JP2006223875A - センターほど速くカバーほど遅い速度勾配を有する多層ゴルフボール - Google Patents
センターほど速くカバーほど遅い速度勾配を有する多層ゴルフボール Download PDFInfo
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- JP2006223875A JP2006223875A JP2006041764A JP2006041764A JP2006223875A JP 2006223875 A JP2006223875 A JP 2006223875A JP 2006041764 A JP2006041764 A JP 2006041764A JP 2006041764 A JP2006041764 A JP 2006041764A JP 2006223875 A JP2006223875 A JP 2006223875A
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Images
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- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/02—Special cores
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0072—Characteristics of the ball as a whole with a specified number of layers
- A63B37/0076—Multi-piece balls, i.e. having two or more intermediate layers
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0077—Physical properties
- A63B37/0078—Coefficient of restitution
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- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
【解決手段】多層ゴルフボール10はセンター11、カバー層15、第1の中間層13、第2の中間層14で構成される。第1のサブアッセンブリはセンタ11であり、第2のサブアッセンブリはセンター11と第2の中間層14の組み合わせであり、以下同様に第3のアッセンブリ、第4のサブアッセンブリとした時に、センタ11、第1の中間層13、第2の中間層14、カバー層15は異なるCORを有し、各アッセンブリのCORはセンタ11側が速くカバー層15側が徐々に遅くなるよう構築される。
【選択図】図1
Description
VC≧VC1≧VC2≧VC3≧VC4≧VC5・・・
CORC≧CORC1−0.003;CORC1≧CORC2−0.003;CORC2≧CORC3−0.003・・・
CORC≧CORC1−0.004;CORC1≧CORC2−0.004;CORC2≧CORC3−0.004
(2)ポリ尿素、例えば、米国特許第5484870号および米国特許出願第10/228311号に開示されているもの。
(3)ウレタンまたは尿素セグメントを含む、ポリウレタン−尿素ハイブリッド、ブレンドまたはコポリマー。
(2) ポリオレフィン、例えばポリエチレン、ポリプロピレン、ポリブチレン及びコポリマー、例えばエチレンメチルアクリレート、エチレンエチルアクリレート、エチレンビニルアセテート、エチレンメタクリル酸又はエチレンアクリル酸又はプロピレンアクリル酸及び単一サイト触媒又はメタローセン触媒を使用して製造したコポリマー及びホモポリマー;
(3) ポリウレタン、例えばポリオールとジイソシアネート又はポリイソシアネートから製造したもの及び米国特許第5,334,673号に開示されているもの;
(4) ポリ尿素、例えば米国特許第5,484,870号に記載されているもの;
(5) ポリアミド、例えばポリ(ヘキサメチレンアジパミド)及びその他のジアミンと二塩基酸から製造したもの、及びアミノ酸、例えばポリ(カプロラクタム)から製造したもの、及びポリアミドとSURLYN、ポリエチレン、エチレンコポリマー、エチル−プロピレン−非共役ジエンターポリマー、及び類似物とのブレンド;
(6) アクリル樹脂及びこれらの樹脂とポリ塩化ビニル、エラストマー、及び類似物とのブレンド;
(7) 熱可塑性物、例えばウレタン;オレフィン系熱可塑性ゴム、例えばポリオレフィンとエチレン−プロピレン−非共役ジエンターポリマーとのブレンド;スチレンとブタジエン、イソプレン又はエチレン−ブチレンゴムのブロックコポリマー;又はコポリ(エーテル−アミド)、例えばフィラデルフィアのエルフ アトケム(ELF Atochem of Philadelphia,PA)が市販するPEBAX;
