JP2006502982A5 - - Google Patents
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- Publication number
- JP2006502982A5 JP2006502982A5 JP2004517759A JP2004517759A JP2006502982A5 JP 2006502982 A5 JP2006502982 A5 JP 2006502982A5 JP 2004517759 A JP2004517759 A JP 2004517759A JP 2004517759 A JP2004517759 A JP 2004517759A JP 2006502982 A5 JP2006502982 A5 JP 2006502982A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- organic halide
- mol
- concentration
- feedstock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 150000004820 halides Chemical class 0.000 claims description 48
- 239000003054 catalyst Substances 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 32
- 229910052736 halogen Inorganic materials 0.000 claims description 14
- 150000002367 halogens Chemical class 0.000 claims description 14
- 238000006735 epoxidation reaction Methods 0.000 claims description 10
- 150000001336 alkenes Chemical class 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052709 silver Inorganic materials 0.000 claims description 7
- 239000004332 silver Substances 0.000 claims description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 239000002019 doping agent Substances 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 4
- 229910052751 metal Inorganic materials 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- 229910052702 rhenium Inorganic materials 0.000 claims 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 3
- 150000000180 1,2-diols Chemical class 0.000 claims 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 239000010937 tungsten Substances 0.000 claims 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 229910052776 Thorium Inorganic materials 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 150000002009 diols Chemical class 0.000 claims 1
- -1 ethylene oxide 1,2-diol Chemical class 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 claims 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 1
- 229910052716 thallium Inorganic materials 0.000 claims 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39249902P | 2002-06-28 | 2002-06-28 | |
| PCT/US2003/019828 WO2004002971A1 (en) | 2002-06-28 | 2003-06-24 | A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010165897A Division JP5431262B2 (ja) | 2002-06-28 | 2010-07-23 | エポキシ化法の始動方法、触媒及びオレフィンのエポキシ化法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006502982A JP2006502982A (ja) | 2006-01-26 |
| JP2006502982A5 true JP2006502982A5 (enExample) | 2010-09-24 |
| JP4624101B2 JP4624101B2 (ja) | 2011-02-02 |
Family
ID=30000882
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517759A Expired - Fee Related JP4624101B2 (ja) | 2002-06-28 | 2003-06-24 | エポキシ化法の始動方法、触媒及びオレフィンのエポキシ化法 |
| JP2010165897A Expired - Lifetime JP5431262B2 (ja) | 2002-06-28 | 2010-07-23 | エポキシ化法の始動方法、触媒及びオレフィンのエポキシ化法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010165897A Expired - Lifetime JP5431262B2 (ja) | 2002-06-28 | 2010-07-23 | エポキシ化法の始動方法、触媒及びオレフィンのエポキシ化法 |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP1532125B1 (enExample) |
| JP (2) | JP4624101B2 (enExample) |
| KR (1) | KR101098051B1 (enExample) |
| CN (1) | CN100376561C (enExample) |
| AU (1) | AU2003243758A1 (enExample) |
| BR (1) | BR0312011B1 (enExample) |
| CA (1) | CA2490892C (enExample) |
| DE (1) | DE60304197T2 (enExample) |
| IN (1) | IN2004DE03915A (enExample) |
| MX (1) | MX257124B (enExample) |
| MY (1) | MY134316A (enExample) |
| RU (1) | RU2311229C2 (enExample) |
| TW (1) | TWI340743B (enExample) |
| WO (1) | WO2004002971A1 (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| US8536083B2 (en) | 2004-09-01 | 2013-09-17 | Shell Oil Company | Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier |
| EP2013194A2 (de) * | 2006-04-21 | 2009-01-14 | Basf Se | Verfahren zur herstellung von ethylenoxid in einem mikrokanalreaktor |
| EP2152411B1 (en) | 2007-05-09 | 2019-12-04 | Shell International Research Maatschappij B.V. | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| WO2008141032A1 (en) * | 2007-05-09 | 2008-11-20 | Shell Oil Company | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| JP5507444B2 (ja) | 2007-05-09 | 2014-05-28 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 酸化オレフィン、１，２−ジオール、１，２−ジオールエーテル、１，２−カーボネートまたはアルカノールアミンの製造方法 |
| US7696368B2 (en) | 2007-05-11 | 2010-04-13 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Start-up of high selectivity catalysts in olefin oxide plants |
| US7553980B2 (en) * | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
| DE102008011767B4 (de) | 2008-02-28 | 2012-07-26 | Basf Se | Verfahren zur Herstellung von olefinisch ungesättigten Carbonylverbindungen durch oxidative Dehydrierung von Alkoholen |
| DE102008014910A1 (de) | 2008-03-19 | 2009-09-24 | Basf Se | Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung |
