTEO-UHFFFAOYSA-N 3-octene Chemical compound CCCCC=CCC YCTDZYMMFQCTEO-UHFFFAOYSA-N 0.000 description 1
- KLCNJIQZXOQYTE-UHFFFAOYSA-N 4,4-dimethylpent-1-ene Chemical compound CC(C)(C)CC=C KLCNJIQZXOQYTE-UHFFFAOYSA-N 0.000 description 1
- KZJIOVQKSAOPOP-UHFFFAOYSA-N 5,5-dimethylhex-1-ene Chemical compound CC(C)(C)CCC=C KZJIOVQKSAOPOP-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- PQQPPHCNBWOJMH-UHFFFAOYSA-N C(CC)C=CCCCCC.CC(=CCCCC)C Chemical compound C(CC)C=CCCCCC.CC(=CCCCC)C PQQPPHCNBWOJMH-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- FCLIIKLPCZLTFC-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)(C)C=1C=C(C=2CC3=CC=C(C=C3C2C1)C(C)(C)C)[Zr+2] Chemical compound [Cl-].[Cl-].C(C)(C)(C)C=1C=C(C=2CC3=CC=C(C=C3C2C1)C(C)(C)C)[Zr+2] FCLIIKLPCZLTFC-UHFFFAOYSA-L 0.000 description 1
- BVNCVULRSLNDBS-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=C(C=C1C)C(C)(C)C Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr+2](C1=C(C=CC=2C3=CC=C(C=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=C(C=C1C)C(C)(C)C BVNCVULRSLNDBS-UHFFFAOYSA-L 0.000 description 1
- BAAQZDCCXHWKDI-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr+2](C1=CC=CC=2C3=CC=CC=C3CC1=2)C1C=C(C=C1C)C(C)(C)C Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr+2](C1=CC=CC=2C3=CC=CC=C3CC1=2)C1C=C(C=C1C)C(C)(C)C BAAQZDCCXHWKDI-UHFFFAOYSA-L 0.000 description 1
- QKTQFVSPMAUOFP-UHFFFAOYSA-L [Cl-].[Cl-].CC(C)=[Zr+2](C1=CC=CC=2C3=CC=CC=C3CC1=2)C1C=C(C=C1C)C(C)(C)C Chemical compound [Cl-].[Cl-].CC(C)=[Zr+2](C1=CC=CC=2C3=CC=CC=C3CC1=2)C1C=C(C=C1C)C(C)(C)C QKTQFVSPMAUOFP-UHFFFAOYSA-L 0.000 description 1
- HQAXJWCVLGNKSL-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C)C Chemical compound [Cl-].[Cl-].[Hf+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C)C HQAXJWCVLGNKSL-UHFFFAOYSA-L 0.000 description 1
- ILBJAYSPEKBNPJ-UHFFFAOYSA-L [Cl-].[Cl-].[Ti+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C)C Chemical compound [Cl-].[Cl-].[Ti+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C)C ILBJAYSPEKBNPJ-UHFFFAOYSA-L 0.000 description 1
- MIYMCUQMWZGCOO-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(C(C(C2=CC(=CC12)C(C)(C)C)(CC)CC)C)CC Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(C(C(C2=CC(=CC12)C(C)(C)C)(CC)CC)C)CC MIYMCUQMWZGCOO-UHFFFAOYSA-L 0.000 description 1
- WUGVIHPLTSPQJE-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C)C Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C)C WUGVIHPLTSPQJE-UHFFFAOYSA-L 0.000 description 1
- WLKSKHXAVRPCBX-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C)C1=CC=CC=C1 WLKSKHXAVRPCBX-UHFFFAOYSA-L 0.000 description 1
- YMSAAXSCPCXALE-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C1=CC=C(C=C1)C)C1=CC=C(C=C1)C Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C1=CC=C(C=C1)C)C1=CC=C(C=C1)C YMSAAXSCPCXALE-UHFFFAOYSA-L 0.000 description 1
- GKZXIHZNBUDXKZ-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)(C)C1=CC=CC=C1)C1=CC=CC=C1 GKZXIHZNBUDXKZ-UHFFFAOYSA-L 0.000 description 1
- UYCLXTLBOZQYPU-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)C)C Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)C)C UYCLXTLBOZQYPU-UHFFFAOYSA-L 0.000 description 1
- JJZDBMPFBDMXPN-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)C)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)C)C1=CC=CC=C1 JJZDBMPFBDMXPN-UHFFFAOYSA-L 0.000 description 1
- CLJXDJAUHKASMG-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)C1=CC=C(C=C1)C)C Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)C1=CC=C(C=C1)C)C CLJXDJAUHKASMG-UHFFFAOYSA-L 0.000 description 1