(8) ポリフェニレンオキシド樹脂又はポリフェニレンオキシドと高耐衝撃性ポリスチレンとのブレンドであってゼネラルエレクトリック社(General Electric Company of Pittsfield,MA)によりNORYLの商標名で市販されているもの;
(9) 熱可塑性ポリエステル、例えばポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンテレフタレート/グリコール変性及びエラストマーであってデュポン社(E.I. DuPont de Neumours & Co. of Wilmington,DE)により商標名HYTRELの名称で、またゼネラルエレクトリック社(General Electric Company of Pittsfield,MA)によりLOMODの名称で市販されているもの;
(10) アクリロニトリルブタジエンスチレン、ポリブチレンテレフタレート、ポリエチレンテレフタレート、スチレン無水マレイン酸、ポリエチレン、エラストマー、及び類似物を有するポリカーボネート、及びアクリロニトリルブタジエンスチレン又はエチレン酢酸ビニル又は他のエラストマーを有するポリ塩化ビニルを含むブレンド及び混合物;及び
(11) 熱可塑性ゴムとポリエチレン、プロピレン、ポリアセタール、ナイロン、ポリエステル、セルロースエステル、及び類似物とのブレンド。
ここで、繰り返し単位の数xは約1〜約70の範囲の値を有する。より好ましくは、繰り返し単位は約5〜約50であり、さらに好ましくは約12〜約35である。
(a)(1)柔軟化モノマーまたは他の手段を添加して結晶性を破壊させた、エチレン、α,β−エチレン系不飽和C3−8カルボン酸コポリマーまたはそのメルトプロセス可能なアイオノマーに、(2)実質的に弾力性を増強させ残存のエチレン結晶性を破壊(好ましくは除去)するにたる非揮発性、非移行性の有機酸を、同時に、または順次にメルトブレンドし、同時にまた順次に、
(b)すべての酸部分(酸コポリマー中の酸部分、および非揮発性、非移行性有機酸が有機酸であればその有機酸中の酸部分を含む)の中和レベルを所望のレベルにするのに十分な量のカチオン源を添加する。
(a)(1)エチレン、α,β−エチレン系不飽和C3−8カルボン酸コポリマーまたはそのメルトプロセス可能なアイオノマー(アイオノマーは処理不能すなわちメルトプロセス不能なレベルまで中和されていない)に、(2)36個未満の炭素原子を有する1または複数の脂肪族、モノ官能性、飽和または不飽和有機酸またはその塩をメルトブレンドし、さらに同時に、または順次に、
(b)すべての酸部分(酸コポリマー中および有機酸中のものを含む)の中和レベルを90%を越え、好ましくは100%近く、より好ましくは100%に増加させるに足る量のカチオン源を添加する。
(a)(1)柔軟化モノマーまたは他の手段を添加して結晶性を破壊させた、エチレン、α,β−エチレン系不飽和C3−8カルボン酸コポリマーまたはそのメルトプロセス可能なアイオノマーに、(2)実質的に残存のエチレン結晶性を除去するにたる非揮発性、非移行性の有機酸を、メルトブレンドし、同時に、または順次に、
(b)すべての酸部分(酸コポリマー中の酸部分、および非揮発性、非移行性有機酸が有機酸であればその有機酸中の酸部分を含む)の中和レベルを90%を越え、好ましくは100%近く、より好ましくは100%のレベルにするのに十分な量のカチオン源を添加する。
B−75%エチレン、14.9%通常のブチルアクリレート、10.1%アクリル酸。
(*)は、カチオンが、樹脂および有機酸中のすべての酸の105%が中和されるに足ることを示す。
100部のポリブタジエンポリマー
5−10部の金属アクリレートまたはメタクリレート架橋剤
5部の密度調製用材料としての酸化亜鉛
2部のフリーラジカル源としてのジクミルペロキサイド
X部の金属粉末フィラー、例えばタングステンまたは他の重い金属である。ただし、Xは、バッチの所望比重に左右される。Xは数、整数および実数である。
C1=センターおよび1の中間層を含むサブアッセンブリ
C2=センターおおび2つの中間層のサブアッセンブリすなわち3層ボール
C3=すべての4つの層を有するボール
Claims (28)
- センター、カバー層およびこれらセンターおよびカバーの間の少なくとも2つの中間層を具備する多層ゴルフボールにおいて、
当該ゴルフボールの各サブアッセンブリの総反発係数の値が、当該サブアッセンブリにつぎの外側の層を加えたものの総反発係数の値より、少なくとも、0.003だけ大きい、
上記サブアッセンブリは少なくともセンターであることを特徴とする多層ゴルフボール。 - 各サブアッセンブリの総反発係数の値が、当該サブアッセンブリにつぎの外側の層を加えたものの総反発係数の値より、少なくとも、0.005だけ大きい請求項1記載の多層ゴルフボール。
