JP2007299969A - Cis系薄膜太陽電池モジュールの改良された耐久性試験方法 - Google Patents
Cis系薄膜太陽電池モジュールの改良された耐久性試験方法 Download PDFInfo
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- 239000010409 thin film Substances 0.000 title claims abstract description 85
- 238000010998 test method Methods 0.000 title claims abstract description 27
- 238000012360 testing method Methods 0.000 claims abstract description 71
- 238000003860 storage Methods 0.000 claims abstract description 29
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 230000005855 radiation Effects 0.000 claims abstract description 8
- 239000010410 layer Substances 0.000 claims description 26
- 229910052733 gallium Inorganic materials 0.000 claims description 14
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 13
- 239000011521 glass Substances 0.000 claims description 12
- 239000010408 film Substances 0.000 claims description 11
- 239000000758 substrate Substances 0.000 claims description 11
- 239000004065 semiconductor Substances 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- HVMJUDPAXRRVQO-UHFFFAOYSA-N copper indium Chemical compound [Cu].[In] HVMJUDPAXRRVQO-UHFFFAOYSA-N 0.000 claims description 7
- KTSFMFGEAAANTF-UHFFFAOYSA-N [Cu].[Se].[Se].[In] Chemical compound [Cu].[Se].[Se].[In] KTSFMFGEAAANTF-UHFFFAOYSA-N 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 5
- 230000031700 light absorption Effects 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 4
- 230000004888 barrier function Effects 0.000 claims description 4
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052951 chalcopyrite Inorganic materials 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 238000000059 patterning Methods 0.000 claims description 3
- 239000002344 surface layer Substances 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- YNLHHZNOLUDEKQ-UHFFFAOYSA-N copper;selanylidenegallium Chemical compound [Cu].[Se]=[Ga] YNLHHZNOLUDEKQ-UHFFFAOYSA-N 0.000 claims description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims 2
- 229910052711 selenium Inorganic materials 0.000 claims 2
- 239000011669 selenium Substances 0.000 claims 2
- YBXVYDUWVUPIDL-UHFFFAOYSA-N [Cu]=S.[In]=S Chemical compound [Cu]=S.[In]=S YBXVYDUWVUPIDL-UHFFFAOYSA-N 0.000 claims 1
- CDZGJSREWGPJMG-UHFFFAOYSA-N copper gallium Chemical compound [Cu].[Ga] CDZGJSREWGPJMG-UHFFFAOYSA-N 0.000 claims 1
- LCUOIYYHNRBAFS-UHFFFAOYSA-N copper;sulfanylideneindium Chemical compound [Cu].[In]=S LCUOIYYHNRBAFS-UHFFFAOYSA-N 0.000 claims 1
- 230000006866 deterioration Effects 0.000 abstract description 11
- 238000011084 recovery Methods 0.000 abstract description 2
- 230000001678 irradiating effect Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229910052738 indium Inorganic materials 0.000 description 4
