JP2006509110A5 - フルオロケミカル処理組成物及び汚染除去特性を繊維基材に与える方法 - Google Patents
フルオロケミカル処理組成物及び汚染除去特性を繊維基材に与える方法 Download PDFInfo
- Publication number
- JP2006509110A5 JP2006509110A5 JP2003586416A JP2003586416A JP2006509110A5 JP 2006509110 A5 JP2006509110 A5 JP 2006509110A5 JP 2003586416 A JP2003586416 A JP 2003586416A JP 2003586416 A JP2003586416 A JP 2003586416A JP 2006509110 A5 JP2006509110 A5 JP 2006509110A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- composition according
- fluorochemical
- aliphatic
- fluoroalkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005202 decontamination Methods 0.000 title 1
- 230000003588 decontaminative Effects 0.000 title 1
- 239000000758 substrate Substances 0.000 title 1
- 239000004753 textile Substances 0.000 title 1
- 125000001931 aliphatic group Chemical group 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 5
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 5
- 125000004432 carbon atoms Chemical group C* 0.000 claims 4
- 125000003709 fluoroalkyl group Chemical group 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 3
- 229920001577 copolymer Polymers 0.000 claims 3
- 125000002947 alkylene group Chemical group 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 2
- -1 fluoroalkyl acrylate Chemical compound 0.000 claims 2
- 125000000524 functional group Chemical group 0.000 claims 2
- 150000003673 urethanes Chemical class 0.000 claims 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- 229920001228 Polyisocyanate Polymers 0.000 claims 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims 1
- 125000005647 linker group Chemical group 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 125000005702 oxyalkylene group Chemical group 0.000 claims 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims 1
- 239000005056 polyisocyanate Substances 0.000 claims 1
- 150000003512 tertiary amines Chemical class 0.000 claims 1
Claims (11)
- 1)a.3個もしくはそれ以上のイソシアネート基を有する脂肪族ポリイソシアネートおよび
b.式Rf−Q’−Zのフルオロケミカル一官能性化合物
(式中、Rfはパーフルオロアルキルまたはパーフルオロヘテロアルキル基であり、
Q’は有機連結基であり、そして、
Zはイソシアネート反応性官能基である)の反応生成物であり、前記フルオロケミカルが利用可能なイソシアネート基の少なくとも50%と反応するのに十分な量で存在する反応生成物を含むフルオロケミカルウレタンと、
2)フルオロアルキル(メタ)アクリレート/ポリオキシアルキレン(メタ)アクリレート共重合体と
を含むフルオロケミカル処理組成物。 - 前記Z基が−NH2、−SH、−OH、−NCO、−NR1Hから選択され、かつ、前記Rf基が3〜5個の炭素原子を有する、請求項1に記載の組成物。
- 前記フルオロケミカルウレタンが脂肪族一官能性化合物のさらなる反応生成物を含み、かつ前記脂肪族一官能性化合物が式R’’’−Zであり、式中、R’’’は脂肪族基であり、かつ、Zはイソシアネート反応性官能基である、請求項1に記載の組成物。
- 式:(Rf *)nA(NHCO−Z’R’’’)m-n
(式中、Rf *はRf−Q’−Z’であり、
Z’はZの残基であり、
Aは、価数mを有する、前記脂肪族イソシアネートの残基であり、
R’’’は脂肪族基であり、かつ、
n(平均)は少なくとも1.5である)のフルオロケミカルウレタンを含む、請求項1に記載の組成物。 - 式中、Rfが3〜5個の炭素原子を有するフルオロアルキル基であり、
Q’が−SO2N(R1)R2−であり、
R1が−Hまたは−CH3であり、
R2が1〜3個の炭素原子を有するアルキレン基であり、かつ、
Zが−OHである、請求項1に記載の組成物。 - 前記脂肪族一官能性化合物が利用可能なイソシアネート基の33%以下と反応するのに十分な量で存在する、請求項3に記載の組成物。
- フルオロケミカル一官能性化合物の量が利用可能なイソシアネート基の75%以上と反応するのに十分な量にある、請求項1に記載の組成物。
- 20〜99.5重量パーセントの上記フルオロケミカルウレタン化合物と、0.5〜80重量パーセントの前記フルオロアルキル(メタ)アクリレート/ポリオキシアルキレン(メタ)アクリレート共重合体とを含む、請求項1に記載の組成物。
- (a)請求項1〜10のいずれか1項に記載の処理組成物を塗布する工程と、
(b)処理組成物を硬化させる工程と
を含む汚染除去特性を繊維基材に与えるための方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/124,523 US7078454B2 (en) | 2002-04-17 | 2002-04-17 | Repellent fluorochemical compositions |
PCT/US2003/004933 WO2003089712A1 (en) | 2002-04-17 | 2003-02-18 | Repellent fluorochemical compositions |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2006509110A JP2006509110A (ja) | 2006-03-16 |
JP2006509110A5 true JP2006509110A5 (ja) | 2006-04-27 |
JP4537073B2 JP4537073B2 (ja) | 2010-09-01 |
Family
ID=29248376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003586416A Expired - Fee Related JP4537073B2 (ja) | 2002-04-17 | 2003-02-18 | フルオロケミカル処理組成物及び汚染除去特性を繊維基材に与える方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US7078454B2 (ja) |
EP (1) | EP1495182B1 (ja) |
JP (1) | JP4537073B2 (ja) |
KR (1) | KR20050000517A (ja) |
CN (1) | CN100408751C (ja) |
AT (1) | ATE406475T1 (ja) |
AU (1) | AU2003213124B2 (ja) |
CA (1) | CA2482489C (ja) |
DE (1) | DE60323216D1 (ja) |
WO (1) | WO2003089712A1 (ja) |
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-
2002
- 2002-04-17 US US10/124,523 patent/US7078454B2/en not_active Expired - Fee Related
-
2003
- 2003-02-18 EP EP03709170A patent/EP1495182B1/en not_active Expired - Lifetime
- 2003-02-18 CN CNB03808645XA patent/CN100408751C/zh not_active Expired - Fee Related
- 2003-02-18 DE DE60323216T patent/DE60323216D1/de not_active Expired - Lifetime
- 2003-02-18 AU AU2003213124A patent/AU2003213124B2/en not_active Expired - Fee Related
- 2003-02-18 AT AT03709170T patent/ATE406475T1/de not_active IP Right Cessation
- 2003-02-18 CA CA2482489A patent/CA2482489C/en not_active Expired - Fee Related
- 2003-02-18 JP JP2003586416A patent/JP4537073B2/ja not_active Expired - Fee Related
- 2003-02-18 KR KR10-2004-7016525A patent/KR20050000517A/ko not_active Application Discontinuation
- 2003-02-18 WO PCT/US2003/004933 patent/WO2003089712A1/en active Application Filing
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