- DAMFFRQVWWEAGF-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)C1=CC=CC=C1)C Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C(C)(C)C)C1=CC=CC=C1)C DAMFFRQVWWEAGF-UHFFFAOYSA-L 0.000 description 1
- KNWYGDJOTDYBNO-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C)(C)C)C Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)C)(C)C)C KNWYGDJOTDYBNO-UHFFFAOYSA-L 0.000 description 1
- STMPQFDOQYDKHX-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)CC)(C)C)C Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CC(C2=CC(=CC12)CC)(C)C)C STMPQFDOQYDKHX-UHFFFAOYSA-L 0.000 description 1
- LYAKPCPMXYAFNV-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CCC2=CC(=CC12)C(C)(C)C)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1(CCC2=CC(=CC12)C(C)(C)C)C1=CC=CC=C1 LYAKPCPMXYAFNV-UHFFFAOYSA-L 0.000 description 1
- IYXNAHKLPMILCK-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1CC(C2=CC(=CC12)C(C)(C)C)(C)C Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1CC(C2=CC(=CC12)C(C)(C)C)(C)C IYXNAHKLPMILCK-UHFFFAOYSA-L 0.000 description 1
- RFMLYNQAOJERIL-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1CCC2=CC=CC12 Chemical compound [Cl-].[Cl-].[Zr+2].C1(=CC=CC=2C3=CC=CC=C3CC12)C1CCC2=CC=CC12 RFMLYNQAOJERIL-UHFFFAOYSA-L 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- LFYJSSARVMHQJB-QIXNEVBVSA-N bakuchiol Chemical compound CC(C)=CCC[C@@](C)(C=C)\C=C\C1=CC=C(O)C=C1 LFYJSSARVMHQJB-QIXNEVBVSA-N 0.000 description 1
- 239000004305 biphenyl Chemical group 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052800 carbon group element Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- PBGGNZZGJIKBMJ-UHFFFAOYSA-N di(propan-2-yl)azanide Chemical group CC(C)[N-]C(C)C PBGGNZZGJIKBMJ-UHFFFAOYSA-N 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- QKIUAMUSENSFQQ-UHFFFAOYSA-N dimethylazanide Chemical group C[N-]C QKIUAMUSENSFQQ-UHFFFAOYSA-N 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical group C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- LJJQENSFXLXPIV-UHFFFAOYSA-N fluorenylidene Chemical group C1=CC=C2[C]C3=CC=CC=C3C2=C1 LJJQENSFXLXPIV-UHFFFAOYSA-N 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical compound CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 1
- WZHKDGJSXCTSCK-UHFFFAOYSA-N hept-3-ene Chemical compound CCCC=CCC WZHKDGJSXCTSCK-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- IRUCBBFNLDIMIK-UHFFFAOYSA-N oct-4-ene Chemical compound CCCC=CCCC IRUCBBFNLDIMIK-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006220679A JP5260846B2 (ja) | 2006-08-11 | 2006-08-11 | 包装材料用プロピレン系樹脂組成物 |
| CN2007800295152A CN101501128B (zh) | 2006-08-11 | 2007-08-06 | 包装材料用丙烯类树脂组合物 |
| US12/310,065 US20090317615A1 (en) | 2006-08-11 | 2007-08-06 | Packaging propylene resin composition |
| KR1020097004993A KR101107825B1 (ko) | 2006-08-11 | 2007-08-06 | 포장 재료용 프로필렌계 수지 조성물 |
| EP07792032A EP2053086A4 (en) | 2006-08-11 | 2007-08-06 | PROPYLENE RESIN COMPOSITION FOR PACKAGING MATERIAL |
| PCT/JP2007/065362 WO2008018409A1 (en) | 2006-08-11 | 2007-08-06 | Propylene resin composition for packaging material |
| TW096129521A TW200833761A (en) | 2006-08-11 | 2007-08-10 | Propylene-based resin composition for packaging materials and its applications |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006220679A JP5260846B2 (ja) | 2006-08-11 | 2006-08-11 | 包装材料用プロピレン系樹脂組成物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008045008A JP2008045008A (ja) | 2008-02-28 |
| JP2008045008A5 true JP2008045008A5 (https=) | 2009-09-10 |
| JP5260846B2 JP5260846B2 (ja) | 2013-08-14 |
Family