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- BVSHTEBQPBBCFT-UHFFFAOYSA-N gallium(iii) sulfide Chemical compound [S-2].[S-2].[S-2].[Ga+3].[Ga+3] BVSHTEBQPBBCFT-UHFFFAOYSA-N 0.000 description 3
- JLKFUGXSXNYLPC-UHFFFAOYSA-N [S].[S].[Cu] Chemical compound [S].[S].[Cu] JLKFUGXSXNYLPC-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000006059 cover glass Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 239000003566 sealing material Substances 0.000 description 2
- IRPLSAGFWHCJIQ-UHFFFAOYSA-N selanylidenecopper Chemical compound [Se]=[Cu] IRPLSAGFWHCJIQ-UHFFFAOYSA-N 0.000 description 2
- NMHFBDQVKIZULJ-UHFFFAOYSA-N selanylideneindium Chemical compound [In]=[Se] NMHFBDQVKIZULJ-UHFFFAOYSA-N 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- ZZEMEJKDTZOXOI-UHFFFAOYSA-N digallium;selenium(2-) Chemical compound [Ga+3].[Ga+3].[Se-2].[Se-2].[Se-2] ZZEMEJKDTZOXOI-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003346 selenoethers Chemical class 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- GKCNVZWZCYIBPR-UHFFFAOYSA-N sulfanylideneindium Chemical compound [In]=S GKCNVZWZCYIBPR-UHFFFAOYSA-N 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S50/00—Monitoring or testing of PV systems, e.g. load balancing or fault identification
- H02S50/10—Testing of PV devices, e.g. of PV modules or single PV cells
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S99/00—Subject matter not provided for in other groups of this subclass
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/541—CuInSe2 material PV cells
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- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Photovoltaic Devices (AREA)
- Testing Resistance To Weather, Investigating Materials By Mechanical Methods (AREA)
Abstract
【解決手段】CIS系薄膜太陽電池モジュールの従来の高温高湿保管試験条件(温度85℃、相対湿度85%、暗闇中に1,000時間格納)中、前記温度、湿度及び格納時間はそのままで、擬似太陽光照射装置(ソーラー・シュミレータ)1Dからの光が、曇りの日の日射量に相当する弱い光の放射照度、即ち、100〜300W/m2 になるように光源1Eの強度を調整して試験期間中継続して照射することにより、開放状態で保管された前記モジュール2’が、1,000時間経過後も、大幅な劣化を示さないという特性を適正に評価できる。
【選択図】図1
Description
本出願人らは、CIS系薄膜太陽電池モジュールに、高温高湿保管試験の間に光を照射し続けたら、如何なる劣化も示さないであろうと予想し、検討を行ってきたが、その確認のために、擬似太陽光照射装置(ソーラー・シミュレータ)のXeランプ等の強度を調整することによって、曇りの日の日射量に相当する放射照度100〜300W/m2 の弱い光を試験期間中継続して照射する改良高温高湿保管試験を行った。
改良された改良高温高湿保管方法において、カバーガラス/EVA樹脂/CIS系薄膜太陽電池サブモジュール/ガラス基板等からなるサンドイッチ構造を有する試験対象のCIS系薄膜太陽電池モジュール2’(図3参照。)に100〜300W/m2 の弱い光を試験期間中継続して照射した場合、試験時間である1,000時間終了後でさえ、図2に示すように、開放端状態で保管された当該太陽電池モジュール2’の太陽電池特性(変換効率Eff〔%〕、曲線因子FF、短絡電流Isc〔A〕、開放電圧Voc〔V〕)の劣化は大幅に減少した。
1A 耐久性試験装置)
1a ガラス窓(光透過窓)
1B I−V測定部
1C 温度・湿度制御部
1D 擬似太陽光照射装置
1E 光源(Xeランプ)
1F 電力供給・制御部
2 CIS系薄膜太陽電池モジュール
2’ 試験対象CIS系薄膜太陽電池モジュール
