JP2008045008A5 - - Google Patents
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- JP2008045008A5 JP2008045008A5 JP2006220679A JP2006220679A JP2008045008A5 JP 2008045008 A5 JP2008045008 A5 JP 2008045008A5 JP 2006220679 A JP2006220679 A JP 2006220679A JP 2006220679 A JP2006220679 A JP 2006220679A JP 2008045008 A5 JP2008045008 A5 JP 2008045008A5
- Authority
- JP
- Japan
- Prior art keywords
- propylene
- ethylene
- resin composition
- weight
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 169
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 168
- 239000011342 resin composition Substances 0.000 claims description 93
- 239000005022 packaging material Substances 0.000 claims description 90
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 64
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 63
- 239000005977 Ethylene Substances 0.000 claims description 63
- 229920001155 polypropylene Polymers 0.000 claims description 36
- 229920001577 copolymer Polymers 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 29
- 229920005653 propylene-ethylene copolymer Polymers 0.000 claims description 29
- 239000004711 α-olefin Substances 0.000 claims description 24
- 239000012968 metallocene catalyst Substances 0.000 claims description 23
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 20
- 238000009826 distribution Methods 0.000 claims description 15
- 238000002844 melting Methods 0.000 claims description 14
- 230000008018 melting Effects 0.000 claims description 14
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 10
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 10
- 238000000465 moulding Methods 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 5
- 239000012785 packaging film Substances 0.000 claims description 5
- 229920006280 packaging film Polymers 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 239000010408 film Substances 0.000 description 130
- 238000006116 polymerization reaction Methods 0.000 description 114
- -1 polypropylene Polymers 0.000 description 73
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 58
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical group CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 56
- 238000004519 manufacturing process Methods 0.000 description 56
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 51
- 239000001257 hydrogen Substances 0.000 description 47
- 229910052739 hydrogen Inorganic materials 0.000 description 47
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 45
- 239000002002 slurry Substances 0.000 description 42
- 239000003054 catalyst Substances 0.000 description 40
- 150000002430 hydrocarbons Chemical group 0.000 description 40
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 31
- 239000007789 gas Substances 0.000 description 31
- 150000001875 compounds Chemical class 0.000 description 27
- 239000011949 solid catalyst Substances 0.000 description 25
- 238000000034 method Methods 0.000 description 19
- 239000007787 solid Substances 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- 230000001681 protective effect Effects 0.000 description 15
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 15
- 239000004743 Polypropylene Substances 0.000 description 14
- MWHBZZADOGTHOW-UHFFFAOYSA-N 5-tert-butyl-1,3,3-trimethyl-2,6a-dihydro-1H-pentalene Chemical compound CC1CC(C)(C)C2=CC(=CC12)C(C)(C)C MWHBZZADOGTHOW-UHFFFAOYSA-N 0.000 description 13
