JP2007514047A5 - - Google Patents
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- JP2007514047A5 JP2007514047A5 JP2006544430A JP2006544430A JP2007514047A5 JP 2007514047 A5 JP2007514047 A5 JP 2007514047A5 JP 2006544430 A JP2006544430 A JP 2006544430A JP 2006544430 A JP2006544430 A JP 2006544430A JP 2007514047 A5 JP2007514047 A5 JP 2007514047A5
- Authority
- JP
- Japan
- Prior art keywords
- solvent
- weight
- acid catalyst
- less
- lactone group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000003377 acid catalyst Substances 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 3
- 125000000457 gamma-lactone group Chemical group 0.000 claims description 3
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims description 3
- 125000000962 organic group Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000000686 lactone group Chemical group 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000011343 solid material Substances 0.000 claims 1
Description
したがって本発明は、固体のリグノセルロース材料又はセルロース材料を酸触媒及び溶剤の存在下で100〜300℃の範囲の温度に加熱するリグノセルロース材料又はセルロース材料の液状化方法において、溶剤対固体材料の重量比が50以下であり、酸触媒が溶剤及び酸の重量に対し、酸濃度で50重量%以下存在し、かつ溶剤が一般分子式
(但し、R1〜R 6 は各々独立に水素原子、又は炭素原子と共にラクトン基に結合した有機基を表す)
のγ−ラクトン基を有する化合物を含む該方法に関する。
(但し、R1〜R 6 は各々独立に水素原子、又は炭素原子と共にラクトン基に結合した有機基を表す)
のγ−ラクトン基を有する化合物を含む該方法に関する。
ここで言うγ−ラクトン基含有化合物とは、一般分子式(1)において、R1〜R 6 が水素原子、又は前述のような有機基である化合物のことである。この化合物の合計炭素原子数は、好ましくは20以下、更に好ましくは15以下である。
Claims (1)
- 固体のリグノセルロース材料又はセルロース材料を酸触媒及び溶剤の存在下で100〜300℃の範囲の温度に加熱するリグノセルロース材料又はセルロース材料の液状化方法において、溶剤対固体材料の重量比が50以下であり、酸触媒が溶剤及び酸の重量に対し、酸濃度で50重量%以下存在し、かつ溶剤が一般分子式
(但し、R1〜R 6 は各々独立に水素原子、又は炭素原子と共にラクトン基に結合した有機基を表す)
のγ−ラクトン基を有する化合物を含む該方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03257858 | 2003-12-15 | ||
PCT/EP2004/053450 WO2005058856A1 (en) | 2003-12-15 | 2004-12-14 | A process for the liquefaction of lignocellulosic material |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007514047A JP2007514047A (ja) | 2007-05-31 |
JP2007514047A5 true JP2007514047A5 (ja) | 2008-01-17 |
Family
ID=34684622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006544430A Pending JP2007514047A (ja) | 2003-12-15 | 2004-12-14 | リグノセルロース材料の液状化方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US20070100162A1 (ja) |
EP (1) | EP1699771A1 (ja) |
JP (1) | JP2007514047A (ja) |
CN (1) | CN1894230A (ja) |
AU (1) | AU2004298440B2 (ja) |
BR (1) | BRPI0417599A (ja) |
CA (1) | CA2549458A1 (ja) |
RU (1) | RU2006125433A (ja) |
WO (1) | WO2005058856A1 (ja) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8003818B2 (en) | 2004-12-23 | 2011-08-23 | Shell Oil Company | Process for the hydrogenation of a lactone or of a carboxylic acid or an ester having a gamma-carbonyl group |
US20070034345A1 (en) * | 2005-06-15 | 2007-02-15 | Leonardus Petrus | Process for organosolv pulping and use of a gamma lactone in a solvent for organosolv pulping |
JP2009523896A (ja) | 2006-01-20 | 2009-06-25 | アーチャー・ダニエルズ・ミッドランド カンパニー | 反応性可塑剤および合体溶剤としてのレブリン酸エステル誘導体 |
US8212062B2 (en) | 2007-04-02 | 2012-07-03 | Inventure Chemical, Inc. | Production of biodiesel, cellulosic sugars, and peptides from the simultaneous esterification and alcoholysis/hydrolysis of oil-containing materials with cellulosic and peptidic content |