- 各サブアッセンブリの総反発係数の値が、当該サブアッセンブリにつぎの外側の層を加えたものの総反発係数の値より、少なくとも、0.010だけ大きい請求項1記載の多層ゴルフボール。
- 上記中間層は8またはそれ未満の数だけある請求項1記載の多層ゴルフボール。
- 上記センターの反発係数の値は少なくとも0.815である請求項1記載の多層ゴルフボール。
- 上記センターの反発係数の値は少なくとも0.825である請求項1記載の多層ゴルフボール。
- 上記センターの反発係数の値は少なくとも0.830である請求項1記載の多層ゴルフボール。
- 上記センターおよび第1の中間層により表されるサブアッセンブリの総反発係数の値は少なくとも0.810である請求項1記載の多層ゴルフボール。
- 上記センターおよび第1の中間層により表されるサブアッセンブリの総反発係数の値は少なくとも0.820である請求項1記載の多層ゴルフボール。
- 上記センターおよび第1の中間層により表されるサブアッセンブリの総反発係数の値は少なくとも0.825である請求項1記載の多層ゴルフボール。
- 上記センター、第1の中間層および第2の中間層により表されるサブアッセンブリの総反発係数の値は少なくとも0.800である請求項1記載の多層ゴルフボール。
- 上記センター、第1の中間層および第2の中間層により表されるサブアッセンブリの総反発係数の値は少なくとも0.810である請求項1記載の多層ゴルフボール。
- 上記センター、第1の中間層および第2の中間層により表されるサブアッセンブリの総反発係数の値は少なくとも0.815である請求項1記載の多層ゴルフボール。
- 1のサブアッセンブリからつぎに大きいサブアッセンブリへの反発係数の変化が、当該つぎに大きいサブアッセンブリの厚さ当たりで、少なくとも1000分の1インチあたり少なくとも0.00015未満である請求項1記載の多層ゴルフボール。
- 反発係数の上記変化が1000分の1インチあたり少なくとも約0.00025である請求項1記載の多層ゴルフボール。
- 反発係数の上記変化が1000分の1インチあたり少なくとも約0.00035である請求項1記載の多層ゴルフボール。
- 上記センターは、ポリマー上の酸基、適切なカチオン源、有機酸またはその塩の間の反応から生成される高度に中和されたポリマーを有し、
上記適切なカチオン源の量は、上記酸基を少なくとも約80%中和するに足るものである請求項1記載の多層ゴルフボール。 - 上記適切なカチオン源の量は、上記酸基を約90%中和するにたるものである請求項17記載の多層ゴルフボール。
- 上記適切なカチオン源の量は、上記酸基を約100%中和するにたるものであり、
上記適切なカチオン源は、マグネシウム、ナトリウム、亜鉛、リチウム、カリウム、およびカルシウムからなるグループから選択され、
上記有機酸またはその塩は、オレイン酸、オレイン酸の塩、ステアリン酸、ステアリン酸の塩、ベヘン酸、ベヘン酸の塩、およびこれらの組み合わせからなるグループから選択される請求項18記載の多層ゴルフボール。 - 上記センターは、ポリブタジエン、シス−トランス変換触媒、フリーラジカル源、架橋剤およびフィラーの反応生成物混合物である請求項1記載の多層ゴルフボール。
- 少なくとも1つの上記中間層は、ポリブタジエン、ポリウレタン、ポリ尿素、高度に中和されたポリマー、シリコーン、ポリオレフィン、ポリアミド、ポリエステル、ポリエーテルアミド、ポリエステルアミド、または、これらのブレンドを有する請求項1記載の多層ゴルフボール。
- 上記カバー層は、ポリウレタン、ポリ尿素、高度に中和されたポリマー、ポリブタジエン、ポリオレフィン、またはこれらのブレンドを含む請求項1記載の多層ゴルフボール。
- センター、カバー層およびこれらセンターおよびカバーの間の1の中間層を具備する多層ゴルフボールにおいて、
当該ゴルフボールの各サブアッセンブリの総反発係数の値が、当該サブアッセンブリにつぎの外側の層を加えたものの総反発係数の値より、少なくとも、0.004だけ大きく、
上記サブアッセンブリは少なくともセンターを有することを特徴とする多層ゴルフボール。 - 各サブアッセンブリの総反発係数の値が、当該サブアッセンブリにつぎの外側の層を加えたものの総反発係数の値より、少なくとも、0.006だけ大きい請求項23記載の多層ゴルフボール。
- 各サブアッセンブリの総反発係数の値が、当該サブアッセンブリにつぎの外側の層を加えたものの総反発係数の値より、少なくとも、0.010だけ大きい請求項24記載の多層ゴルフボール。
- 1のサブアッセンブリからつぎに大きいサブアッセンブリへの反発係数の変化が、当該つぎに大きいサブアッセンブリの厚さ当たりで、少なくとも1000分の1インチあたり少なくとも約0.00015である請求項23記載の多層ゴルフボール。
- 反発係数の上記変化が1000分の1インチあたり少なくとも約0.00025である請求項26記載の多層ゴルフボール。
