JP2007182567A - 特定の担体を有する触媒を利用する選択的水素化法 - Google Patents

特定の担体を有する触媒を利用する選択的水素化法 Download PDF

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Publication number
JP2007182567A
JP2007182567A JP2006345142A JP2006345142A JP2007182567A JP 2007182567 A JP2007182567 A JP 2007182567A JP 2006345142 A JP2006345142 A JP 2006345142A JP 2006345142 A JP2006345142 A JP 2006345142A JP 2007182567 A JP2007182567 A JP 2007182567A
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Prior art keywords
catalyst
support
pore volume
metal
weight
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JP2006345142A
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Japanese (ja)
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JP2007182567A5 (enExample
Inventor
Christophe Bouchy
クリストフ　ブシィ
Florent Picard
フロラン　ピカール
Nathalie Marchal
マルシャル ナタリ
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IFP Energies nouvelles
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/38—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
JP2006345142A 2005-12-22 2006-12-22 特定の担体を有する触媒を利用する選択的水素化法 Ceased JP2007182567A (ja)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0513173A FR2895415B1 (fr) 2005-12-22 2005-12-22 Procede d'hydrogenation selective mettant en oeuvre un catalyseur presentant un support specifique

Publications (2)

Publication Number Publication Date
JP2007182567A true JP2007182567A (ja) 2007-07-19
JP2007182567A5 JP2007182567A5 (enExample) 2010-02-12

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ID=37052763

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JP2006345142A Ceased JP2007182567A (ja) 2005-12-22 2006-12-22 特定の担体を有する触媒を利用する選択的水素化法

Country Status (7)

Country Link
US (1) US7736492B2 (enExample)
EP (1) EP1800749B1 (enExample)
JP (1) JP2007182567A (enExample)
KR (1) KR20070066980A (enExample)
CN (1) CN101205483B (enExample)
BR (1) BRPI0605369A (enExample)
FR (1) FR2895415B1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20100028502A (ko) * 2008-09-04 2010-03-12 아이에프피 특성 조성을 갖는 황화 촉매를 사용하는 선택적 수소화 방법
JP2011512247A (ja) * 2008-02-07 2011-04-21 イエフペ エネルジ ヌヴェル 選択的水素化触媒およびその調製方法
JP2023524797A (ja) * 2020-05-07 2023-06-13 イエフペ エネルジ ヌヴェル アルミン酸塩の形態にある特定の担体を含んでいる選択的水素化触媒
JP2023524798A (ja) * 2020-05-07 2023-06-13 イエフペ エネルジ ヌヴェル 担体と特定の比率のニッケル・モリブデンとを含む水素化触媒

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2895414B1 (fr) * 2005-12-22 2011-07-29 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur presentant une porosite controlee
US7811474B2 (en) * 2008-12-04 2010-10-12 Uop Llc Simultaneous warm gas desulfurization and CO-shift for improved syngas cleanup
US8017545B2 (en) 2008-12-04 2011-09-13 Uop Llc Dynamic composition for the removal of sulfur from a gaseous stream
CN103146429B (zh) 2011-12-06 2015-08-19 中国石油天然气股份有限公司 一种液化气加氢处理的方法
FR2993570B1 (fr) * 2012-07-17 2015-12-04 IFP Energies Nouvelles Procede de production d'une essence legere basse teneur en soufre
FR2993569B1 (fr) * 2012-07-17 2015-12-04 IFP Energies Nouvelles Procede de desulfuration d'une essence
US9806164B1 (en) * 2013-03-26 2017-10-31 The Penn State Research Foundation Controlled synthesis and transfer of large area heterostructures made of bilayer and multilayer transition metal dichalocogenides
EP2816094B1 (fr) * 2013-06-19 2020-04-29 IFP Energies nouvelles Procédé de production d'une essence à basse teneur en soufre et en mercaptans
FR3080117B1 (fr) * 2018-04-11 2020-04-03 IFP Energies Nouvelles Procede de captation de l'arsenic mettant en œuvre une masse de captation a base de particules d'oxyde de nickel
EP3822332A1 (en) 2019-11-13 2021-05-19 Indian Oil Corporation Limited Catalyst for selective hydrogenation of diolefins and method for preparing catalyst
CN113559870A (zh) * 2020-04-28 2021-10-29 中国石油化工股份有限公司 重油加氢催化剂及其制备方法和应用
FR3109898B1 (fr) * 2020-05-07 2023-04-14 Ifp Energies Now Catalyseur d’hydrogénation sélective comprenant une répartition particulière du nickel et du molybdène
FR3116831B1 (fr) 2020-11-27 2023-11-03 Ifp Energies Now Procede d’hydrogenation selective d’une essence en presence d’un catalyseur sur support meso-macroporeux

