JP2007084601A - 被覆用樹脂組成物 - Google Patents
被覆用樹脂組成物 Download PDFInfo
- Publication number
- JP2007084601A JP2007084601A JP2005271864A JP2005271864A JP2007084601A JP 2007084601 A JP2007084601 A JP 2007084601A JP 2005271864 A JP2005271864 A JP 2005271864A JP 2005271864 A JP2005271864 A JP 2005271864A JP 2007084601 A JP2007084601 A JP 2007084601A
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- Prior art keywords
- meth
- acrylate
- resin composition
- acid
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000011342 resin composition Substances 0.000 title claims abstract description 19
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- 239000012169 petroleum derived wax Substances 0.000 claims abstract description 21
- 235000019381 petroleum wax Nutrition 0.000 claims abstract description 21
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims abstract description 15
- 238000002844 melting Methods 0.000 claims abstract description 14
- 230000008018 melting Effects 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims description 26
- 238000000576 coating method Methods 0.000 claims description 26
- 238000001035 drying Methods 0.000 abstract description 13
- 229920000642 polymer Polymers 0.000 abstract description 13
- 238000010526 radical polymerization reaction Methods 0.000 abstract description 5
- 238000004132 cross linking Methods 0.000 abstract 1
- 229920013730 reactive polymer Polymers 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 19
- 229920005989 resin Polymers 0.000 description 18
- 239000011347 resin Substances 0.000 description 18
- 239000002253 acid Substances 0.000 description 16
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 14
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- 238000007605 air drying Methods 0.000 description 12
- 239000003822 epoxy resin Substances 0.000 description 12
- 229920000647 polyepoxide Polymers 0.000 description 12
- 229920005862 polyol Polymers 0.000 description 10
- 150000003077 polyols Chemical class 0.000 description 10
- 239000004925 Acrylic resin Substances 0.000 description 9
- 239000010408 film Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 150000005846 sugar alcohols Polymers 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
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- 229920006305 unsaturated polyester Polymers 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 6
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
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- 239000005056 polyisocyanate Substances 0.000 description 5
- 229920001228 polyisocyanate Polymers 0.000 description 5
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- 239000000843 powder Substances 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920005906 polyester polyol Polymers 0.000 description 4
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 3
- MOBNLCPBAMKACS-UHFFFAOYSA-N 2-(1-chloroethyl)oxirane Chemical compound CC(Cl)C1CO1 MOBNLCPBAMKACS-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- IZSHZLKNFQAAKX-UHFFFAOYSA-N 5-cyclopenta-2,4-dien-1-ylcyclopenta-1,3-diene Chemical group C1=CC=CC1C1C=CC=C1 IZSHZLKNFQAAKX-UHFFFAOYSA-N 0.000 description 3