3 CIS系薄膜太陽電池サブモジュール
3’ CIS系薄膜太陽電池デバイス
3A ガラス基板
3B アルカリバリア層
3C 金属裏面電極層
3D p形光吸収層
3E 高抵抗バッファ層
3F n形窓層(透明導電膜)
4 EVA樹脂フィルム
5 カバーガラス
6 バックシート
7 ケーブル付接続箱
8 シール材
9 フレーム
Claims (3)
- CIS系薄膜太陽電池モジュールが弱い光の照射により変換効率等が回復するという特性を適正に評価することができる耐久性試験方法であって、前記耐久性試験の対象であるCIS系薄膜太陽電池モジュールを温度85℃、相対湿度85%の比較的高温、高湿の条件下で、暗闇中に1,000時間格納する試験であるDampHeat試験を行う際に、前記温度、湿度及び格納時間はそのままで、擬似太陽光照射装置(ソーラー・シュミレータ)からの光が、曇りの日の日射量に相当する弱い光になるようにXeランプ等の強度を調整して試験期間中継続して照射して各種太陽電池特性を計測することを特徴とするCIS系薄膜太陽電池モジュールの改良された耐久性試験方法。
- 前記弱い光の放射照度が、100〜300W/m2 でであることをを特徴とする請求項1に記載のCIS系薄膜太陽電池モジュールの改良された耐久性試験方法。
- 前記CIS系薄膜太陽電池モジュールは、パターンニングにより複数個のCIS系薄膜太陽電池デバイスを電気的に接続したCIS系薄膜太陽電池サブモジュールを接着剤である加熱、架橋したEVA樹脂フィルムを介してカバーカラスを貼着し、裏面側は、ガラス基板に、加熱、架橋したEVA樹脂フィルムを介してバックシートを貼着し、その下にケーブル付き接続箱等を設け、この構造体の外周囲にシール材を介してフレームを取り付けたものであり、前記CIS系薄膜太陽電池デバイスは、ガラス基板上に、アルカリバリア層、金属裏面電極層(一般的には、Mo)、p形CIS系光吸収層、高抵抗バッファ層、n形窓層(透明導電膜)の順で高品質薄膜層が順次積層されたサブストレート構造のpnヘテロ接合デバイスであり、前記光吸収層は、多元化合物半導体薄膜、特に、I-III-VI2 族カルコパイライト半導体、例えば、2セレン化銅インジウム(CuInSe2:以下、CISeと略称する。) 、2セレン化銅インジウム・ガリウム(CuInGaSe2:以下、CIGSeと略称する。) 、2セレン化銅ガリウム(CuGaSe2:以下、CGSeと略称する。) 、2セレン・イオウ化銅インジウム・ガリウム(Cu(InGa)(SSe)2 :以下、CIGSSeと略称する。) 、2イオウ化銅インジウム(CuInS2 :以下、CISと略称する。))、2イオウ化銅ガリウム(CuGaS2 :以下、CGSと略称する。) ) 、2イオウ化銅インジウム・ガリウム(CuInGaS2 :以下、CIGSと略称する。) 、薄膜の2セレン・イオウ化銅インジウム・ガリウム(Cu(InGa)(SSe)2 :CIGSSe) を表面層として有する2セレン化銅インジウム・ガリウム(CuInGaSe2:CIGSe) のようなp形半導体からなることを特徴とする請求項1又は2に記載のCIS系薄膜太陽電池モジュールの改良された耐久性試験方法。
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
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JP2006127193A JP5054326B2 (ja) | 2006-05-01 | 2006-05-01 | Cis系薄膜太陽電池モジュールの改良された耐久性試験方法 |
CNA2007800157716A CN101432891A (zh) | 2006-05-01 | 2007-03-29 | Cis系薄膜太阳电池模块的改进的耐久性试验方法 |
US12/298,721 US8242795B2 (en) | 2006-05-01 | 2007-03-29 | Method of testing durability of CIS based thin-film solar cell module |
KR20087026870A KR101304855B1 (ko) | 2006-05-01 | 2007-03-29 | Cis계 박막 태양전지 모듈의 개량된 내구성 시험 방법 |
PCT/JP2007/056993 WO2007129512A1 (ja) | 2006-05-01 | 2007-03-29 | Cis系薄膜太陽電池モジュールの改良された耐久性試験方法 |
EP07740431.7A EP2023400A4 (en) | 2006-05-01 | 2007-03-29 | METHOD FOR TESTING IMPROVED DURABILITY OF THIN-FILM PHOTOVOLTAIC CELL MODULE BASED ON CIS |
TW96115257A TW200802907A (en) | 2006-05-01 | 2007-04-30 | Improved durability test method of CIS based thin film solar cell module |
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JP2006127193A JP5054326B2 (ja) | 2006-05-01 | 2006-05-01 | Cis系薄膜太陽電池モジュールの改良された耐久性試験方法 |
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JP2007299969A true JP2007299969A (ja) | 2007-11-15 |
JP5054326B2 JP5054326B2 (ja) | 2012-10-24 |
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JP2006127193A Expired - Fee Related JP5054326B2 (ja) | 2006-05-01 | 2006-05-01 | Cis系薄膜太陽電池モジュールの改良された耐久性試験方法 |