- 230000000903 blocking effect Effects 0.000 description 13
- 229920001971 elastomer Polymers 0.000 description 13
- 238000003780 insertion Methods 0.000 description 12
- 230000000704 physical effect Effects 0.000 description 12
- 238000004898 kneading Methods 0.000 description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 229910004298 SiO 2 Inorganic materials 0.000 description 9
- 229920001400 block copolymer Polymers 0.000 description 9
- 125000004122 cyclic group Chemical group 0.000 description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 9
- 239000004033 plastic Substances 0.000 description 9
- 229920003023 plastic Polymers 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 8
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
- 239000003446 ligand Substances 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 7
- 238000012685 gas phase polymerization Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000006467 substitution reaction Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 238000012661 block copolymerization Methods 0.000 description 6
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 6
- 235000013305 food Nutrition 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 229920005629 polypropylene homopolymer Polymers 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- 239000006228 supernatant Substances 0.000 description 6
- 239000003017 thermal stabilizer Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000002981 blocking agent Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 230000037431 insertion Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 229930195734 saturated hydrocarbon Natural products 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229910052723 transition metal Inorganic materials 0.000 description 5
- 150000003624 transition metals Chemical class 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 235000010724 Wisteria floribunda Nutrition 0.000 description 4
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 4
- 239000008116 calcium stearate Substances 0.000 description 4
- 235000013539 calcium stearate Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 150000002902 organometallic compounds Chemical class 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 4
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- ABIPLJQFLRXYES-UHFFFAOYSA-N 1,2,3,3a-tetrahydropentalene Chemical compound C1=CC=C2CCCC21 ABIPLJQFLRXYES-UHFFFAOYSA-N 0.000 description 3
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- XNNZEUNRCXKWIQ-UHFFFAOYSA-N 1,3,3,5-tetramethyl-2,6a-dihydro-1H-pentalene Chemical compound CC1(CC(C2C=C(C=C12)C)C)C XNNZEUNRCXKWIQ-UHFFFAOYSA-N 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 3
- NJAFJHNZERDADB-UHFFFAOYSA-N 5-ethyl-1,3,3-trimethyl-2,6a-dihydro-1H-pentalene Chemical compound CC1(CC(C2C=C(C=C12)CC)C)C NJAFJHNZERDADB-UHFFFAOYSA-N 0.000 description 3
- WOEGXONSDLQQML-UHFFFAOYSA-N 5-tert-butyl-1,3,3-triethyl-2-methyl-2,6a-dihydro-1H-pentalene Chemical compound CCC1C(C)C(CC)(CC)C2=CC(=CC12)C(C)(C)C WOEGXONSDLQQML-UHFFFAOYSA-N 0.000 description 3
- IQCQSLHNXPMLNH-UHFFFAOYSA-N 5-tert-butyl-1,3-diphenyl-1,2,3,3a-tetrahydropentalene Chemical compound C1(=CC=CC=C1)C1CC(C2C=C(C=C12)C(C)(C)C)C1=CC=CC=C1 IQCQSLHNXPMLNH-UHFFFAOYSA-N 0.000 description 3
