JP2006503132A - 気泡質のポリウレタンエラストマー、その製造方法及びその使用 - Google Patents
気泡質のポリウレタンエラストマー、その製造方法及びその使用 Download PDFInfo
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- 230000001413 cellular effect Effects 0.000 title claims abstract description 14
- 229920003225 polyurethane elastomer Polymers 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 150000001412 amines Chemical class 0.000 claims abstract description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 19
- 239000005056 polyisocyanate Substances 0.000 claims description 19
- 239000004604 Blowing Agent Substances 0.000 claims description 13
- 229920005862 polyol Polymers 0.000 claims description 13
- 239000004970 Chain extender Substances 0.000 claims description 12
- 150000003077 polyols Chemical class 0.000 claims description 12
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 150000004982 aromatic amines Chemical class 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 229920005906 polyester polyol Polymers 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- 229920000570 polyether Polymers 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 150000002009 diols Chemical class 0.000 claims description 6
- 229920001971 elastomer Polymers 0.000 claims description 6
- 239000000806 elastomer Substances 0.000 claims description 6
- 150000003141 primary amines Chemical group 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 238000005187 foaming Methods 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- -1 amine compound Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 description 2
- RQEOBXYYEPMCPJ-UHFFFAOYSA-N 4,6-diethyl-2-methylbenzene-1,3-diamine Chemical compound CCC1=CC(CC)=C(N)C(C)=C1N RQEOBXYYEPMCPJ-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- SSZRBEFNYHIARF-UHFFFAOYSA-M diethyl phosphate;tetrabutylazanium Chemical compound CCOP([O-])(=O)OCC.CCCC[N+](CCCC)(CCCC)CCCC SSZRBEFNYHIARF-UHFFFAOYSA-M 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 235000013847 iso-butane Nutrition 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- JGYUBHGXADMAQU-UHFFFAOYSA-N 2,4,6-triethylbenzene-1,3-diamine Chemical compound CCC1=CC(CC)=C(N)C(CC)=C1N JGYUBHGXADMAQU-UHFFFAOYSA-N 0.000 description 1
- ZVDSMYGTJDFNHN-UHFFFAOYSA-N 2,4,6-trimethylbenzene-1,3-diamine Chemical group CC1=CC(C)=C(N)C(C)=C1N ZVDSMYGTJDFNHN-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- LNWBFIVSTXCJJG-UHFFFAOYSA-N [diisocyanato(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(N=C=O)(N=C=O)C1=CC=CC=C1 LNWBFIVSTXCJJG-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- FEIHSRFOPKYFEB-UHFFFAOYSA-M benzyl(triethyl)azanium;diethyl phosphate Chemical compound CCOP([O-])(=O)OCC.CC[N+](CC)(CC)CC1=CC=CC=C1 FEIHSRFOPKYFEB-UHFFFAOYSA-M 0.000 description 1
- KXHPPCXNWTUNSB-UHFFFAOYSA-M benzyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1=CC=CC=C1 KXHPPCXNWTUNSB-UHFFFAOYSA-M 0.000 description 1