US7943792B2 (en) * | 2007-04-02 | 2011-05-17 | Inventure Chemical Inc. | Production of biodiesel, cellulosic sugars, and peptides from the simultaneous esterification and alcoholysis/hydrolysis of materials with oil-containing substituents including phospholipids and peptidic content |
JP4957661B2 (ja) * | 2007-07-25 | 2012-06-20 | トヨタ自動車株式会社 | バイオマスを原料とする液化燃料油の製造方法 |
FI121541B (fi) * | 2008-04-21 | 2010-12-31 | Kemira Oyj | Menetelmä muurahaishapon talteenottamiseksi |
US7777085B2 (en) | 2008-10-01 | 2010-08-17 | Inventure Chemical, Inc. | Method for conversion of oil-containing algae to 1,3-propanediol |
US8871989B2 (en) * | 2009-02-27 | 2014-10-28 | Uop Llc | Combination of hydrogenation and base catalyzed depolymerization for lignin conversion |
US8138371B2 (en) | 2009-03-11 | 2012-03-20 | Biofine Technologies Llc | Production of formic acid |
US8653312B2 (en) * | 2009-06-05 | 2014-02-18 | Toyota Jidosha Kabushiki Kaisha | Method for producing water-insoluble liquefied fuel oil from biomass |
US20110112326A1 (en) * | 2009-08-07 | 2011-05-12 | Jean-Paul Lange | Process for hydrogenation |
US8580978B2 (en) | 2009-08-07 | 2013-11-12 | Shell Oil Company | Process for preparing a hydroxyacid or hydroxyester |
US20110173877A1 (en) * | 2009-12-24 | 2011-07-21 | Jeroen Van Buijtenen | Process for preparing a hydrocarbon or mixture of hydrocarbons |
WO2011141545A1 (en) | 2010-05-12 | 2011-11-17 | Shell Internationale Research Maatschappij B.V. | Process for liquefying a cellulosic material |
CN102939323B (zh) * | 2010-05-12 | 2016-03-30 | 国际壳牌研究有限公司 | 液化纤维素材料的方法 |
CA2805881C (en) * | 2010-07-30 | 2019-10-22 | Purdue Research Foundation | Biomass liquefaction processes, and uses of same |
JP2014519476A (ja) * | 2011-03-28 | 2014-08-14 | エージェンシー フォー サイエンス,テクノロジー アンド リサーチ | 二価酸の合成 |
US20140007492A1 (en) | 2011-11-14 | 2014-01-09 | Shell Oil Company | Process for conversion of a cellulosic material |
EP2782897A4 (en) | 2011-11-23 | 2015-06-24 | Segetis Inc | PROCESS FOR PREPARING LÄVULINIC ACID |
CN103304821B (zh) * | 2012-03-09 | 2016-01-20 | 东北林业大学 | 一种木质素的精制方法 |
US9416319B2 (en) | 2012-10-08 | 2016-08-16 | Shell Oil Company | Process for liquefying a cellulosic material |
US9073841B2 (en) | 2012-11-05 | 2015-07-07 | Segetis, Inc. | Process to prepare levulinic acid |
US9359650B2 (en) * | 2013-12-20 | 2016-06-07 | Wisconsin Alumni Research Foundation | Biomass pre-treatment for co-production of high-concentration C5- and C6-carbohydrates and their derivatives |
CN109071478A (zh) * | 2016-05-03 | 2018-12-21 | 国际壳牌研究有限公司 | 木质素基溶剂和其制备方法 |
WO2019014604A1 (en) | 2017-07-14 | 2019-01-17 | Battelle Memorial Institute | HYDROGENATION BY TRANSFERRING HEAVY HYDROCARBONS WITH HYDROGEN DONOR SOLVENTS |
CN109053906B (zh) * | 2018-09-10 | 2021-02-12 | 北京理工大学 | 一种纳米纤维素纤维干粉的制备方法 |
CN113293637B (zh) * | 2021-04-30 | 2022-09-20 | 中国林业科学研究院林产化学工业研究所 | 一种木质纤维组分分离的方法 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4594130A (en) * | 1978-11-27 | 1986-06-10 | Chang Pei Ching | Pulping of lignocellulose with aqueous alcohol and alkaline earth metal salt catalyst |
US4462865A (en) * | 1981-09-30 | 1984-07-31 | The Dow Chemical Company | Delignification of lignocellulosic materials with 2-imidazolidinones and 2-oxazolidinones |
US4652685A (en) * | 1985-11-15 | 1987-03-24 | General Electric Company | Hydrogenation of lactones to glycols |