- LVSLBYMNQQGTTG-UHFFFAOYSA-N 5-tert-butyl-1-methyl-3-phenyl-1,2,3,3a-tetrahydropentalene Chemical compound CC1CC(C2C=C(C=C12)C(C)(C)C)C1=CC=CC=C1 LVSLBYMNQQGTTG-UHFFFAOYSA-N 0.000 description 3
- PXGSJNDESQUKFH-UHFFFAOYSA-N 5-tert-butyl-3,3-dimethyl-1-phenyl-2,6a-dihydro-1H-pentalene Chemical compound CC1(CC(C2C=C(C=C12)C(C)(C)C)C1=CC=CC=C1)C PXGSJNDESQUKFH-UHFFFAOYSA-N 0.000 description 3
- MJYVQZBLTLRRGK-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1,2,3,3a-tetrahydropentalene Chemical compound CC1CCC2=CC(=CC12)C(C)(C)C MJYVQZBLTLRRGK-UHFFFAOYSA-N 0.000 description 3
- TUNPFRVURLQXEC-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1,3-bis(4-methylphenyl)-2,6a-dihydro-1H-pentalene Chemical compound C1(=CC=C(C=C1)C1(CC(C2C=C(C=C12)C(C)(C)C)C1=CC=C(C=C1)C)C)C TUNPFRVURLQXEC-UHFFFAOYSA-N 0.000 description 3
- QFQHDNUJRSACMB-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1,3-diphenyl-2,6a-dihydro-1H-pentalene Chemical compound C1(=CC=CC=C1)C1(CC(C2C=C(C=C12)C(C)(C)C)C1=CC=CC=C1)C QFQHDNUJRSACMB-UHFFFAOYSA-N 0.000 description 3
- LJWOIODETWAUER-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1-(4-methylphenyl)-1,2,3,3a-tetrahydropentalene Chemical compound C1(=CC=C(C=C1)C1CC(C2C=C(C=C12)C(C)(C)C)C)C LJWOIODETWAUER-UHFFFAOYSA-N 0.000 description 3
- DZKZYBUGCVZKLY-UHFFFAOYSA-N 5-tert-butyl-3-methyl-1-phenyl-1,2,3,3a-tetrahydropentalene Chemical compound C1(=CC=CC=C1)C1CC(C2C=C(C=C12)C(C)(C)C)C DZKZYBUGCVZKLY-UHFFFAOYSA-N 0.000 description 3
- UIMOYEAWIMSMRR-UHFFFAOYSA-N 5-tert-butyl-3-phenyl-1,2,3,3a-tetrahydropentalene Chemical compound C1(=CC=CC=C1)C1CCC2=CC(=CC12)C(C)(C)C UIMOYEAWIMSMRR-UHFFFAOYSA-N 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- KUNZSLJMPCDOGI-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2] Chemical compound [Cl-].[Cl-].[Hf+2] KUNZSLJMPCDOGI-UHFFFAOYSA-L 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 238000001802 infusion Methods 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 125000001624 naphthyl group Chemical group 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229920001384 propylene homopolymer Polymers 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 3
- 125000003944 tolyl group Chemical group 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 2
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- 125000005917 3-methylpentyl group Chemical group 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- SXJQRFQLVQBFJU-UHFFFAOYSA-N 5-tert-butyl-1,3-dimethyl-1,2,3,3a-tetrahydropentalene Chemical compound CC1CC(C2C=C(C=C12)C(C)(C)C)C SXJQRFQLVQBFJU-UHFFFAOYSA-N 0.000 description 2
- GJWJNDOIDSVRBF-UHFFFAOYSA-N 5-tert-butyl-3,3-dimethyl-2,6a-dihydro-1H-pentalene Chemical compound CC1(CCC2C=C(C=C12)C(C)(C)C)C GJWJNDOIDSVRBF-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- FLFNHHSXSLXYQB-UHFFFAOYSA-L CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 FLFNHHSXSLXYQB-UHFFFAOYSA-L 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical group CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- 229920011250 Polypropylene Block Copolymer Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- GBUUAQMMMLMUGS-UHFFFAOYSA-L [Cl-].[Cl-].CC(C)=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=C(C=C1C)C(C)(C)C Chemical compound [Cl-].[Cl-].CC(C)=[Zr+2](C1=CC(=CC=2C3=CC(=CC=C3CC1=2)C(C)(C)C)C(C)(C)C)C1C=C(C=C1C)C(C)(C)C GBUUAQMMMLMUGS-UHFFFAOYSA-L 0.000 description 2
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