- WHVHWBHVQUIBBP-UHFFFAOYSA-M benzyl(trimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.C[N+](C)(C)CC1=CC=CC=C1 WHVHWBHVQUIBBP-UHFFFAOYSA-M 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000012973 diazabicyclooctane Substances 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- ZGXMTNLMMZCPNB-UHFFFAOYSA-M dodecyl(trimethyl)azanium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CCCCCCCCCCCC[N+](C)(C)C ZGXMTNLMMZCPNB-UHFFFAOYSA-M 0.000 description 1
- KQPPJWHBSYEOKV-UHFFFAOYSA-M dodecyl-ethyl-dimethylazanium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CCCCCCCCCCCC[N+](C)(C)CC KQPPJWHBSYEOKV-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- ZOHMQDNXNJSRBZ-UHFFFAOYSA-M ethyl sulfate;trimethyl(octyl)azanium Chemical compound CCOS([O-])(=O)=O.CCCCCCCC[N+](C)(C)C ZOHMQDNXNJSRBZ-UHFFFAOYSA-M 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- CTYRPMDGLDAWRQ-UHFFFAOYSA-N phenyl hydrogen sulfate Chemical compound OS(=O)(=O)OC1=CC=CC=C1 CTYRPMDGLDAWRQ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005903 polyol mixture Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1875—Catalysts containing secondary or tertiary amines or salts thereof containing ammonium salts or mixtures of secondary of tertiary amines and acids
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Materials For Medical Uses (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
A)ポリイソシアネート、ポリイソシアネートプレポリマー及び変性ポリイソシアネートを含んでなる群からの一種以上の化合物、
B)ポリエーテルポリオール及びポリエステルポリオールを含んでなる群からの一種以上のポリオール、及び
C)連鎖延長剤、
を、
D)水及び/又は物理発泡剤、
E)触媒、及び任意に
F)更なる補助物質及び/又は添加剤、
の存在下で反応させることによって得ることができ、
(C1)1分子あたり少なくとも2個の第一級アミン基を有する芳香族アミン、
(C2)第四級アンモニウム塩、及び任意に、
(C3)分子量が≦400 g/mol、好ましくは60〜400 g/mol、特に好ましくは60〜150 g/molの短鎖ジオール、
を連鎖延長剤C)として使用することを特徴とする気泡質のアミン架橋ポリウレタンエラストマーを提供する。
第四級アンモニウム塩C2)は、成分B)、C)、D)及びE)の合計100重量部に対して、好ましくは0.25〜12重量部の量で、特に好ましくは0.5〜8重量部の量で用いられる。
水は、成分B)、C)、D)及びE)の合計100重量部に対して、好ましくは0.01〜0.8重量部、特に好ましくは0.1〜0.6重量部の量で、成分D)として用いられる。
ポリエステルポリオールは、好適にはOH価が28〜112である。
A)ポリイソシアネート、ポリイソシアネートプレポリマー及び変性ポリイソシアネートを含んでなる群からの一種以上の化合物、
B)ポリエーテルポリオール及びポリエステルポリオールを含んでなる群からの一種以上の化合物、及び
C)連鎖延長剤、
を、
D)水及び/又は物理発泡剤、
E)触媒、及び任意に
F)更なる補助物質及び/又は添加剤、
の存在下で反応させることを含む、本発明による気泡質のアミン架橋ポリウレタンエラストマーの製造方法であって、
成分C)は、1分子あたり少なくとも2個の第一級アミン基を有する芳香族アミン(C1)、第四級アンモニウム塩(C2)及び任意に、分子量が≦400 g/mol、好ましくは60〜400 g/mol、特に好ましくは60〜150 g/molの短鎖ジオール(C3)を含んでなることを特徴とする製造方法を提供する。
出発原料:
B1:OH価が28で90%の第一級OH基を有し、80%プロピレンオキシド(PO)と20%エチレンオキシド(EO)の添加により得られる、始動材としてのプロピレングリコールをベースとするポリエーテルポリオール。
B2:OH価が28で90%の第一級OH基を有し、83%POと17%EOの添加により得られる、始動材としてのグリセリンをベースとするポリエーテルポリオール。
B3:OH価が56である、アジピン酸、エチレングリコール、1,4-ブタンジオールをベースとするポリエステルポリオール。
A2:部分カルボジイミド化によって調製される4,4'-MDI55部及び変性MDI6部(NCO含量は30重量%)と、ポリエステルポリオール39部(OH価は56)を、反応させることにより調製されるポリイソシアネート2)(ここで、ポリイソシアネート2)のNCO含量19.0%が得られる)。
第四級アンモニウム塩C2):ジメチルエチルドデシルアンモニウムエチルスルフェート
第四級アンモニウム塩C2'):テトラブチルアンモニウムジエチルホスフェート
DABCO:1,4-ジアザビシクロ-[2.2.2]-オクタン
DBTDL:ジブチル錫ジラウレート
安定剤:DC 193(Air Productsから)
以下の配合物(表1)をマニュアル処理によって反応させた:
全てのデータは重量部として記載されている。
Claims (3)
- A)ポリイソシアネート、ポリイソシアネートプレポリマー及び変性ポリイソシアネートを含んでなる群からの一種以上の化合物、
B)ポリエーテルポリオール及びポリエステルポリオールを含んでなる群からの一種以上のポリオール、
C)連鎖延長剤、
を、
D)水及び/又は物理発泡剤、
E)触媒、及び任意に
F)更なる補助物質及び/又は添加剤、
の存在下で反応させることによって得ることができ、