Country Status (7)
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US (1) | US8242795B2 (ja) |
EP (1) | EP2023400A4 (ja) |
JP (1) | JP5054326B2 (ja) |
KR (1) | KR101304855B1 (ja) |
CN (1) | CN101432891A (ja) |
TW (1) | TW200802907A (ja) |
WO (1) | WO2007129512A1 (ja) |
Cited By (7)
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JP2012169451A (ja) * | 2011-02-14 | 2012-09-06 | Espec Corp | 太陽電池パネルの試験装置、試験方法、制御装置、及びプログラム |
KR101194685B1 (ko) | 2011-02-01 | 2012-10-29 | 한국에너지기술연구원 | 고집광 태양전지모듈 내열특성 분석장치 |
KR101338801B1 (ko) * | 2012-12-07 | 2013-12-06 | 주식회사 티엔이테크 | 태양전지 특성 평가용 광 조사 시스템 |
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2007
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- 2007-03-29 EP EP07740431.7A patent/EP2023400A4/en not_active Withdrawn
- 2007-03-29 CN CNA2007800157716A patent/CN101432891A/zh active Pending
- 2007-03-29 KR KR20087026870A patent/KR101304855B1/ko active IP Right Grant
- 2007-03-29 WO PCT/JP2007/056993 patent/WO2007129512A1/ja active Application Filing
- 2007-04-30 TW TW96115257A patent/TW200802907A/zh unknown
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JPH11135811A (ja) * | 1997-10-28 | 1999-05-21 | Yazaki Corp | Cis系太陽電池モジュール及びその製造方法 |
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KR101194685B1 (ko) | 2011-02-01 | 2012-10-29 | 한국에너지기술연구원 | 고집광 태양전지모듈 내열특성 분석장치 |
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KR101438668B1 (ko) * | 2013-04-08 | 2014-11-04 | 한국에너지기술연구원 | 태양전지모듈 가속시험 방법 |
CN105099365A (zh) * | 2014-05-15 | 2015-11-25 | 中国科学院苏州纳米技术与纳米仿生研究所 | 太阳能电池的测试设备 |
CN105099365B (zh) * | 2014-05-15 | 2017-07-18 | 中国科学院苏州纳米技术与纳米仿生研究所 | 太阳能电池的测试设备 |
JP2018536148A (ja) * | 2015-09-24 | 2018-12-06 | エイチイーイーソーラー,エルエルシー | 感光装置劣化を試験するシステム及び方法 |
US10797641B2 (en) | 2015-09-24 | 2020-10-06 | Hunt Perovskite Technologies, LLC | System and method for testing photosensitive device degradation |
US11387779B2 (en) | 2015-09-24 | 2022-07-12 | Cubicpv Inc. | System and method for testing photosensitive device degradation |
US11863122B2 (en) | 2015-09-24 | 2024-01-02 | Cubicpv Inc. | System and method for testing photosensitive device degradation |
Also Published As
Publication number | Publication date |
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KR20090016450A (ko) | 2009-02-13 |
TW200802907A (en) | 2008-01-01 |
EP2023400A1 (en) | 2009-02-11 |
US20090072837A1 (en) | 2009-03-19 |
EP2023400A4 (en) | 2015-06-17 |
JP5054326B2 (ja) | 2012-10-24 |
WO2007129512A1 (ja) | 2007-11-15 |
KR101304855B1 (ko) | 2013-09-05 |
US8242795B2 (en) | 2012-08-14 |
CN101432891A (zh) | 2009-05-13 |
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