JP2006518347A5 - - Google Patents
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- Publication number
- JP2006518347A5 JP2006518347A5 JP2006501692A JP2006501692A JP2006518347A5 JP 2006518347 A5 JP2006518347 A5 JP 2006518347A5 JP 2006501692 A JP2006501692 A JP 2006501692A JP 2006501692 A JP2006501692 A JP 2006501692A JP 2006518347 A5 JP2006518347 A5 JP 2006518347A5
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- alkoxy
- substituted
- aryl
- heterocyclyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 125000000217 alkyl group Chemical group 0.000 claims description 44
- 125000001424 substituent group Chemical group 0.000 claims description 38
- 125000003118 aryl group Chemical group 0.000 claims description 36
- 125000000623 heterocyclic group Chemical group 0.000 claims description 34
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 24
- -1 benzylthio Chemical group 0.000 claims description 22
- 229910052736 halogen Inorganic materials 0.000 claims description 21
- 150000002367 halogens Chemical class 0.000 claims description 21
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 20
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 claims description 19
- 238000006467 substitution reaction Methods 0.000 claims description 19
- 125000004414 alkyl thio group Chemical group 0.000 claims description 17
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 17
- 229910052799 carbon Inorganic materials 0.000 claims description 16
- 125000005844 heterocyclyloxy group Chemical group 0.000 claims description 16
- 125000004641 (C1-C12) haloalkyl group Chemical group 0.000 claims description 15
- 125000004995 haloalkylthio group Chemical group 0.000 claims description 15
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 14
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 claims description 14
- 125000004649 C2-C8 alkynyl group Chemical group 0.000 claims description 14
- 125000004104 aryloxy group Chemical group 0.000 claims description 14
- 125000004643 (C1-C12) haloalkoxy group Chemical group 0.000 claims description 13
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 125000006711 (C2-C12) alkynyl group Chemical group 0.000 claims description 11
- 125000000392 cycloalkenyl group Chemical group 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 229910052717 sulfur Inorganic materials 0.000 claims description 11
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 10
- 125000005110 aryl thio group Chemical group 0.000 claims description 10
- 125000005144 cycloalkylsulfonyl group Chemical group 0.000 claims description 10
- 125000004468 heterocyclylthio group Chemical group 0.000 claims description 9
- 125000004644 alkyl sulfinyl group Chemical group 0.000 claims description 8
- 125000002947 alkylene group Chemical group 0.000 claims description 8
- 125000001072 heteroaryl group Chemical group 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 241000607479 Yersinia pestis Species 0.000 claims description 7
- 125000005149 cycloalkylsulfinyl group Chemical group 0.000 claims description 7
- 239000004480 active ingredient Substances 0.000 claims description 6
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 claims description 5
- 125000004741 (C1-C6) haloalkylsulfonyl group Chemical group 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000000000 cycloalkoxy group Chemical group 0.000 claims description 5
- 125000005366 cycloalkylthio group Chemical group 0.000 claims description 5
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims description 5
- 125000001188 haloalkyl group Chemical group 0.000 claims description 5
- 125000004440 haloalkylsulfinyl group Chemical group 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 claims description 4
- 125000003302 alkenyloxy group Chemical group 0.000 claims description 4
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 4
- 125000000304 alkynyl group Chemical group 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000004441 haloalkylsulfonyl group Chemical group 0.000 claims description 4