- 229930185605 Bisphenol Natural products 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 230000032050 esterification Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 229920001610 polycaprolactone Polymers 0.000 description 3
- 239000004632 polycaprolactone Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 230000001846 repelling effect Effects 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 2
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 2
- OJPDDQSCZGTACX-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)anilino]ethanol Chemical compound OCCN(CCO)C1=CC=CC=C1 OJPDDQSCZGTACX-UHFFFAOYSA-N 0.000 description 2
- CEXQWAAGPPNOQF-UHFFFAOYSA-N 2-phenoxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOC1=CC=CC=C1 CEXQWAAGPPNOQF-UHFFFAOYSA-N 0.000 description 2
- GCYHRYNSUGLLMA-UHFFFAOYSA-N 2-prop-2-enoxyethanol Chemical compound OCCOCC=C GCYHRYNSUGLLMA-UHFFFAOYSA-N 0.000 description 2
- JJYPMNFTHPTTDI-UHFFFAOYSA-N 3-methylaniline Chemical compound CC1=CC=CC(N)=C1 JJYPMNFTHPTTDI-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
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- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
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- 150000001298 alcohols Chemical class 0.000 description 2
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- AYAUWVRAUCDBFR-ARJAWSKDSA-N (z)-4-oxo-4-propoxybut-2-enoic acid Chemical compound CCCOC(=O)\C=C/C(O)=O AYAUWVRAUCDBFR-ARJAWSKDSA-N 0.000 description 1
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- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
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Abstract
【解決手段】 (A)分子末端に少なくとも2個以上の(メタ)アクリロイル基を有する反応性オリゴマー、(B)空乾性を有しラジカル重合により架橋できる不飽和基を含有する重合体、(C)フェニル基を有し、数平均分子量が180以上の(メタ)アクリレート基を有する単量体、(D)石油ワックス及び(E)ポリオキシエチレンアルキルフェニルエーテルを含んでなる被覆用樹脂組成物であって、前記(C)石油ワックスが、JIS K 2235に基づいて測定される融点で115〜155°Fであり、かつ前記融点を有する石油ワックスが10°F以上離れた2種類以上の混合物であることを特徴とする被覆用樹脂組成物に関する。
【選択図】 なし
Description
しかし、これらのラジカル重合性樹脂は、嫌気性であり、自然環境下での硬化であると、表面硬化性及び薄膜での硬化性に問題があった。
この問題に対し、石油ワックスを添加し、かつ空気乾燥性樹脂を用いることが提案されてきている(例えば参考文献1参照)。
しかし、乾燥速度が、石油ワックス配合したものと比べて大きく劣るという問題がある。
すなわち本発明は、(A)分子末端に少なくとも2個以上の(メタ)アクリロイル基を有する反応性オリゴマー、(B)空乾性を有しラジカル重合により架橋できる不飽和基を含有する重合体、(C)フェニル基を有し、数平均分子量が180以上の(メタ)アクリレート基を有する単量体、(D)石油ワックス及び(E)ポリオキシエチレンアルキルフェニルエーテルを含んでなる被覆用樹脂組成物であって、前記(C)石油ワックスが、JIS K 2235に基づいて測定される融点で115〜155°Fであり、かつ前記融点を有する石油ワックスが10°F以上離れた2種類以上の混合物であることを特徴とする被覆用樹脂組成物を提供するものである。
石油ワックス(C)の融点は、110°F〜160°Fのものであり、特に春から冬までの全季節(5〜35℃)での使用を想定すると、融点が115°F〜155°Fのものが好ましい。
ここでいう融点は、JIS K 2235に基づいて測定される融点である。
さらに、本発明は、全季節(5〜35℃)での表面乾燥性の点で、10°F以上離れている融点を有する石油ワックスを2種類以上配合するものである。そして前記範囲の融点を有するパラフィンワックスを同量配合することが好ましい。
ポリオキシエチレンアルキルフェニルエーテル(D)のHLB値は8.0〜18.0までのものが好ましい。尚、HLB値とは、親水−親油バランス(Hydrophile−Lipophile Balance)を称するもので、グリフィン式:HLB値=20×(親水基の重量%)による値である。
また、上記(D)成分は、樹脂100重量部に対して0.03〜1.0重量部添加されるのが好ましい。特に、0.1〜0.5重量部添加されるのが、表面乾燥性、上塗り適合性から好ましい。
温度計、攪拌機、不活性ガス導入口、及び還流冷却器を備えた5リットルの四つ口フラスコに、ポリプロピレングリコール(数平均分子量984.2)2461部、トリレンジイソシアネート739.5部、イソホロンジイソシアネート166.8部を仕込み、窒素雰囲気中80℃まで昇温し、3時間反応させ、NCO等量697になったところで、50℃まで冷却した後、窒素/空気(流量比1/1)混合気流下でトルハイドロキノン0.337部、ヒドロキシエチルメタクリレート657.7部を加え、90℃まで再度昇温させる。3時間反応させ、残存NCO量0.0343%のウレタンメタクリレート重合体を得た。この重合体を以下[VU]とする。