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- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- IRUCBBFNLDIMIK-UHFFFAOYSA-N oct-4-ene Chemical compound CCCC=CCCC IRUCBBFNLDIMIK-UHFFFAOYSA-N 0.000 description 1
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| JP2006220679A JP5260846B2 (ja) | 2006-08-11 | 2006-08-11 | 包装材料用プロピレン系樹脂組成物 |
| EP07792032A EP2053086A4 (en) | 2006-08-11 | 2007-08-06 | PROPYLENE RESIN COMPOSITION FOR PACKAGING MATERIAL |
| CN2007800295152A CN101501128B (zh) | 2006-08-11 | 2007-08-06 | 包装材料用丙烯类树脂组合物 |
| PCT/JP2007/065362 WO2008018409A1 (en) | 2006-08-11 | 2007-08-06 | Propylene resin composition for packaging material |
| US12/310,065 US20090317615A1 (en) | 2006-08-11 | 2007-08-06 | Packaging propylene resin composition |
| KR1020097004993A KR101107825B1 (ko) | 2006-08-11 | 2007-08-06 | 포장 재료용 프로필렌계 수지 조성물 |
| TW096129521A TW200833761A (en) | 2006-08-11 | 2007-08-10 | Propylene-based resin composition for packaging materials and its applications |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| JP2006220679A JP5260846B2 (ja) | 2006-08-11 | 2006-08-11 | 包装材料用プロピレン系樹脂組成物 |
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| JP2008045008A JP2008045008A (ja) | 2008-02-28 |
| JP2008045008A5 true JP2008045008A5 (enExample) | 2009-09-10 |
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| CN (1) | CN101501128B (enExample) |
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| JP4944058B2 (ja) * | 2008-03-31 | 2012-05-30 | 株式会社エフピコ | ポリプロピレン系樹脂シート及びポリプロピレン系樹脂容器 |
| WO2013125670A1 (ja) * | 2012-02-24 | 2013-08-29 | 日本ポリプロ株式会社 | プロピレン－エチレン共重合体樹脂組成物並びにその成形体、フィルム及びシート |
| JP5807605B2 (ja) * | 2012-04-04 | 2015-11-10 | 日本ポリプロ株式会社 | 加熱殺菌処理食品の包装フィルム用ポリプロピレン系樹脂組成物及び包装用フィルム |
| KR101838785B1 (ko) | 2012-09-25 | 2018-03-14 | 미쓰이 가가쿠 가부시키가이샤 | 전이 금속 화합물, 올레핀 중합용 촉매 및 올레핀 중합체의 제조 방법 |
| KR101640356B1 (ko) | 2012-09-25 | 2016-07-15 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합체의 제조 방법 및 올레핀 중합체 |
| JP6020312B2 (ja) * | 2012-11-27 | 2016-11-02 | 日本ポリプロ株式会社 | プロピレン−エチレン共重合体樹脂組成物並びにフィルム及びシート |
| CN105143279B (zh) * | 2013-03-12 | 2017-10-27 | 三井化学株式会社 | 烯烃聚合物的制造方法及烯烃聚合用催化剂 |
| KR101496028B1 (ko) * | 2013-08-28 | 2015-02-25 | 삼성토탈 주식회사 | 보호필름용 폴리프로필렌 수지 및 보호필름 |
| JP2015160853A (ja) * | 2014-02-26 | 2015-09-07 | 日本ポリプロ株式会社 | プロピレン−エチレン共重合体樹脂組成物及びフィルムもしくはシート |
| CN107903499A (zh) * | 2017-12-04 | 2018-04-13 | 天津科技大学 | 一种透明增韧改性聚丙烯塑料及其制备 |
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| DE69622986T2 (de) * | 1995-09-14 | 2003-04-30 | Mitsui Chemicals, Inc. | Polyolefinzusammensetzung und daraus geformter gegenstand |
| JP2001081255A (ja) * | 1999-09-17 | 2001-03-27 | Ube Ind Ltd | カレンダー成形用ポリオレフィン系樹脂組成物およびこの成形物 |
| WO2002074855A1 (en) * | 2001-03-15 | 2002-09-26 | Mitsui Chemicals, Inc. | Automotive part made of polypropylene resin composition |
| JP4869514B2 (ja) * | 2001-08-06 | 2012-02-08 | 三井化学株式会社 | 軟質シンジオタクティックポリプロピレン組成物および該組成物からなる成形体 |
| JP2004051801A (ja) * | 2002-07-19 | 2004-02-19 | Mitsui Chemicals Inc | ポリオレフィン樹脂組成物及びその用途 |
| JP2004107490A (ja) * | 2002-09-18 | 2004-04-08 | Mitsui Chemicals Inc | 軟質シンジオタクティックポリプロピレン系組成物及び該組成物を含む成形体 |
| KR100886444B1 (ko) * | 2004-11-25 | 2009-03-04 | 미쓰이 가가쿠 가부시키가이샤 | 프로필렌계 수지 조성물 및 그 용도 |
| JP4732749B2 (ja) * | 2004-12-21 | 2011-07-27 | 三井化学株式会社 | 熱可塑性樹脂組成物、成形体およびその用途 |
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