- 125000005347 halocycloalkyl group Chemical group 0.000 claims description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- 125000004749 (C1-C6) haloalkylsulfinyl group Chemical group 0.000 claims description 3
- 125000001475 halogen functional group Chemical group 0.000 claims description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims description 2
- 125000004450 alkenylene group Chemical group 0.000 claims description 2
- 125000005133 alkynyloxy group Chemical group 0.000 claims description 2
- 125000004438 haloalkoxy group Chemical group 0.000 claims description 2
- 230000000749 insecticidal effect Effects 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- 150000003839 salts Chemical group 0.000 claims description 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000000033 alkoxyamino group Chemical group 0.000 claims 5
- 239000012752 auxiliary agent Substances 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 125000005356 cycloalkylalkenyl group Chemical group 0.000 claims 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 125000003107 substituted aryl group Chemical group 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- 125000000676 alkoxyimino group Chemical group 0.000 description 2
- 0 CC(**1)[C@@](*)O[C@]1(C[C@](C1)OC([C@@]([C@@]([C@]2OC3)(C3=CC=C[C@@]3C)O)C=C(C)[C@@]2O)=O)OC1CC=C(C)[C@]3O[C@@](C[C@@]1OC)O[C@@](C)C1N(C)** Chemical compound CC(**1)[C@@](*)O[C@]1(C[C@](C1)OC([C@@]([C@@]([C@]2OC3)(C3=CC=C[C@@]3C)O)C=C(C)[C@@]2O)=O)OC1CC=C(C)[C@]3O[C@@](C[C@@]1OC)O[C@@](C)C1N(C)** 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0302309.0A GB0302309D0 (en) | 2003-01-31 | 2003-01-31 | Avermectin monosaccharide derivatives substituted in the 4 -position having pesticidal properties |
| PCT/EP2004/000899 WO2004067534A1 (en) | 2003-01-31 | 2004-01-30 | Avermectin monosaccharide derivatives having pesticidal properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006518347A JP2006518347A (ja) | 2006-08-10 |
| JP2006518347A5 true JP2006518347A5 (enExample) | 2011-02-24 |
Family
ID=9952240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006501692A Pending JP2006518347A (ja) | 2003-01-31 | 2004-01-30 | 殺虫特性を有するアベルメクチン単糖誘導体 |
Country Status (28)
| Country | Link |
|---|---|
| US (1) | US20060205595A1 (enExample) |
| EP (1) | EP1594878B1 (enExample) |
| JP (1) | JP2006518347A (enExample) |
| KR (1) | KR20050097524A (enExample) |
| CN (1) | CN100410259C (enExample) |
| AR (1) | AR042967A1 (enExample) |
| AT (1) | ATE397610T1 (enExample) |
| AU (1) | AU2004207073B2 (enExample) |
| BR (1) | BRPI0406875B1 (enExample) |
| CA (1) | CA2513573C (enExample) |
| CL (1) | CL2004000147A1 (enExample) |
| CY (1) | CY1108295T1 (enExample) |
| DE (1) | DE602004014252D1 (enExample) |
| DK (1) | DK1594878T3 (enExample) |
| ES (1) | ES2308140T3 (enExample) |
| GB (1) | GB0302309D0 (enExample) |
| IL (1) | IL169598A (enExample) |
| MA (1) | MA27587A1 (enExample) |
| MX (1) | MXPA05007923A (enExample) |
| NZ (1) | NZ541252A (enExample) |
| PL (1) | PL218731B1 (enExample) |
| PT (1) | PT1594878E (enExample) |
| RU (1) | RU2329268C2 (enExample) |
| SI (1) | SI1594878T1 (enExample) |
| TW (1) | TW200508240A (enExample) |
| UA (1) | UA81012C2 (enExample) |
| WO (1) | WO2004067534A1 (enExample) |
| ZA (1) | ZA200505545B (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CR6574A (es) * | 2001-02-27 | 2004-10-28 | Syngenta Participations Ag | Sales de avermectinas substituidas en la posicion 4 con propiedades plaguicidas |
| EG23124A (en) * | 2001-02-27 | 2004-04-28 | Syngenta Participations Ag | Avermectins substituted in the 4-position having pesticidal properties |
| AR036486A1 (es) * | 2001-08-28 | 2004-09-15 | Syngenta Participations Ag | Derivados 4"-desoxi-4"-(s)-amino avermectina, composicion plaguicida, procedimiento para la preparacion de esa composicion, metodo para controlar plagas, y uso de estos derivados para preparar una composicion |
| AR040073A1 (es) * | 2002-05-07 | 2005-03-16 | Syngenta Participations Ag | Derivados de 4''-desoxi-4''-(s)-amido avermectina y su uso como plaguicidas |