- 反発係数の上記変化が1000分の1インチあたり少なくとも約0.00035である請求項27記載の多層ゴルフボール。
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EP1950212B1 (en) | 2005-10-27 | 2016-02-24 | Shionogi Co., Ltd. | Polycyclic carbamoylpyridone derivative having inhibitory activity on hiv integrase |
JP2009039233A (ja) * | 2007-08-08 | 2009-02-26 | Sri Sports Ltd | ゴルフボール |
JP2009039230A (ja) * | 2007-08-08 | 2009-02-26 | Sri Sports Ltd | ゴルフボール |
US8282507B2 (en) | 2007-08-08 | 2012-10-09 | Sri Sports Limited | Golf ball |
US8672774B2 (en) | 2007-08-08 | 2014-03-18 | Sri Sports Limited | Golf ball |
JP2011502578A (ja) * | 2007-11-01 | 2011-01-27 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 高度中和エチレンコポリマーおよび有機酸から製造されたコアまたは中間層を有するゴルフボール |
JP2011005257A (ja) * | 2009-06-29 | 2011-01-13 | Acushnet Co | 多層ゴルフボール |
JP2012011171A (ja) * | 2010-06-30 | 2012-01-19 | Nike Internatl Ltd | 架橋結合熱可塑性ポリウレタンを含むゴルフボール |
JP2016000358A (ja) * | 2010-08-20 | 2016-01-07 | ナイキ イノヴェイト シーヴィー | 指定の曲げ弾性率及び硬度を持つ複数層を有するゴルフボール |
US8858366B2 (en) | 2010-08-20 | 2014-10-14 | Nike, Inc. | Golf ball having layers with specified moduli and hardnesses |
JP2012040382A (ja) * | 2010-08-20 | 2012-03-01 | Nike Internatl Ltd | 指定の曲げ弾性率及び硬度を持つ複数層を有するゴルフボール。 |
JP2014523791A (ja) * | 2011-07-28 | 2014-09-18 | ナイキ インターナショナル リミテッド | 高度に中和された酸ポリマーのブレンドを含むゴルフボールおよび製造方法 |
JP2014524267A (ja) * | 2011-07-29 | 2014-09-22 | ナイキ インターナショナル リミテッド | 高度に中和された酸ポリマーのブレンドを含むゴルフボールを製造する方法 |
WO2015029761A1 (ja) * | 2013-09-02 | 2015-03-05 | 株式会社ポリテック・デザイン | 中空体およびその製造方法 |
JP2017113308A (ja) * | 2015-12-24 | 2017-06-29 | 株式会社ブリヂストン | ゴルフボール |
JP2020103602A (ja) * | 2018-12-27 | 2020-07-09 | ブリヂストンスポーツ株式会社 | ゴルフボール |
JP7225798B2 (ja) | 2018-12-27 | 2023-02-21 | ブリヂストンスポーツ株式会社 | ゴルフボール |
Also Published As
Publication number | Publication date |
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US20080171617A1 (en) | 2008-07-17 |
US7530908B2 (en) | 2009-05-12 |
US7300364B2 (en) | 2007-11-27 |
US7635312B2 (en) | 2009-12-22 |
JP5025139B2 (ja) | 2012-09-12 |
US20060189413A1 (en) | 2006-08-24 |
US20090186719A1 (en) | 2009-07-23 |
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