| CN102056909B (zh) * | 2008-05-07 | 2014-03-05 | 国际壳牌研究有限公司 | 环氧化工艺的开车方法及环氧乙烷、1，2-二醇、1，2-二醇醚、1，2-碳酸酯或链烷醇胺的制备方法 |
| KR101629038B1 (ko) | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| BRPI0915854A2 (pt) | 2008-07-14 | 2015-08-04 | Basf Se | Processo para preparar óxido de etileno |
| WO2010009021A2 (en) * | 2008-07-14 | 2010-01-21 | Velocys Inc. | Process for making ethylene oxide using microchannel process technology |
| CN101497045B (zh) * | 2009-03-11 | 2011-03-30 | 华东理工大学 | 一种丙烯液相一步氧化制环氧丙烷用催化剂及制备方法 |
| JP5756087B2 (ja) | 2009-04-21 | 2015-07-29 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法 |
| US8524927B2 (en) | 2009-07-13 | 2013-09-03 | Velocys, Inc. | Process for making ethylene oxide using microchannel process technology |
| TWI485141B (zh) * | 2009-12-17 | 2015-05-21 | Scient Design Co | 環氧化反應的起動方法 |
| CN102666515B (zh) | 2009-12-23 | 2015-05-20 | 科学设计公司 | 高选择性氧化乙烯催化剂启动的方法 |
| US8742147B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| US8742146B2 (en) * | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| WO2012082389A1 (en) | 2010-12-15 | 2012-06-21 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
| JP6174566B2 (ja) | 2011-04-11 | 2017-08-02 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 高効率エチレンオキシド触媒の調整方法 |
| EP2714670B2 (en) | 2011-04-29 | 2022-03-02 | Shell Internationale Research Maatschappij B.V. | Process for improving the selectivity of an eo catalyst |
| US20130253209A1 (en) * | 2011-09-22 | 2013-09-26 | Shell Oil Company | Process for the start-up of an epoxidation process |
| CN103360346B (zh) * | 2012-04-06 | 2015-02-11 | 中国石油化工股份有限公司 | 一种高选择性银催化剂催化乙烯氧化制环氧乙烷的方法 |
| EP2920159B1 (en) | 2012-12-31 | 2020-02-12 | Scientific Design Company Inc. | Start-up process for high selectivity ethylene oxide catalysts |
| CN105980368B (zh) * | 2013-12-23 | 2019-02-19 | 科学设计有限公司 | 环氧化方法 |
| CA3043504A1 (en) | 2016-12-02 | 2018-06-07 | Shell Internationale Research Maatschappij B.V. | Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide |
| CN113121474A (zh) * | 2019-12-30 | 2021-07-16 | 中国石油化工股份有限公司 | 乙烯环氧化银催化剂的开车方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2219575A (en) * | 1939-06-16 | 1940-10-29 | Carbide & Carbon Chem Corp | Catalyst and process for making olefin oxides |
| FR2412538A1 (fr) * | 1977-12-22 | 1979-07-20 | Ugine Kuhlmann | Catalyseurs a base d'argent pour la production d'oxyde d'ethylene |
| IL84232A (en) * | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
| US4950773A (en) * | 1988-01-28 | 1990-08-21 | Eastman Kodak Company | Selective epoxidation of olefins |
| CN1009437B (zh) * | 1988-02-03 | 1990-09-05 | 中国石油化工总公司 | 乙烯氧化制环氧乙烷高效银催化剂 |
| CA1339317C (en) * | 1988-07-25 | 1997-08-19 | Ann Marie Lauritzen | Process for producing ethylene oxide |
| US4874879A (en) * | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| JP3233652B2 (ja) * | 1991-05-21 | 2001-11-26 | 株式会社日本触媒 | エチレンオキシド製造用銀触媒 |
| US5155242A (en) * | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| WO1995005896A1 (en) * | 1993-08-23 | 1995-03-02 | Shell Internationale Research Maatschappij B.V. | Ethylene oxide catalyst |
| DE69600628T2 (de) * | 1995-02-01 | 1999-02-25 | Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage | Alkylenoxidkatalysator und verfahren |
| US5770746A (en) * | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
| JPH11191963A (ja) * | 1997-12-25 | 1999-07-13 | Fujitsu Ltd | 電源装置 |
| US6372925B1 (en) * | 2000-06-09 | 2002-04-16 | Shell Oil Company | Process for operating the epoxidation of ethylene |
| CN1181118C (zh) * | 2001-12-03 | 2004-12-22 | 蔡晨宁 | 共聚酰亚胺及其合成方法 |
-
2003
- 2003-06-24 BR BRPI0312011-2A patent/BR0312011B1/pt not_active IP Right Cessation
- 2003-06-24 CA CA2490892A patent/CA2490892C/en not_active Expired - Fee Related
- 2003-06-24 EP EP03761993A patent/EP1532125B1/en not_active Revoked
- 2003-06-24 WO PCT/US2003/019828 patent/WO2004002971A1/en not_active Ceased
- 2003-06-24 RU RU2005102014/04A patent/RU2311229C2/ru not_active IP Right Cessation
- 2003-06-24 MX MXPA04012742 patent/MX257124B/es active IP Right Grant
- 2003-06-24 DE DE60304197T patent/DE60304197T2/de not_active Revoked
- 2003-06-24 KR KR1020047021328A patent/KR101098051B1/ko not_active Expired - Fee Related
- 2003-06-24 AU AU2003243758A patent/AU2003243758A1/en not_active Abandoned
- 2003-06-24 JP JP2004517759A patent/JP4624101B2/ja not_active Expired - Fee Related
- 2003-06-24 CN CNB038153122A patent/CN100376561C/zh not_active Expired - Fee Related
- 2003-06-26 TW TW092117447A patent/TWI340743B/zh not_active IP Right Cessation
- 2003-06-26 MY MYPI20032403A patent/MY134316A/en unknown
-
2004
- 2004-12-09 IN IN3915DE2004 patent/IN2004DE03915A/en unknown
-
2010
- 2010-07-23 JP JP2010165897A patent/JP5431262B2/ja not_active Expired - Lifetime
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