| GB0302310D0 (en) * | 2003-01-31 | 2003-03-05 | Syngenta Participations Ag | Avermectin- and avermectin monosaccharide derivatives substituted in the 4"- or 4' - positionhaving pesticidal properties |
| GB0302308D0 (en) * | 2003-01-31 | 2003-03-05 | Syngenta Participations Ag | Avermectin and avermectin monosaccharide derivatives substituted in the 4"- or 4'-position having pesticidal properties |
| GB0302547D0 (en) * | 2003-02-04 | 2003-03-12 | Syngenta Participations Ag | Avermectins and avermectin monosaccharide substituted in the 4'- and 4" position having pesticidal properties |
| GB0320176D0 (en) | 2003-08-28 | 2003-10-01 | Syngenta Participations Ag | Avermectins and avermectin monosaccharides substitued in the 4'-and 4"-positionhaving pesticidal properties |
| TW200538461A (en) * | 2004-04-07 | 2005-12-01 | Syngenta Participations Ag | Avermectin and avermectin monosaccharide substituted in the 4"-and 4'-position respectively |
| WO2012027521A1 (en) * | 2010-08-26 | 2012-03-01 | Dow Agrosciences Llc | Pesticidal compositions |
| CN103214532B (zh) * | 2013-02-28 | 2018-07-06 | 河北威远生物化工有限公司 | 阿维菌素B2a/2b胺基衍生物、衍生物盐和阿维菌素B2a/2b胺基衍生物盐的制备方法及用途 |
| CN103613625B (zh) * | 2013-12-02 | 2016-03-02 | 兰州大学 | 一种阿维菌素类化合物及其制备方法和在农药中的用途 |
| CN104402953B (zh) * | 2014-11-28 | 2017-07-28 | 大庆志飞生物化工有限公司 | 阿维菌素单糖化合物及其制备方法和用途 |
| CN104402954A (zh) * | 2014-11-28 | 2015-03-11 | 大庆志飞生物化工有限公司 | 甲胺基阿维菌素单糖化合物及其制备方法和用途 |
| CN107501368B (zh) * | 2017-09-30 | 2020-02-21 | 中国科学院成都生物研究所 | 一种多拉菌素衍生物的合成及其杀虫应用 |
| CN108690108B (zh) * | 2018-07-27 | 2022-03-11 | 河北威远生物化工有限公司 | 一种磺酰胺基取代的阿维菌素B2a/B2b衍生物及其制备方法与应用 |
| CN113150053B (zh) * | 2020-01-22 | 2024-10-01 | 华东理工大学 | 偶氮苯类阿维菌素衍生物及其制备方法和应用 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4206205A (en) * | 1977-10-03 | 1980-06-03 | Merck & Co., Inc. | Monosaccharide and aglycone derivatives of C-076 |
| US4203976A (en) * | 1978-08-02 | 1980-05-20 | Merck & Co., Inc. | Sugar derivatives of C-076 compounds |
| US4427663A (en) * | 1982-03-16 | 1984-01-24 | Merck & Co., Inc. | 4"-Keto-and 4"-amino-4"-deoxy avermectin compounds and substituted amino derivatives thereof |
| US4622313A (en) * | 1985-08-01 | 1986-11-11 | Merck & Co., Inc. | O-sulfate derivatives of avermectins and milbemycins having improved water solubility |
| US4886828A (en) * | 1986-09-12 | 1989-12-12 | American Cyanamid Company | Δ22 -derivatives of LL-F28249 compounds |
| US4831016A (en) * | 1986-10-31 | 1989-05-16 | Merck & Co., Inc. | Reduced avermectin derivatives |
| US4895837A (en) * | 1988-01-29 | 1990-01-23 | Merck & Co., Inc. | Avermectin derivatives |
| NZ228866A (en) * | 1988-05-02 | 1991-10-25 | Merck & Co Inc | Fluoro-substituted milbemycins and avermectins for combatting parasites and insects |
| US5008250A (en) * | 1988-05-25 | 1991-04-16 | Merck & Co., Inc. | Avermectins with a cleaved furan ring and an 8a hydroxy group |
| GB2220856A (en) * | 1988-07-18 | 1990-01-24 | Merck & Co Inc | Novel synergistic agricultural insecticidal and acaricidal combinations containing avermectin derivatives |
| NZ231773A (en) * | 1988-12-23 | 1992-09-25 | Merck & Co Inc | Avermectin derivatives, preparation and parasiticidal pharmaceutical compositions thereof |
| FR2646237B1 (fr) * | 1989-04-21 | 1994-01-07 | Fabrication Instruments Mesure | Dispositif de jaugeage de gaz haute pression, en particulier pour la reserve d'oxygene gazeux embarquee a bord d'un avion |
| US5057499A (en) * | 1989-06-02 | 1991-10-15 | Merck & Co. Inc. | Avermectin derivatives |
| US5023241A (en) * | 1989-07-31 | 1991-06-11 | Merck & Co., Inc. | Avermectin derivatives |
| US5169839A (en) * | 1990-05-11 | 1992-12-08 | Merck & Co., Inc. | Derivatives of 3'- and 3"-o-desmethyl avermectin compounds, compositions and methods of treating melmintic and parasitic infections |
| US5346698A (en) * | 1991-01-15 | 1994-09-13 | Mycogen Corporation | Synergistic pesticidal compositions |
| US5192546A (en) * | 1991-01-15 | 1993-03-09 | Mycogen Corporation | Synergistic pesticidal compositions |
| US5208222A (en) * | 1991-03-28 | 1993-05-04 | Merck & Co., Inc. | 4"-and 4'-alkylthio avermectin derivatives |