GB8721528D0 (en) * | 1987-09-14 | 1987-10-21 | Shell Int Research | Pulping lignocellulose-containing material |
CA2048388C (en) * | 1990-08-16 | 1996-12-03 | Yasuo Tamura | Laminated material and process for manufacturing the same |
JP3012296B2 (ja) * | 1990-08-24 | 2000-02-21 | 信夫 白石 | リグノセルロース物質の液化溶液の製造法 |
JP3155603B2 (ja) * | 1992-03-17 | 2001-04-16 | 信夫 白石 | リグノセルロース物質の液化溶液の製造法 |
US5508435A (en) * | 1992-07-29 | 1996-04-16 | Merck & Co., Inc. | Asymmetric hydrogenation of beta- or gamma-ketoesters and beta- or gamma-ketoamides |
US5614564A (en) * | 1993-07-28 | 1997-03-25 | Samsung General Chemicals Co., Ltd. | Degradable foam and the method for its production |
US5608105A (en) * | 1995-06-07 | 1997-03-04 | Biofine Incorporated | Production of levulinic acid from carbohydrate-containing materials |
US5892107A (en) * | 1996-11-08 | 1999-04-06 | Arkenol, Inc. | Method for the production of levulinic acid |
JP3699257B2 (ja) * | 1997-10-30 | 2005-09-28 | 信夫 白石 | リグノセルロース物質の液化物の製造方法 |
US5883266A (en) * | 1998-01-16 | 1999-03-16 | Battelle Memorial Institute | Hydrogenated 5-carbon compound and method of making |
JP3131420B2 (ja) * | 1999-03-29 | 2001-01-31 | 茨城県 | 植物系物質からの樹脂原料組成物の製造方法 |
JP4651786B2 (ja) * | 2000-07-21 | 2011-03-16 | フジカーボン株式会社 | バイオマス由来のポリオール及び生分解性ポリウレタン |
US20020069987A1 (en) * | 2000-08-08 | 2002-06-13 | Pye Edward Kendall | Integrated processing of biomass and liquid effluents |
US6767565B2 (en) * | 2001-03-22 | 2004-07-27 | Archer Daniels Midland Company | Process for obtaining lignan |
US6894199B2 (en) * | 2001-04-27 | 2005-05-17 | Danisco Sweeteners Oy | Process for the production of xylitol |
FI117632B (fi) * | 2001-07-13 | 2006-12-29 | Chempolis Oy | Menetelmä massan valmistamiseksi |
US6527914B1 (en) * | 2002-01-30 | 2003-03-04 | Ondeo Nalco Company | Method of enhancing brightness and brightness stability of paper made with mechanical pulp |
US7439280B2 (en) * | 2004-04-06 | 2008-10-21 | Basf Corporation | Lignocellulosic composite material and method for preparing the same |
US20060135793A1 (en) * | 2004-11-26 | 2006-06-22 | Blessing Robert W | Process for the dimerisation of levulinic acid, dimers obtainable by such process and esters of such dimers |
US8003818B2 (en) * | 2004-12-23 | 2011-08-23 | Shell Oil Company | Process for the hydrogenation of a lactone or of a carboxylic acid or an ester having a gamma-carbonyl group |
US20070034345A1 (en) * | 2005-06-15 | 2007-02-15 | Leonardus Petrus | Process for organosolv pulping and use of a gamma lactone in a solvent for organosolv pulping |
-
2004
- 2004-12-14 BR BRPI0417599-9A patent/BRPI0417599A/pt not_active IP Right Cessation
- 2004-12-14 US US10/582,888 patent/US20070100162A1/en not_active Abandoned
- 2004-12-14 CA CA002549458A patent/CA2549458A1/en not_active Abandoned
- 2004-12-14 CN CNA200480037424XA patent/CN1894230A/zh active Pending
- 2004-12-14 RU RU2006125433/04A patent/RU2006125433A/ru not_active Application Discontinuation
- 2004-12-14 EP EP04804809A patent/EP1699771A1/en not_active Withdrawn
- 2004-12-14 JP JP2006544430A patent/JP2007514047A/ja active Pending
- 2004-12-14 WO PCT/EP2004/053450 patent/WO2005058856A1/en active Application Filing
- 2004-12-14 AU AU2004298440A patent/AU2004298440B2/en not_active Ceased
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