温度計、攪拌機、ガス導入口、及び還流冷却器を備えた5リットルの四つ口フラスコに、エピクロン830(大日本インキ化学工業(株)製エポキシ樹脂:エピクロルヒドリンとビスフェノールAの反応物:数平均分子量344)2970部、メタクリル酸1456部、2,6−ジ−tert−ブチル−4−メチルフェノール1.55部、トリエチルアミン13.3部を仕込み、窒素/空気(流量比1/1)混合気流下90℃まで昇温し、2時間反応させる。次いで、反応温度を105℃まで昇温させ、30時間反応を続け、酸価8.87、エポキシ当量23900のものを得た。この重合体を以下[VE]とする。
温度計、攪拌機、不活性ガス導入口、及び還流冷却器を備えた2リットルの四つ口フラスコに、ジエチレングリコール576部、無水フタル酸285部、無水マレイン酸81部、ピペリレン・無水マレイン酸付加物457部を公知の条件で加熱脱水縮合させて酸価10.2の空乾性ポリエステル樹脂を得た。この重合体を以下[UPE]とする。
上記参考例で得られたソリッドを、フェノキシエチルメタクリレート[以下:PHOEMA]又はスチレン[以下:SM]の任意量で希釈し、これに石油ワックス及びポリオキシエチレンノニルフェニルエーテルを溶解、分散して被覆用硬化性樹脂組成物を得た。
実施例1〜4及び比較例1〜4で得られた被覆用硬化性樹脂組成物100部に、8%オクチル酸コバルトを35℃は1部、25℃は1部、15℃は1.5部、5℃は1.5部を添加攪拌した後、55%メチルエチルケトンパーオキサイドを35℃は1部、25℃1.5部、15℃は2部、5℃は2部かつα−アセチル−γ−ブチロラクトンを0.4部配合した物を0.15mm厚みのアプリケーターにて、繊維強化セメント板上に塗布し、その塗膜表面乾燥状態を観察した。
樹脂の硬化時間は、上記、各促進剤及び硬化剤の配合により、各温度において15分に設定し、45分以内に乾燥したものを「○」。90分以内に乾燥したものを「△」。90分以上乾燥に要したものを「×」とした。
実施例1〜4及び比較例1〜4で得られた乾燥した塗膜を下地とし、ディオバー NS−800(大日本インキ化学工業株式会社製)を、0.15kg/m2塗布し、JIS K 5600−3−4に準じ、主に、ハジキ有無について目視観察を行った。
ハジキの無いものは「○」、若干ハジキのあるものは「△」、ハジキのあるものは「×」とした。
実施例1〜4及び比較例1〜4で得られた塗膜から、1m離れて全く臭わないものを「○」、若干臭うものを「△」、臭うものを「×」とした。
Claims (2)
- (A)分子末端に少なくとも2個以上の(メタ)アクリロイル基を有する反応性オリゴマー、(B)フェニル基を有し、数平均分子量が180以上の(メタ)アクリレート基を有する単量体、(C)石油ワックス及び(D)ポリオキシエチレンアルキルフェニルエーテルを含んでなる被覆用樹脂組成物であって、前記(C)石油ワックスが、JIS K 2235に基づいて測定される融点で115〜155°Fであり、かつ前記石油ワックスが10°F以上離れた融点を有する2種類以上の混合物であることを特徴とする被覆用樹脂組成物。
- 前記被覆用樹脂組成物中、(A)成分に対する(B)成分の割合が、重量比で20/80〜80/20であり、(A)成分と(B)成分との合計量[(A)+(B)]に対し、(C)成分が0.05〜2重量%であり、(D)成分が0.03〜1重量%である請求項1記載の被覆用樹脂組成物。
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US8557879B2 (en) | 2010-02-26 | 2013-10-15 | Jx Nippon Oil & Energy Corporation | Process for production of activated Fischer-Tropsch synthesis catalyst, and process for production of hydrocarbon |
KR20140041328A (ko) | 2012-09-27 | 2014-04-04 | 디아이씨 가부시끼가이샤 | 라디칼 중합성 화합물 |
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JP2004155936A (ja) * | 2002-11-07 | 2004-06-03 | Dainippon Ink & Chem Inc | 防水材用樹脂組成物 |
JP2005120305A (ja) * | 2003-10-20 | 2005-05-12 | Showa Highpolymer Co Ltd | 低臭気樹脂組成物およびそれを含む被覆材およびそれを用いた被覆工法 |
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JP2004155936A (ja) * | 2002-11-07 | 2004-06-03 | Dainippon Ink & Chem Inc | 防水材用樹脂組成物 |
JP2005120305A (ja) * | 2003-10-20 | 2005-05-12 | Showa Highpolymer Co Ltd | 低臭気樹脂組成物およびそれを含む被覆材およびそれを用いた被覆工法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US8557879B2 (en) | 2010-02-26 | 2013-10-15 | Jx Nippon Oil & Energy Corporation | Process for production of activated Fischer-Tropsch synthesis catalyst, and process for production of hydrocarbon |
WO2011158566A1 (ja) * | 2010-06-18 | 2011-12-22 | Dic株式会社 | ウレタン(メタ)アクリレート樹脂組成物及びそれを用いた被覆材 |
JP4973965B2 (ja) * | 2010-06-18 | 2012-07-11 | Dic株式会社 | ウレタン(メタ)アクリレート樹脂組成物及びそれを用いた被覆材 |
CN102906137A (zh) * | 2010-06-18 | 2013-01-30 | Dic株式会社 | 氨基甲酸酯(甲基)丙烯酸酯树脂组合物及使用其的被覆材料 |
US8592514B2 (en) | 2010-06-18 | 2013-11-26 | Dic Corporation | Urethane (meth) acrylate resin composition and coating material using the same |
KR101786778B1 (ko) | 2010-06-18 | 2017-10-18 | 디아이씨 가부시끼가이샤 | 우레탄(메타)아크릴레이트 수지 조성물 및 그것을 사용한 피복재 |
KR20140041328A (ko) | 2012-09-27 | 2014-04-04 | 디아이씨 가부시끼가이샤 | 라디칼 중합성 화합물 |
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