成分C)は、(C1)1分子あたり少なくとも2個の第一級アミン基を有する芳香族アミン、(C2)第四級アンモニウム塩及び任意に、(C3)分子量が≦400 g/molの短鎖ジオール、の混合物である、
気泡質のアミン架橋ポリウレタンエラストマー。 - A)ポリイソシアネート、ポリイソシアネートプレポリマー及び変性ポリイソシアネートを含んでなる群からの一種以上の化合物、
を、
B)ポリエーテルポリオール及びポリエステルポリオールを含んでなる群からの一種以上の化合物、及び
C)連鎖延長剤、
と、
D)水及び/又は物理発泡剤、
E)触媒、及び任意に
F)更なる補助物質及び/又は添加剤、
の存在下で反応させることを含む、気泡質のアミン架橋ポリウレタンエラストマーの製造方法であって、
成分C)は、1分子あたり少なくとも2個の第一級アミン基を有する芳香族アミン(C1)、第四級アンモニウム塩(C2)及び任意に、分子量が≦400の短鎖ジオール(C3)、の混合物を含んでなることを特徴とする製造方法。 - 靴部品及び靴底を製造するための、請求項1に記載のエラストマー及び請求項2に記載の方法で製造されるエラストマーの使用。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10247789A DE10247789A1 (de) | 2002-10-14 | 2002-10-14 | Zellige Polyurethanelastomere, Verfahren zu ihrer Herstellung und ihre Verwendung |
PCT/EP2003/010896 WO2004035648A1 (de) | 2002-10-14 | 2003-10-01 | Zellige polyurethanelastomere, ein verfahren zu ihrer herstellung und ihre verwendung |
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JP2006503132A true JP2006503132A (ja) | 2006-01-26 |
JP2006503132A5 JP2006503132A5 (ja) | 2006-10-26 |
Family
ID=32038630
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JP2004544057A Pending JP2006503132A (ja) | 2002-10-14 | 2003-10-01 | 気泡質のポリウレタンエラストマー、その製造方法及びその使用 |
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---|---|
US (1) | US20040077740A1 (ja) |
EP (1) | EP1554327B1 (ja) |
JP (1) | JP2006503132A (ja) |
KR (1) | KR20050048685A (ja) |
CN (1) | CN1315901C (ja) |
AT (1) | ATE390448T1 (ja) |
AU (1) | AU2003273937A1 (ja) |
BR (1) | BR0315256A (ja) |
CA (1) | CA2501962A1 (ja) |
DE (2) | DE10247789A1 (ja) |
ES (1) | ES2302943T3 (ja) |
HK (1) | HK1086019A1 (ja) |
MX (1) | MXPA05003900A (ja) |
PL (1) | PL374952A1 (ja) |
WO (1) | WO2004035648A1 (ja) |
Cited By (2)
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---|---|---|---|---|
JP2007131672A (ja) * | 2005-11-08 | 2007-05-31 | Toyo Tire & Rubber Co Ltd | 研磨パッド |
WO2008018601A1 (en) * | 2006-08-11 | 2008-02-14 | Tosoh Corporation | Catalyst composition for polyurethane resin production and method for producing polyurethane resin |
Families Citing this family (2)
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---|---|---|---|---|
CN1754914B (zh) * | 2004-09-28 | 2010-05-26 | 拜耳(中国)有限公司 | 聚氨酯复合材料、其制备方法和用途 |
CN105038189A (zh) * | 2015-07-27 | 2015-11-11 | 江苏欣润塑胶有限公司 | 一种环保无毒聚氨酯树脂 |
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Also Published As
Publication number | Publication date |
---|---|
DE50309488D1 (de) | 2008-05-08 |
CN1705695A (zh) | 2005-12-07 |
PL374952A1 (en) | 2005-11-14 |
MXPA05003900A (es) | 2005-06-22 |
DE10247789A1 (de) | 2004-04-22 |
EP1554327A1 (de) | 2005-07-20 |
AU2003273937A1 (en) | 2004-05-04 |
ATE390448T1 (de) | 2008-04-15 |
WO2004035648A1 (de) | 2004-04-29 |
HK1086019A1 (en) | 2006-09-08 |
KR20050048685A (ko) | 2005-05-24 |
ES2302943T3 (es) | 2008-08-01 |
CN1315901C (zh) | 2007-05-16 |
US20040077740A1 (en) | 2004-04-22 |
CA2501962A1 (en) | 2004-04-29 |
EP1554327B1 (de) | 2008-03-26 |
BR0315256A (pt) | 2005-08-23 |
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