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5154087A (enExample) * 1974-09-24 1976-05-12 American Cyanamid Co
JPS58205547A (ja) * 1982-05-07 1983-11-30 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− 高表面積スピネル型アルミン酸ニツケル触媒及びこれを用いたスチ−ムリホ−ミング法
JP2000239668A (ja) * 1999-02-24 2000-09-05 Inst Fr Petrole 低硫黄含有量のガソリン製造方法
JP2001055584A (ja) * 1999-08-19 2001-02-27 Inst Fr Petrole 硫黄含有量の低いガソリンの製造方法
JP2003327970A (ja) * 2002-03-29 2003-11-19 Inst Fr Petrole 硫黄およびメルカプタンの含量の低い炭化水素を製造する方法
JP2004010892A (ja) * 2002-06-03 2004-01-15 Inst Fr Petrole 第８族および第６ｂ族の元素を含む担持触媒の存在下に、硫黄含有化合物およびオレフィンを含む留分を水素化脱硫するための方法
JP2004230383A (ja) * 2003-01-29 2004-08-19 Inst Fr Petrole 硫黄化合物及びオレフィンを含む留分の水素処理に使用可能な部分的にコーキングされた触媒

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
OA02047A (fr) 1965-02-13 1970-05-05 Inst Francais Du Petrole Procédé d'hydrogenation selective des diolefines.
GB1379202A (en) * 1970-11-30 1975-01-02 Shell Int Research Two-stage hydrocracking process employing a supported nickel- molybdenum catalyst
GB1415417A (en) * 1973-10-12 1975-11-26 American Cyanamid Co Hydrotreating of petroleum distillates using shaped catalyst prtticles
FR2840316B1 (fr) * 2002-06-03 2005-08-26 Inst Francais Du Petrole Procede d'hydrodesulfuration de coupes contenant des composes soufres et des olefines en presence d'un catalyseur comprenant un element du groupe viii et du tungstene
FR2857974B1 (fr) * 2003-07-25 2008-01-18 Inst Francais Du Petrole Procede de desulfuration d'une charge d'hydrocarbures par adsorption/desorption
FR2895416B1 (fr) 2005-12-22 2011-08-26 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur sulfure
FR2895414B1 (fr) 2005-12-22 2011-07-29 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur presentant une porosite controlee

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5154087A (enExample) * 1974-09-24 1976-05-12 American Cyanamid Co
JPS58205547A (ja) * 1982-05-07 1983-11-30 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− 高表面積スピネル型アルミン酸ニツケル触媒及びこれを用いたスチ−ムリホ−ミング法
JP2000239668A (ja) * 1999-02-24 2000-09-05 Inst Fr Petrole 低硫黄含有量のガソリン製造方法
JP2001055584A (ja) * 1999-08-19 2001-02-27 Inst Fr Petrole 硫黄含有量の低いガソリンの製造方法
JP2003327970A (ja) * 2002-03-29 2003-11-19 Inst Fr Petrole 硫黄およびメルカプタンの含量の低い炭化水素を製造する方法
JP2004010892A (ja) * 2002-06-03 2004-01-15 Inst Fr Petrole 第８族および第６ｂ族の元素を含む担持触媒の存在下に、硫黄含有化合物およびオレフィンを含む留分を水素化脱硫するための方法
JP2004230383A (ja) * 2003-01-29 2004-08-19 Inst Fr Petrole 硫黄化合物及びオレフィンを含む留分の水素処理に使用可能な部分的にコーキングされた触媒

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011512247A (ja) * 2008-02-07 2011-04-21 イエフペ エネルジ ヌヴェル 選択的水素化触媒およびその調製方法
KR20100028502A (ko) * 2008-09-04 2010-03-12 아이에프피 특성 조성을 갖는 황화 촉매를 사용하는 선택적 수소화 방법
JP2010090366A (ja) * 2008-09-04 2010-04-22 Ifp 特定の組成を有する硫化触媒を用いる選択的水素化方法
KR101668481B1 (ko) 2008-09-04 2016-10-21 아이에프피 에너지 누벨르 특성 조성을 갖는 황화 촉매를 사용하는 선택적 수소화 방법
JP2023524797A (ja) * 2020-05-07 2023-06-13 イエフペ エネルジ ヌヴェル アルミン酸塩の形態にある特定の担体を含んでいる選択的水素化触媒
JP2023524798A (ja) * 2020-05-07 2023-06-13 イエフペ エネルジ ヌヴェル 担体と特定の比率のニッケル・モリブデンとを含む水素化触媒

Also Published As

Publication number Publication date
EP1800749A3 (fr) 2011-04-20
US20070187297A1 (en) 2007-08-16
US7736492B2 (en) 2010-06-15
CN101205483A (zh) 2008-06-25
FR2895415B1 (fr) 2011-07-15
CN101205483B (zh) 2012-05-23
FR2895415A1 (fr) 2007-06-29
EP1800749B1 (fr) 2013-05-15
KR20070066980A (ko) 2007-06-27
EP1800749A2 (fr) 2007-06-27
BRPI0605369A (pt) 2007-10-16

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