ID=39179057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006220679A Active JP5260846B2 (ja) | 2006-08-11 | 2006-08-11 | 包装材料用プロピレン系樹脂組成物 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP5260846B2 (https=) |
| CN (1) | CN101501128B (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4944058B2 (ja) * | 2008-03-31 | 2012-05-30 | 株式会社エフピコ | ポリプロピレン系樹脂シート及びポリプロピレン系樹脂容器 |
| US9328232B2 (en) | 2012-02-24 | 2016-05-03 | Japan Polypropylene Corporation | Propylene-ethylene copolymer resin composition and moulded article, film and sheet thereof |
| JP5807605B2 (ja) * | 2012-04-04 | 2015-11-10 | 日本ポリプロ株式会社 | 加熱殺菌処理食品の包装フィルム用ポリプロピレン系樹脂組成物及び包装用フィルム |
| SG11201502288TA (en) | 2012-09-25 | 2015-05-28 | Mitsui Chemicals Inc | Process for producing olefin polymer and olefin polymer |
| JP6033322B2 (ja) * | 2012-09-25 | 2016-11-30 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| JP6020312B2 (ja) * | 2012-11-27 | 2016-11-02 | 日本ポリプロ株式会社 | プロピレン−エチレン共重合体樹脂組成物並びにフィルム及びシート |
| US9540459B2 (en) | 2013-03-12 | 2017-01-10 | Mitsui Chemicals, Inc. | Production method of olefin polymer and olefin polymerization catalyst |
| KR101496028B1 (ko) * | 2013-08-28 | 2015-02-25 | 삼성토탈 주식회사 | 보호필름용 폴리프로필렌 수지 및 보호필름 |
| JP2015160853A (ja) * | 2014-02-26 | 2015-09-07 | 日本ポリプロ株式会社 | プロピレン−エチレン共重合体樹脂組成物及びフィルムもしくはシート |
| CN107903499A (zh) * | 2017-12-04 | 2018-04-13 | 天津科技大学 | 一种透明增韧改性聚丙烯塑料及其制备 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0792914B1 (en) * | 1995-09-14 | 2002-08-14 | Mitsui Chemicals, Inc. | Polyolefin composition and article molded therefrom |
| JP2001081255A (ja) * | 1999-09-17 | 2001-03-27 | Ube Ind Ltd | カレンダー成形用ポリオレフィン系樹脂組成物およびこの成形物 |
| DE60211444T2 (de) * | 2001-03-15 | 2006-11-30 | Mitsui Chemicals, Inc. | Automobilteile aus einer polypropylenharzzusammensetzung |
| JP4869514B2 (ja) * | 2001-08-06 | 2012-02-08 | 三井化学株式会社 | 軟質シンジオタクティックポリプロピレン組成物および該組成物からなる成形体 |
| JP2004051801A (ja) * | 2002-07-19 | 2004-02-19 | Mitsui Chemicals Inc | ポリオレフィン樹脂組成物及びその用途 |
| JP2004107490A (ja) * | 2002-09-18 | 2004-04-08 | Mitsui Chemicals Inc | 軟質シンジオタクティックポリプロピレン系組成物及び該組成物を含む成形体 |
| CN104085160B (zh) * | 2004-11-25 | 2018-08-24 | 三井化学株式会社 | 聚烯烃系装饰片 |
| JP4732749B2 (ja) * | 2004-12-21 | 2011-07-27 | 三井化学株式会社 | 熱可塑性樹脂組成物、成形体およびその用途 |
-
2006
- 2006-08-11 JP JP2006220679A patent/JP5260846B2/ja active Active
-
2007
- 2007-08-06 CN CN2007800295152A patent/CN101501128B/zh active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101107825B1 (ko) | 포장 재료용 프로필렌계 수지 조성물 | |
| JP5167120B2 (ja) | プロピレン系ランダムブロック共重合体、該共重合体を含む樹脂組成物およびそれからなる成形体 | |
| CN104640925B (zh) | 1‑丁烯‑α‑烯烃共聚物组合物 | |
| US7354655B2 (en) | Adhesive resin composition and multi-layer laminated structure using the same | |
| CN101501128B (zh) | 包装材料用丙烯类树脂组合物 | |
| WO1997010299A1 (en) | Polyolefin composition and article molded therefrom | |
| CN106068291A (zh) | 烯烃系树脂、其制造方法及丙烯系树脂组合物 | |
| JP2000239462A (ja) | プロピレン系樹脂組成物、その製造方法および用途 | |
| JP5455311B2 (ja) | 表面保護フィルム | |
| JP2001064335A (ja) | プロピレン系樹脂組成物およびその製造方法 | |
| JP2008045008A5 (https=) | ||
| JP6564289B2 (ja) | オレフィン系樹脂とその製造方法および組成物並びに成形体 | |
| JP5342115B2 (ja) | 包装材料用プロピレン系樹脂組成物 | |
| JP2000198893A (ja) | 結晶性α―オレフィン系共重合体組成物および該組成物を含む熱可塑性樹脂組成物 | |
| JP5052068B2 (ja) | 包装材料用プロピレン系樹脂組成物およびその用途 | |
| JP5224840B2 (ja) | ガス透過性フィルム | |
| JP6666089B2 (ja) | プロピレン系樹脂組成物および成形体 | |
| JP2017222850A (ja) | プロピレン系樹脂組成物およびその製造方法、ならびに該プロピレン系樹脂組成物を用いた成形体 | |
| JP5224763B2 (ja) | シュリンクラベル | |
| JP7055598B2 (ja) | 滅菌容器 | |
| JP5221093B2 (ja) | シュリンクフィルム | |
| JP6615554B2 (ja) | オレフィン系樹脂、その製造方法および組成物並びに成形体 | |
| JP6594140B2 (ja) | プロピレン系樹脂組成物の製造方法 | |
| JP5159352B2 (ja) | マット調延伸積層フィルム | |
| JP2020122145A (ja) | プロピレン系樹脂組成物 |