| GB9201505D0 (en) * | 1992-01-24 | 1992-03-11 | Pfizer Ltd | Antiparasitic agents |
| US5229415A (en) * | 1992-03-24 | 1993-07-20 | Merck & Co., Inc. | Alkylthio alkyl avermectins are active antiparasitic agents |
| US5362863A (en) * | 1993-09-29 | 1994-11-08 | Merck & Co., Inc. | Process for the preparation of 4"-amino avermectin compounds |
| US5981500A (en) * | 1994-01-12 | 1999-11-09 | Pfizer Inc. | Antiparasitic agents related to the milbemycins and avermectins |
| US5436355A (en) * | 1994-02-03 | 1995-07-25 | Merck & Co., Inc. | Process for making avermectin/zein compositions |
| TW327125B (en) * | 1994-02-07 | 1998-02-21 | Merck & Co Inc | Composition and method for protecting against pine exhausted |
| US6875727B2 (en) * | 1997-12-23 | 2005-04-05 | Syngenta Crop Protection, Inc. | Use of macrolides in pest control |
| JP4832645B2 (ja) * | 1999-02-09 | 2011-12-07 | 社団法人北里研究所 | エバーメクチン誘導体 |
| WO2002012248A1 (en) * | 2000-08-09 | 2002-02-14 | The Kitasato Institute | Avermectin derivatives |
| EG23124A (en) * | 2001-02-27 | 2004-04-28 | Syngenta Participations Ag | Avermectins substituted in the 4-position having pesticidal properties |
| CR6574A (es) * | 2001-02-27 | 2004-10-28 | Syngenta Participations Ag | Sales de avermectinas substituidas en la posicion 4 con propiedades plaguicidas |
| AR037938A1 (es) * | 2001-12-21 | 2004-12-22 | Syngenta Participations Ag | Derivados de avermectina b1 que tienen un substituyente de aminosulfoniloxilo en la posicion 4'' |
| GB0302308D0 (en) * | 2003-01-31 | 2003-03-05 | Syngenta Participations Ag | Avermectin and avermectin monosaccharide derivatives substituted in the 4"- or 4'-position having pesticidal properties |
| GB0302548D0 (en) * | 2003-02-04 | 2003-03-12 | Syngenta Participations Ag | Avermectins substituted in the 4"- and 4' -positions having pesticidal properties |
| TW200538461A (en) * | 2004-04-07 | 2005-12-01 | Syngenta Participations Ag | Avermectin and avermectin monosaccharide substituted in the 4"-and 4'-position respectively |
-
2003
- 2003-01-31 GB GBGB0302309.0A patent/GB0302309D0/en not_active Ceased
-
2004
- 2004-01-29 AR ARP040100268A patent/AR042967A1/es active IP Right Grant
- 2004-01-29 CL CL200400147A patent/CL2004000147A1/es unknown
- 2004-01-29 TW TW093102006A patent/TW200508240A/zh unknown
- 2004-01-30 KR KR1020057014004A patent/KR20050097524A/ko not_active Ceased
- 2004-01-30 AT AT04706630T patent/ATE397610T1/de active
- 2004-01-30 US US10/543,643 patent/US20060205595A1/en not_active Abandoned
- 2004-01-30 DK DK04706630T patent/DK1594878T3/da active
- 2004-01-30 DE DE602004014252T patent/DE602004014252D1/de not_active Expired - Lifetime
- 2004-01-30 MX MXPA05007923A patent/MXPA05007923A/es active IP Right Grant
- 2004-01-30 EP EP04706630A patent/EP1594878B1/en not_active Expired - Lifetime
- 2004-01-30 PT PT04706630T patent/PT1594878E/pt unknown
- 2004-01-30 BR BRPI0406875-0A patent/BRPI0406875B1/pt not_active IP Right Cessation
- 2004-01-30 RU RU2005127321/04A patent/RU2329268C2/ru active
- 2004-01-30 UA UAA200508413A patent/UA81012C2/uk unknown
- 2004-01-30 ES ES04706630T patent/ES2308140T3/es not_active Expired - Lifetime
- 2004-01-30 WO PCT/EP2004/000899 patent/WO2004067534A1/en not_active Ceased
- 2004-01-30 SI SI200430826T patent/SI1594878T1/sl unknown
- 2004-01-30 CN CNB2004800043694A patent/CN100410259C/zh not_active Expired - Fee Related
- 2004-01-30 NZ NZ541252A patent/NZ541252A/en not_active IP Right Cessation
- 2004-01-30 AU AU2004207073A patent/AU2004207073B2/en not_active Ceased
- 2004-01-30 JP JP2006501692A patent/JP2006518347A/ja active Pending
- 2004-01-30 PL PL378024A patent/PL218731B1/pl unknown
- 2004-01-30 CA CA2513573A patent/CA2513573C/en not_active Expired - Fee Related
-
2005
- 2005-07-07 IL IL169598A patent/IL169598A/en active IP Right Grant
- 2005-07-08 ZA ZA200505545A patent/ZA200505545B/en unknown
- 2005-08-30 MA MA28474A patent/MA27587A1/fr unknown
-
2008
- 2008-08-25 CY CY20081100913T patent/CY1108295T1/el unknown
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